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    • 6. 发明授权
    • Methods and compositions for reducing the viscosity of treatment fluids
    • 降低处理液粘度的方法和组合物
    • US07082995B2
    • 2006-08-01
    • US10794607
    • 2004-03-05
    • Robert E. Hanes, Jr.Jimmie D. WeaverBilly F. Slabaugh
    • Robert E. Hanes, Jr.Jimmie D. WeaverBilly F. Slabaugh
    • E21B43/26E21B43/04
    • C09K8/68C09K8/06
    • Methods of reducing the viscosity of a viscosified treatment fluid are provided which comprise the steps of: providing a viscosified treatment fluid that comprises water, a crosslinked gelling agent, and a delinking composition capable of delinking at least a portion of the crosslinked gelling agent wherein the delinking composition comprises a delinking agent; and allowing the crosslinked gelling agent and the delinking composition to interact so as to delink at least a portion of the crosslinked gelling agent. Also provided are methods of reusing viscosified treatment fluids, methods of fracturing subterranean formations, and methods of gravel packing subterranean formations. Also provided are delinking compositions capable of delinking at lest a portion of a crosslinked gelling agent; and a viscosified treatment fluid comprising water, a crosslinked gelling agent, and a delinking composition capable of delinking at least a portion of the crosslinked gelling agent wherein the delinking composition comprises a delinking agent.
    • 提供了降低稠化处理流体粘度的方法,其包括以下步骤:提供包含水,交联胶凝剂和能够使交联胶凝剂的至少一部分脱胶的脱胶组合物的增稠处理流体,其中 脱胶组合物包含脱胶剂; 并且允许交联的胶凝剂和脱胶组合物相互作用以使至少一部分交联的胶凝剂脱胶。 还提供了使用稠化处理流体的方法,压裂地下地层的方法,以及砾石堆积地下地层的方法。 还提供了能够以至少一部分交联的胶凝剂脱胶的脱胶组合物; 以及包含水,交联胶凝剂和能够使交联胶凝剂的至少一部分脱胶的脱胶组合物的增稠处理流体,其中脱胶组合物包含脱胶剂。
    • 7. 发明授权
    • Methods and compositions for enhancing guar hydration rates and performing guar derivitization reactions
    • 提高瓜尔胶水合速率和进行瓜尔胶衍生反应的方法和组合物
    • US07637322B2
    • 2009-12-29
    • US11035305
    • 2005-01-13
    • Billy F. SlabaughRobert E. Hanes, Jr.Jimmie D. Weaver
    • Billy F. SlabaughRobert E. Hanes, Jr.Jimmie D. Weaver
    • E21B43/26
    • C08B37/0096C09K8/68C09K8/90
    • One embodiment of the present invention provides a method of treating guar splits comprising exposing guar splits to a treatment chemical to create treated guar splits; and then, without first washing the treated guar splits, grinding the treated guar splits; and, then drying the ground, treated guar splits. Another embodiment of the present invention provides a method of treating a portion of a subterranean formation comprising providing a treatment fluid comprising a viscosifying agent wherein the viscosifying agent comprises ground, treated guar splits made by the following method: exposing guar splits to a treatment chemical to create treated guar splits; and then, without first washing the treated guar splits, grinding the treated guar splits; and, then drying the ground, treated guar splits; placing the treatment fluid into a portion of a subterranean formation.
    • 本发明的一个实施方案提供了一种治疗瓜尔胶裂片的方法,包括将瓜尔胶裂片暴露于处理化学品以产生经处理的瓜尔胶; 然后,没有首先洗涤经处理的瓜尔胶,研磨经处理的瓜尔胶; 然后干燥地面,处理瓜尔胶。 本发明的另一个实施方案提供了一种处理地下地层的一部分的方法,其包括提供包含增粘剂的处理流体,其中所述增粘剂包括研磨,通过以下方法制备的处理过的瓜尔分裂:将瓜尔胶裂化至处理化学品 创造经治疗的瓜尔胶; 然后,没有首先洗涤经处理的瓜尔胶,研磨经处理的瓜尔胶; 然后干燥地面,处理瓜尔胶; 将处理流体放置到地下地层的一部分中。
    • 8. 发明授权
    • Boronic acid networking agents and associated methods
    • 硼酸网络代理及相关方法
    • US07687441B2
    • 2010-03-30
    • US10972642
    • 2004-10-25
    • Robert E. Hanes, Jr.Jimmie D. WeaverBilly F. Slabaugh
    • Robert E. Hanes, Jr.Jimmie D. WeaverBilly F. Slabaugh
    • C09K8/588C09K8/68
    • C08K5/55C09K8/62C09K8/66
    • In one embodiment, the present invention provides a method of increasing the viscosity of a treatment fluid comprising the steps of: adding a networking agent to the treatment fluid, wherein the networking agent is represented by the formula: Y—X—[B(OR)2]n, wherein: Y is at least partially capable of forming a crosslink between a gelling agent molecule, a second networking agent, and/or a combination thereof; X is at least partially capable of preventing or inhibiting a reaction represented by the formula: ROH+R′B(OR)2→R′OH+B(OR)3; R and R′ are a hydrogen, an alkyl group, an aryl group, or a combination thereof; and n is a positive integer greater than or equal to 1; allowing at least one crosslink to form between the networking agent and a gelling agent molecule, a second networking agent, and/or a combination thereof; and allowing the viscosity of the treatment fluid to increase. Methods of treating a portion of a subterranean formation, networking agent compositions, and treatment fluid compositions also are provided.
    • 在一个实施方案中,本发明提供了一种提高处理流体粘度的方法,包括以下步骤:向处理流体中加入组合试剂,其中组合试剂由下式表示:Y-X- [B )2] n,其中:Y至少部分地能够在胶凝剂分子,第二组合剂和/或其组合之间形成交联; X至少部分能够防止或抑制下式表示的反应:ROH + R'B(OR)2→R'OH + B(OR)3; R和R'是氢,烷基,芳基或其组合; 并且n是大于或等于1的正整数; 允许至少一个交联在所述组合试剂和凝胶剂分子,第二组合试剂和/或其组合之间形成; 并使处理液的粘度增加。 还提供了处理地下地层,网络剂组合物和处理液组合物的一部分的方法。