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    • 3. 发明申请
    • Method for adding boron to metal alloys
    • 硼添加到金属合金中的方法
    • US20060260778A1
    • 2006-11-23
    • US11132621
    • 2005-05-19
    • Samuel DavisNeil BakerJohn RiskallaRichard Carrano
    • Samuel DavisNeil BakerJohn RiskallaRichard Carrano
    • B22D27/00
    • B22D27/20B22D11/001B22D21/00B22F2998/00B22F9/08
    • A method to grain refine and deoxidize a precious metal alloy or a master alloy includes the steps of (a) forming a precursor melt consisting essentially of constituents of the precious metal alloy or master alloy and inevitable impurities; (b) dispersing a compound selected from the group consisting of boron containing metal hydrides, boron containing metal fluorides and mixtures thereof throughout the precursor melt; and (c) solidifying the boron containing precious melt alloy or master alloy. One suitable compound is solid sodium borohydride (sodium tetrahydroborate). To minimize evaporation of the boron on contact with the precursor alloy melt, the sodium borohydride may be wrapped in a metal foil formed from constituents of the precious metal alloy or master alloy. The cast precious metal alloy or master alloy has been found to have a reduced number of hard spots and reduced silicon contamination when compared to conventional casting methods.
    • 一种对贵金属合金或母合金进行晶粒细化和脱氧的方法包括以下步骤:(a)形成基本上由贵金属合金或母合金的成分组成的前体熔体和不可避免的杂质; (b)将选自含硼金属氢化物,含硼金属氟化物及其混合物的化合物的化合物分散在整个前体熔体中; 和(c)固化含硼珍贵熔体合金或母合金。 一种合适的化合物是固体硼氢化钠(四氢硼酸钠)。 为了最小化与前体合金熔体接触时硼的蒸发,硼氢化钠可以包裹在由贵金属合金或母合金的成分形成的金属箔中。 与传统的铸造方法相比,已经发现铸造的贵金属合金或母合金具有减少的硬斑数量和减少的硅污染。