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1. 发明申请

US20050014883A1 Aqueous polymerization process for preparing an aqueous polymer dispersion 有权
标题翻译：用于制备聚合物水分散体的水性聚合方法
公开(公告)号：US20050014883A1
公开(公告)日：2005-01-20
申请号：US10890572
申请日：2004-07-14
申请人： Robert Blankenship , Gary Dombrowski , Ralph Even
发明人： Robert Blankenship , Gary Dombrowski , Ralph Even
IPC分类号： C08F2/38 , C08F2/00 , C08F2/22 , C08F2/40 , C08F265/04 , C08F265/06 , C08F285/00 , C08F291/00 , C08L51/00 , C09D151/00 , C09J151/00 , G03G13/20
CPC分类号： C09D151/003 , C08F2/001 , C08F265/04 , C08F265/06 , C08F285/00 , C08F291/00 , C08L51/003 , C08L2666/02 , C09J151/003 , C08F2/22
摘要： The present invention relates to a process for preparing an aqueous polymer dispersion containing polymer particles dispersed in an aqueous medium. The process includes providing first polymer particles; adding a hydrophobic polymerization blocker or a styrenic monomer polymerization blocker to the aqueous medium containing the first polymer particles; and preparing second polymer particles in the presence of the first polymer particles. The aqueous polymer dispersion contain first polymer particles and the second polymer that differ according to at least one attribute such as particle diameter, molecular weight, composition, glass transition temperature, or morphology; or contain polymer particles having a broad polydispersity. The aqueous polymer dispersion prepared by the process of this invention is useful in a wide range of applications, including paints, adhesive, binders for nonwovens, and binders for paper coatings.
摘要翻译：本发明涉及一种制备含有分散在水介质中的聚合物颗粒的含水聚合物分散体的方法。该方法包括提供第一聚合物颗粒; 向包含第一聚合物颗粒的水性介质中加入疏水性聚合阻滞剂或苯乙烯单体聚合阻滞剂; 以及在所述第一聚合物颗粒的存在下制备第二聚合物颗粒。含水聚合物分散体含有第一聚合物颗粒和第二聚合物，其根据至少一种属性如颗粒直径，分子量，组成，玻璃化转变温度或形态而不同; 或含有具有广泛多分散性的聚合物颗粒。通过本发明的方法制备的水性聚合物分散体可用于广泛的应用，包括涂料，粘合剂，无纺布粘合剂和纸张涂料用粘合剂。

2. 发明申请

US20060189479A1 Protected catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers 有权
标题翻译：受保护的催化剂组合物及其制备和用于从烯属不饱和单体制备聚合物的用途
公开(公告)号：US20060189479A1
公开(公告)日：2006-08-24
申请号：US11340040
申请日：2006-01-26
申请人： Ralph Even , Willie Lau
发明人： Ralph Even , Willie Lau
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , B01J33/00 , C08F210/16 , C08F4/027 , C08F210/14 , C08F220/00 , C08F4/7006
摘要： A method for polymerizing ethylenically unsaturated monomers, including non-polar olefinic monomers, polar olefinic monomers, and combinations thereof, using a protected catalytic composition in an aqueous medium, is disclosed. An aqueous dispersion containing the protected catalytic composition is also disclosed, along with an aqueous dispersion of the addition polymer produced by the polymerization.
摘要翻译：公开了一种使用保护的催化组合物在水性介质中聚合烯属不饱和单体，包括非极性烯烃单体，极性烯烃单体及其组合的方法。还公开了含有受保护的催化组合物的水性分散体以及通过聚合制备的加成聚合物的水分散体。

3. 发明申请

US20070100074A1 Aqueous emulsion polymers comprising stable epoxy groups 失效
标题翻译：包含稳定的环氧基团的水乳液聚合物
公开(公告)号：US20070100074A1
公开(公告)日：2007-05-03
申请号：US11583303
申请日：2006-10-19
申请人： Wayne Devonport , Ralph Even
发明人： Wayne Devonport , Ralph Even
IPC分类号： C08L63/00 , B32B27/38
CPC分类号： C09D133/02 , C08L33/02 , C08L33/066 , C08L33/068 , C09D133/068 , C09D133/08 , C09D151/003 , C09D163/00 , C08L2666/04
摘要： According to the present invention, aqueous multi-stage polymer dispersions comprising an acid-functional first polymer and an epoxy-functional second polymer, wherein 90 mole % or more of the said epoxy groups, based on the moles of epoxy groups in the monomer mixture used to form the second polymer, are retained in the aqueous dispersion after said dispersion is stored in a sealed container for 10 days at 60° C. Further, methods of making the aqueous multistage polymer dispersion comprise polymerizing the monomers used to make the second polymer in the presence of an aqueous dispersion of the first polymer. Preferably, the second polymer is formed in the presence of 0.3 wt. % or less, based on the total weight of the first polymer and the ingredients to form the second polymer, of one or more strong acid surfactant, and 3) 0.1 wt. % or less, based on the total weight of the first polymer and the ingredients to form the second polymer, of one or more initiator that contains strong acid groups or generates strong acid groups under the conditions of aqueous emulsion polymerization. The aqueous dispersions provide non-toxic, odor free storage stable coating compositions that form coatings having excellent film toughness and hardness.
摘要翻译：根据本发明，包含酸官能的第一聚合物和环氧官能的第二聚合物的水性多阶段聚合物分散体，其中基于单体混合物中的环氧基的摩尔数，所述环氧基的90摩尔％或更多用于形成第二聚合物的物质在所述分散体在60℃下储存在密封容器中10天后保留在水性分散体中。此外，制备水性多级聚合物分散体的方法包括聚合用于制备第二聚合物的单体在第一聚合物的水分散体存在下进行。优选地，第二聚合物在0.3wt。％或更少，基于第一聚合物的总重量和形成第二聚合物的成分，一种或多种强酸表面活性剂，和3）0.1wt。基于第一聚合物的总重量和形成第二聚合物的成分的一种或多种引发剂，其含有强酸基团或在水乳液聚合的条件下产生强酸基团。水分散体提供无毒，无气味的储存稳定的涂料组合物，其形成具有优异的膜韧性和硬度的涂料。

4. 发明申请

US20060217453A1 POLYMERIC NANOPARTICLE FORMULATIONS AND THEIR USE FOR IMPROVING THE DIRT PICK UP RESISTANCE OF A COATING 有权
标题翻译：聚合物纳米材料制剂及其用于改善涂料耐沾污性能的用途
公开(公告)号：US20060217453A1
公开(公告)日：2006-09-28
申请号：US10461963
申请日：2003-06-13
申请人： Rosemarie Lauer , Ralph Even , Donna Grecian , Robert Solomon
发明人： Rosemarie Lauer , Ralph Even , Donna Grecian , Robert Solomon
IPC分类号： C08J3/28
CPC分类号： B82Y30/00 , C08F220/14 , C08F220/18 , C08F222/1006 , C08F230/08 , C09D5/1668 , C09D5/1687 , C09D143/04
摘要： A formulation for repelling particulate matter on the surface of a coating comprising polymeric nanoparticles having a mean particle diameter of from 1 to 50 nm. The polymeric nanoparticles may further be functionalized to impart additional characteristics to modify the surface of the dried coating to minimize the chances for particles to become embedded or attached to the coating.
摘要翻译：用于排斥包含平均粒径为1至50nm的聚合物纳米颗粒的涂层表面上的颗粒物质的制剂。聚合物纳米颗粒可以进一步官能化以赋予干燥涂层的表面的附加特性以最小化颗粒嵌入或附着到涂层的机会。

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