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    • 3. 发明授权
    • Bentonite-sulfate fabric softening particulate agglomerate, processes
for manufacture and use thereof, and detergent compositions containing
it
    • 硫酸膨润土织物软化颗粒附聚物,其制备方法及其用途,以及含有它的洗涤剂组合物
    • US4609473A
    • 1986-09-02
    • US711796
    • 1985-03-14
    • Pallassana N. RamachandranCharles J. Schramm, Jr.H. Peter LazeckyMartin D. Reinish
    • Pallassana N. RamachandranCharles J. Schramm, Jr.H. Peter LazeckyMartin D. Reinish
    • C11D3/04C11D3/00C11D3/12C11D3/37C11D3/60D06M11/00
    • C11D3/10C11D3/001C11D3/126
    • Agglomerated particles of finely divided fabric softening bentonite and sodium sulfate particles have been found to possess improved fabric softening properties, compared to agglomerated bentonite, especially when employed in the hand washing of laundry which is subsequently line dried. Such agglomerates are also of excellent particle strength and are readily dispersible in water. The described product may be made by agglomerating finely divided bentonite and sodium sulfate powders with the aid of excess moisture, after which the agglomerated particles resulting are dried and those of desired size, preferably in the No's. 30 to 100 sieve size range (U.S.), are obtained. The fabric softening agglomerate made may be mixed with spray dried synthetic organic anionic detergent composition beads of about the same or lower bulk density, preferably in the 0.3 to 0.5 g./cc. range, with about 5 to 30% of the agglomerate particles being present, to make a non-segregating fabric softening particulate detergent composition of improved softening properties. Detergency, soil anti-redeposition properties, bead physical characteristics and processing are improved by the presence in the detergent composition of a minor proportion of a water soluble copolymer of maleic and acrylic acids which, unlike other polymers which can impart such properties to detergent compositions, does not adversely affect the softening of hand washed laundry by the present agglomerate. Soda ash may be used in place of some or all of the sodium sulfate of the agglomerate and a good softening additive will also be obtained.
    • 已经发现与聚集的膨润土相比,细碎的织物软化膨润土和硫酸钠颗粒的聚集的颗粒具有改善的织物软化性能,特别是当用于手洗洗衣机时,随后进行干燥。 这种附聚物也具有优异的颗粒强度,并且易于分散在水中。 所描述的产品可以通过借助于过量水分使细碎的膨润土和硫酸钠粉末凝聚而制成,之后将所得的附聚颗粒干燥,所需的尺寸,优选为No。 30至100筛分尺寸范围(美国)。 制成的织物软化附聚物可以与大约相同或更低堆积密度的喷雾干燥的合成有机阴离子洗涤剂组合物珠混合,优选为0.3至0.5g./cc。 存在约5至30%的附聚颗粒,以使非偏析织物软化颗粒状洗涤剂组合物具有改善的软化性能。 通过在洗涤剂组合物中存在少量马来酸和丙烯酸的水溶性共聚物来改善洗涤剂,土壤抗再沉积性质,珠粒物理特性和加工,与可以赋予洗涤剂组合物这种性质的其它聚合物不同, 不会对目前的附聚物的洗手衣物的软化产生不良影响。 可以使用苏打灰代替附聚物的一些或全部硫酸钠,并且还可以获得良好的软化添加剂。
    • 5. 发明授权
    • Alpha-sulfo-fatty acid ester and/or amide salt(s) detergent laundry bars
and processes for manufacture thereof
    • α-磺基脂肪酸酯和/或酰胺盐洗涤剂洗涤条及其制造方法
    • US4707289A
    • 1987-11-17
    • US836910
    • 1986-03-06
    • Pallassana N. RamachandranPatrizia Barone
    • Pallassana N. RamachandranPatrizia Barone
    • C11D1/28C11D3/12C11D17/00
    • C11D17/0069C11D1/28C11D3/126
    • Detergent laundry bars of acceptable mildness, detergency, foaming properties, processing characteristics and resistance to breakage are described which are based on built water soluble salts of alpha-sulfo-higher fatty acid-lower alcohol ester detergent and/or alpha-sulfo-higher fatty acid-amide, and which contain bentonite, which acts as a bodying agent for the laundry bars, facilitating production thereof, and contributing fabric softening properties to laundry washed with such laundry bars. When the bentonite is omitted or is replaced by water insoluble filler, such as calcium carbonate powder, and the alpha-sulfo-fatty acid derivative detergent is employed as an aqueous solution, bars made are not of acceptable hardness and such compositions are not satisfactorily processable in conventional soapmaking apparatuses.Also described are processes for converting aqueous solutions of alpha-sulfo-fatty acid derivative detergent to solid form by treatment with bentonite, and for making detergent laundry bars from such solidified detergent.
    • 描述了基于建立的α-磺基 - 高级脂肪酸 - 低级醇酯洗涤剂和/或α-磺基 - 高级脂肪酸的水溶性盐的可接受的温和性,洗涤性,起泡性,加工特性和耐断裂性的洗涤剂洗涤条 酸 - 酰胺,并且其含有膨润土,其膨胀物作为洗衣条的固化剂,促进其生产,并且对用这种洗衣条洗涤的衣物提供织物柔软性。 使用碳酸钙粉末和α-磺基脂肪酸衍生物洗涤剂作为水溶液时,不使用膨润土或被水不溶性填料代替时,制成的棒不具有可接受的硬度,而且这些组成不能令人满意地加工 在传统的肥皂制造装置中。 还描述了通过用膨润土处理将α-磺基脂肪酸衍生物洗涤剂的水溶液转化成固体形式,并且从这种固化的洗涤剂制备洗涤剂洗涤条的方法。
    • 6. 发明授权
    • Fabric softening heavy duty liquid detergent and process for manufacture
thereof
    • 织物软化重垢液体洗涤剂及其制造方法
    • US4469605A
    • 1984-09-04
    • US449261
    • 1982-12-13
    • Pallassana N. RamachandranPaul S. Grand
    • Pallassana N. RamachandranPaul S. Grand
    • B01F17/04B01F17/12B01F17/54C11D1/29C11D1/37C11D3/00C11D3/12D06M13/24
    • C11D3/1266C11D1/37C11D3/0015C11D1/29
    • A fabric softening heavy duty liquid detergent, useful for both cleaning and softening laundry, includes certain proportions of sodium linear higher alkylbenzene sulfonate, sodium alkyl polyethoxy sulfate, builder salt (highly preferably a mixture of sodium tripolyphosphate and sodium carbonate), finely divided swelling bentonite and water. Such product is a stable pourable liquid, convenient for use in washing machines, for hand washing of laundry and for pre-treatment of badly soiled portions of items to be laundered. Preferably, the liquid detergent comprises about 9% of sodium linear tridecylbenzene sulfonate, about 2% of sodium alkyl polyethoxy sulfate wherein the alkyl is of 12 to 15 carbon atoms and the polyethoxy is of 3 ethylene oxide groups, 10 to 17% of sodium tripolyphosphate, e.g., 12% and 15%, 2 to 6% of sodium carbonate, e.g., 2% and 6%, about 12% of Wyoming bentonite, and 55 to 65% of water. Also within the invention is a process for manufacturing such liquid detergent wherein the swelling bentonite is admixed with a mixture of the other detergent composition components except for part of the water, which is added last to the mixture of such components and the bentonite.
    • 用于清洁和软化衣物的织物软化重垢液体洗涤剂包括一定比例的线性高级烷基苯磺酸钠,烷基聚乙氧基硫酸钠,助洗剂盐(高度优选三聚磷酸钠和碳酸钠的混合物),细碎膨胀膨润土 和水。 这种产品是稳定的可倾倒液体,便于在洗衣机中使用,用于洗手洗衣和预处理待洗涤物品的脏污部分。 优选地,液体洗涤剂包含约9%的直链十三烷基苯磺酸钠,约2%的烷基聚乙氧基硫酸钠,其中烷基为12至15个碳原子,聚乙氧基为3个环氧乙烷基团,10至17%的三聚磷酸钠 ,例如12%和15%,2至6%的碳酸钠,例如2%和6%,约12%的怀俄明膨润土和55至65%的水。 在本发明中也是制造这种液体洗涤剂的方法,其中溶胀膨润土与除了部分水之外的其它洗涤剂组合物组分的混合物混合,最后再添加到这些组分的混合物和膨润土中。
    • 7. 发明授权
    • Fabric softening and antistatic liquid detergent compositions
    • 织物软化和抗静电液体洗涤剂组合物
    • US4873001A
    • 1989-10-10
    • US207843
    • 1988-06-17
    • Pallassana N. RamachandranPaul S. GrandRobert A. Bauman
    • Pallassana N. RamachandranPaul S. GrandRobert A. Bauman
    • C11D1/52C11D3/00C11D3/12
    • C11D1/521C11D3/0015C11D3/1266
    • A fabric softening and antistatic liquid laundry detergent composition includes synthetic anionic organic detergent, bentonite and higher aliphatic isostearamide antistat in an aqueous medium. The liquid detergent composition preferably contains a builder for the detergent component, such as polyphosphate and/or carbonate. Also within the invention is a process for washing and drying laundry, utilizing the described liquid detergent in the washing operation, whcih produces laundry that is soft and static-free or of low electrostatic charge despite having been subjected to a tumble drying process or similar static charging drying process, which normally causes laundry of similar fabrics to become electrostatically charged, resulting in objectionable "static cling". Also described is a "softstat" product which comprises bentonite fabric softener and N-isostearamide antistat in an aqueous medium, which is intended for addition to liquid detergent compositions or to wash waters to make them fabric softening and antistatic, so that laundry washed with them will be soft to the touch and free of static cling.
    • 织物软化和抗静电液体衣物洗涤剂组合物包括在水性介质中的合成阴离子有机洗涤剂,膨润土和高级脂肪异硬脂酰胺抗静电剂。 液体洗涤剂组合物优选含有用于洗涤剂组分的助洗剂,例如多磷酸盐和/或碳酸盐。 本发明还涉及一种在洗涤操作中利用所述液体洗涤剂洗涤和干燥衣物的方法,即使经受了滚筒干燥过程或类似的静电,也可产生软静电或静电荷低的衣物 充电干燥过程通常使类似织物的衣物变得静电,导致令人反感的“静电粘附”。 还描述了一种“软静态”产品,其在水性介质中包含膨润土织物柔软剂和N-异硬脂酰胺抗静电剂,其旨在添加到液体洗涤剂组合物中或洗涤水以使织物软化和抗静电,使得衣物用它们洗涤 将柔软触感并且没有静电附着。
    • 8. 发明授权
    • Breakage resistant higher fatty alcohol sulfate detergent laundry bars
    • 耐破坏的高级脂肪醇硫酸盐洗涤剂洗衣条
    • US4806273A
    • 1989-02-21
    • US74587
    • 1987-07-17
    • Patrizia BaronePallassana N. Ramachandran
    • Patrizia BaronePallassana N. Ramachandran
    • C11D1/14C11D1/52C11D1/65C11D3/20C11D17/00
    • C11D3/2065C11D1/652C11D17/0069C11D1/14C11D1/523
    • Detergent laundry bars of improved physical characteristics, including improved resistance to breakage on handling, are described which include 10 to 35% of sodium higher fatty alcohol sulfate detergent, 10 to 60% of builder for the detergent mixture, a bodying proportion, in the range of 10 to 60% of water insoluble powder, 1 to 10% of higher fatty lower alkanolamide, 0.2 to 5% of glycerol, with the ratio of alkanolamide to glycerol being in the range of 1:5 to 25:1, and 5 to 20% of water (including that which is removable from any hydrate components when the bar is subjected to heating at 105.degree. C. for two hours). Preferably the invented bars will comprise 10 to 25% of sodium coco alcohol sulfate or equivalent sodium higher fatty alcohol sulfate, up to 5 or 10% of secondary detergents, 15 to 30% of sodium tripolyphosphate, 5 to 25% of sodium carbonate, 0 to 10% of sodium silicate, 10 to 50% of calcium carbonate powder, 3 to 7% of cocomonoethanolamide; 0.3 to 1% of glycerol, with the ratio of cocomonoethanolamide:glycerol being in the range of 2:1 to 25:1, and 5 to 12% of water. The described bars, which preferably are milled and plodded, exhibit better resistance to breakage on handling than do bars of similar formulas which do not contain the ethanolamide and glycerol, which is very surprising. They are also of acceptable hardness and do not slough or erode excessively on standing in contact with water, and in use. The bars process satisfactorily and foam well, too.
    • 描述了具有改善的物理特性的洗涤剂洗涤条,包括改进的耐操作性破坏性,其包括10至35%的高级高级脂肪醇硫酸盐洗涤剂,10至60%的洗涤剂混合物助洗剂,占据比例 10〜60%的水不溶性粉末,1〜10%的高级脂肪低级烷醇酰胺,0.2〜5%的甘油,烷醇酰胺与甘油的比例在1:5〜25:1的范围内,5〜 20%的水(包括当条在105℃加热2小时时可从任何水合物成分中除去的水)。 优选地,本发明的棒将包含10-25%的椰子醇硫酸钠或当量的高级高级脂肪酸硫酸钠,至多5或10%的二次洗涤剂,15至30%的三聚磷酸钠,5至25%的碳酸钠,0 至10%的硅酸钠,10至50%的碳酸钙粉末,3至7%的共聚乙醇酰胺; 0.3至1%的甘油,其中共聚乙醇酰胺:甘油的比例在2:1至25:1的范围内,和5至12%的水。 所描述的棒,其优选地被研磨和分散,与不含乙醇酰胺和甘油的类似配方的条形物相比,在处理方面表现出更好的抗破裂性,这是非常令人惊讶的。 它们也具有可接受的硬度,并且在与水接触和使用时不会过度脱落或腐蚀。 酒吧过程也令人满意,泡沫也很好。
    • 9. 发明授权
    • Fabric softening compositions and methods for manufacture thereof
    • 织物柔软组合物及其制造方法
    • US4203851A
    • 1980-05-20
    • US916072
    • 1978-06-16
    • Pallassana N. Ramachandran
    • Pallassana N. Ramachandran
    • C11D17/00D06M23/00D06M13/34
    • D06M23/00C11D17/0034
    • A free flowing particulate fabric softening composition includes base beads, of a water soluble or water insoluble builder for a synthetic organic detergent, impregnated with a fabric softening agent. For example, the base beads may be of a mixture of a zeolite softener (usually a hydrated sodium aluminosilicate), sodium bicarbonate and sodium silicate and the softening agent may be a quaternary ammonium compound, such as distearyl dimethyl ammonium methyl sulfate, with at least 80% and preferably more of the softener being within the original peripheries of the base beads. Also within the invention are softener-detergent compositions which incorporate the described particulate softening composition, a method of using the softening composition in conjunction with a synthetic organic detergent to wash and soften laundry fabrics and a method for the manufacture of the particulate softening compositions.
    • 自由流动的颗粒织物柔软组合物包括用织物软化剂浸渍的用于合成有机洗涤剂的水溶性或水不溶性助洗剂的底部珠粒。 例如,碱性珠粒可以是沸石软化剂(通常为水合铝硅酸钠),碳酸氢钠和硅酸钠的混合物,并且软化剂可以是季铵化合物,例如二硬脂基二甲基甲基硫酸铵,至少具有 80%,优选更多的软化剂位于原始珠粒的原始周边内。 本发明还包括掺入所述颗粒软化组合物的软化剂 - 洗涤剂组合物,使用软化组合物与合成有机洗涤剂结合来洗涤和软化洗衣织物的方法以及制备颗粒软化组合物的方法。
    • 10. 发明授权
    • Alkyl ethoxylate sulfate detergent laundry bars and processes for
manufacture thereof
    • 烷基乙氧基硫酸盐洗涤剂洗衣条及其制造方法
    • US4721581A
    • 1988-01-26
    • US836908
    • 1986-03-06
    • Pallassana N. RamachandranPatrizia Barone
    • Pallassana N. RamachandranPatrizia Barone
    • C11D1/29C11D3/12C11D17/00
    • C11D3/126C11D1/29C11D17/0069
    • Detergent laundry bars of acceptable mildness, foaming properties and processing characteristics are described which are based on built higher fatty alcohol ethoxylate sulfate detergent and which contain bentonite, which acts as a bodying agent for the laundry bars, facilitating production thereof, and contributes fabric softening properties to laundry washed with such laundry bar. When the bentonite is omitted or is replaced by water insoluble filler, such as calcium carbonate powder, bars made are not of acceptable hardness and such compositions are not satisfactorily processable in conventional soapmaking apparatuses.Also described are processes for converting aqueous solutions of higher fatty alcohol ethoxylate sulfate detergent to solid form by treatment with bentonite, and for making detergent laundry bars from such solidified detergent.
    • 描述了基于建立的高级脂肪醇乙氧基硫酸盐洗涤剂的基本上具有可接受的温和性,发泡性能和加工特性的洗涤剂洗涤条,其含有作为洗衣条的保养剂的膨润土,促进其生产,并且有助于织物柔软性 用这种洗衣条洗衣服。 当膨润土被省略或被水不溶性填料如碳酸钙粉末代替时,制成的棒不具有可接受的硬度,并且这些组合物在传统的肥皂设备中不能令人满意地加工。 还描述了通过用膨润土处理将高级脂肪醇乙氧基化硫酸盐洗涤剂的水溶液转化为固体形式,以及从这种固化的洗涤剂制备洗涤剂洗涤条的方法。