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1. 发明申请

US20140230691A1 COATING AND A METHOD FOR PREPARING THEREOF 审中-公开
标题翻译：涂料及其制备方法
公开(公告)号：US20140230691A1
公开(公告)日：2014-08-21
申请号：US14237149
申请日：2012-08-02
申请人： Riku Talja , Jarmo Ropponen , Hanne Wikberg , Kristiina Poppius-Levlin , Ali Harlin
发明人： Riku Talja , Jarmo Ropponen , Hanne Wikberg , Kristiina Poppius-Levlin , Ali Harlin
IPC分类号： C09D101/10
CPC分类号： C09D101/10 , C08B3/10 , C08B37/0057 , C09D105/14 , D21H19/20 , D21H19/34 , D21H19/52 , D21H19/56
摘要： The invention relates to a method for preparing a thermoplastic coating on a substrate from a hemicellulose polymer or a cellulose polymer wherein the method comprises at least following steps: —providing a cellulose polymer or a hemicellulose polymer having at least one hydroxyl group which can be used for forming cellulose or hemicellulose ester, —reacting hemicellulose polymer or cellulose polymer with a residue originating to fatty acid with an aliphatic carbon tail of 4-28 carbons or ester thereof, for obtaining hemicellulose fatty acid ester or cellulose fatty acid ester, —dispersing the hemicellulose fatty acid ester or cellulose fatty acid ester into aqueous solution, —dispersion coating a substrate with dispersed hemicellulose fatty acid ester or cellulose fatty acid ester for preparing a coated substrate and —heating the coated substrate for preparing a substrate provided with a coating, so that the substrate provided with a coating is heat-sealable with the same substrate provided with said coating or with an uncoated substrate.
摘要翻译：本发明涉及一种从半纤维素聚合物或纤维素聚合物制备基材上的热塑性涂层的方法，其中该方法包括至少以下步骤： - 提供具有至少一个可以使用的羟基的纤维素聚合物或半纤维素聚合物用于形成纤维素或半纤维素酯，将具有4-28个碳原子的脂肪族碳末端的脂肪酸残基的半纤维素聚合物或纤维素聚合物或其酯用于获得半纤维素脂肪酸酯或纤维素脂肪酸酯，分散半纤维素脂肪酸酯或纤维素脂肪酸酯转化成水溶液，用分散的半纤维素脂肪酸酯或纤维素脂肪酸酯分散底物，制备涂布的基材，并加热涂布的基材以制备具有涂层的基材，因此设置有涂层的基板与相同的可热封提供有所述涂层或未涂覆的基底的基底。

2. 发明授权

US09079978B2 Treatment of fibres to endure processing 有权
标题翻译：处理纤维以忍受加工
公开(公告)号：US09079978B2
公开(公告)日：2015-07-14
申请号：US13257435
申请日：2010-03-18
申请人： Jari Räsänen , Tapani Penttinen , Ali Harlin , Jaakko Hiltunen , Hanne Wikberg , Tekla Tammelin
发明人： Jari Räsänen , Tapani Penttinen , Ali Harlin , Jaakko Hiltunen , Hanne Wikberg , Tekla Tammelin
IPC分类号： D21H11/20 , C08B3/20 , C08B3/14 , D21H17/14 , D21H21/14 , D21H27/10
CPC分类号： C08B3/20 , C08B3/14 , D21H11/20 , D21H17/14 , D21H21/14 , D21H27/10
摘要： The invention relates to a method of treating chemical pulp fibers by a polymerizing hydroxy acid, the fibers thus obtained and the products refined from them. In the method, the hydroxy acid reacts with the reactive groups of the fibers in the presence of a catalyst, forming ester bonds. The following units of the same hydroxy acid are oligomerized and/or polymerized to these grafted acid residues. The fibers thus treated and the products refined thereof endure better processing stages that include drawing and stretching than untreated fibers.
摘要翻译：本发明涉及一种通过聚合羟基酸，如此获得的纤维和从其中精炼的产品来处理化学纸浆纤维的方法。在该方法中，羟基酸在催化剂存在下与纤维的反应性基团反应，形成酯键。以下相同羟基酸的单元被低聚和/或聚合到这些接枝的酸残基。如此处理的纤维和其精制产品具有比未处理的纤维更好的加工阶段，包括拉伸和拉伸。

3. 发明申请

US20120097352A1 TREATMENT OF FIBRES TO ENDURE PROCESSING 有权
标题翻译：处理纤维以保持加工
公开(公告)号：US20120097352A1
公开(公告)日：2012-04-26
申请号：US13257435
申请日：2010-03-18
申请人： Jari Räsänen , Tapani Penttinen , Ali Harlin , Jaakko Hiltunen , Hanne Wikberg , Tekla Tammelin
发明人： Jari Räsänen , Tapani Penttinen , Ali Harlin , Jaakko Hiltunen , Hanne Wikberg , Tekla Tammelin
IPC分类号： D21H13/02
CPC分类号： C08B3/20 , C08B3/14 , D21H11/20 , D21H17/14 , D21H21/14 , D21H27/10
摘要： The invention relates to a method of treating chemical pulp fibres by a polymerizing hydroxy acid, the fibres thus obtained and the products refined from them. In the method, the hydroxy acid reacts with the reactive groups of the fibres in the presence of a catalyst, forming ester bonds. The following units of the same hydroxy acid are oligomerized and/or polymerized to these grafted acid residues. The fibres thus treated and the products refined thereof endure better processing stages that include drawing and stretching than untreated fibres.
摘要翻译：本发明涉及一种通过聚合羟基酸，如此获得的纤维和从其中精炼的产品来处理化学纸浆纤维的方法。在该方法中，羟基酸在催化剂存在下与纤维的反应性基团反应，形成酯键。以下相同羟基酸的单元被低聚和/或聚合到这些接枝的酸残基。如此处理的纤维和其精制产品具有比未处理的纤维更好的加工阶段，包括拉伸和拉伸。

4. 发明授权

US09657147B2 Method for preparing glycolide polyester by ring opening polymerization 有权
公开(公告)号：US09657147B2
公开(公告)日：2017-05-23
申请号：US14123065
申请日：2012-05-23
申请人： Jun Shan , Mika Härkönen , Jarmo Ropponen , Ali Harlin , Harri Heikkinen , Virpi Rämö , Thomas Gädda , Leena Nurmi , Pia Willberg-Keyriläinen
发明人： Jun Shan , Mika Härkönen , Jarmo Ropponen , Ali Harlin , Harri Heikkinen , Virpi Rämö , Thomas Gädda , Leena Nurmi , Pia Willberg-Keyriläinen
IPC分类号： C08G63/82 , C08J3/20 , C08G63/06 , C08G63/81 , C08G63/87
CPC分类号： C08J3/203 , C08G63/06 , C08G63/81 , C08G63/82 , C08G63/823 , C08G63/87 , Y10T428/2982
摘要： The present invention relates to a method for preparation a glycolide polyester by ring opening polymerization characterized in that glycolide monomer with optional co-monomer(s) of cyclic ester(s) is/are subjected to ring opening polymerization in the presence of a dispersion stabilizer and a catalyst, said catalyst being selected for precipitating glycolide homopolymer or copolymer from solvent, said solvent being selected so that the glycolide monomer and the optional co-monomer(s), the dispersion stabilizer and the catalyst are soluble therein but said glycolide homopolymer or copolymer is non-soluble. The present invention further relates to an in situ ring opening polymerizing process product, and to use of said glycolide polyester, and to further processing of said glycolide polyester.

5. 发明申请

US20120160433A1 PROCESS FOR PRODUCING MICROFIBRILLATED CELLULOSE 有权
标题翻译：生产微晶纤维素的方法
公开(公告)号：US20120160433A1
公开(公告)日：2012-06-28
申请号：US13382573
申请日：2010-07-02
申请人： Marianna Vehvilainen , Taina Kamppuri , Maarit Peltola , Ali Harlin , Pertti Nousiainen
发明人： Marianna Vehvilainen , Taina Kamppuri , Maarit Peltola , Ali Harlin , Pertti Nousiainen
IPC分类号： D21B1/16
CPC分类号： D21H11/18 , D21C5/005 , D21C9/007 , D21H11/20 , D21H17/005
摘要： A process for treating cellulosic fibres comprises mechanically pre-treating the fibres followed by treating the fibres with an enzyme and thereafter mixing the fibres with a solution comprising an alkali metal hydroxide followed by mechanically treating the fibres to form microfibrillated cellulose. In this way it is possible to produce microfibrillated cellulose (MFC) in an improved and energy efficient way.
摘要翻译：用于处理纤维素纤维的方法包括机械预处理纤维，然后用酶处理纤维，然后将纤维与包含碱金属氢氧化物的溶液混合，然后机械处理纤维以形成微纤化纤维素。以这种方式，可以以改进和节能的方式生产微纤维化纤维素（MFC）。

6. 发明申请

US20110223401A1 FIBROUS PRODUCT HAVING A BARRIER LAYER AND METHOD OF PRODUCING THE SAME 审中-公开
标题翻译：具有障碍层的纤维制品及其生产方法
公开(公告)号：US20110223401A1
公开(公告)日：2011-09-15
申请号：US13122341
申请日：2009-10-01
申请人： Ali Harlin , Eero Iiskola , Mika Vähä-Nissi , Terhi Hirvikorpi , Tuomas Mustonen
发明人： Ali Harlin , Eero Iiskola , Mika Vähä-Nissi , Terhi Hirvikorpi , Tuomas Mustonen
IPC分类号： B32B7/02 , B32B5/00 , C23C16/44 , C23C16/513 , C23C16/06 , C23C16/22
CPC分类号： C23C16/45555 , C23C16/45525 , D21H19/18 , D21H19/20 , D21H19/52 , D21H19/54 , D21H23/50 , D21H25/04 , D21H27/10 , Y10T428/24975 , Y10T428/265
摘要： The invention relates to barrier products and a method for the manufacture thereof. The product comprises a fibrous substrate, a coating layer on at least one surface of the fibrous substrate, and a barrier applied on the coating layer, comprising a thin film with a thickness of less than about 1 micrometer and capable of providing barrier properties to the fibrous product. According to the invention, the coating layer comprises biopolymer, which have been found to be suitable for atomic layer deposition of thin barrier films comprising e.g. metal oxide. Improved oxygen, water vapour and aroma barrier properties can be achieved by the invention for papers and paperboards for packaging purposes.
摘要翻译：本发明涉及阻挡产品及其制造方法。该产品包括纤维基材，纤维基材的至少一个表面上的涂层和涂覆在涂层上的阻挡层，其包含厚度小于约1微米的薄膜，并能够提供阻挡性能纤维制品。根据本发明，涂层包括生物聚合物，其已被发现适合于薄膜阻挡膜的原子层沉积，所述薄阻挡膜包括例如金属氧化物。通过本发明，用于包装目的的纸和纸板可以实现改善的氧气，水蒸气和香气阻隔性能。

7. 发明授权

US5684097A Process for preparing polyethylene 失效
标题翻译：制备聚乙烯的方法
公开(公告)号：US5684097A
公开(公告)日：1997-11-04
申请号：US475842
申请日：1995-06-07
申请人： Ari Palmroos , Ali Harlin , Antero Ahvenainen , Jouni Takakarhu , Aimo Sahila
发明人： Ari Palmroos , Ali Harlin , Antero Ahvenainen , Jouni Takakarhu , Aimo Sahila
IPC分类号： C08F2/14 , B01J8/24 , B01J19/24 , C08F2/06 , C08F2/34 , C08F10/02 , C08F210/16
CPC分类号： C08F10/02 , B01J19/2435 , B01J19/245 , B01J8/24 , B01J2219/00051 , B01J2219/00166 , B01J2219/00173 , C08F210/16
摘要： A process for producing polyethylene compositions in the presence of a catalytic system of ethylene polymerizing catalyst and cocatalyst in a multistage continuous reaction sequence consisting of successive liquid phase and gas phase polymerizations is disclosed. In the first step of the process, ethylene and optionally hydrogen and comonomer are polymerized in a first loop reactor in a low boiling hydrocarbon medium in the presence of ethylene polymerizing catalyst and cocatalyst. The reaction mixture is then removed and then transferred to a second loop reactor where polymerization is continued by addiing ethylene, hydrogen and optionally inert hydrocarbon, comonomers and cocatalysts. Thereafter, the reaction mixture is removed from the second loop reactor along with an essential part of the reaction medium and transferred to a gas phase reactor where polymerizing is continued in the presence of added ethylene and optionally hydrogen, comonomers and cocatalysts to form an end product. The residence time and reaction temperature being such that the proportion of the ethylene polymer produced in the first loop reactor to the end product of the process is between 1-20%.
摘要翻译：在由连续液相和气相聚合组成的多级连续反应序列中，在乙烯聚合催化剂和助催化剂催化体系存在下生产聚乙烯组合物的方法。在该方法的第一步中，在乙烯聚合催化剂和助催化剂存在下，乙烯和任选的氢和共聚单体在第一回路反应器中在低沸点烃介质中聚合。然后除去反应混合物，然后转移到第二环管反应器中，其中通过加入乙烯，氢气和任选的惰性烃，共聚单体和助催化剂继续聚合。此后，将反应混合物与反应介质的主要部分一起从第二环管反应器中除去，并转移到气相反应器中，在气相反应器中，在加入的乙烯和任选的氢，共聚单体和助催化剂的存在下，继续聚合以形成最终产物。停留时间和反应温度使得在第一回路反应器中产生的乙烯聚合物与该方法的最终产物的比例为1-20％。

8. 发明申请

US20140088252A1 METHOD FOR MAKING SPECIFIC PRODUCTS FROM POLYSACCHARIDE MOLECULE 审中-公开
标题翻译：从多糖分子制备特定产品的方法
公开(公告)号：US20140088252A1
公开(公告)日：2014-03-27
申请号：US14006797
申请日：2012-03-22
申请人： Ali Harlin , Harri Setälä , Helinä Talja
发明人： Ali Harlin , Harri Setälä , Helinä Talja
IPC分类号： C08F8/00 , C08B15/00 , C08B37/00
CPC分类号： C08F8/00 , C08B11/187 , C08B11/193 , C08B11/20 , C08B15/005 , C08B15/10 , C08B37/00 , C08B37/0057 , C08F251/00 , C08G2210/00 , C08G2650/26 , C08H8/00 , C08J3/075 , C08J3/246 , C08J5/18 , C08J2301/02 , C08J2387/00 , C08L1/02 , C08L1/08 , C08L5/00 , D06M14/04 , D06M15/263 , D06M15/285 , D06M15/3562 , D06M2101/06 , D21C9/002
摘要： A method for preparing a specific product from a polysaccharide in which at least one hydroxyl of a saccharide unit is substituted with an ether or ester moiety. The ether or ester moiety is provided with ethenyl and/or epoxy functionality for preparing an activatable polysaccharide polymer and the activatable polysaccharide polymer with ethenyl and/or epoxy functionality is optionally reacted with an additional coupling reagent, having at least two coupling functionality for preparing polysaccharide polymer with additional activatable crosslinker. Thereafter, the activatable polysaccharide polymer or the polysaccharide polymer with an additional activatable crosslinker, is activated for crosslinking the polysaccharide polymer with another polysaccharide polymer by reacting the activatable polysaccharide polymer or polysaccharide polymer with an additional activatable crosslinker with a crosslinking initiator for crosslinking the polysaccharide polymer chains with each other, for preparing a product such as hydrogel, film, coating or membrane with polysaccharide backbone.
摘要翻译：一种由糖单元的至少一个羟基被醚或酯部分取代的多糖制备特定产品的方法。醚或酯部分具有用于制备可活化多糖聚合物的乙烯基和/或环氧官能团，并且具有乙烯基和/或环氧官能团的可活化多糖聚合物任选与另外的偶联试剂反应，其具有至少两个用于制备多糖的偶联官能团聚合物与另外的活化交联剂。此后，活化的多糖聚合物或具有另外的可活化交联剂的多糖聚合物被活化，以通过使可活化的多糖聚合物或多糖聚合物与另外的可活化的交联剂与交联引发剂反应来交联多糖聚合物与多糖聚合物，以交联多糖聚合物链条，用于制备具有多糖骨架的产品如水凝胶，膜，涂层或膜。

9. 发明申请

US20120053379A1 METHOD FOR PRODUCING OLEFINIC MONOMERS FROM BIO OIL 有权
标题翻译：从生物油生产烯烃单体的方法
公开(公告)号：US20120053379A1
公开(公告)日：2012-03-01
申请号：US13146857
申请日：2010-01-29
申请人： Ali Harlin , Tapani Penttinen , Jari Räsänen , Olli Aaltonen
发明人： Ali Harlin , Tapani Penttinen , Jari Räsänen , Olli Aaltonen
IPC分类号： C07C1/20
CPC分类号： C10G51/02 , C07C11/02 , C07C11/04 , C07C11/06 , C10G3/46 , C10G3/50 , C10G3/54 , C10G9/00 , C10G9/36 , C10G11/02 , C10G2300/1014 , C10G2300/807 , C10G2400/20 , Y02P30/42
摘要： The invention relates to a method of producing olefinic monomers for the production of a polymer. The invention particularly relates to the production of tall oil-based biopolymers, such as polyolefins. In the stages of the method bio oil, with a content of over 50% of fatty acids of tall oil and no more than 25% of resin acids of tall oil, and hydrogen gas are fed into a catalyst bed (7); the oil is catalytically deoxygenated in the bed by hydrogen; the flow exiting the bed is cooled down and divided into a hydrocarbon-bearing liquid phase (10) and a gas phase; and the hydrocarbon-bearing liquid (13) is subjected to steam cracking (4) to provide a product containing polymerizing olefins. The deoxygenation in the bed can be followed by a catalytic cracking or, with a suitable catalyst, the deoxygenation and cracking can be simultaneous. The separated hydrogen-bearing gas phase can be circulated in the process.
摘要翻译：本发明涉及生产用于生产聚合物的烯烃单体的方法。本发明特别涉及妥尔油基生物聚合物如聚烯烃的生产。在方法生物油的阶段，含量超过50％的妥尔油的脂肪酸和不超过25％的妥尔油的树脂酸，并将氢气进料到催化剂床（7）中; 油通过氢气在床中催化脱氧; 离开床的流被冷却并分成含烃液相（10）和气相; 并对含烃液体（13）进行蒸汽裂化（4）以提供含有聚合烯烃的产物。床中的脱氧可能是催化裂化，或者使用合适的催化剂，脱氧和裂解可以同时进行。分离的含氢气相可以在该过程中循环。

10. 发明申请

US20070292663A1 Fabric Structure For Use In Paper Machine And Manufacturing Method Thereof 有权
标题翻译：织物结构用于造纸机及其制造方法
公开(公告)号：US20070292663A1
公开(公告)日：2007-12-20
申请号：US11632777
申请日：2005-09-12
申请人： Hannu Martikainen , Pekka Kortelainen , Tania Rautio , Mari Seppanen , Ali Harlin , Tuula Wilenius-Jaakonaho
发明人： Hannu Martikainen , Pekka Kortelainen , Tania Rautio , Mari Seppanen , Ali Harlin , Tuula Wilenius-Jaakonaho
IPC分类号： D21F1/10 , D21F7/08
CPC分类号： D21F1/0027 , Y10S162/903 , Y10T428/24802 , Y10T428/2481
摘要： The invention relates to a flexible and porous fabric structure comprising a support structure (1) and a coating material for use in a paper machine. The coating material (2) is arranged solely on the surface of the support structure (1) at a predefined location(s) so that the coating material (2) does not substantially alter the permeability properties of the support structure (1). The invention also relates to a method for manufacturing a fabric structure.
摘要翻译：本发明涉及一种柔性和多孔织物结构，其包括支撑结构（1）和用于造纸机的涂层材料。涂层材料（2）仅在预定位置处布置在支撑结构（1）的表面上，使得涂层材料（2）基本上不改变支撑结构（1）的渗透性能。本发明还涉及一种用于制造织物结构的方法。

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