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1. 发明授权

US07015175B2 High-activity isomerization catalyst and process 有权
标题翻译：高活性异构化催化剂和工艺
公开(公告)号：US07015175B2
公开(公告)日：2006-03-21
申请号：US10872581
申请日：2004-06-21
申请人： James G. Vassilakis , Richard R. Rosin , Steven A. Bradley , Ralph D. Gillespie , Michelle J. Cohn , Feng Xu
发明人： James G. Vassilakis , Richard R. Rosin , Steven A. Bradley , Ralph D. Gillespie , Michelle J. Cohn , Feng Xu
IPC分类号： B01J27/053 , B01J23/00 , B01J23/56 , C07C5/22 , C07C5/13
CPC分类号： C10G45/60 , B01J21/06 , B01J21/066 , B01J23/63 , B01J23/894 , B01J27/053 , B01J37/0205 , B01J37/031 , B01J37/20 , C07C5/2791 , C07C2523/63 , C10G45/62 , C10G2400/02 , C07C9/16
摘要： A catalyst and process is disclosed to selectively upgrade a paraffinic feedstock to obtain an isoparaffin-rich product for blending into gasoline. The catalyst comprises a support of a sulfated oxide or hydroxide of a Group IVB (IUPAC 4) metal, a first component of at least one lanthanide element or yttrium component, which is preferably ytterbium, and at least one platinum-group metal component which is preferably platinum and a refractory-oxide binder having at least one platinum-group metal component dispersed thereon.
摘要翻译：公开了一种催化剂和方法，用于选择性地升级链烷烃原料以获得用于混合成汽油的富含异链烷烃的产物。该催化剂包含硫酸化氧化物或IVB（IUPAC 4）金属的氢氧化物的载体，至少一种镧系元素或钇组分的第一组分，其优选为镱，以及至少一种铂族金属组分，其为优选铂和具有分散在其上的至少一个铂族金属组分的难熔氧化物粘合剂。

2. 发明授权

US5439864A Shaped carbonaceous composition 失效
标题翻译：形状碳质组成
公开(公告)号：US5439864A
公开(公告)日：1995-08-08
申请号：US172980
申请日：1993-12-27
申请人： Richard R. Rosin , Steven A. Bradley
发明人： Richard R. Rosin , Steven A. Bradley
IPC分类号： B01J20/20 , B01J21/18 , B01J35/10
CPC分类号： B01J20/20 , B01J21/18 , B01J35/002 , B01J35/0026 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/109
摘要： This invention relates to a shaped composition composed of a carbonaceous pyropolymer having recurring units containing at least carbon and hydrogen atoms. The composition is characterized by a crush strength of at least 6 kg and has a bimodal pore distribution having maxima at pore diameters of about 60 to 900 .ANG. and about 120 to 160 .ANG..
摘要翻译：本发明涉及由具有至少含有碳原子和氢原子的重复单元的含碳焦聚合物组成的成形组合物。该组合物的特征在于至少6kg的压碎强度，并且具有在孔直径为约60至900安培和约120至160安培的情况下具有最大值的双峰孔分布。

3. 发明申请

US20120004480A1 ADSORBENT FOR FEED AND PRODUCTS PURIFICATION IN BENZENE SATURATION PROCESS 有权
标题翻译：用于进料和产品的添加剂在苯酐饱和过程中的纯化
公开(公告)号：US20120004480A1
公开(公告)日：2012-01-05
申请号：US13151449
申请日：2011-06-02
申请人： Vladislav I. Kanazirev , Jayant K. Gorawara , Dana K. Sullivan , Richard R. Rosin
发明人： Vladislav I. Kanazirev , Jayant K. Gorawara , Dana K. Sullivan , Richard R. Rosin
IPC分类号： C07C5/10
CPC分类号： C07C7/12 , C07C15/04
摘要： The service life and deactivation rate of a benzene saturation catalyst is improved through use of a new sulfur guard bed containing a chloride additive. This sulfur guard bed, which contains supported CuO material having an increased resistance to reduction, shows such improvement. Thus, the danger of run-away reduction followed by a massive release of water and deactivation of an isomerization catalyst is practically eliminated. The fact that the guard bed material preserves the active metal phase-copper in an active (oxide) form is an important advantage leading to very low sulfur content in the product stream. The sulfur capacity per unit weight of sorbent is also significantly increased, making this sorbent a superior cost effective sulfur guard product. The guard bed is effective in treating mixed phase feed streams.
摘要翻译：通过使用含有氯化物添加剂的新型硫磺保护床，可提高苯饱和催化剂的使用寿命和失活率。这种含有具有增加的还原性能的负载型CuO材料的硫磺保护床显示出这种改进。因此，实际上消除了逃逸减少的危险，随后大量释放水并使异构化催化剂失活。保护床材料以活性（氧化物）形式保留活性金属相铜的事实是导致产物流中硫含量非常低的重要优点。吸附剂每单位重量的硫含量也显着增加，使得该吸附剂成为一种优异的成本效益的硫磺防护产品。防护床在处理混合相进料物流中是有效的。

4. 发明申请

US20100018906A1 APPARATUS AND PROCESS FOR REMOVAL OF CARBON MONOXIDE 有权
标题翻译：去除一氧化碳的装置和方法
公开(公告)号：US20100018906A1
公开(公告)日：2010-01-28
申请号：US12177851
申请日：2008-07-22
申请人： Mark P. Lapinski , Richard R. Rosin
发明人： Mark P. Lapinski , Richard R. Rosin
IPC分类号： C10G45/00 , B01D53/94 , C01B31/18
CPC分类号： B01D53/864 , B01D53/02 , B01D2251/202 , B01D2253/108 , B01D2255/1026 , B01D2255/20746 , B01D2255/20753 , B01D2256/16 , B01D2256/24 , B01D2257/502 , B01J23/96 , B01J38/10 , C10G35/06
摘要： One exemplary embodiment can be a process for lowering an amount of carbon monoxide in a stream rich in hydrogen. The process can include passing the stream rich in hydrogen through a carbon monoxide removal zone to produce a product stream having no more than about 10 vppm carbon monoxide and communicating the product stream to a reduction zone receiving a catalyst comprising unreduced metal species.
摘要翻译：一个示例性实施方案可以是用于降低富含氢气的一氧化碳的量的方法。该方法可以包括使富含氢的物流通过一氧化碳去除区，以产生具有不超过约10vppm一氧化碳的产物流，并将产物流连通至含有未还原金属物质的催化剂的还原区。

5. 发明申请

US20100166622A1 Apparatus and Process for Removal of Carbon Monoxide 审中-公开
标题翻译：用于去除一氧化碳的装置和方法
公开(公告)号：US20100166622A1
公开(公告)日：2010-07-01
申请号：US12722035
申请日：2010-03-11
申请人： Mark P. Lapinski , Richard R. Rosin
发明人： Mark P. Lapinski , Richard R. Rosin
IPC分类号： B01J19/00
CPC分类号： B01D53/864 , B01D53/02 , B01D2251/202 , B01D2253/108 , B01D2255/1026 , B01D2255/20746 , B01D2255/20753 , B01D2256/16 , B01D2256/24 , B01D2257/502 , B01J23/96 , B01J38/10 , C10G35/06
摘要： One exemplary embodiment can be a process for lowering an amount of carbon monoxide in a stream rich in hydrogen. The process can include passing the stream rich in hydrogen through a carbon monoxide removal zone to produce a product stream having no more than about 10 vppm carbon monoxide and communicating the product stream to a reduction zone receiving a catalyst comprising unreduced metal species.
摘要翻译：一个示例性实施方案可以是用于降低富含氢气的一氧化碳的量的方法。该方法可以包括使富含氢的物流通过一氧化碳去除区，以产生具有不超过约10vppm一氧化碳的产物流，并将产物流连通至含有未还原金属物质的催化剂的还原区。

6. 发明申请

US20090261018A1 PROCESS AND SYSTEM FOR THE TRANSFER OF A METAL CATALYST COMPONENT FROM ONE PARTICLE TO ANOTHER 有权
标题翻译：金属催化剂组分从一种颗粒转移到另一种颗粒的方法和系统
公开(公告)号：US20090261018A1
公开(公告)日：2009-10-22
申请号：US12104482
申请日：2008-04-17
申请人： Mark P. Lapinski , Gregory J. Gajda , Jeffry T. Donner , Richard R. Rosin , Marc R. Schreier , Simon R. Bare
发明人： Mark P. Lapinski , Gregory J. Gajda , Jeffry T. Donner , Richard R. Rosin , Marc R. Schreier , Simon R. Bare
IPC分类号： C10G35/04 , B01J8/02
CPC分类号： C10G35/085 , C10G35/095 , C10G35/24
摘要： One exemplary embodiment can be a process for facilitating a transfer of a metal catalyst component from at least one donor particle to at least one recipient particle in a catalytic naphtha reforming unit. The process can include transferring an effective amount of the metal catalyst component from the at least one donor particle to the at least one recipient particle under conditions to effect such transfer to improve a conversion of a hydrocarbon feed.
摘要翻译：一个示例性实施方案可以是促进金属催化剂组分从催化石脑油重整单元中的至少一个供体颗粒转移至至少一个受体颗粒的方法。该方法可以包括在有效量的金属催化剂组分从至少一个供体颗粒转移到至少一个受体颗粒的条件下进行这种转移以提高烃进料的转化率。

7. 发明授权

US6074624A Titanostannosilicates and preparation thereof 失效
标题翻译：钛酸铵和其制备
公开(公告)号：US6074624A
公开(公告)日：2000-06-13
申请号：US109854
申请日：1998-07-02
申请人： Laszlo Nemeth , Gregory J. Lewis , Richard R. Rosin
发明人： Laszlo Nemeth , Gregory J. Lewis , Richard R. Rosin
IPC分类号： C07D301/12 , C01B39/06
CPC分类号： C07D301/12 , Y10S423/22
摘要： A new family of crystalline titanostannosilicate molecular sieves have been synthesized. These molecular sieves have a microporous three-dimensional framework of TiO.sub.2, SnO.sub.2 and SiO.sub.2 tetrahedral oxide units and are represented by the empirical formula:(Ti.sub.x Sn.sub.y Si.sub.z)O.sub.2where "X", "y" and "z" are the mole fractions of Ti, Sn and Si respectively. These molecular sieves are active catalysts for the epoxidation of olefins by peroxides such as hydrogen peroxide.
摘要翻译：已经合成了一种新的结晶钛酸铵分子筛系列。这些分子筛具有TiO 2，SnO 2和SiO 2四面体氧化物单元的微孔三维框架，并且由经验式（TixSnySiz）O 2表示，其中“X”，“y”和“z”是Ti的摩尔分数， Sn和Si。这些分子筛是用过氧化物如过氧化氢对烯烃进行环氧化的活性催化剂。

8. 发明授权

US08314277B2 Adsorbent for feed and products purification in benzene saturation process 有权
标题翻译：苯饱和过程中的饲料和产品净化用吸附剂
公开(公告)号：US08314277B2
公开(公告)日：2012-11-20
申请号：US13151449
申请日：2011-06-02
申请人： Vladislav I. Kanazirev , Jayant K. Gorawara , Dana K. Sullivan , Richard R. Rosin
发明人： Vladislav I. Kanazirev , Jayant K. Gorawara , Dana K. Sullivan , Richard R. Rosin
IPC分类号： C07C5/10
CPC分类号： C07C7/12 , C07C15/04
摘要： The service life and deactivation rate of a benzene saturation catalyst is improved through use of a new sulfur guard bed containing a chloride additive. This sulfur guard bed, which contains supported CuO material having an increased resistance to reduction, shows such improvement. Thus, the danger of run-away reduction followed by a massive release of water and deactivation of an isomerization catalyst is practically eliminated. The fact that the guard bed material preserves the active metal phase-copper in an active (oxide) form is an important advantage leading to very low sulfur content in the product stream. The sulfur capacity per unit weight of sorbent is also significantly increased, making this sorbent a superior cost effective sulfur guard product. The guard bed is effective in treating mixed phase feed streams.
摘要翻译：通过使用含有氯化物添加剂的新型硫磺保护床，可提高苯饱和催化剂的使用寿命和失活率。这种含有具有增加的还原性能的负载型CuO材料的硫磺保护床显示出这种改进。因此，实际上消除了逃逸减少的危险，随后大量释放水并使异构化催化剂失活。保护床材料以活性（氧化物）形式保留活性金属相铜的事实是导致产物流中硫含量非常低的重要优点。吸附剂每单位重量的硫含量也显着增加，使得该吸附剂成为一种优异的成本效益的硫磺防护产品。防护床在处理混合相进料物流中是有效的。

9. 发明授权

US08313641B2 Adsorbent for feed and products purification in a reforming process 有权
标题翻译：在重整过程中用于饲料和产物纯化的吸附剂
公开(公告)号：US08313641B2
公开(公告)日：2012-11-20
申请号：US13151470
申请日：2011-06-02
申请人： Vladislav I. Kanazirev , Jayant K. Gorawara , Dana K. Sullivan , Richard R. Rosin
发明人： Vladislav I. Kanazirev , Jayant K. Gorawara , Dana K. Sullivan , Richard R. Rosin
IPC分类号： C10G35/04 , C10G17/00
CPC分类号： C10G29/04 , C10G25/003 , C10G2300/1044 , C10G2300/202 , C10G2300/207
摘要： The service life and deactivation rate of a reforming catalyst is improved through use of a new sulfur guard bed containing a chloride additive. This sulfur guard bed, which contains supported CuO material having an increased resistance to reduction, shows such improvement. Thus, the danger of run-away reduction followed by a massive release of water causing process upsets in a catalytic reforming process is practically eliminated. The fact that the guard bed material preserves the active metal phase—copper in an active (oxide) form is an important advantage leading to very low sulfur content in the product stream. The sulfur capacity per unit weight of sorbent is also significantly increased, making this sorbent a superior cost effective sulfur guard product.
摘要翻译：通过使用含有氯化物添加剂的新型硫磺保护床，可提高重整催化剂的使用寿命和失活率。这种含有具有增加的还原性能的负载型CuO材料的硫磺保护床显示出这种改进。因此，实际上消除了催化重整过程中逃逸减少的危险，随后大量释放水引起过程紊乱。保护床材料以活性（氧化物）形式保留活性金属相铜的事实是导致产物流中硫含量非常低的重要优点。吸附剂每单位重量的硫含量也显着增加，使得该吸附剂成为一种优异的成本效益的硫磺防护产品。

10. 发明授权

US5780654A Titanostannosilicalites: epoxidation of olefins 失效
标题翻译：钛土矿石：烯烃的环氧化
公开(公告)号：US5780654A
公开(公告)日：1998-07-14
申请号：US840531
申请日：1997-04-22
申请人： Laszlo Nemeth , Gregory J. Lewis , Richard R. Rosin
发明人： Laszlo Nemeth , Gregory J. Lewis , Richard R. Rosin
IPC分类号： B01J29/04 , C01B39/04 , C07B41/04 , C07B61/00 , C07D301/12 , C07D303/04
CPC分类号： C07D301/12
摘要： Titanostannosilicalites molecular sieves as new compositions of matter have been found to be very selective, active catalysts in the epoxidation of olefins by peroxides. Dilute hydrogen peroxide suffices to afford high yields of the epoxide with good selectivity. The sieves described within have a unit empirical formula, on an anhydrous basis of (Ti.sub.x Sn.sub.y Si.sub.z)O.sub.2, where 0.0005
摘要翻译：已经发现，作为物质的新组合物的Titanostannosilicalites分子筛是非常选择性的，通过过氧化物使烯烃环氧化的活性催化剂。稀释的过氧化氢足以以良好的选择性提供高产率的环氧化物。所述筛子具有单位经验公式，以（TixSnySiz）O 2的无水为基准，其中0.0005

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