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    • 2. 发明授权
    • Method for reducing the temperature in a regeneration zone of a fluid
catalytic cracking process
    • 降低流化催化裂化过程再生区温度的方法
    • US4859313A
    • 1989-08-22
    • US896569
    • 1986-08-15
    • Robert A. LengemannGregory J. ThompsonAnthony G. VickersRaymond W. Mott
    • Robert A. LengemannGregory J. ThompsonAnthony G. VickersRaymond W. Mott
    • C10G11/18
    • C10G11/18
    • A method for operating a fluid catalytic cracking unit comprising a regeneration zone and a reaction zone with a relatively reduced temperature in the regeneration zone while processing a hydrocarbon feedstock having a 50 volume percent distillation temperature greater than about 500.degree. F. which method comprises contacting the feedstock in a reaction zone with a mixture of regenerated fluidizable cracking catalyst and fluidizable low coke make solid particles comprising a refractory inorganic oxide in a ratio of low coke make solid particles to cracking catalyst from about 1:100 to about 10:1, the low coke made solid particles having a surface area of less than about 5 m.sup.2 /g and a coke making capability of less than about 0.2 weight percent coke on the spent low coke make solid particles in the ASTM standard method for testing cracking catalyst by microactivity test (MAT); separating the resulting vaporized hydrocarbon products from the mixture of deactivated fluidizable cracking catalyst and fluidizable low coke made solid particles; recovering the resulting vaporized hydrocarbon products; passing the mixture of cracking catalyst and low coke made solid particles to the regeneration zone for regeneration by removal of coke; and passing the resulting regenerated mixture of cracking catalyst and low coke make solid particles from the regeneration zone to the reaction zone to contact the feedstock as described above whereby the regeneration zone temperature is maintained at a reduced temperature as compared to an equivalent operation without the use of the fluidizable low coke make solid particles while simultaneously not affecting the operation of the reaction zone.
    • 一种用于操作流化催化裂化装置的方法,所述流化催化裂化装置包括再生区和在再生区中具有相对降低的温度的反应区,同时处理具有大于约500°F的50体积%蒸馏温度的烃原料。该方法包括使 在与可再生的可流化裂化催化剂和可流化的低焦炭的混合物的反应区中的原料使固体颗粒包含低焦度的难熔性无机氧化物,使固体颗粒与裂化催化剂的比例为约1:100至约10:1,低 焦炭制成的表面积小于约5m 2 / g的固体颗粒和焦炭制造能力小于约0.2重量%的焦炭在废低焦炭上制成固体颗粒,按照ASTM标准方法通过微活性试验测试裂化催化剂( 垫); 将所得蒸发的烃产物与可失活的可流化裂化催化剂和可流化的低焦炭固体颗粒的混合物分离; 回收所得蒸发的烃产物; 将裂解催化剂和低焦炭固体颗粒的混合物通过除去焦炭再生到再生区; 并将得到的裂解催化剂和低焦炭再生混合物从固体颗粒从再生区制成固体颗粒至反应区,以与上述原料接触,由此与无需使用的等效操作相比,再生区温度保持在降低的温度 的可流化的低焦炭制成固体颗粒,同时不影响反应区的操作。
    • 3. 发明授权
    • Catalyst regeneration apparatus
    • 催化剂再生装置
    • US4285908A
    • 1981-08-25
    • US101295
    • 1979-12-07
    • Gregory J. ThompsonAnthony G. Vickers
    • Gregory J. ThompsonAnthony G. Vickers
    • B01J8/18B01J8/26B01J21/20B01J23/90B01J29/90B01J37/14C10G11/18B01J8/32B01J8/44F27B15/08F27B15/10
    • B01J8/1818B01J21/20B01J23/90B01J29/90B01J37/14B01J8/26C10G11/182Y02P30/446
    • A catalyst regeneration apparatus for the oxidation of coke from a spent catalyst, said coke being converted to CO, and for the conversion of the CO to CO.sub.2. Hot regenerated catalyst is recycled from a dense bed in the regeneration zone to mix with incoming spent catalyst in a mixer zone. The mixer zone operates in dense phase and is supplied with a relatively small amount of a fluidizing medium, preferably air. After the mixing of spent and fresh catalyst is substantially completed, a relatively large amount of a regenerating gas, preferably air, is admixed with the catalyst mixture, and some coke oxidation occurs. The balance of coke oxidation takes place in a downstream-situated regeneration zone of substantially conventional design. There is a transfer section connecting the mixer zone to the regeneration zone through which the relatively large amount of the regenerating gas is admitted. The transfer section is preferably a frustoconical surface, the horizontal cross section of smallest perimeter of which adjoins the outlet of said mixer zone, and regenerating gas addition is made at the base of the transfer section in order to provide a venturi effect which ensures good air-catalyst mixing.
    • 一种用于从废催化剂氧化焦炭的催化剂再生装置,所述焦炭转化为CO,并将CO转化为CO 2。 热再生催化剂从再生区中的致密床再循环,以在混合区中与进入的废催化剂混合。 混合器区域以密相工作,并且供应相对少量的流化介质,优选空气。 在废旧催化剂的混合基本上完成之后,将相当大量的再生气体,优选空气与催化剂混合物混合,并发生一些焦炭氧化。 焦炭氧化的平衡发生在基本上常规设计的位于下游的再生区中。 存在将混合器区域连接到再生区域的转移段,通过该再生区域允许相对大量的再生气体。 转印部优选为截头圆锥形表面,其最小周边的水平截面与所述混合区的出口相邻,并且在转印部分的底部形成再生气体添加,以提供确保良好空气的文丘里效应 催化剂混合。
    • 4. 发明授权
    • Catalyst regeneration apparatus
    • 催化剂再生装置
    • US4340566A
    • 1982-07-20
    • US239814
    • 1981-03-02
    • Gregory J. ThompsonAnthony G. Vickers
    • Gregory J. ThompsonAnthony G. Vickers
    • B01J8/18B01J8/26B01J21/20B01J23/90B01J29/90B01J37/14C10G11/18B01J8/32B01J8/44F27B15/08F27B15/10
    • C10G11/182B01J21/20B01J23/90B01J29/90B01J37/14B01J8/1818B01J8/26Y02P30/446
    • A catalyst regeneration apparatus for the oxidation of coke from a spent catalyst, said coke being converted to CO, and for the conversion of the CO to CO.sub.2. Hot regenerated catalyst is recycled from a dense bed in the regeneration zone to mix with incoming spent catalyst in a mixer zone. The mixer zone operates in dense phase and is supplied with a relatively small amount of a fluidizing medium, preferably air. After the mixing of spent and fresh catalyst is substantially completed, a relatively large amount of a regenerating gas, preferably air, is admixed with the catalyst mixture, and some coke oxidation occurs. The balance of coke oxidation takes place in a downstream-situated regeneration zone of substantially conventional design. There is a transfer section connecting the mixer zone to the regeneration zone through when the relatively large amount of the regenerating gas is admitted. The transfer section is preferably a substantially horizontal surface having an outside perimeter intermediate the outside perimeters of the regeneration and mixer zones. Regeneration gas addition is made through multiple perforations in the transfer section.
    • 一种用于从废催化剂氧化焦炭的催化剂再生装置,所述焦炭转化为CO,并将CO转化为CO 2。 热再生催化剂从再生区中的致密床再循环,以在混合区中与进入的废催化剂混合。 混合器区域以密相工作,并且供应相对少量的流化介质,优选空气。 在废旧催化剂的混合基本上完成之后,将相当大量的再生气体,优选空气与催化剂混合物混合,并发生一些焦炭氧化。 焦炭氧化的平衡发生在基本上常规设计的位于下游的再生区中。 当相当大量的再生气体被允许时,存在将混合器区域连接到再生区域的转移段。 传送部优选地是具有在再生和混合区之外的周边的中间的大致水平的表面。 通过转印部分中的多个穿孔进行再生气体添加。
    • 5. 发明授权
    • Catalyst regeneration process
    • 催化剂再生过程
    • US4197189A
    • 1980-04-08
    • US908301
    • 1978-05-22
    • Gregory J. ThompsonAnthony G. Vickers
    • Gregory J. ThompsonAnthony G. Vickers
    • B01J8/18B01J21/20B01J23/90B01J29/90B01J37/14C10G11/18B01D15/00B01J37/12C10G13/18
    • B01J21/20B01J23/90B01J29/90B01J37/14B01J8/1818C10G11/182Y02P30/446
    • A catalyst regeneration process and apparatus for the oxidation of coke from a spent catalyst, said coke being converted to CO, and for the conversion of the CO to CO.sub.2. Hot regenerated catalyst is recycled from a dense bed in the regeneration zone to mix with incoming spent catalyst in a riser-mixer. The riser-mixer operates in dense phase and is supplied with a relatively small amount of a fluidizing medium, preferably air. After the mixing of spent and fresh catalyst is substantially completed, a relatively large amount of a regenerating gas, preferably air, is admixed with the catalyst mixture, and some coke oxidation occurs. The balance of coke oxidation takes place in a downstream-situated regeneration zone of substantially conventional design. The regenerating gas addition is preferably made at the base of a cone-shaped combustor in order to provide a venturi effect which ensures good air-catalyst mixing.
    • 用于从废催化剂氧化焦炭的催化剂再生方法和装置,所述焦炭转化为CO,并将CO转化为CO 2。 热再生催化剂从再生区中的致密床再循环,与提升管混合器中的输入的废催化剂混合。 提升混合器以密相工作,并且供应相对少量的流化介质,优选空气。 在废旧催化剂的混合基本上完成之后,将相当大量的再生气体,优选空气与催化剂混合物混合,并发生一些焦炭氧化。 焦炭氧化的平衡发生在基本上常规设计的位于下游的再生区中。 再生气体添加优选在锥形燃烧器的基部制成,以提供确保良好的空气 - 催化剂混合的文氏管效应。
    • 6. 发明授权
    • Fluid catalyst regeneration process and apparatus
    • 流体催化剂再生过程和装置
    • US4364849A
    • 1982-12-21
    • US301923
    • 1981-09-14
    • Anthony G. VickersDavid A. Lomas
    • Anthony G. VickersDavid A. Lomas
    • C10G11/18B01J29/38B01J21/20
    • C10G11/182
    • A catalyst regeneration process and apparatus for the oxidative removal of coke from a coke contaminated fluid catalyst. The process comprises a high temperature coke combustion zone, a catalyst disengagement zone and an external heat removal zone comprising a shell and tube heat exchanger. Catalyst is cooled by passing it through the shell side of the heat exchanger with a cooling medium through the tube side. A mixture of coke contaminated catalyst, oxygen containing gas, and cool regenerated catalyst from the heat removal zone are contacted in the high temperature combustion zone, the temperature of which is controlled by adjusting the rate at which catalyst is passed through the heat exchanger. This rate is adjusted by adjusting the difference in catalyst head between the catalyst inlet and outlet of the heat exchanger and thus the hydraulic driving force which effects catalyst circulation through the heat exchanger.
    • 用于从焦炭污染的流体催化剂氧化除去焦炭的催化剂再生方法和装置。 该方法包括高温焦炭燃烧区,催化剂分离区和包括管壳式热交换器的外部除热区。 通过将冷却介质穿过管侧通过热交换器的外壳侧来冷却催化剂。 来自除热区的焦炭污染催化剂,含氧气体和冷再生催化剂的混合物在高温燃烧区接触,其温度通过调节催化剂通过热交换器的速率来控制。 该速率通过调节热交换器的催化剂入口和出口之间的催化剂头的差异以及因此通过热交换器使催化剂循环的液压驱动力来调节。
    • 7. 发明授权
    • Fluid catalyst regeneration apparatus
    • 流体催化剂再生装置
    • US4438071A
    • 1984-03-20
    • US407681
    • 1982-08-12
    • Anthony G. VickersDavid A. Lomas
    • Anthony G. VickersDavid A. Lomas
    • C10G11/18F27B15/08B01J21/20B01J29/38
    • C10G11/182
    • A catalyst regeneration process and apparatus for the oxidative removal of coke from a coke contaminated fluid catalyst. The process comprises a high temperature coke combustion zone, a catalyst disengagement zone and an external heat removal zone comprising a shell and tube heat exchanger. Catalyst is cooled by passing it through the shell side of the heat exchanger with a cooling medium through the tube side. A mixture of coke contaminated catalyst, oxygen containing gas, and cool regenerated catalyst from the heat removal zone are contacted in the high temperature combustion zone, the temperature of which is controlled by adjusting the rate at which catalyst is passed through the heat exchanger. This rate is adjusted by adjusting the difference in catalyst head between the catalyst inlet and outlet of the heat exchanger and thus the hydraulic driving force which effects catalyst circulation through the heat exchanger.
    • 用于从焦炭污染的流体催化剂氧化除去焦炭的催化剂再生方法和装置。 该方法包括高温焦炭燃烧区,催化剂分离区和包括管壳式热交换器的外部除热区。 通过将冷却介质穿过管侧通过热交换器的外壳侧来冷却催化剂。 来自除热区的焦炭污染催化剂,含氧气体和冷再生催化剂的混合物在高温燃烧区接触,其温度通过调节催化剂通过热交换器的速率来控制。 该速率通过调节热交换器的催化剂入口和出口之间的催化剂头的差异以及因此通过热交换器使催化剂循环的液压驱动力来调节。
    • 9. 发明授权
    • Fluid catalyst regeneration apparatus
    • 流体催化剂再生装置
    • US4423006A
    • 1983-12-27
    • US423373
    • 1982-09-24
    • Anthony G. Vickers
    • Anthony G. Vickers
    • C10G11/18F27B15/08B01J21/20B01J29/38
    • C10G11/182C10G11/187
    • An apparatus for regenerating coke-contaminated fluid catalyst which comprises a vertical combustion chamber, an inlet to said chamber for spent catalyst and regeneration gas, a disengagement chamber above and in communication with the combustion chamber, a heat removal chamber below the combustion chamber in which may be maintained a dense phase catalyst bed, heat removal means positioned within the heat removal chamber such that it will be immersed in the catalyst bed, a recycle conduit for passing catalyst from the disengagement chamber to the heat removal chamber, a vertical cooled catalyst inlet conduit connecting the heat removal chamber with the lower portion of the combustion chamber so that catalyst can pass from the former to the latter, and a regeneration gas inlet line connecting with a lower part of the cooled catalyst inlet conduit to enable the flow of cooled catalyst up into the combustion chamber, wherein a control system senses the catalyst level in the heat removal zone, formulates an output signal via a level control means having an adjustable set point, and regulates the flow rate of regeneration gas into the cooled catalyst inlet conduit via transmission of the output signal to a flow control means responsive thereto and thereby controls such level.
    • 一种用于再生焦炭污染的流体催化剂的装置,其包括垂直燃烧室,用于废催化剂和再生气体的所述室的入口,在燃烧室上方并与其连通的分离室,在燃烧室下方的除热室, 可以保持密相催化剂床,位于除热室内的散热装置,使其浸入催化剂床中,将催化剂从分离室传递到除热室的循环管道,垂直冷却的催化剂入口 将排热室与燃烧室的下部连接的导管,以使催化剂能够从前者传递到后者;以及再生气体入口管线,其与冷却的催化剂入口导管的下部连接,以使冷却的催化剂 进入燃烧室,其中控制系统感测除热器z中的催化剂水平 一个通过具有可调节设定点的电平控制装置制定输出信号,并且通过将输出信号传送到流量控制装置并响应于此而调节进入冷却的催化剂入口导管的再生气体的流量,从而控制这种水平。
    • 10. 发明授权
    • Fluid catalyst regeneration apparatus
    • 流体催化剂再生装置
    • US4371501A
    • 1983-02-01
    • US303256
    • 1981-09-17
    • Anthony G. Vickers
    • Anthony G. Vickers
    • B01J8/00B01J8/18B01J8/24C10G11/18F27B15/08B01J21/20B01J29/38
    • C10G11/182B01J8/0055B01J8/1836B01J8/24
    • An apparatus for regenerating coke-contaminated fluid catalyst is disclosed which comprises a vertical combustion chamber, an inlet to said chamber for spent catalyst and regeneration gas, a fluid catalyst collecting means within the upper portion of said chamber, a first catalyst withdrawal conduit in communication with said collecting means, a heat removal chamber possessing heat removal means super adjacent said chamber, a second catalyst withdrawal conduit connected to said heat removal chamber and a mixing conduit connecting said first and second withdrawal conduits, wherein a control system senses the catalyst temperature in the first withdrawal conduit downstream of the mixer conduit, formulates an output signal via a temperature control means having an adjustable set point, and regulates the flow rate of regenerated catalyst through said mixing conduit via transmission of said output signal to a flow control means responsive thereto.
    • 公开了一种用于再生焦炭污染的流体催化剂的装置,其包括垂直燃烧室,用于废催化剂和再生气体的所述室的入口,在所述室的上部内的流体催化剂收集装置,连通的第一催化剂排出管道 具有所述收集装置的除热室具有超过邻近所述室的除热装置,连接到所述除热室的第二催化剂取出管道和连接所述第一和第二取出管道的混合管道,其中控制系统感测催化剂温度 混合器管道下游的第一取出导管,经由具有可调节设定点的温度控制装置制定输出信号,并通过所述输出信号经由所述输出信号传递到流量控制装置来调节再生催化剂通过所述混合导管的流速 。