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1. 发明授权

US3974241A Blends of sulfonated elastomers with crystalline polyolefins 失效
标题翻译：磺化弹性体与结晶聚烯烃的共混物
公开(公告)号：US3974241A
公开(公告)日：1976-08-10
申请号：US524512
申请日：1974-11-18
申请人： Robert D. Lundberg , Robert R. Phillips , Lowell Westerman , Jan Bock
发明人： Robert D. Lundberg , Robert R. Phillips , Lowell Westerman , Jan Bock
IPC分类号： C08L23/32 , C08L23/16 , C08L23/06 , C08L23/12
CPC分类号： C08L23/32
摘要： This invention relates to blends of sulfonated elastomers with crystalline polyolefins. The sulfonated elastomer comprises from about 0.2 to about 20 mole percent sulfonate groups, at least 95% of which are combined with metal counter ions selected from the group consisting of Groups I and II of the Periodic Table of the Elements, aluminum, and lead; organic amines; and mixtures thereof. The crystalline polyolefin is preferably selected from the group consisting of polyethylene, including high and low density polyethylenes, and polypropylene. The crystalline polyolefin comprises a minor portion of said blends.
摘要翻译：本发明涉及磺化弹性体与结晶聚烯烃的共混物。磺化弹性体包含约0.2至约20摩尔％的磺酸盐基团，其中至少95％与选自元素周期表第I和II族的金属抗衡离子，铝和铅组合; 有机胺; 及其混合物。结晶聚烯烃优选选自包括高密度和低密度聚乙烯的聚乙烯和聚丙烯。结晶聚烯烃包含少部分所述共混物。

2. 发明授权

US3974240A Thermoplastic elastomer compositions 失效
标题翻译：热塑性弹性体组合物
公开(公告)号：US3974240A
公开(公告)日：1976-08-10
申请号：US524502
申请日：1974-11-18
申请人： Jan Bock , Robert D. Lundberg , Robert R. Phillips , Henry S. Makowski
发明人： Jan Bock , Robert D. Lundberg , Robert R. Phillips , Henry S. Makowski
IPC分类号： C08L23/32 , C08L23/16 , C08L23/06 , C08L23/12
CPC分类号： C08L23/32
摘要： This invention relates to processable ionic elastomer compositions having improved compression set properties, especially at elevated temperatures. In this invention an intractable ionic elastomer, for example, a sulfonated elastomer is blended with from 10 to 70 parts per hundred of a crystalline polyolefin to yield novel compositions having the above properties. Preferably the ionic elastomer is a sulfonated ethylene propylene terpolymer having from about 0.2 to 20 mole percent sulfonate groups, at least 95% of which are combined with counterions selected from the group consisting of Groups IA, IIA, IB, and IIB of the Periodic Table of Elements, aluminum, antimony, lead, and mixtures thereof. The sulfonated polymer is combined with said counterions by neutralization of a polysulfonic acid precurser with a basic material in which the desired counterion is present as the cation thereof. The anion of said basic material is preferably selected from the group consisting of oxide, hydroxide, and lower alkanoates, for example, acetate, formate, and propionate.
摘要翻译：本发明涉及具有改进的压缩变形特性的可加工的离子弹性体组合物，特别是在高温下。在本发明中，难溶性离子弹性体，例如磺化弹性体与每100份结晶聚烯烃共混10至70份，得到具有上述性能的新型组合物。优选地，离子弹性体是具有约0.2至20摩尔％磺酸盐基团的磺化乙烯丙烯三元共聚物，其至少95％与选自元素周期表IA，IIA，IB和IIB族的抗衡离子组合元素，铝，锑，铅及其混合物。将磺化聚合物与所述抗衡离子组合，通过用其中存在所需抗衡离子作为其阳离子的碱性材料中和多磺酸前体。所述碱性物质的阴离子优选选自氧化物，氢氧化物和低级链烷酸酯，例如乙酸盐，甲酸盐和丙酸盐。

3. 发明授权

US4220573A Novel ionic polymer compositions 失效
标题翻译：新型离子聚合物组合物
公开(公告)号：US4220573A
公开(公告)日：1980-09-02
申请号：US2787
申请日：1979-01-11
申请人： Jan Bock , Neville G. Thame , Lowell Westerman
发明人： Jan Bock , Neville G. Thame , Lowell Westerman
IPC分类号： C08K5/09 , C08L91/00
CPC分类号： C08K5/09
摘要： The instant invention relates to unique and novel ionic polymer compositions which are characterized as being processable at high temperatures, for example, 200.degree. C., while retaining adequate physical properties at both room temperature and elevated temperatures which are below the processing temperature. The ionic polymer compositions include a metal neutralized sulfonated polymer which is plasticized with a preferential plasticizer, at a concentration level of about at least 7 parts by weight per 100 parts of the metal neutralized sulfonated polymer. The preferential plasticizer acts to disrupt the ionic association of the metal or ammonium salt groups of the neutralized sulfonated polymer, thus allowing the ionic polymer to act as a noncrosslinked material at the processing temperature. When the composition is in this state, it can be compounded with oils, fillers, etc. The plasticized metal neutralized sulfonated polymer has excellent physical properties at room temperature and up to 100.degree. C. and more than adequate processability at temperatures of from 200.degree. C. and above thereby providing a proper balance of rheological and physical properties. Preferably, the ionic polymer is an ionic elastomer having from 0.2 to 25 mole % pendant acid groups, for example, carboxylic, phosphonic and sulfonic acid groups. Preferably, the pendant acid groups are sulfonic acid groups.
摘要翻译：本发明涉及独特和新颖的离子聚合物组合物，其特征在于可在高温例如200℃下加工，同时在室温和高于处理温度的高温下保持足够的物理性能。离子聚合物组合物包括用优选增塑剂增塑的金属中和磺化聚合物，其浓度水平为每100份金属中和磺化聚合物约至少7重量份。优选的增塑剂用于破坏中和的磺化聚合物的金属或铵盐基团的离子缔合，从而允许离子聚合物在加工温度下用作非交联材料。当组合物处于这种状态时，它可以与油，填料等混合。塑化金属中和的磺化聚合物在室温和高达100℃下具有优异的物理性能，并且在200℃的温度下具有足够的加工性能 C.以上，从而提供流变学和物理性质的适当平衡。优选地，离子聚合物是具有0.2至25摩尔％侧基酸基团的离子弹性体，例如羧酸，膦酸和磺酸基团。优选地，侧基酸基团是磺酸基团。

4. 发明授权

US4014831A Novel ionic polymer compositions 失效
公开(公告)号：US4014831A
公开(公告)日：1977-03-29
申请号：US579496
申请日：1975-05-21
申请人： Jan Bock , Neville G. Thame , Lowell Westerman
发明人： Jan Bock , Neville G. Thame , Lowell Westerman
IPC分类号： C08L23/00 , C08F8/00 , C08F8/44 , C08K3/00 , C08K3/22 , C08K5/00 , C08K5/05 , C08K5/09 , C08K5/17 , C08K5/19 , C08L23/26 , C08L25/00 , C08L101/00 , C08L101/02 , C08F8/42
CPC分类号： C08F8/44
摘要： The instant invention relates to a method for making processable ionic polymer compositions which are characterized as being processable at high temperatures, for example, 200.degree. C, while retaining adequate physical properties at both room temperatures and elevated temperatures which are below the processing temperature, for example, up to 100.degree. C and more. In this method, an ionic polymer comprising an elastomeric or plastic backbone and pendant acid groups is combined with a first neutralizing agent having two components. One component of said neutralizing agent is a metal or ammonium type moiety which combines with the pendant acid groups as a metal or ammonium salt thereof; the other component of neutralizing agent takes up the hydrogen ion present in the pendant acid groups and is converted into a preferential plasticizer for said ionomer. The preferential plasticizer acts to disrupt the ionic association of the metal or ammonium salt groups, thus allowing the ionic polymer to act as a noncrosslinked material. When the composition is in this state, it can be compounded with oils, fillers, etc. An ionic composition in this state is also characterized as having poor physical properties, for example, tensile strength, and excellent processing characteristics, e.g., low viscosity at elevated temperatures. This neutralized composition is then contacted with a second neutralizing agent which acts to substantially convert said preferential plasticizer to a higher melting species, for example, a salt. The composition, after the second neutralizing step, is then characterized as having the desired properties, for example, excellent physical properties at room temperature and up to 100.degree. C and more than adequate processability at temperatures of from 200.degree. C and above. Preferably, the ionic polymer is an ionic elastomer having from 0.2 to 25 mole % pendant acid groups, for example, carboxylic, phosphonic and sulfonic acid groups. Preferably, the pendant acid groups are sulfonic acid groups.The first neutralizing agent is preferably selected from the group consisting of metal salts of fatty acids wherein said metal is selected from Groups IA, IIA, IIB, IIA, Al and Pb of the Periodic Table of the Elements or ammonium salts of fatty acids said ammonium moiety has the general formula R.sub.4 N wherein R is selected from the group consisting of hydrogen and lower alkyl, e.g., methyl and ethyl, more preferably hydrogen radicals.The second neutralizing agent is preferably selected from the group consisting of Group IA, IIA and IIB derivatives of lower organic acids, for example, from 1 to 4 carbon atoms and their hydroxides. Preferably, the first neutralizing agent is combined with said ionic polymer at from 0.5 equivalents/equivalent of acid to 5 equivalents/equivalent acid and more preferably from 1 equivalent/equivalent acid to 3 equivalents/equivalent acid and said second neutralizing agent is combined with said ionic polymer preferably at from 0.25 equivalent/equivalent acid to 3 equivalents/equivalent acid, and more preferably between 0.75 equivalent/equivalent acid and 3 equivalents/equivalent acid.

5. 发明授权

US4193901A Process for the sulfonation of an elastomeric polymer 失效
标题翻译：磺化弹性聚合物的方法
公开(公告)号：US4193901A
公开(公告)日：1980-03-18
申请号：US19312
申请日：1979-03-12
申请人： Henry S. Makowski , Robert D. Lundberg , Jan Bock
发明人： Henry S. Makowski , Robert D. Lundberg , Jan Bock
IPC分类号： C08C19/20 , C08F8/36 , C08F8/44 , C08L91/00
CPC分类号： C08C19/20 , C08F8/36 , C08F8/44 , C08F2800/20 , Y10S260/31
摘要： An improved process for the sulfonation of an unsaturated elastomeric polymer to form a sulfonated elastomeric polymer, wherein a cement which contains an elastomeric polymer dissolved in a non-reactive solvent is contacted with a sulfonating agent at between about -100.degree. C. and +100.degree. C. for a period of time sufficient to result in the sulfonation of the elastomeric polymer wherein the improvement includes the use of a sulfonating agent which is formed from mixtures of a sulfur trioxide donor complexed with a Lewis base and a carboxylic acid anhydride ##STR1## or an acyl halide ##STR2## or with both, wherein R is selected from the group consisting of CH.sub.3 --, C.sub.2 H.sub.5 --, C.sub.3 H.sub.7 --, C.sub.4 H.sub.9 --, C.sub.5 H.sub.11, C.sub.6 H.sub.13 and C.sub.6 H.sub.5 and mixtures thereof. The molar ratio of ##STR3## and/or ##STR4## with the SO.sub.3 of the complex is at least 0.5.
摘要翻译：用于磺化不饱和弹性体聚合物以形成磺化弹性体聚合物的改进方法，其中含有溶解在非反应性溶剂中的弹性体聚合物的水泥在约-100℃和+ 100℃之间与磺化剂接触在一段时间内足以导致弹性体聚合物的磺化，其中改进包括使用磺化剂，其由与路易斯碱和羧酸酐复合的三氧化硫供体的混合物形成和/或与络合物的SO 3的摩尔比为至少0.5。

6. 发明授权

US4316828A Bulk neutralization 失效
标题翻译：大量中和
公开(公告)号：US4316828A
公开(公告)日：1982-02-23
申请号：US47753
申请日：1979-06-12
申请人： Henry S. Makowski , Robert D. Lundberg , Jan Bock
发明人： Henry S. Makowski , Robert D. Lundberg , Jan Bock
IPC分类号： C08C19/20 , C08F8/44 , C08L91/00
CPC分类号： C08C19/20 , C08F8/44
摘要： An improved process for the manufacture of extended gel free sulfonated elastomeric products includes the formation of a homogeneous mixture of fillers and oils with the acid form of the sulfonated polymer prior to the neutralization of the acid form of the sulfonated polymer with a basic material thereby resulting in a composition having improved physical properties.
摘要翻译：用于制造延伸的无凝胶磺化弹性体产品的改进方法包括在用磺化聚合物的酸形式与碱性物质中和之前，将磺酸化聚合物的酸形式的填料和油的均匀混合物形成，由此得到在具有改进的物理性质的组合物中。

7. 发明授权

US4222914A Process for forming a Zn sulfonate containing elastomer 失效
标题翻译：形成含有磺酸锌的弹性体的方法
公开(公告)号：US4222914A
公开(公告)日：1980-09-16
申请号：US22951
申请日：1979-03-23
申请人： Henry S. Makowski , Robert R. Klein , Robert D. Lundberg , Jan Bock
发明人： Henry S. Makowski , Robert R. Klein , Robert D. Lundberg , Jan Bock
IPC分类号： C08F8/44 , C08L91/00
CPC分类号： C08F8/44
摘要： This invention relates to a process for the formation of a neutralized sulfonated polymer having about 10 to about 60 meq. sulfonate groups, wherein the sulfonate groups are neutralized with a zinc counterion. A cement of a polymer having olefinic functional groups and a non-reactive solvent is contacted with a sulfonated agent such as an acyl sulfate. The sulfonated polymer is then neutralized with a solution of zinc acetate dissolved in a solvent system of methanol alone or methanol and water, wherein the volume percent of methanol based on non-reactive solvent is less than about 10. A carboxylic acid can be then added to the cement of the neutralized sulfonated polymer thereby forming a zinc salt of the carboxylic acid in situ, wherein the zinc salt of the carboxylic acid is a preferential plasticizer for the zinc sulfonate groups. The Brookfield viscosity at 0.6 rpm at room temperature of the cement of the zinc neutralized sulfonated polymer is less than about 50,000 cps.
摘要翻译：本发明涉及形成约10至约60meq的中和磺化聚合物的方法。磺酸盐基团，其中磺酸盐基团用锌抗衡离子中和。具有烯属官能团和非反应性溶剂的聚合物的水泥与磺化剂如酰基硫酸盐接触。然后将磺化聚合物用溶于仅甲醇溶剂体系的乙酸锌溶液或甲醇和水中和，其中基于非反应性溶剂的甲醇的体积百分比小于约10.然后可以加入羧酸到中和的磺化聚合物的水泥上，由此原位形成羧酸的锌盐，其中羧酸的锌盐是磺酸锌基团的优选增塑剂。锌中和磺化聚合物的水泥在室温下在0.6rpm下的Brookfield粘度小于约50,000cps。

8. 发明授权

US4221712A Process for forming a metal sulfonate containing EPDM 失效
标题翻译：用于形成含有EPDM的金属磺酸盐的方法
公开(公告)号：US4221712A
公开(公告)日：1980-09-09
申请号：US22976
申请日：1979-03-23
申请人： Henry S. Makowski , Jan Bock , Robert D. Lundberg
发明人： Henry S. Makowski , Jan Bock , Robert D. Lundberg
IPC分类号： C08F8/44 , C08L91/00
CPC分类号： C08F8/44
摘要： This invention relates to an improved process for the formation of an improved gel-free neutralized sulfonated elastomeric polymer having about 10 to about 50 meq. unneutralized sulfonate groups, wherein the unneutralized sulfonate groups are neutralized with a metal counterion being selected from the group including lithium, sodium, potassium, cesium, barium, calcium, magnesium, zinc, lead, iron (II), copper (II), mercury (II), and nickel. A cement of an elastomeric polymer having olefinic functional groups dissolved in a non-reactive solvent is contacted with a sulfonating agent such as an acyl sulfate thereby sulfonating the elastomeric polymer, and the sulfonation reaction is subsequently quenched by the addition of isopropanol at a concentration level of about 5 to about 30 volume percent based on a volume of the non-reactive solvent. The unneutralized sulfonated elastomeric polymer is then neutralized with a neutralizing agent dissolved in water, the water being at a concentration level of less than about 2.5 volume percent based on the volume of the non-reactive solvent thereby forming a gel-free cement of the neutralized sulfonated elastomeric polymer having a Brookfield viscosity at room temperature of less than about 20,000 cps.
摘要翻译：本发明涉及形成具有约10至约50meq的改进的无凝胶中和磺化弹性体聚合物的改进方法。未中和磺酸酯基团，其中所述未中和磺酸酯基团被金属抗衡离子中和，所述金属抗衡离子选自锂，钠，钾，铯，钡，钙，镁，锌，铅，铁（II），铜（II），汞（II）和镍。将具有溶解在非反应性溶剂中的烯属官能团的弹性体聚合物的水泥与磺化剂如酰基硫酸酯接触，从而使弹性体聚合物磺化，然后通过加入浓度级别的异丙醇淬灭磺化反应约5至约30体积％，基于非反应性溶剂的体积。然后将未中和的磺化弹性体聚合物用溶解在水中的中和剂中和，基于非反应性溶剂的体积，水的浓度水平低于约2.5体积％，从而形成中和的无凝胶的水泥磺化弹性体聚合物在室温下的Brookfield粘度小于约20,000cps。

9. 发明授权

US4169820A Elastomeric compositions 失效
标题翻译：弹性组合物
公开(公告)号：US4169820A
公开(公告)日：1979-10-02
申请号：US855757
申请日：1977-11-29
申请人： Jan Bock , Robert D. Lundberg , Henry S. Makowski
发明人： Jan Bock , Robert D. Lundberg , Henry S. Makowski
IPC分类号： C08L23/32 , C08L91/00
CPC分类号： C08L23/32
摘要： This invention relates to extrusion and injection moldable type elastomeric compositions having a viscosity at 200.degree. C. at 0.73 sec.sup.-1 of about 8.times.10.sup.4 to about 8.times.10.sup.5 poises. The compositions used for elastomeric articles include 100 parts of a neutralized sulfonated EPDM terpolymer; about 25 to about 150 parts per hundred of a non-polar process oil; about 50 to about 300 parts per hundred of a filler; and a preferential plasticizer at about 0 to about 50 parts per hundred based on 100 parts of the sulfonated elastomeric polymer. The composition may also include a crystalline polyolefinic thermoplastic at less than about 100 parts per hundred by weight.These blend compositions can be readily processed due to their superior rheological properties on conventional plastic fabrication equipment into elastomeric articles having excellent physical properties and desirable rubbery characteristics.
摘要翻译：本发明涉及在200℃，0.73秒-1时粘度为约8×10 4至约8×10 5泊的挤出和注射成型型弹性体组合物。用于弹性制品的组合物包括100份中和的磺化EPDM三元共聚物; 每百份非极性加工油约25至约150份; 每百份填料约50至约300份; 和基于100份磺化弹性体聚合物的约0至约50份/ 100的优选增塑剂。组合物还可以包含小于约100重量份/ 100重量份的结晶聚烯烃热塑性塑料。

10. 发明授权

US4160751A Low pressure injection moldable compositions 失效
标题翻译：低压注塑成型组合物
公开(公告)号：US4160751A
公开(公告)日：1979-07-10
申请号：US855765
申请日：1977-11-29
申请人： Jan Bock , Robert D. Lundberg , Henry S. Makowski
发明人： Jan Bock , Robert D. Lundberg , Henry S. Makowski
IPC分类号： C08L23/32 , C08L91/00
CPC分类号： C08L23/32 , Y10S260/31
摘要： This invention relates to injection moldable type elastomeric compositions having a viscosity at 200.degree. C. at 0.73 sec.sup.-1 of less than about 8.times.10.sup.4 poises. The compositions used for elastomeric articles include 100 parts of a neutralized sulfonated EPDM terpolymer; about 25 to about 150 parts per hundred of a non-polar process oil; about 25 to about 200 parts per hundred of a filler; and a preferential plasticizer at about less than 50 parts per hundred based on 100 parts of the sulfonated elastomeric polymer. The composition may also include a crystalline polyolefinic thermoplastic at least than about 100 parts per hundred by weight.These blend compositions can be readily processed due to their superior rheological properties on conventional plastic fabrication equipment, especially on low pressure injection molding equipment into elastomeric articles having excellent physical properties and desirable rubbery characteristics.
摘要翻译：本发明涉及可注射成型的弹性体组合物，其在200℃下的粘度为0.73秒-1小于约8×10 4泊。用于弹性制品的组合物包括100份中和的磺化EPDM三元共聚物; 每百份非极性加工油约25至约150份; 每百份填料约25至约200份; 和基于100份磺化弹性体聚合物的约百分之50的优选增塑剂。组合物还可以包括至少约100重量份/ 100重量％的结晶聚烯烃热塑性塑料。

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