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    • 1. 发明授权
    • Endurance of NiA1 coatings by controlling thermal spray processing variables
    • 通过控制热喷涂处理变量,NiAl涂层的耐久性
    • US06485792B1
    • 2002-11-26
    • US09644491
    • 2000-08-23
    • Richard John GryllsJoseph David RigneyMatthew David SaylorTheodore Robert GrossmanYuk-Chiu Lau
    • Richard John GryllsJoseph David RigneyMatthew David SaylorTheodore Robert GrossmanYuk-Chiu Lau
    • C23C406
    • C23C4/18C23C4/08Y02T50/67
    • A method for applying substantially stoichiometric NiAl to the surface of a superalloy substrate. These coatings are applied to substrates subjected to high temperatures and thermal cycling by providing a powder of the substantially stoichiometric material with the desired minor additions of rare earth elements, Cr or Zr. The coatings are applied by a thermal spray process utilizing hydrogen as a fuel while generating a highly reducing flame. The thermal spray method melts the powder and directs it onto the surface of the turbine component that is to be coated. The powder size is carefully controlled to prevent oxidation of the powder while providing a controlled surface finish. The surface roughness of the bond coat is further mechanically worked to a predetermined surface finish prior to application of the ceramic thermal barrier layer by a PVD method. Thermal barrier systems applied using these carefully controlled predetermined parameters provide outstanding resistance to TBC spallation under conditions of high cyclic stresses.
    • 将基本上化学计量的NiAl施加到超级合金基底的表面上的方法。 通过提供具有理想化学计量的材料的粉末和所需的稀土元素Cr或Zr的少量添加,将这些涂层施加到经受高温和热循环的基底上。 通过使用氢作为燃料的热喷涂方法施加涂层,同时产生高度还原的火焰。 热喷雾法将粉末熔化并将其引导到待涂覆的涡轮机部件的表面上。 仔细控制粉末尺寸以防止粉末氧化,同时提供受控的表面光洁度。 在通过PVD方法施加陶瓷热障层之前,将粘合涂层的表面粗糙度进一步机械加工至预定的表面光洁度。 使用这些仔细控制的预定参数应用的热障系统在高循环应力的条件下提供了出色的耐TBC剥落性能。
    • 4. 发明授权
    • Process for a beta-phase nickel aluminide overlay coating
    • 一种β相镍铝覆盖涂层的工艺
    • US07244467B2
    • 2007-07-17
    • US10604368
    • 2003-07-15
    • Theodore Robert GrossmanRamgopal DaroliaJoseph David Rigney
    • Theodore Robert GrossmanRamgopal DaroliaJoseph David Rigney
    • C23C16/00
    • C23C14/5886C23C4/18C23C14/16C23C26/00C23C28/3215C23C28/345C23C28/3455
    • A process for forming a beta-phase nickel aluminide (NiAl) overlay coating that is suitable for use as a bond coat for a thermal barrier coating (TBC). The overlay coating is deposited by a method that produces a generally columnar grain structure in which grains extend through the coating such that at least some grain boundaries are open at the coating surface. The coating is then peened with a particulate media, followed by heating the overlay coating to a temperature sufficient to cause the overlay coating to recrystallize and form new grain boundaries that are not open to the outer surface of the coating and significantly less susceptible to accelerated oxidation than the original grain boundaries. The particulate media is formed of a composition containing nickel and aluminum, such that an oxide scale that forms on the surface of the coating after the peening operation is substantially free of deleterious oxide compounds, notably iron-containing spinels.
    • 用于形成适合用作热障涂层(TBC)的粘合涂层的β-相镍铝化物(NiAl)覆盖涂层的方法。 覆盖涂层通过产生大致柱状晶粒结构的方法沉积,其中晶粒延伸穿过涂层,使得至少一些晶界在涂层表面开口。 然后用颗粒介质对涂层进行喷丸处理,然后将覆盖涂层加热至足以使覆盖涂层再结晶并形成不对涂层外表面开放的新晶粒边界,并显着降低易受加速氧化影响的温度 比原来的晶界。 颗粒介质由包含镍和铝的组合物形成,使得在喷丸操作之后在涂层表面上形成的氧化皮基本上不含有害氧化物化合物,特别是含铁尖晶石。
    • 8. 发明申请
    • VACUUM COATER DEVICE AND MECHANISM FOR SUPPORTING AND MANIPULATING WORKPIECES IN SAME
    • 用于支持和操作其工作的真空涂料装置和机构
    • US20080223291A1
    • 2008-09-18
    • US11685354
    • 2007-03-13
    • Robert William BruceTheodore Robert GrossmanJohn Douglas EvansBrian Harvey Pilsner
    • Robert William BruceTheodore Robert GrossmanJohn Douglas EvansBrian Harvey Pilsner
    • C23C14/00
    • C23C14/30C23C14/50C23C14/505C23C14/568
    • An apparatus for providing a vacuum coating to a workpiece, including: a coating chamber containing a coating material, with the coating chamber being operable at an elevated temperature and a sub-atmospheric pressure; an electron beam gun projecting an electron beam into the coating chamber and onto the coating material, where the electron beam gun is operable to melt the coating material and to evaporate molten coating material; and, a mechanism for supporting manipulating the workpiece in the coating chamber. The supporting mechanism further includes: a coupling device for retaining the workpiece; a joint connected to the coupling device enabling movement of the workpiece in all directions; an intermediate member connecting the coupling device and the joint; and, a device connected to the intermediate member for moving the workpiece in a designated vertical plane. The supporting mechanism may also include a device connected to the intermediate member for moving the workpiece in a designated horizontal plane.
    • 一种用于向工件提供真空涂层的设备,包括:包含涂层材料的涂层室,涂层室可在升高的温度和低于大气压的压力下操作; 电子束枪将电子束投射到涂覆室和涂覆材料上,其中电子束枪可操作以熔化涂层材料并蒸发熔融涂覆材料; 以及用于支撑在涂布室中操作工件的机构。 支撑机构还包括:用于保持工件的联接装置; 连接到联接装置的联接器,其能够使工件在所有方向上移动; 连接所述联接装置和所述接头的中间构件; 以及连接到中间构件的装置,用于在指定的垂直平面中移动工件。 支撑机构还可以包括连接到中间构件的装置,用于在指定的水平面中移动工件。