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1. 发明申请

US20070240609A1 Photoinitiators 有权
公开(公告)号：US20070240609A1
公开(公告)日：2007-10-18
申请号：US11578595
申请日：2005-04-11
申请人： Rinaldo Husler , Thomas Horni , Andre Fuchs , Tunja Jung , Reinhard Sommerlade
发明人： Rinaldo Husler , Thomas Horni , Andre Fuchs , Tunja Jung , Reinhard Sommerlade
IPC分类号： D21H17/07 , C08F2/48 , C08J3/28
CPC分类号： C07C45/46 , B33Y70/00 , C07C45/58 , C07C45/63 , C07C45/64 , C07C45/71 , C07C45/74 , C07C49/792 , C07C49/82 , C07C49/83 , C07C49/84 , C07C69/96 , C07C271/12 , C07C317/24 , C07D295/108 , C07D295/112 , C07D493/08 , C08F2/50 , C07C49/76 , C07C49/80 , C07C49/813
摘要： The invention relates to novel photoinitators of formulae (V), (II), (III), (IV), (V) and (VI) wherein R1 and R2 are each independently of the other C1-C8alkyl; C1-C4alkyl substituted by OH, C1-C4alkoxy, —COO(C1-C8alkyl), (C1-C4alkyl)-COO—, —CN, benzyl, phenyl or by —N(R15)(R16); C3-C6alkerlyl, benzyl, —CH2—C6H4—(C1-C4alkyl) or phenyl; or R1 and R2 together are unbranched or branched C2-C9alkylene or C3-C6-oxa- or -azaalkylene; R3, R4, R5 and R6 are each independently of the others hydrogen, C1-C8alkyl, C3-C6alkenyl, benzyl, —CH2—C6H4—(C1-C4alkyl) or phenyl; R3 and R4 together and/or R5 and R6 together are unbranched or branched C2-C9alkylene; A is Cl, Br, —O—R9, —N(R11)(R12) or —S—R18, A′ is —O—, —NH— or —NR11—; A″ is Cl, Br, —O—R9, —N(R11)(R12) or —S—R18 or hydrogen, X is —O—R10 or —N(R13)(R14), n is an integer from 1 to 10, preferably an integer from 1 to 4, especially 1, 2 or 3; R7 is a linker; R8 is a bivalent C2-C3alkylele radical.

2. 发明授权

US07642296B2 Photoinitiators 有权
标题翻译：光引发剂
公开(公告)号：US07642296B2
公开(公告)日：2010-01-05
申请号：US11578595
申请日：2005-04-11
申请人： Rinaldo Hüsler , Thomas Horni , André Fuchs , Tunja Jung , Reinhard H. Sommerlade
发明人： Rinaldo Hüsler , Thomas Horni , André Fuchs , Tunja Jung , Reinhard H. Sommerlade
IPC分类号： C08F2/50 , C03C25/10 , C07C49/84
CPC分类号： C07C45/46 , B33Y70/00 , C07C45/58 , C07C45/63 , C07C45/64 , C07C45/71 , C07C45/74 , C07C49/792 , C07C49/82 , C07C49/83 , C07C49/84 , C07C69/96 , C07C271/12 , C07C317/24 , C07D295/108 , C07D295/112 , C07D493/08 , C08F2/50 , C07C49/76 , C07C49/80 , C07C49/813
摘要： The invention relates to novel photoinitators of formulae (I), (II), (III), (IV), (V) and (VI) wherein R1 and R2 are each independently of the other C1-C8alkyl; C1-C4alkyl substituted by OH, C1-C4alkoxy, —COO(C1-C8alkyl), (C1-C4alkyl)-COO—, —CN, benzyl, phenyl or by —N(R15)(R16); C3-C6alkerlyl, benzyl, —CH2—C6H4—(C1-C4alkyl) or phenyl; or R1 and R2 together are unbranched or branched C2-C9alkylene or C3-C6-oxa- or -azaalkylene; R3, R4, R5 and R6 are each independently of the others hydrogen, C1-C8alkyl, C3-C6alkenyl, benzyl, —CH2—C6H4—(C1-C4alkyl) or phenyl; R3 and R4 together and/or R5 and R6 together are unbranched or branched C2-C9alkylene; A is CI, Br, —O—R9, —N(R11)(R12) or —S—R18, A′ is —O—, —NH— or —NR11—; A″ is CI, Br, —O—R9, —N(R11)(R12) or —S—R18 or hydrogen, X is —O—R10 or —N(R13)(R14), n is an integer from 1 to 10, preferably an integer from 1 to 4, especially 1, 2 or 3; R7 is a linker; R8 is a bivalent C2-C3alkylele radical.
摘要翻译：本发明涉及式（I），（II），（III），（IV），（V）和（VI）的新型光引发剂，其中R 1和R 2各自独立地为C 1 -C 8烷基; 被OH，C1-C4烷氧基，-COO（C1-C8烷基），（C1-C4烷基）-COO-，-CN，苄基，苯基或-N（R15）（R16）取代的C1-C4烷基; C3-C6链烯基，苄基，-CH2-C6H4-（C1-C4烷基）或苯基; 或R 1和R 2一起是非支链或支链C 2 -C 9亚烷基或C 3 -C 6 - 氧杂 - 或 - 亚烷基; R 3，R 4，R 5和R 6各自独立地为氢，C 1 -C 8烷基，C 3 -C 6烯基，苄基，-CH 2 -C 6 H 4 - （C 1 -C 4烷基）或苯基; R 3和R 4一起和/或R 5和R 6一起是非支链或支链C 2 -C 9亚烷基; A是Cl，Br，-O-R9，-N（R11）（R12）或-S-R18，A'是-O - ， - NH-或-NR11-; A“是Cl，Br，-O-R9，-N（R11）（R12）或-S-R18或氢，X是-O-R10或-N（R13）（R14），n是 1至10，优选1至4的整数，特别是1,2或3; R7是连接体; R8是二价C2-C3烷基基团。

3. 发明申请

US20070060667A1 Process for preparing pigment concentrates for use in radiation-curable coatings 审中-公开
标题翻译：用于制备用于可辐射固化涂料的颜料浓缩物的方法
公开(公告)号：US20070060667A1
公开(公告)日：2007-03-15
申请号：US10557227
申请日：2004-05-24
申请人： Tunja Jung , Thomas Healy , Andre Fuchs , Thomas Bolle
发明人： Tunja Jung , Thomas Healy , Andre Fuchs , Thomas Bolle
IPC分类号： C08K5/00 , C09D11/00
CPC分类号： C09D11/101 , B41M7/0045 , B41M7/0081 , C08F290/061 , C09B67/006
摘要： A process for preparing pigment concentrates is provided which comprises dispersing a dry pigment in a radiation polymerizable (curable) ethylenically-unsaturated compound. The concentrates to which optionally photoinitiators are added can be used for preparing radiation, preferably ultraviolet radiation, curable printing inks, paints or other coating compositions which in turn are applied in printing processes or in the painting or coating of substrates. The performance enhancement of the cured pigmented inks/paints/coatings include e.g. good tinctorial strength and gloss, as well as surface hardness, good adhesion to substrate and chemical and corrosion resistance.
摘要翻译：提供了一种制备颜料浓缩物的方法，其包括将干颜料分散在可辐射聚合的（可固化的）烯属不饱和化合物中。添加任选的光引发剂的浓缩物可以用于制备辐射，优选紫外线辐射，可固化的印刷油墨，油漆或其它涂料组合物，这些涂料组合物又被应用于印刷方法或涂料或涂料中。固化的着色油墨/油漆/涂料的性能提高包括例如。良好的着色强度和光泽度，以及表面硬度，对基材的良好粘合性以及耐化学腐蚀性。

4. 发明授权

US09199934B2 Alpha-hydroxyketones 有权
标题翻译： α-羟基酮
公开(公告)号：US09199934B2
公开(公告)日：2015-12-01
申请号：US12593025
申请日：2008-03-25
申请人： Kurt Dietliker , Peter Murer , Rinaldo Hüsler , Tunja Jung
发明人： Kurt Dietliker , Peter Murer , Rinaldo Hüsler , Tunja Jung
IPC分类号： G03F7/004 , C07C69/95 , C07D307/00 , C07D211/32 , G03F7/38 , G03F7/40 , C07C49/83 , C07C49/835 , C07C49/84 , C07C62/38 , C07C69/757 , C07C219/12 , C07C235/82 , C07D295/185 , C07D305/12 , C07F7/08 , C07F7/18
CPC分类号： C07D211/32 , C07C49/83 , C07C49/835 , C07C49/84 , C07C62/38 , C07C69/757 , C07C219/12 , C07C235/82 , C07C2601/14 , C07D295/185 , C07D305/12 , C07F7/0836 , C07F7/0838 , C07F7/1804 , G03F7/004 , G03F7/38 , G03F7/40
摘要： Compounds of the Formula (I) wherein x is an integer from 1-4; p is an integer from 1-3; q is an integer from 0-3; Ar is phenyl, naphthyl, anthryl or phenanthryl each of which optionally is substituted by one or more Cl, CN, OR5, C3-C5alkenyl or C1-C6alkyl which optionally is substituted by one or more OR6, COOR or halogen; R1 if x is 1, is OR7, O—X+, NR8R9, C1-C20alkyl optionally substituted by one or more COOR10, or is C2-C20alkyl interrupted by one ore more O, or is C2-C5alkenyl or phenyl-C1-C4alkyl; R1 if x is 2, is for example C1-C20alkylene; R1 if x is 3, is for example a tri-valent radical; R1 if x is 4, is for example a tetravalent radical; R2 and R3 are hydrogen or C1-C8alkyl, or R2 and R3 together are O, C1-C3alkylene or CH═CH; R4 is C1-C4alkyl; R5, R6, R7, R8, R9 and R10 are for example hydrogen or C1-C4alkyl; and X is a x-valent cationic counter ion; are in particular suitable as photoinitiators for the curing with UV-A light (320-450 nm).
摘要翻译：式（I）的化合物，其中x为1-4的整数; p是1-3的整数; q是0-3的整数; Ar是苯基，萘基，蒽基或菲基，其各自任选被一个或多个被一个或多个OR 6，COOR或卤素取代的C 1，CN，OR 5，C 3 -C 5链烯基或C 1 -C 6烷基取代; R 1如果x是1，是OR 7，O-X +，NR 8 R 9，任选被一个或多个COOR 10取代的C 1 -C 20烷基，或者是被一个或多个O取代的C 2 -C 20烷基，或者是C 2 -C 5烯基或苯基-C 1 -C 4烷基; R1如果x为2，例如为C 1 -C 20亚烷基; 如果x是3，则R1是例如三价基; R1如果x为4，则为例如四价基团; R 2和R 3是氢或C 1 -C 8烷基，或者R 2和R 3一起是O，C 1 -C 3亚烷基或CH = CH; R4是C1-C4烷基; R5，R6，R7，R8，R9和R10是例如氢或C1-C4烷基; X为x-阳离子抗衡离子; 特别适用于用UV-A光（320-450nm）固化的光引发剂。

5. 发明授权

US08049186B2 UV-dosis indicators 失效
标题翻译：紫外线指示剂
公开(公告)号：US08049186B2
公开(公告)日：2011-11-01
申请号：US12310260
申请日：2007-08-15
申请人： Katia Studer , Tunja Jung , Kurt Dietliker , Urs Lehmann
发明人： Katia Studer , Tunja Jung , Kurt Dietliker , Urs Lehmann
IPC分类号： G01N21/00
CPC分类号： G03C1/73 , G03C1/685 , G03C1/732 , G03F7/0045 , G03F7/105
摘要： The present application provides a composition showing a color change depending on the absorbed radiation-dose, comprising (a) an acid responsive colorant; (b) a photolatent acid; characterized in that (b) is a sulfonyloxime ester compound; and its use as a radiation dose indicator.
摘要翻译：本申请提供了根据吸收的辐射剂量显示颜色变化的组合物，其包含（a）酸响应着色剂; （b）光潜酸; 其特征在于（b）是磺酰肟酯化合物; 并将其用作辐射剂量指示剂。

6. 发明申请

US20090298962A1 PHOTOLATENT BASES FOR SYSTEMS BASED ON BLOCKED ISOCYANATES 审中-公开
标题翻译：基于堵塞的异氰酸酯的系统的光致抗体基础
公开(公告)号：US20090298962A1
公开(公告)日：2009-12-03
申请号：US12442173
申请日：2007-09-19
申请人： Katia Studer , Kurt Dietliker , Tunja Jung
发明人： Katia Studer , Kurt Dietliker , Tunja Jung
IPC分类号： C08F2/50 , C08K5/3462
CPC分类号： C08G18/8093 , C08G18/2063 , C08G18/42 , C08G18/792 , C09D5/002 , C09D5/033 , C09D5/4465 , C09D7/63 , C09D11/03 , C09D175/04 , C09J175/04
摘要： The present invention pertains to a composition comprising (a) a photolatent base; (b) a blocked isocyanate or blocked isothiocyanate and (c) a hydrogen donor compound; and its applications.
摘要翻译：本发明涉及一种组合物，其包含（a）光致变色基材; （b）封端的异氰酸酯或封闭的异硫氰酸酯和（c）氢供体化合物; 及其应用。

7. 发明申请

US20070026509A1 Novel surface-active polysiloxane photoinitiators 审中-公开
标题翻译：新型表面活性聚硅氧烷光引发剂
公开(公告)号：US20070026509A1
公开(公告)日：2007-02-01
申请号：US10558779
申请日：2004-05-28
申请人： Jonathan Rogers , Gisele Baudin , Tunja Jung , Reinhold Ohrlein , Gabriele Baisch
发明人： Jonathan Rogers , Gisele Baudin , Tunja Jung , Reinhold Ohrlein , Gabriele Baisch
IPC分类号： C12P7/62
CPC分类号： G03F7/029 , C08F2/50 , C08G77/38 , G03F7/0007 , G03F7/001 , G03F7/0037 , G03F7/0757
摘要： Polymeric photoinitiators of the formula I or II wherein n and m independently of one another are 3-5; o is 10-16; p is 4-8; R is phenyl-CO—CO—O—; Y and Y′ independently of one another are C1-C10alkylene or —[(CH2)a—O—(CH2)b]c— wherein a is 2-10, b is 0-10, c is 1-3; with the proviso that they are, however, at least 1 if the methylene group in question is between two oxygen atoms.
摘要翻译：其中n和m彼此独立的式I或II的聚合物光引发剂为3-5; o是10-16; p为4-8; R是苯基-CO-CO-O-; Y和Y'彼此独立地是C 1 -C 10亚烷基或 - [（CH 2）n）其中a为2-10，b为0-10，c为1-10个碳原子， 3; 但是，如果所讨论的亚甲基在两个氧原子之间，则它们至少为1。

8. 发明授权

US07001644B2 Surface-active photoinitiators 有权
标题翻译：表面活性光引发剂
公开(公告)号：US07001644B2
公开(公告)日：2006-02-21
申请号：US10450228
申请日：2001-12-06
申请人： Gisèle Baudin , Tunja Jung
发明人： Gisèle Baudin , Tunja Jung
IPC分类号： C08J3/24 , C08J3/28 , C08F2/46 , C08F2/50
CPC分类号： G03F7/031 , B33Y70/00 , C07C45/54 , C07C45/64 , C07C45/71 , C07C49/825 , C07C49/84 , C08F2/50 , Y10T428/12097 , Y10T428/12104
摘要： A process for the production of coatings with scratch-resistant durable surfaces that comprise as photoinitiator (B) in a photocurable formulation at least one surface-active photoinitiator, concentrated at the surface of the formulation, of formula (Ia) or (Ib), wherein Ra is a radical of formula (IIa), Rb is a radical of formula (IIb)), or Ra and Rb are naphthyl, anthracyl, phenanthryl or a heterocyclic radical each of which is unsubstituted or substituted; R1, R2, R3, R4, R5, R6, R7, R8, R9 and R10 are, for example, each independently of the others hydrogen; A-Y; C1–C12alkyl, halogen or phenyl; R11 and R12 are, for example, C1–C12 alkyl; X is —OR20 or —N(R21)(R22); R20 is, for example, hydrogen or C1–C4alkyl; R21 and R22 are, for example, hydrogen or C1–C12 alkyl; X1 is, for example, —O—; Y is, for example, a single bond or —O—; Y1 is, for example, a single bond; and A is, for example, C6–C30alkyl.
摘要翻译：一种用于生产具有抗划伤耐久表面的涂层的方法，其在光固化制剂中包含作为光引发剂（B）的至少一种表面活性光引发剂，其在制剂的表面浓缩，式（Ia）或（Ib），其中R a a是式（IIa）的基团，R b b是式（IIb）的基团）或R a a和R a b是萘基，蒽基，菲基或杂环基，其各自为未取代或取代的; R 1，R 2，R 3，R 4，R 5， R 6，R 7，R 8，R 9和R 10是，例如，各自独立地为氢; A-Y; C 1 -C 12烷基，卤素或苯基; R 11和R 12是例如C 1 -C 12烷基; X是-OR 20或-N（R 21）（R 22）; R 20是例如氢或C 1 -C 4烷基; R 21和R 22是例如氢或C 1 -C 12烷基; X 1是例如-O-; Y是例如单键或-O-; Y 1是例如单键; A是例如C 6 -C 30烷基。

9. 发明授权

US06929828B2 Surface-active photoinitiators 失效
公开(公告)号：US06929828B2
公开(公告)日：2005-08-16
申请号：US10432301
申请日：2001-12-06
申请人： Gisèle Baudin , Tunja Jung
发明人： Gisèle Baudin , Tunja Jung
IPC分类号： C08F2/46 , C08F2/50 , G03F7/031 , B05D3/02 , B05D3/06
CPC分类号： C08F2/50 , B33Y70/00
摘要： A process for the production of coatings having scratch-resistant durable surfaces, in which there is used a photocurable formulation comprising a surface-active photoinitiator, concentrated at the surface of the formulation, of formula (Ia) or (Ib), wherein R and R3 are, for example, a radical of formula (II); R1 is, for example, hydrogen, A1-X1- or a radical of formula (II); R2 is, for example, unsubstituted or substituted C1-C12alkyl or A2-X2-; R4 is, for example, hydrogen or A4-X4-; R5 is, for example, hydrogen or A5-X5- or is a radical of formula (II); R6, R7, R8, R9 and R10 are each independently of the others, for example, hydrogen, A-X- , A3-X3- or C1-C12alkyl; A, A1, A2, A3, A4 and A5 are each independently of the others, for example, a surface-active radical of formula (III); n is a number from 1 to 1000, m is a number from 0 to 100; p is a number from 0 to 10 000; R18, R19, R20, R21, G1 and G2 are, for example, C1-C18alkyl; and X, X1, X2, X3, X4 and X5 are, for example, a single bond.

10. 发明申请

US20090076200A1 Letter with continuation application 有权
标题翻译：信继续申请
公开(公告)号：US20090076200A1
公开(公告)日：2009-03-19
申请号：US12291604
申请日：2008-11-12
申请人： Gisele Baudin , Kurt Dietliker , Tunja Jung
发明人： Gisele Baudin , Kurt Dietliker , Tunja Jung
IPC分类号： C08K5/3442
CPC分类号： C07D487/04 , B33Y70/00 , G03F7/0045 , G03F7/0295 , G03F7/031
摘要： Base-polymerizable or base-crosslinkable compositions comprising select bicyclic amines with benzylic substitution undergo photochemically induced, base-catalysed reactions upon photochemical conversion of the benzylically substituted amine to an amidine derivative.
摘要翻译：包含具有苄基取代的选择性双环胺的碱性可聚合或碱交联组合物在苄基取代的胺对脒衍生物进行光化学转化时经光学诱导的碱催化反应。

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