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1. 发明申请

US20110201841A1 OXIDATIVE MONO-HALOGENATION OF METHANE 有权
标题翻译：氧化甲烷的单氧化反应
公开(公告)号：US20110201841A1
公开(公告)日：2011-08-18
申请号：US13123908
申请日：2009-08-19
申请人： Robert G. Bowman , Eric E. Stangland , Mark E. Jones , Dean M. Millar , Simon G. Podkolzin , Brien A. Stears , Richard M. Wehmeyer
发明人： Robert G. Bowman , Eric E. Stangland , Mark E. Jones , Dean M. Millar , Simon G. Podkolzin , Brien A. Stears , Richard M. Wehmeyer
IPC分类号： C07C51/14 , C07C17/013
CPC分类号： C07C17/154 , C07C19/03
摘要： Oxidatively halogenate methane by placing a feedstream that comprises methane, a source of halogen, a source of oxygen and, optionally, a source of diluent gas in contact with a first catalyst (e.g. a solid super acid or a solid super base) that has greater selectivity to methyl halide and carbon monoxide than to methylene halide, trihalomethane or carbon tetrahalide. Improve overall selectivity to methyl halide by using a second catalyst that converts at least part of the feedstream to a mixture of methyl halide, methylene halide, trihalomethane, carbon tetrahalide and unreacted oxygen, and placing that mixture in contact with the first catalyst which converts at least a portion of the methylene halide, trihalomethane and carbon tetrahalide to carbon monoxide, hydrogen halide and water.
摘要翻译：通过放置包含甲烷，卤素源，氧源和任选的稀释气体源的进料流，将第一催化剂（例如固体超强酸或固体超级碱）接触，从而氧化卤化甲烷，所述第一催化剂对甲基卤和一氧化碳的选择性高于二氯甲烷，三卤甲烷或四卤化碳。通过使用将至少部分进料流转化为甲基卤化物，二卤甲烷，三卤代甲烷，四卤化碳和未反应的氧的混合物的第二催化剂来提高对甲基卤的总体选择性，并将该混合物与第一种催化剂接触，二卤甲烷，三卤代甲烷和四卤化碳中的至少一部分与一氧化碳，卤化氢和水反应。

2. 发明授权

US08674149B2 Oxidative mono-halogenation of methane 有权
标题翻译：甲烷的氧化单卤化
公开(公告)号：US08674149B2
公开(公告)日：2014-03-18
申请号：US13123908
申请日：2009-08-19
申请人： Robert G. Bowman , Eric E. Stangland , Mark E. Jones , Dean M. Millar , Simon G. Podkolzin , Brien A. Stears , Richard M. Wehmeyer
发明人： Robert G. Bowman , Eric E. Stangland , Mark E. Jones , Dean M. Millar , Simon G. Podkolzin , Brien A. Stears , Richard M. Wehmeyer
IPC分类号： C07C17/154 , C07C19/03
CPC分类号： C07C17/154 , C07C19/03
摘要： Oxidatively halogenate methane by placing a feedstream that comprises methane, a source of halogen, a source of oxygen and, optionally, a source of diluent gas in contact with a first catalyst (e.g. a solid super acid or a solid super base) that has greater selectivity to methyl halide and carbon monoxide than to methylene halide, trihalomethane or carbon tetrahalide. Improve overall selectivity to methyl halide by using a second catalyst that converts at least part of the feedstream to a mixture of methyl halide, methylene halide, trihalomethane, carbon tetrahalide and unreacted oxygen, and placing that mixture in contact with the first catalyst which converts at least a portion of the methylene halide, trihalomethane and carbon tetrahalide to carbon monoxide, hydrogen halide and water.
摘要翻译：通过放置包含甲烷，卤素源，氧源和任选的稀释气体源的进料流，将第一催化剂（例如固体超强酸或固体超级碱）接触，从而氧化卤化甲烷，所述第一催化剂对甲基卤和一氧化碳的选择性高于二氯甲烷，三卤甲烷或四卤化碳。通过使用将至少部分进料流转化为甲基卤化物，二卤甲烷，三卤代甲烷，四卤化碳和未反应的氧的混合物的第二催化剂来提高对甲基卤的总体选择性，并将该混合物与第一种催化剂接触，二卤甲烷，三卤代甲烷和四卤化碳中的至少一部分与一氧化碳，卤化氢和水反应。

3. 发明申请

US20130079576A1 CONVERSION OF METHYLAMINE TO OLEFIN OR MIXTURE OF OLEFINS 失效
标题翻译：甲胺转化为烯烃或烯烃的混合物
公开(公告)号：US20130079576A1
公开(公告)日：2013-03-28
申请号：US13639940
申请日：2011-05-31
申请人： Robert G. Bowman , Eric E. Stangland , Rainer Bruening , Angelika Heilmann , Roland Wagner , Jason Lee Bronkema
发明人： Robert G. Bowman , Eric E. Stangland , Rainer Bruening , Angelika Heilmann , Roland Wagner , Jason Lee Bronkema
IPC分类号： C07C1/32
CPC分类号： C07C1/323 , B01J29/08 , B01J29/18 , B01J29/40 , B01J29/50 , B01J29/65 , B01J29/85 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/50 , C07C2529/66 , C07C2529/85 , Y02P20/52 , C07C11/02 , C07C11/06 , C07C11/04
摘要： Convert a methylamine (e.g. monomethylamine, dimethylamine and trimethylamine) to a mixture of olefins (e.g. ethylene, propylene and butylene) by placing the methylamine, optionally in a mixture with at least one of ammonia and an inert diluent, in contact with a microporous acidic silicoaluminophosphate catalyst or a microporous aluminosilicate catalyst.
摘要翻译：将甲胺（例如一甲胺，二甲胺和三甲胺）转化为烯烃（如乙烯，丙烯和丁烯）的混合物，将甲胺，任选地与氨和惰性稀释剂中的至少一种的混合物与微孔酸硅铝磷酸盐催化剂或微孔硅铝酸盐催化剂。

4. 发明授权

US08697930B2 Conversion of methylamine to olefin or mixture of olefins 失效
标题翻译：甲胺转化为烯烃或烯烃混合物
公开(公告)号：US08697930B2
公开(公告)日：2014-04-15
申请号：US13639940
申请日：2011-05-31
申请人： Robert G. Bowman , Eric E. Stangland , Rainer Bruening , Angelika Heilmann , Roland Wagner , Jason Lee Bronkema
发明人： Robert G. Bowman , Eric E. Stangland , Rainer Bruening , Angelika Heilmann , Roland Wagner , Jason Lee Bronkema
IPC分类号： C07C211/03
CPC分类号： C07C1/323 , B01J29/08 , B01J29/18 , B01J29/40 , B01J29/50 , B01J29/65 , B01J29/85 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/50 , C07C2529/66 , C07C2529/85 , Y02P20/52 , C07C11/02 , C07C11/06 , C07C11/04
摘要： Convert a methylamine (e.g. monomethylamine, dimethylamine and trimethylamine) to a mixture of olefins (e.g. ethylene, propylene and butylene) by placing the methylamine, optionally in a mixture with at least one of ammonia and an inert diluent, in contact with a microporous acidic silicoaluminophosphate catalyst or a microporous aluminosilicate catalyst.
摘要翻译：将甲胺（例如一甲胺，二甲胺和三甲胺）转化为烯烃（如乙烯，丙烯和丁烯）的混合物，将甲胺，任选地与氨和惰性稀释剂中的至少一种的混合物与微孔酸硅铝磷酸盐催化剂或微孔硅铝酸盐催化剂。

5. 发明申请

US20100310719A1 Manufacture of seed derivative compositions 有权
标题翻译：种子衍生物组合物的制造
公开(公告)号：US20100310719A1
公开(公告)日：2010-12-09
申请号：US12802337
申请日：2010-06-04
申请人： John M. Finney , Christoper J. Rueb , William A. Hendrickson , Daniel R. Roesler , Robert G. Bowman , David A. Canfield
发明人： John M. Finney , Christoper J. Rueb , William A. Hendrickson , Daniel R. Roesler , Robert G. Bowman , David A. Canfield
IPC分类号： A23L1/36
CPC分类号： A23L1/366 , A21D2/266 , A23L25/30 , A23L29/238
摘要： A method is used to separate fractions from a seed. This can be done by: a) Physically breaking down the Chia seed into smaller particles; b) Adding a liquid carrier to the broken Chia seed to form a Chia liquid carrier blend; c) Optionally providing further processing of the Chia liquid carrier blend to further reduce the particle size of the Chia particles d) Optionally centrifuging the Chia liquid carrier blend; e) Optionally forming at least three discernible layers of materials within the centrifuged Chia liquid carrier blend; f) Optionally separating the composition of at least one layer from remaining layers; and g) Optionally combining the separated layers together into a desired combination/ratios h) Drying the separated layers or combined layers into a flowable powder.
摘要翻译：一种方法用于从种子中分离级分。这可以通过以下方式完成：a）将Chia种子物理分解成更小的颗粒; b）将液体载体添加到破碎的Chia种子中以形成Chia液体载体共混物; c）任选地提供Chia液体载体共混物的进一步处理以进一步降低Chia颗粒的粒度d）任选地将Chia液体载体共混物离心; e）任选地在离心的Chia液体载体共混物内形成至少三个可辨别的材料层; f）任选地将至少一层的组合物与剩余的层分离; 和g）任选地将分离的层组合成所需的组合/比例h）将分离的层或组合层干燥成可流动的粉末。

6. 发明申请

US20100076208A1 HYDRO-OXIDATION PROCESS USING A CATALYST PREPARED FROM A GOLD CLUSTER COMPLEX 失效
标题翻译：使用从金色复合物制备的催化剂的氢氧化工艺
公开(公告)号：US20100076208A1
公开(公告)日：2010-03-25
申请号：US12445547
申请日：2007-11-07
申请人： Sandeep S. Dhingra , Rick C. Schroden , Keith J. Watson , David G. Barton , Robert G. Bowman , Larry N. Ito , David L. Trent , Heiko Weiner
发明人： Sandeep S. Dhingra , Rick C. Schroden , Keith J. Watson , David G. Barton , Robert G. Bowman , Larry N. Ito , David L. Trent , Heiko Weiner
IPC分类号： C07D301/04 , B01J23/52 , B01J23/50 , B01J23/66 , C07D301/06
CPC分类号： B01J31/2404 , B01J23/52 , B01J23/66 , B01J29/89 , B01J31/1691 , B01J35/0013 , B01J37/0203 , B01J2229/186 , B01J2231/325 , B01J2231/72 , B01J2531/18 , B01J2531/62 , B01J2531/842 , C07D301/10 , Y02P20/52 , Y02P20/588
摘要： A process and catalyst for the hydro-oxidation of an olefin having three or more carbon atoms, such as propylene, to form an olefin oxide, such as propylene oxide. The process involves contacting the olefin with oxygen in the presence of hydrogen and a hydro-oxidation catalyst under reaction conditions; the catalyst comprising gold nanoparticles deposited on a nanoporous titanium-containing support, prepared by depositing a gold-ligand cluster complex onto the support to form a catalyst precursor, and then heating and/or chemically treating the catalyst precursor to form the hydro-oxidation catalyst composition. The hydro-oxidation catalyst exhibits stabilized catalyst activity, enhanced lifetime, and improved hydrogen efficiency.
摘要翻译：用于将具有三个或更多个碳原子的烯烃如丙烯进行加氢氧化的方法和催化剂，以形成环氧丙烷等烯烃氧化物。该方法包括在氢气和氢氧化催化剂存在下，在反应条件下使烯烃与氧接触; 催化剂包含沉积在纳米多孔含钛载体上的金纳米颗粒，其通过在载体上沉积金 - 配体簇复合物以形成催化剂前体，然后加热和/或化学处理催化剂前体以形成加氢氧化催化剂组成。氢氧化催化剂表现出稳定的催化剂活性，寿命延长，氢效率提高。

7. 发明授权

US5965754A Process for the direct oxidation of olefins to olefin oxides 有权
标题翻译：将烯烃直接氧化成烯烃氧化物的方法
公开(公告)号：US5965754A
公开(公告)日：1999-10-12
申请号：US209699
申请日：1998-12-11
申请人： Howard W. Clark , Robert G. Bowman , Joseph J. Maj , Simon R. Bare , George E. Hartwell
发明人： Howard W. Clark , Robert G. Bowman , Joseph J. Maj , Simon R. Bare , George E. Hartwell
IPC分类号： B01J23/66 , B01J23/50 , B01J23/52 , B01J23/96 , B01J29/89 , C07D301/04 , C07D301/06 , C07D301/10 , C07D303/04 , B01J21/08
CPC分类号： B01J23/50 , B01J23/52 , B01J23/66 , B01J29/89 , C07D301/04 , C07D301/10 , Y02P20/52 , Y02P20/584 , Y02P20/588
摘要： A process and catalyst for the direct oxidation of an olefin having three or more carbon atoms, such as propylene, by oxygen to an olefin oxide, such as propylene oxide. The process involves contacting the olefin with oxygen under reaction conditions in the presence of hydrogen and a catalyst. The catalyst comprises gold on a support of titanium dispersed on silica. The titanium phase is disorganized and substantially free of crystalline titanium dioxide, as determined by analytical methods, such as, high resolution transmission electron microscopy and Raman spectroscopy. Selectivity to olefin oxide is high at good conversions of the olefin. The time between catalyst regenerations is long, and the catalyst is readily regenerated.
摘要翻译：用于将具有三个或更多个碳原子的烯烃（例如丙烯）通过氧气直接氧化成烯烃氧化物如环氧丙烷的方法和催化剂。该方法包括在氢气和催化剂存在下，在反应条件下使烯烃与氧接触。该催化剂包含分散在二氧化硅上的钛的载体上的金。通过分析方法如高分辨率透射电子显微镜和拉曼光谱测定，钛相是无组织的并且基本上不含结晶二氧化钛。烯烃氧化物的选择性高，烯烃转化率高。催化剂再生之间的时间长，催化剂容易再生。

8. 发明授权

US5380041A Protective boot for heel ends of skis 失效
标题翻译：滑雪板脚跟端的防护靴
公开(公告)号：US5380041A
公开(公告)日：1995-01-10
申请号：US132537
申请日：1993-10-06
申请人： Robert G. Bowman
发明人： Robert G. Bowman
IPC分类号： A63C11/02
CPC分类号： A63C11/027 , A63C11/02
摘要： A boot for protecting heel ends of a pair of skis includes a pocket-shaped body having a pair of side walls, a pair of end walls extending between and interconnecting the side walls and a bottom wall extending between and connecting the lower ends of the side walls and end walls. The side, end and bottom walls together forming a cavity open at a top end for receiving the heel ends of a pair of skis. The bottom wall is of greater thickness than the side and end walls. The pocket-shaped body is made of a material sufficiently flexible and resilient to removably fit over the heel ends of the skis and to grip the surfaces thereon. A plurality of raised ribs are formed on the exterior of lower end portions of the side walls of the pocket-shaped body for gripping by the user to pull the body off from the heel ends of the skis. A plurality of protuberances are spaced apart and formed on and protrude outwardly from the exterior of the bottom wall for absorbing shock to, and providing traction at, the heel ends of the skis when received in the pocket-shaped body.
摘要翻译：用于保护一对滑雪板的脚跟端部的靴子包括具有一对侧壁的一个袋状体，在侧壁之间延伸并在其之间互连的一对端壁和在该侧壁之间延伸并连接该侧壁的下端的底壁墙壁和墙壁。侧壁，端壁和底壁一起形成在顶端开口的腔，用于接收一对滑雪板的脚跟端部。底壁的厚度大于侧壁和端壁。口袋形主体由足够弹性和弹性的材料制成，以可拆卸地装配在滑雪板的脚跟端部上并且夹紧其上的表面。在袋状体的侧壁的下端部的外侧上形成有多个凸肋，用于由使用者握持以从滑雪板的后端拉出身体。多个突起间隔开并形成在底壁的外部上并从底壁的外部向外突出，用于当容纳在口袋形主体中时吸收滑雪板的脚跟端部的冲击并提供牵引力。

9. 发明授权

US5166442A Catalytic reforming of alkyleneamines 失效
标题翻译：亚烷基胺的催化重整
公开(公告)号：US5166442A
公开(公告)日：1992-11-24
申请号：US730415
申请日：1991-07-16
申请人： George E. Hartwell , Robert G. Bowman , David C. Molzahn
发明人： George E. Hartwell , Robert G. Bowman , David C. Molzahn
IPC分类号： C07C209/64
CPC分类号： C07C209/64
摘要： A process of reforming an alkyleneamine feedstock or a mixture of such feedstocks to an alkyleneamine or a mixture of alkyleneamines which is different from the feedstock or feedstock mixture. The process is catalyzed by one of the following: Group VB metal oxides, Group VB metal phosphates, Group IIA metal silicates, and tungsten oxides. For example, ethylenediamine is contacted with a catalyst of niobic acid or magnesium silicate to yield predominantly diethylenetriamine and non-cyclic triethylenetetramines; whereas high molecular weight polyethylenepolyamines are cracked by the same catalysts to mixtures of lower molecular weight linear and cyclic materials.
摘要翻译：将亚烷基胺原料或这些原料的混合物重整成不同于原料或原料混合物的亚烷基胺或亚烷基胺的混合物的方法。该方法由以下之一催化：VB族金属氧化物，VB族金属磷酸盐，IIA族金属硅酸盐和钨氧化物。例如，乙二胺与铌酸或硅酸镁的催化剂接触，主要产生二亚乙基三胺和非环状三亚乙基四胺; 而高分子量聚亚乙基多胺通过相同的催化剂裂解成低分子量线性和环状材料的混合物。

10. 发明授权

US4996363A Catalytic reforming of alkyleneamines to linearly-extended polyalkylenepolyamines 失效
标题翻译：将亚烷基胺催化重整成线性延伸的聚亚烷基多胺
公开(公告)号：US4996363A
公开(公告)日：1991-02-26
申请号：US287189
申请日：1988-12-20
申请人： Robert G. Bowman , David C. Molzahn , George E. Hartwell
发明人： Robert G. Bowman , David C. Molzahn , George E. Hartwell
IPC分类号： B01J21/16 , B01J23/20 , B01J23/30 , B01J27/186 , B01J27/195 , B01J27/24 , C07B61/00 , C07C209/60 , C07C209/64 , C07C211/14 , C07C213/00 , C07C217/08 , C08G73/02
CPC分类号： C07C209/64
摘要： A process for reforming alkyleneamines to predominantly linearly-extended polyalkylenepolyamines comprising contacting an alkyleneamine or mixture thereof with a catalyst under conditions such that a mixture of polyalkylenepolyamines enriched in linearly-extended products is formed, said catalyst containing at least one compound selected from the group consisting of (a) Group VB metal oxides, (b) Group VB metal phosphates, (c) silicates of Groups IIA, IIIB, IVB, VB, and the lanthanide and actinide metals, and (d) tungsten oxides, with the proviso that the silicates and tungsten oxides are essentially free of aluminum. For example, ethylenediamine is contacted with a catalyst of niobium phosphate or niobic acid under reaction conditions to yield predominantly non-cyclic polyethylenepolyamines.

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