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1. 发明申请

US20130046072A1 AROMATIC MONOMERS DERIVING FROM GLYCEROL UNITS, PROCESS FOR THEIR PREPARATION AND USE THEREOF FOR THE PREPARATION OF WATER-SOLUBLE CONJUGATED POLYMERS 有权
标题翻译：从甘油单位获得的芳族单体，其制备和使用它们制备水溶性聚合物的方法
公开(公告)号：US20130046072A1
公开(公告)日：2013-02-21
申请号：US13643438
申请日：2011-04-29
申请人： Giuliana Schimperna , Riccardo Po' , Andrea Pellegrino , Maria Caldararo
发明人： Giuliana Schimperna , Riccardo Po' , Andrea Pellegrino , Maria Caldararo
IPC分类号： C07D317/22 , C07D405/12 , C08G79/08 , C07D409/12
CPC分类号： C07D405/12 , C07D317/22 , C07D409/12 , C08G61/123 , C08G61/124 , C08G61/126 , C08G75/06 , C08G2261/124 , C08G2261/1422 , C08G2261/1424 , C08G2261/3142 , C08G2261/3223 , C08G2261/3241 , C08G2261/3246 , C08G2261/411 , C08G2261/91 , H01L51/0036 , H01L51/0039 , H01L51/0043 , H01L51/0068 , H01L51/0072 , H01L51/42
摘要： Monomers having formula (I) and process for their synthesis which comprises the etherification reaction of a halogen-derivative (Z═Cl, Br, I) having formula (III) with the hydroxyl group of the glycerol derivative (IV), according to the following scheme:(Formula III, IV & I) (III) (IV) (I)
摘要翻译：具有式（I）的单体及其合成方法，其包括具有式（III）的卤素衍生物（Z = Cl，Br，I）与甘油衍生物（IV）的羟基的醚化反应，根据（式III，IV＆I）（III）（IV）（I）

2. 发明授权

US08680231B2 π-conjugated low-band-gap copolymers containing benzotriazole units 有权
标题翻译：含有苯并三唑单元的共轭低带隙共聚物
公开(公告)号：US08680231B2
公开(公告)日：2014-03-25
申请号：US13125402
申请日：2009-10-16
申请人： Riccardo Po' , Andrea Pellegrino , Giuliana Schimperna , Maria Caldararo
发明人： Riccardo Po' , Andrea Pellegrino , Giuliana Schimperna , Maria Caldararo
IPC分类号： C08G79/08 , C08G73/00
CPC分类号： C08G73/08 , C08G61/123 , C08G61/126 , C08G73/0672 , C08G2261/3142 , C08G2261/3223 , C08G2261/3241 , H01L51/0035 , H01L51/0036 , H01L51/0043 , H01L51/42 , Y02E10/549
摘要： The present invention relates to an alternating or statistical conjugated copolymer comprising: at least one benzotriazole unit B having general formula (Ia) or (Ib): wherein the group R is selected from alkyl, aryl, acyl or thioacyl groups, possibly substituted; at least one conjugated structural unit A, wherein each unit B is connected with at least one unit A in any of the positions 4, 5, 6 or 7, preferably in positions 4 or 7.
摘要翻译：本发明涉及一种交替或统计共轭共聚物，其包含：至少一种具有通式（Ia）或（Ib）的苯并三唑单元B：其中基团R选自可能被取代的烷基，芳基，酰基或硫代酰基; 至少一个共轭结构单元A，其中每个单元B与位置4,5,6或7中的任何位置中的至少一个单元A连接，优选位置4或7。

3. 发明授权

US09290483B2 Aromatic monomers deriving from glycerol units, process for their preparation and use thereof for the preparation of water-soluble conjugated polymers 有权
标题翻译：衍生自甘油单元的芳族单体，其制备方法及其用于制备水溶性共轭聚合物的方法
公开(公告)号：US09290483B2
公开(公告)日：2016-03-22
申请号：US13643438
申请日：2011-04-29
申请人： Giuliana Schimperna , Riccardo Po' , Andrea Pellegrino , Maria Caldararo
发明人： Giuliana Schimperna , Riccardo Po' , Andrea Pellegrino , Maria Caldararo
IPC分类号： C08G65/26 , C08G65/04 , C07D317/22 , C07D409/12 , C07D405/12 , C08G61/12 , H01L51/00 , H01L51/42
CPC分类号： C07D405/12 , C07D317/22 , C07D409/12 , C08G61/123 , C08G61/124 , C08G61/126 , C08G75/06 , C08G2261/124 , C08G2261/1422 , C08G2261/1424 , C08G2261/3142 , C08G2261/3223 , C08G2261/3241 , C08G2261/3246 , C08G2261/411 , C08G2261/91 , H01L51/0036 , H01L51/0039 , H01L51/0043 , H01L51/0068 , H01L51/0072 , H01L51/42
摘要： Monomers having formula (I) and process for their synthesis which comprises the etherification reaction of a halogen-derivative (Z═Cl, Br, I) having formula (III) with the hydroxyl group of the glycerol derivative (IV), according to the following scheme:(Formula III, IV & I) (III) (IV) (I)
摘要翻译：具有式（I）的单体及其合成方法，其包括具有式（III）的卤素衍生物（Z = Cl，Br，I）与甘油衍生物（IV）的羟基的醚化反应，根据（式III，IV＆I）（III）（IV）（I）

4. 发明申请

US20130001474A1 COPOLYMERS FOR SOLAR CELLS BASED ON ACRIDONIC UNITS 有权
标题翻译：基于ACRIDONIC单位的太阳能电池共聚物
公开(公告)号：US20130001474A1
公开(公告)日：2013-01-03
申请号：US13516857
申请日：2010-12-15
申请人： Maria Caldararo , Andrea Pellegrino , Giuliana Schimperna , Riccardo Po'
发明人： Maria Caldararo , Andrea Pellegrino , Giuliana Schimperna , Riccardo Po'
IPC分类号： C08G75/32 , C08G73/08 , H01B1/12
CPC分类号： C07D409/14 , C08G61/122 , C08G61/123 , C08G61/126 , C08G2261/3241 , C08G2261/3246 , C08G2261/411 , C08G2261/91 , H01L51/0036 , H01L51/0043 , H01L51/4253 , Y02E10/549
摘要： The present invention relates to copolymers for solar cells based on acridonic units comprising: a monomeric unit (A) having general formula (I) wherein X is S or Se, Y is 0, S or NR′ and R′, R′, the same or different, are C4-C24 alkyl groups, aryl groups optionally substituted with other functional groups, acyl groups or thioacyl groups; at least one monomer unit (B) having general formula (II) wherein Z is 0, S, Se or N—R″, wherein R″ is a C4-C24 alkyl group, an aryl group op-tionally substituted with other functional groups, an acyl group or thioacyl group, said monomeric unit (B) being connected to any position available of a hetero-aromatic side ring of the unit (A) through one of the two positions indicated by the dashed lines in general formula (II). Photovoltaic devices comprising said alternating π-conjugated polymers are also described.
摘要翻译：本发明涉及基于吖啶单体的太阳能电池用共聚物，包括：具有通式（I）的单体单元（A），其中X为S或Se，Y为0，S或NR'，R'，R'，相同或不同的是C 4 -C 24烷基，任选被其它官能团取代的芳基，酰基或硫代酰基; 至少一种具有通式（II）的单体单元（B），其中Z为0，S，Se或N-R“，其中R”为C 4 -C 24烷基，被其它官能团取代的芳基，酰基或硫代酰基，所述单体单元（B）通过通式（II）中的虚线所示的两个位置之一连接到单元（A）的杂芳族侧环的任何位置上，。还描述了包含所述交替共轭聚合物的光伏器件。

5. 发明申请

US20110319573A1 PI-CONJUGATED LOW-BAND-GAP COPOLYMERS CONTAINING BENZOTRIAZOLE UNITS 有权
标题翻译：含有苯并噻唑单体的PI-CONJGGGAL低粘合剂共聚物
公开(公告)号：US20110319573A1
公开(公告)日：2011-12-29
申请号：US13125402
申请日：2009-10-16
申请人： Riccardo Po' , Andrea Pellegrino , Giuliana Schimperna , Maria Caldararo
发明人： Riccardo Po' , Andrea Pellegrino , Giuliana Schimperna , Maria Caldararo
IPC分类号： C08G75/06 , C08G75/00 , C08G73/08
CPC分类号： C08G73/08 , C08G61/123 , C08G61/126 , C08G73/0672 , C08G2261/3142 , C08G2261/3223 , C08G2261/3241 , H01L51/0035 , H01L51/0036 , H01L51/0043 , H01L51/42 , Y02E10/549
摘要： The present invention relates to an alternating or statistical conjugated copolymer comprising: at least one benzotriazole unit B having general formula (Ia) or (Ib): wherein the group R is selected from alkyl, aryl, acyl or thioacyl groups, possibly substituted; at least one conjugated structural unit A, wherein each unit B is connected with at least one unit A in any of the positions 4, 5, 6 or 7, preferably in positions 4 or 7.
摘要翻译：本发明涉及一种交替或统计共轭共聚物，其包含：至少一种具有通式（Ia）或（Ib）的苯并三唑单元B：其中基团R选自可能被取代的烷基，芳基，酰基或硫代酰基; 至少一个共轭结构单元A，其中每个单元B与位置4,5,6或7中的任何位置中的至少一个单元A连接，优选位置4或7。

6. 发明授权

US06576730B2 Organic initiators and their use in the polymerization of unsaturated monomers 有权
公开(公告)号：US06576730B2
公开(公告)日：2003-06-10
申请号：US09852697
申请日：2001-05-11
申请人： Nicoletta Cardi , Riccardo Po' , Giuliana Schimperna , Maria Caldararo , Maria Anna Cardaci , Fabio Garbassi
发明人： Nicoletta Cardi , Riccardo Po' , Giuliana Schimperna , Maria Caldararo , Maria Anna Cardaci , Fabio Garbassi
IPC分类号： C08F400
CPC分类号： C07D265/02 , C07D261/20 , C07D273/00 , C08F4/00
摘要： Process for the polymerization of unsaturated vinyl and/or vinylidene monomers which comprises reacting one or more monomers in the presence of heterocyclic initiators having a nitrogen atom bound to an oxygen atom at a temperature ranging from 100 to 130° C.

7. 发明授权

US07982052B2 Process for the preparation of stable nitroxyl radicals 有权
标题翻译：制备稳定硝酰自由基的方法
公开(公告)号：US07982052B2
公开(公告)日：2011-07-19
申请号：US12161283
申请日：2007-02-09
申请人： Maria Caldararo , Riccardo Po' , Marco Ricci
发明人： Maria Caldararo , Riccardo Po' , Marco Ricci
IPC分类号： C07D209/44
CPC分类号： C07D209/46
摘要： Process for the preparation of stable nitroxyl radicals (I) starting from N-benzylphthalimide in two steps. In the first step, the intermediate N-benzyl-1,1,3,3-tetra-alkylisoindoline is prepared by treatment with a Grignard reagent, prepared in methyl-tert-butyl ether, of N-benzylphthalimide, obtained in the same reaction environment starting from phthalic anhydride and benzylamine. In the second step, the N-benzyl-1,1,3,3-tetra-alkylisoindoline is transformed into the nitroxyl radical by hydrogenolysis and subsequent oxidation with hydrogen peroxide in the presence of a catalyst selected from acids and salts of polymolybdic or polytungstic acids.
摘要翻译：从N-苄基邻苯二甲酰亚胺开始制备稳定的硝酰基（I）的方法分两步进行。在第一步中，中间体N-苄基-1,1,3,3-四烷基异吲哚啉通过用在相同反应中获得的N-苄基邻苯二甲酰亚胺的甲基叔丁基醚中制备的格氏试剂进行处理环境从邻苯二甲酸酐和苄胺开始。在第二步中，N-苄基-1,1,3,3-四烷基异吲哚啉通过氢解反应转化为硝酰基，随后在选自酸和多钼或多元酸的盐的催化剂存在下用过氧化氢氧化酸。

8. 发明授权

US5601780A Process for the preparation of re-usable bottles starting from modified PET 失效
标题翻译：从改性PET开始制备可重复使用的瓶子的方法
公开(公告)号：US5601780A
公开(公告)日：1997-02-11
申请号：US444368
申请日：1995-05-18
申请人： Ernesto Occhiello , Riccardo Po'
发明人： Ernesto Occhiello , Riccardo Po'
IPC分类号： C08G63/60 , C08L67/00 , B29C49/06
CPC分类号： C08L67/00 , C08G63/605 , Y10T428/1352 , Y10T428/139 , Y10T428/1397 , Y10T428/31786
摘要： Process for the preparation of transparent re-usable bottles, which consists in moulding by injection-blow moulding cycle copolymers containing units deriving from terephthalic acid and ethylene glycol characterized in that said copolymers contain from 0.1 to 10% in moles of units deriving from aromatic diacids different from terephthalic acid and from 0.1-15% in moles of units deriving from aromatic hydroxyacids, making reference to the units deriving from terephthalic acid.
摘要翻译：用于制备透明可重复使用的瓶子的方法，其包括通过含有衍生自对苯二甲酸和乙二醇的单元的注射吹塑成型循环共聚物进行成型，其特征在于所述共聚物含有0.1-10％摩尔衍生自芳族二酸的单元不同于对苯二甲酸和0.1至15％摩尔衍生自芳族羟基酸的单元，参考衍生自对苯二甲酸的单元。

9. 发明申请

US20120130037A1 RELATIVE PERMEABILITY MODIFIERS BASED ON HYDROPHOBICALLY MODIFIED CATIONIC COPOLYMERS 失效
标题翻译：基于疏水性改性阳离子共聚物的相对渗透性改性剂
公开(公告)号：US20120130037A1
公开(公告)日：2012-05-24
申请号：US13139737
申请日：2009-12-10
申请人： Cecilia Querci , Matteo Russo , Riccardo Po' , Maria Anna Cardaci
发明人： Cecilia Querci , Matteo Russo , Riccardo Po' , Maria Anna Cardaci
IPC分类号： C08F220/60 , C08F226/06 , C08F236/20
CPC分类号： C08F220/56
摘要： Copolymers of acrylamide or methacrylamide, suitably modified with appropriate percentages of units deriving from comonomers of a hydrophobic nature and comonomers containing a positively charged ionic group, which are capable of effectively reducing the water permeability of a porous medium.
摘要翻译：丙烯酰胺或甲基丙烯酰胺的共聚物，适当地以衍生自疏水性的共聚单体的单元和含有带正电荷的离子基团的共聚单体适当地改性，能够有效降低多孔介质的透水性。

10. 发明授权

US5882751A Parison for the preparation of re-usable bottles starting from modified pet 失效
标题翻译：从改良宠物开始制备可重复使用的瓶子的比较
公开(公告)号：US5882751A
公开(公告)日：1999-03-16
申请号：US718870
申请日：1996-09-24
申请人： Ernesto Occhiello , Riccardo Po'
发明人： Ernesto Occhiello , Riccardo Po'
IPC分类号： C08G63/60 , C08L67/00 , B29B7/00
CPC分类号： C08L67/00 , C08G63/605 , Y10T428/1352 , Y10T428/139 , Y10T428/1397 , Y10T428/31786
摘要： A parison for transparent re-usable bottles, obtained by molding by injection-blow moulding cycle copolymers containing units deriving from terephthalic acid and ethylene glycol characterized in that said copolymers contain from 0.1 to 10% in moles of units deriving from aromatic diacids different from terephthalic acid and from 0.1-15% in moles of units deriving from aromatic hydroxyacids, making reference to the units deriving from terephthalic acid.
摘要翻译：用于通过注射吹塑成型循环共聚物通过成型由透明对苯二甲酸和乙二醇衍生的单元获得的透明可重复使用的瓶子型坯，其特征在于所述共聚物含有0.1-10％（摩尔）衍生自不同于对苯二甲酸的芳族二酸酸和0.1至15％摩尔衍生自芳族羟酸的单元，参考衍生自对苯二甲酸的单元。

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