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1. 发明授权

US4454098A Process for reclaiming tungsten from a hazardous waste 失效
标题翻译：从危险废物回收钨的工艺
公开(公告)号：US4454098A
公开(公告)日：1984-06-12
申请号：US556765
申请日：1983-12-01
申请人： Richard A. Scheithauer , Clarence D. Vanderpool , Michael J. Miller , Martin B. MacInnis
发明人： Richard A. Scheithauer , Clarence D. Vanderpool , Michael J. Miller , Martin B. MacInnis
IPC分类号： C01G28/02 , C01G41/00 , C22B7/00 , C22B34/36
CPC分类号： C22B34/36 , C01G28/023 , C01G41/00 , C22B7/008 , Y02P10/234
摘要： A process is disclosed wherein tungsten is recovered from hazardous waste material containing said tungsten, arsenic, and other impurities which can consist of magnesium, phosphorus, and silicon and the resulting waste is treated to render it nonhazardous according to EPA standards for arsenic. Said process involves digesting said hazardous waste material in an aqueous solution of an alkali metal hydroxide, adjusting the pH of the resulting solution to about 11.0 to about 13.0 with NaOH to precipitate essentially all of the magnesium and silicon species, filtering the digestion mix to remove the solids from said resulting solution which contains about 80 to about 100% of said tungsten and essentially none of said magnesium and said silicon, slurrying the hazardous solids in hot water, and adding to the slurry a ferric salt solution to precipitate ferric hydroxide, filtering this mixture to give a solid which passes the EPA standard test for solids with respect to arsenic.
摘要翻译：公开了一种方法，其中钨从含有所述钨，砷和其它可由镁，磷和硅组成的杂质的有害废物中回收，并且根据EPA的砷标准对所得的废物进行处理以使其非危险。所述方法包括在碱金属氢氧化物的水溶液中消化所述有害废物，用NaOH将所得溶液的pH调节至约11.0至约13.0，以沉淀基本上所有的镁和硅物质，过滤消化混合物以除去来自所述所得溶液的固体含有约80至约100％的所述钨，基本上不含所述镁和所述硅，将有害固体在热水中制浆，并向浆料中加入铁盐溶液以沉淀氢氧化铁，过滤该混合物得到固体，其通过关于砷的固体的EPA标准测试。

2. 发明授权

US4626425A Recovery of tungsten from ammoniacal solutions 失效
标题翻译：从氨溶液中回收钨
公开(公告)号：US4626425A
公开(公告)日：1986-12-02
申请号：US704840
申请日：1985-02-25
申请人： Richard A. Scheithauer , Clarence D. Vanderpool , Martin B. MacInnis , Michael J. Miller
发明人： Richard A. Scheithauer , Clarence D. Vanderpool , Martin B. MacInnis , Michael J. Miller
IPC分类号： C01G41/00 , C22B3/28 , C22B34/36
CPC分类号： C22B3/0012 , C01G41/003 , C22B34/36 , Y02P10/234
摘要： A method is disclosed for recovering tungsten from a relatively dilute ammoniacal tungsten solution. The method involves adding hexamethylenetetramine to the tungsten solution in an amount sufficient to form a hexamethylenetetramine complex then adjusting the pH to from about 1.0 to about 2.0 with a mineral acid to form a precipitate of the complex containing at least about 99% of the tungsten, and separating the precipitate from the resulting mother liquor.
摘要翻译：公开了从相对稀释的氨质钨溶液中回收钨的方法。该方法包括以足以形成六亚甲基四胺复合物的量向钨溶液中加入六亚甲基四胺，然后用无机酸将pH调节至约1.0至约2.0，以形成含有至少约99％的钨的络合物的沉淀物，并从所得母液中分离出沉淀物。

3. 发明授权

US4624844A Process for producing ammonium paratungstate 失效
标题翻译：生产仲钨酸铵的方法
公开(公告)号：US4624844A
公开(公告)日：1986-11-25
申请号：US697662
申请日：1985-02-04
申请人： Richard A. Scheithauer , Clarence D. Vanderpool , Martin B. MacInnis , Michael J. Miller
发明人： Richard A. Scheithauer , Clarence D. Vanderpool , Martin B. MacInnis , Michael J. Miller
IPC分类号： C01G41/00
CPC分类号： C01G41/00
摘要： A process is disclosed for producing ammonium paratungstate which involves adding hexamethylenetetramine to a first solution of ammonium tungstate, adjusting the pH to about 2 with an acid to form a precipitate which contains the major portion of the tungsten and the hexamethylenetetramine and separating the precipitate from the resulting mother liquor. The tungsten hexamethylenetetramine precipitate is then dissolved in aqueous ammonia to form a second ammonium tungstate solution which is then heated at from about 90.degree. C. to about 100.degree. C. to form a precipitate essentially all of which is ammonium paratungstate and a mother liquor which contains essentially all of the hexamethylenetetramine. The ammonium paratungstate precipitate is then separated from the mother liquor.
摘要翻译：公开了一种用于生产仲钨酸铵的方法，其涉及将六亚甲基四胺加入到钨酸铵的第一溶液中，用酸将pH调节至约2以形成含有主要部分的钨和六亚甲基四胺的沉淀物，并将沉淀物与产生母液。然后将六亚甲基四胺钨沉淀物溶解在氨水中形成第二钨酸铵溶液，然后将其加热至约90℃至约100℃，以形成基本上全部为仲钨酸铵的母液和母液，含有基本上所有的六亚甲基四胺。然后将仲钨酸铵沉淀物与母液分离。

4. 发明授权

US4608084A Recovery of cobalt and chromium 失效
标题翻译：回收钴和铬
公开(公告)号：US4608084A
公开(公告)日：1986-08-26
申请号：US718257
申请日：1985-04-01
申请人： Richard A. Scheithauer , Michael J. Miller , Clarence D. Vanderpool , Martin B. MacInnis
发明人： Richard A. Scheithauer , Michael J. Miller , Clarence D. Vanderpool , Martin B. MacInnis
IPC分类号： C22B23/00 , C22B3/32 , C22B7/00 , C22B34/32 , C22B23/04
CPC分类号： C22B23/0484 , C22B23/0423 , C22B3/0025 , C22B34/32 , C22B7/007 , Y02P10/234
摘要： A process is disclosed for recovering cobalt and chromium from a cobalt and chromium containing alloy. The process involves first digesting the alloy in concentrated hydrochloric acid at a sufficient temperature for a sufficient time to form a first solution containing the major portion of the cobalt, chromium, and any iron and nickel present in the alloy and a first solid and separating the first solution from the first solid. Oxalic acid is then added to the first solution in an amount sufficient to subsequently precipitate the major portion of the cobalt and any iron and nickel contained in the first solution followed by adjustment of the ph to from about 1 to about 2 with a base and maintaining the temperature below about 20.degree. for a sufficient time to form a second solid containing the major portion of the cobalt and the major portion of any iron and nickel which is present in the first solution and a second solution containing the major portion of the chromium which is present in the first solution and separation of the second solid from the second solution. The second solid is then washed with sufficient water to remove any water soluble impurities and separated from the resulting wash water. The resulting washed second solid is then contacted with a calcium chloride solution of sufficient calcium chloride concentration, at a sufficient temperature, for a sufficient time to form a third solution containing the major portion of the cobalt which was present in the second solid, and a third solid. The third solution is then separated from the third solid.
摘要翻译：公开了从含钴和铬的合金中回收钴和铬的方法。该方法包括首先在足够的温度下将浓缩的合金中的合金消化足够的时间以形成含有合金中存在的钴，铬和任何铁和镍的主要部分的第一溶液和第一固体，从第一个固体的第一个解决方案。然后将草酸以足以随后沉淀出主要部分的钴和第一溶液中所含的任何铁和镍的量，然后用碱将ph调节至约1至约2，并保持温度低于约20°足够的时间以形成第二固体，其含有钴的主要部分和存在于第一溶液中的任何铁和镍的主要部分和含有主要部分铬的第二溶液，存在于第一溶液中并且将第二固体与第二溶液分离。然后用足够的水洗涤第二固体以除去任何水溶性杂质并从得到的洗涤水中分离。然后将所得洗涤后的第二固体在足够的温度下与足够氯化钙浓度的氯化钙溶液接触足够的时间以形成含有存在于第二固体中的钴的主要部分的第三溶液，第三个固体。然后将第三溶液与第三固体分离。

5. 发明授权

US4612039A Production of pure cobalt metal powder 失效
标题翻译：生产纯钴金属粉末
公开(公告)号：US4612039A
公开(公告)日：1986-09-16
申请号：US793420
申请日：1985-10-31
申请人： Richard A. Scheithauer , Clarence D. Vanderpool , Michael J. Miller
发明人： Richard A. Scheithauer , Clarence D. Vanderpool , Michael J. Miller
IPC分类号： B22F9/22 , C01G51/04 , C01G51/12 , C22B15/00
CPC分类号： B22F9/22 , C01G51/04 , C01G51/12 , C01P2006/80
摘要： A method is disclosed for producing pure cobalt metal powder. The method involves reducing a cobalt containing source material to produce an intermediate cobalt metal, contacting this intermediate with an ammoniacal ammonium halide solution and a catalyst with oxidation to form a solution of hexamminecobalt(III) ions, removing insoluble material, and adding a sufficient amount of a halide salt to the solution to precipitate hexamminecobalt(III) halide which is separated from the mother liquor. The hexamminecobalt(III) halide precipitate is dissolved in water and the pH is adjusted to greater than about 10 with a base, while the solution is heated at a sufficient temperature for a sufficient time to form an insoluble cobalt oxide containing material which is separated from its mother liquor and reduced to pure cobalt metal powder.
摘要翻译：公开了一种用于生产纯钴金属粉末的方法。该方法包括还原含钴原料以产生中间体钴金属，使该中间体与氨基卤化铵溶液和催化剂氧化形成六氨基钴（III）离子溶液，除去不溶物质，并加入足量的的卤化物盐溶解以沉淀与母液分离的六氰基钴（III）卤化物。将六氰酸钴（III）沉淀物溶于水中，用碱将pH调节至大于约10℃，同时将溶液在足够的温度下加热足够的时间以形成不溶性的含氧化钴的材料，其母液还原成纯钴金属粉末。

6. 发明授权

US4452633A Method for producing cobalt metal powder 失效
标题翻译：钴金属粉末的制造方法
公开(公告)号：US4452633A
公开(公告)日：1984-06-05
申请号：US547181
申请日：1983-10-31
申请人： Michael J. Miller , Richard A. Scheithauer , Clarence D. Vanderpool , Eric F. Husted
发明人： Michael J. Miller , Richard A. Scheithauer , Clarence D. Vanderpool , Eric F. Husted
IPC分类号： B22F9/24 , C22B3/46 , B22F9/20
CPC分类号： C22B3/46 , C22B11/04 , C22B23/0423 , Y02P10/234
摘要： In a process for producing fine size cobalt metal powder from scrap material containing brazing compositions, the silver ions are removed by cementation with iron to form an insoluble mixture which is subsequently treated with concentrated hydrochloric acid to solubilize the silver which is then precipitated as silver chloride.
摘要翻译：在由含有钎焊组合物的废料制造精细钴金属粉末的方法中，通过用铁胶化除去银离子以形成不溶性混合物，随后用浓盐酸处理以溶解银，然后将其沉淀为氯化银。

7. 发明授权

US4690710A Process for producing cobalt metal powder 失效
标题翻译：钴金属粉末生产工艺
公开(公告)号：US4690710A
公开(公告)日：1987-09-01
申请号：US793079
申请日：1985-10-31
申请人： Richard A. Scheithauer , Clarence D. Vanderpool , Michael J. Miller , Richard G. W. Gingerich
发明人： Richard A. Scheithauer , Clarence D. Vanderpool , Michael J. Miller , Richard G. W. Gingerich
IPC分类号： B22F9/22 , B22F9/24 , C01G51/00 , C22B23/00 , C22C1/04
CPC分类号： B22F9/22 , C22B23/0423 , C22B23/0461
摘要： A process is disclosed for producing pure cobalt metal powder. The process involves contacting a cobaltous salt with a sufficient amount of an alkaline earth halide in an aqueous solution at a sufficient temperature for a sufficient time to form a solution which is essentially cobaltous halide and a solid which consists essentially of a salt of the alkaline earth and the anion of the cobaltous salt. The cobaltous halide solution is removed from the solid and the ions in the solution are complexed with ammonia in the presence of a catalyst to form a cobaltic hexammine ion. The resulting solution is treated with an acid in the presence of halide ions to form a cobaltic hexammine halide precipitate which is removed from the resulting mother liquor and dissolved in an aqueous solution to form a relatively pure solution which is treated with a sufficient amount of a metallic hydroxide to form a cobalt containing precipitate which is reduced to cobalt metal.
摘要翻译：公开了用于生产纯钴金属粉末的方法。该方法包括将钴盐与足量的碱土卤化物在水溶液中在足够的温度下接触足够的时间以形成基本上为卤化钴和基本上由碱土金属盐组成的固体的溶液和钴耳盐的阴离子。将卤化钴溶液从固体中除去，并且在催化剂存在下，溶液中的离子与氨络合以形成钴六胺离子。所得溶液在卤离子存在下用酸处理以形成钴六卤化物沉淀物，其从所得母液中除去并溶解在水溶液中以形成相对纯的溶液，该溶液用足量的金属氢氧化物以形成还原成钴金属的含钴沉淀物。

8. 发明授权

US4804407A Method for recovering cobalt from hexammine cobaltic (111) solutions 失效
标题翻译：从钴酸钴（111）溶液中回收钴的方法
公开(公告)号：US4804407A
公开(公告)日：1989-02-14
申请号：US194647
申请日：1988-05-13
申请人： Richard A. Scheithauer , Clarence D. Vanderpool , Michael J. Miller
发明人： Richard A. Scheithauer , Clarence D. Vanderpool , Michael J. Miller
IPC分类号： B22F9/24
CPC分类号： C22B23/0469 , C22B23/0461
摘要： A method is disclosed for recovering cobalt, which comprises adding ammonia to a cobalt chloride solution to a pH of from about 8.8 to about 9.6 with oxidation, to form hexammine cobalt (III) chloride, adding to the resulting solution of hexammine cobalt (III) chloride, sodium chloride in an amount sufficient to result in the precipitation of at least about 98% by weight of the cobalt as cobalt hexammine (III) chloride at a temperature of no greater than about 40.degree. C., separating the precipitate of cobalt hexammine (III) chloride from the resulting mother liquor which contains the balance of the cobalt, adding to the mother liquor, aluminum powder in an amount sufficient to result in the precipitation of the balance of the cobalt as cobalt metal, and separating the cobalt metal from the resulting spent liquor.
摘要翻译：公开了一种用于回收钴的方法，其中包括通过氧化将氨添加到氯化钴溶液中至约8.8至约9.6的pH，形成氯化六氯化钴（III），向所得到的六氨基钴（III）溶液中加入，氯化物，氯化钠，其量足以导致至少约98重量％的钴作为氯化钴六胺（III）在不高于约40℃的温度下沉淀，分离出六氯化钴沉淀物（III）的氯化物从含有余量钴的所得母液中加入到母液中，铝粉的量足以导致作为钴金属的钴的余量沉淀，并将钴金属从所产生的废酒。

9. 发明授权

US4623534A Method for producing ammonium paratungstate 失效
标题翻译：生产仲钨酸铵的方法
公开(公告)号：US4623534A
公开(公告)日：1986-11-18
申请号：US714327
申请日：1985-03-21
申请人： Richard A. Scheithauer , Clarence D. Vanderpool , Michael J. Miller
发明人： Richard A. Scheithauer , Clarence D. Vanderpool , Michael J. Miller
IPC分类号： C01G41/00 , C22B3/28
CPC分类号： C22B3/0012 , C01G41/00 , C01G41/003 , Y02P10/234
摘要： A method is disclosed for producing relatively pure ammonium paratungstate from an impure tungsten solution. The method involves first adding hexamethylenetetramine to the tungsten solution and adjusting the pH to from about 1.0 to about 2.0 with a mineral acid to form a first precipitate of a tungsten hexamethylenetetramine product, which is then separated from its mother liquor. The precipitate is then slurried in water and the pH adjusted to from about 7.0 to about 8.5 with ammonia to dissolve the precipitate. The resulting solution is then adjusted to from about 1.0 to about 2.0 with a mineral acid to form a second precipitate of the tungsten hexamethylenetetramine product which is then separated from its mother liquor. The second precipitate is then slurried in a solution of water and sufficient ammonia to form ammonium paratungstate which crystallizes out on evaporation of the slurry. The ammonium paratungstate is then separated from its mother liquor.
摘要翻译：公开了从不纯的钨溶液中生产相对纯的仲钨酸铵的方法。该方法包括首先将六亚甲基四胺加入到钨溶液中，并用无机酸将pH调节至约1.0至约2.0，以形成六亚甲基四胺产物的第一沉淀，然后将其从母液中分离出来。然后将沉淀物在水中浆化并用氨将pH调节至约7.0至约8.5以溶解沉淀物。然后将所得溶液用无机酸调节至约1.0至约2.0，以形成六亚甲基四胺产物的第二沉淀物，然后从其母液中分离。然后将第二沉淀物在水和足够的氨的溶液中浆化以形成仲钨酸铵，其在浆料蒸发时结晶出来。然后将仲钨酸铵与母液分离。

10. 发明授权

US4594230A Recovery of cobalt 失效
标题翻译：钴的回收
公开(公告)号：US4594230A
公开(公告)日：1986-06-10
申请号：US697661
申请日：1985-02-04
申请人： Richard A. Scheithauer , Michael J. Miller , Clarence D. Vanderpool
发明人： Richard A. Scheithauer , Michael J. Miller , Clarence D. Vanderpool
IPC分类号： C01G51/00 , C01G51/08 , C07C55/07 , C22B3/32
CPC分类号： C22B23/0423 , C01G51/003 , C01G51/085 , C07C55/07 , C22B3/0025 , Y02P10/234
摘要： A process is disclosed for recovering cobalt in a relatively pure form from an impure cobalt bearing material. The process involves digesting the material in hydrochloric acid to form a solution essentially all of the cobalt and some impurities and insoluble material containing the remainder of the impurities, separating the solution from the insolubles, adding an oxalate producing compound in an amount sufficient to subsequently convert essentially all of the cobalt to cobalt oxalate to the solution, adjusting the pH of the oxalate treated solution to from about 1.5 to about 2.0 with a base to precipitate the cobalt, and finally separating the precipitate from the resulting mother liquor.
摘要翻译：公开了从不纯的含钴材料中以相对纯的形式回收钴的方法。该方法包括在盐酸中消化材料以形成基本上所有的钴和一些杂质的溶液以及含有其余杂质的不溶性材料，将溶液与不溶物分离，加入足以随后转化的量的产生草酸的化合物基本上所有的钴 - 草酸钴溶液，用碱处理草酸盐处理溶液的pH至约1.5至约2.0以沉淀钴，最后将沉淀物与所得母液分离。

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