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1. 发明授权

US4522762A Diisocyanate 失效
公开(公告)号：US4522762A
公开(公告)日：1985-06-11
申请号：US440565
申请日：1982-11-10
申请人： Richard W. Oertel, III , Reinhard H. Richter , Benjamin W. Tucker
发明人： Richard W. Oertel, III , Reinhard H. Richter , Benjamin W. Tucker
IPC分类号： C07C265/04 , C08G18/75 , C07C69/00 , C08G18/10
CPC分类号： C07C255/00 , C07C265/00 , C08G18/757
摘要： A novel aliphatic diisocyanate, namely 1,4-bis(2-isocyanatoethyl)cyclohexane, is disclosed. Polyurethanes derived from this diisocyanate exhibit advantageous properties. Illustratively, polyurethane elastomers prepared from the above diisocyanate, a polymeric diol and a low molecular weight diol extender, possess significantly improved resilience properties and are useful in the preparation of automobile bumpers, fenders and the like.

2. 发明授权

US4565835A Diisocyanate 失效
标题翻译：二异氰酸酯
公开(公告)号：US4565835A
公开(公告)日：1986-01-21
申请号：US715861
申请日：1985-03-25
申请人： Richard W. Oertel, III , Benjamin W. Tucker , Reinhard H. Richter
发明人： Richard W. Oertel, III , Benjamin W. Tucker , Reinhard H. Richter
IPC分类号： C07C17/16 , C08G18/75
CPC分类号： C08G18/757 , C07C17/16 , C07C255/00 , C07C265/00
摘要： A novel aliphatic diisocyanate, namely 1,4-bis(2-isocyanatoethyl)cyclohexane, is disclosed. Polyurethanes derived from this diisocyanate exhibit advantageous properties. Illustratively, polyurethane elastomers prepared from the above diisocyanate, a polymeric diol and a low molecular weight diol extender, possess significantly improved resilience properties and are useful in the preparation of automobile bumpers, fenders and the like.
摘要翻译：公开了一种新型脂族二异氰酸酯，即1,4-双（2-异氰酸根合乙基）环己烷。衍生自该二异氰酸酯的聚氨酯显示出有利的性质。说明性地，由上述二异氰酸酯，聚合二醇和低分子量二醇增量剂制备的聚氨酯弹性体具有显着改善的弹性性能，并且可用于汽车缓冲器，挡泥板等的制备。

3. 发明授权

US4379904A Novel polyurethane product 失效
标题翻译：新型聚氨酯产品
公开(公告)号：US4379904A
公开(公告)日：1983-04-12
申请号：US371534
申请日：1982-04-26
申请人： Benjamin S. Ehrlich , Richard W. Oertel, III
发明人： Benjamin S. Ehrlich , Richard W. Oertel, III
IPC分类号： C08G18/40 , C08G18/48 , C08G18/66
CPC分类号： C08G18/4018 , C08G18/4804 , C08G18/66
摘要： Improved thermoplastic polyurethane elastomers are disclosed which are the reaction product of 4,4'-methylene-bis(phenyl isocyanate); a polymeric diol; and an extender wherein the equivalent proportions of said diol to said extender fall within the range of about 1:2 to about 1:20 and the isocyanate to total hydroxyl equivalents are within the range of about 0.99:1 to 1.06:1, the improvement which comprises replacing at least about 15 percent by weight of said polymeric diol by a polyol selected from the class consisting of: (i) polyoxypropylene-polyoxyethylene glycols having a molecular weight of about 3500 to about 4500 and an ethylene oxide content of about 10 to about 60 percent by weight; (ii) polyoxypropylene-polyoxyethylene triols having a molecular weight from about 5000 to about 7000 and an ethylene oxide content of about 10 to about 40 percent by weight; and (iii) mixtures of (i) and (ii).The elastomers find particular utility in the manufacture of ski boots, hockey boots and automotive exterior panels, bumpers, fascia, and the like.
摘要翻译：公开了改进的热塑性聚氨酯弹性体，其是4,4'-亚甲基 - 双（苯基异氰酸酯）的反应产物; 聚合二醇; 和增量剂，其中所述二醇与所述增量剂的当量比例在约1:2至约1:20的范围内，异氰酸酯与总羟基当量的比例在约0.99:1至1.06:1的范围内，改进其包括用选自以下的多元醇代替至少约15重量％的所述聚合二醇：（i）分子量为约3500至约4500的聚氧丙烯 - 聚氧乙烯二醇和约10至约10的环氧乙烷含量，约60重量％（ii）分子量为约5000至约7000并且环氧乙烷含量为约10至约40重量％的聚氧丙烯 - 聚氧乙烯三醇; 和（iii）（i）和（ii）的混合物。弹性体在制造滑雪靴，曲棍球靴和汽车外部面板，保险杠，面板等方面具有特别的用途。

4. 发明授权

US4420603A Continuous, solvent-free process for preparing thermoplastic polyamides and polyesteramides 失效
标题翻译：连续，无溶剂的制备热塑性聚酰胺和聚酯酰胺的方法
公开(公告)号：US4420603A
公开(公告)日：1983-12-13
申请号：US424419
申请日：1982-09-27
申请人： Robert G. Nelb, II , Richard W. Oertel, III
发明人： Robert G. Nelb, II , Richard W. Oertel, III
IPC分类号： C08G18/00 , C08G18/08 , C08G18/34 , C08G18/42 , C08G69/28 , C08G69/44 , C08G18/32
CPC分类号： C08G18/0895 , C08G18/341 , C08G18/4263 , C08G69/28 , C08G69/44
摘要： A continuous, solvent-free process is described for the preparation of thermoplastic polyamides and polyester-amides by the reaction of the appropriate organic diisocyanate and dicarboxylic acid or difunctional carboxylic acid-terminated polyester.
摘要翻译：描述了通过适当的有机二异氰酸酯和二羧酸或双官能羧酸封端的聚酯的反应制备热塑性聚酰胺和聚酯 - 酰胺的连续的无溶剂方法。

5. 发明授权

US4567236A Novel polymer blends 失效
标题翻译：新型聚合物共混物
公开(公告)号：US4567236A
公开(公告)日：1986-01-28
申请号：US514414
申请日：1983-07-18
申请人： David J. Goldwasser , Richard W. Oertel, III
发明人： David J. Goldwasser , Richard W. Oertel, III
IPC分类号： C08G18/00 , C08G18/65 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L25/14 , C08L27/00 , C08L33/00 , C08L33/02 , C08L33/08 , C08L51/00 , C08L51/02 , C08L75/00 , C08L75/04 , C08L101/00 , C08F8/30
CPC分类号： C08L75/04 , C08G18/6505 , C08L25/14 , C08L33/08
摘要： Blends are disclosed of a clear polyurethane plastic and a minor amount (up to 30 parts by weight per 100 parts by weight of blend) of an incompatible polymeric impact modifier. The resulting blends exhibit properties (high impact resistance, high flexural modulus and resistance to heat) comparable to those of engineering plastics such as nylon.
摘要翻译：公开了一种不透明的聚氨酯塑料和少量（高达30重量份/ 100重量份共混物）的不相容的聚合抗冲改性剂的共混物。所得共混物表现出与工程塑料如尼龙相当的性能（高抗冲击性，高弯曲模量和耐热性）。

6. 发明授权

US4420602A Melt-polymerization process for the preparation of thermoplastic polyamides and polyesteramides 失效
标题翻译：用于制备热塑性聚酰胺和聚酯酰胺的熔融聚合方法
公开(公告)号：US4420602A
公开(公告)日：1983-12-13
申请号：US424418
申请日：1982-09-27
申请人： Henry W. Bonk , Robert G. Nelb, II , Richard W. Oertel, III
发明人： Henry W. Bonk , Robert G. Nelb, II , Richard W. Oertel, III
IPC分类号： C08G18/00 , C08G18/08 , C08G18/34 , C08G18/42 , C08G18/32
CPC分类号： C08G18/0895 , C08G18/341 , C08G18/4263
摘要： A melt-polymerization process is described for the preparation of thermoplastic polyamides and polyesteramides by reaction of the appropriate organic diisocyanate and dicarboxylic acid or difunctional carboxylic acid-terminated polyol. The process, which can be conducted in a batch or continuous manner, comprises the steps of admixing the reactants (preferably in the liquid state), heating the mixed reactants at reaction temperature in a manner such that eliminated carbon dioxide can be vented freely, allowing the reaction to proceed until approximately 25-95 percent (preferably at least 50 percent) of the theoretical carbon dioxide has been eliminated and reducing the resulting intermediate to a powder before completing the reaction by melting, homogenizing, and devolatilizing.
摘要翻译：描述了通过合适的有机二异氰酸酯和二羧酸或双官能的羧酸封端的多元醇的反应来制备热塑性聚酰胺和聚酯酰胺的熔融聚合方法。可以以间歇或连续方式进行的方法包括以下步骤：将反应物混合（优选为液态），在反应温度下加热混合的反应物，使得可以自由排出二氧化碳，允许直到理论二氧化碳的大约25-95％（优选至少50％）的反应进行消除，并且在通过熔融，均化和脱挥发分完成反应之前将所得中间体还原成粉末。

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