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1. 发明授权

US5865936A Rapid curing structural acrylic adhesive 失效
标题翻译：快速固化结构丙烯酸粘合剂
公开(公告)号：US5865936A
公开(公告)日：1999-02-02
申请号：US828447
申请日：1997-03-28
申请人： Robert Edelman , William J. Catena
发明人： Robert Edelman , William J. Catena
IPC分类号： C08F4/40 , C08F4/26 , C08F220/18 , C08F220/20 , C09J4/00 , C09J4/02 , C09J133/08 , C09J133/10 , C09J133/14 , C09J133/06 , B32B7/12 , C08F220/28 , C08F222/02
CPC分类号： C09J4/00
摘要： A two part structural acrylic adhesive contains as a first part a mixture of acrylate or methacrylate monomers or oligomers, maleic acid, a hydroperoxide, and a source of ferric ions, and as a second activator part a substituted dihydropyridine. The adhesive is fast-curing and stable.
摘要翻译：两部分结构丙烯酸粘合剂作为第一部分含有丙烯酸酯或甲基丙烯酸酯单体或低聚物，马来酸，氢过氧化物和铁离子源的混合物，并且作为第二活化剂部分含有取代的二氢吡啶。粘合剂快速固化和稳定。

2. 发明授权

US4054480A Anaerobic adhesive and sealant compositions containing alpha-hydroxysulfone 失效
标题翻译：含有α-羟基砜的厌氧胶和密封剂组合物
公开(公告)号：US4054480A
公开(公告)日：1977-10-18
申请号：US579782
申请日：1975-05-22
申请人： Martin M. Skoultchi , Dilip K. Ray-Chaudhuri , William J. Catena
发明人： Martin M. Skoultchi , Dilip K. Ray-Chaudhuri , William J. Catena
IPC分类号： C08F20/00 , C08F20/10 , C08F290/00 , C08F299/00 , C09J4/00 , C09J4/02 , C09J5/04 , C08F2/00 , C08F3/62 , C08F18/00
CPC分类号： C09J4/00
摘要： Anaerobic curing compositions useful as anaerobic adhesives and sealants are described. These compositions comprise mixtures of polymerizable acrylic and substituted acrylic monomers together with a catalyst comprising an alpha-hydroxy sulfone compound. As an alternate embodiment of the invention, certain organic peroxides may be added to the composition to further prolong the shelf life thereof and to increase the shear strength of the resulting adhesive bond.
摘要翻译：描述了用作厌氧粘合剂和密封剂的厌氧固化组合物。这些组合物包括可聚合的丙烯酸和取代的丙烯酸单体与包含α-羟基砜化合物的催化剂的混合物。作为本发明的替代实施方案，可以将某些有机过氧化物加入到组合物中以进一步延长其保质期并提高所得粘合剂粘合的剪切强度。

3. 发明授权

US4235986A Anaerobic curing adhesive composition and process for making same 失效
标题翻译：厌氧固化胶粘剂组合物及其制备方法
公开(公告)号：US4235986A
公开(公告)日：1980-11-25
申请号：US26091
申请日：1979-04-02
申请人： William J. Catena
发明人： William J. Catena
IPC分类号： C09J4/02 , C09J4/00 , C08F20/20
CPC分类号： C09J4/00
摘要： Storage-stable anaerobic curing adhesive compositions useful as anaerobic adhesives and sealants are prepared by first mixing a polymerizable acrylate ester monomer, an inhibitor for free radical polymerization, a chelator, and at least an effective amount of an accelerator system consisting of an organic cyclic sulfimide, preferably saccharin, and an aromatic tertiary amine. The resultant homogeneous mixture is thereafter heated at a temperature of about 45.degree.-100.degree. C. for a period of time sufficient to provide the composition with anaerobic curing properties and a specified minimum amount of active oxygen. In one embodiment, the mixture is stirred at a temperature of 45.degree.-70.degree. C. for 10-24 hours. In another embodiment, the mixture is maintained at an elevated temperature without stirring.
摘要翻译：可用作厌氧粘合剂和密封剂的储存稳定的厌氧固化粘合剂组合物通过首先混合可聚合的丙烯酸酯单体，用于自由基聚合的抑制剂，螯合剂和至少有效量的由有机环状酰亚胺，优选糖精和芳族叔胺。然后将得到的均匀混合物在约45℃-100℃的温度下加热足以使组合物具有厌氧固化性能和规定的最小量的活性氧的时间。在一个实施方案中，将混合物在45-70℃的温度下搅拌10-24小时。在另一个实施方案中，将混合物保持在升高的温度下而不搅拌。

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