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    • 1. 发明授权
    • Method for processing a natural gas with extraction of the solvent contained in the acid gases
    • 通过萃取酸性气体中所含的溶剂来处理天然气的方法
    • US07459011B2
    • 2008-12-02
    • US11057011
    • 2005-02-14
    • Renaud CadoursFabrice LecomteLionel MagnaCécile Barrere-Tricca
    • Renaud CadoursFabrice LecomteLionel MagnaCécile Barrere-Tricca
    • B01D53/14
    • C10L3/10
    • The natural gas arriving through pipe 1 is deacidified by being brought into contact with a solvent in zone C. The solvent charged with acid compounds is regenerated in zone R. The acid gases, released into pipe 5 upon regeneration, include a quantity of solvent. The method enables the solvent contained in the acid gases to be extracted. In zone ZA, the acid gases are brought into contact with a non-aqueous ionic liquid whose general formula is Q+ A−, where Q+ designates an ammonium, phosphonium, and/or sulfonium cation, and A− designates an anion able to form a liquid salt. The solvent is removed from the acid gases evacuated through pipe 6. The ionic liquid charged with solvent is regenerated by heating in an evaporator DE. The ionic liquid regenerated is recycled through pipes 8 and 9 to zone ZA. The solvent is evacuated through pipe 13.
    • 通过管道1到达的天然气通过与区域C中的溶剂接触而脱酸。在酸性化合物中加入的溶剂在区域R中再生。再生时释放到管道5中的酸性气体包括一定量的溶剂。 该方法能够提取酸性气体中所含的溶剂。 在区域ZA中,酸性气体与通式为Q + A-的非水性离子液体接触,其中Q +表示铵,鏻和/或锍阳离子,A-表示能形成 液体盐 从通过管道6排出的酸性气体中除去溶剂。加入溶剂的离子液体通过在蒸发器DE中加热而再生。 再生的离子液体通过管道8和9循环到区域ZA。 溶剂通过管13排出。
    • 8. 发明申请
    • Method for processing a natural gas with extraction of the solvent contained in the acid gases
    • 通过提取酸性气体中所含的溶剂来处理天然气的方法
    • US20050183337A1
    • 2005-08-25
    • US11057011
    • 2005-02-14
    • Renaud CadoursFabrice LecomteLionel MagnaCecile Barrere-Tricca
    • Renaud CadoursFabrice LecomteLionel MagnaCecile Barrere-Tricca
    • C10L3/10C10J1/00
    • C10L3/10
    • The natural gas arriving through pipe 1 is deacidified by being brought into contact with a solvent in zone C. The solvent charged with acid compounds is regenerated in zone R. The acid gases, released into pipe 5 upon regeneration, include a quantity of solvent. The method enables the solvent contained in the acid gases to be extracted. In zone ZA, the acid gases are brought into contact with a non-aqueous ionic liquid whose general formula is Q+ A−, where Q+ designates an ammonium, phosphonium, and/or sulfonium cation, and A− designates an anion able to form a liquid salt. The solvent is removed from the acid gases evacuated through pipe 6. The ionic liquid charged with solvent is regenerated by heating in an evaporator DE. The ionic liquid regenerated is recycled through pipes 8 and 9 to zone ZA. The solvent is evacuated through pipe 13.
    • 通过管道1到达的天然气通过与区域C中的溶剂接触而脱酸。在酸性化合物中加入的溶剂在区域R中再生。再生时释放到管道5中的酸性气体包括一定量的溶剂。 该方法能够提取酸性气体中所含的溶剂。 在区域ZA中,使酸性气体与通式为Q +的非水离子液体接触,其中Q + >表示铵,鏻和/或锍阳离子,A>表示能够形成液体盐的阴离子。 从通过管道6排出的酸性气体中除去溶剂。加入溶剂的离子液体通过在蒸发器DE中加热而再生。 再生的离子液体通过管道8和9循环到区域ZA。 溶剂通过管13排出。
    • 10. 发明授权
    • Method and device for processing a gas containing hydrogen sulfide and sulfur dioxide comprising a stage of removal of by-products
    • 用于处理含有硫化氢和二氧化硫的气体的方法和装置,包括除去副产物的阶段
    • US06872368B2
    • 2005-03-29
    • US09902104
    • 2001-07-11
    • Fabrice LecomteChristian StreicherCécile Barrere-Tricca
    • Fabrice LecomteChristian StreicherCécile Barrere-Tricca
    • C01B17/04B01D53/86C01B17/05B01J8/00
    • B01D53/8615C01B17/05
    • A method for processing a gas containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the steps of contacting the gas with a liquid solvent containing at least one catalyst in a contacting stage, recovering gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide from the contacting stage, and separating liquid sulfur from liquid solvent in a decantation zone downstream of the contacting stage. In order to remove by-products resulting from degradation of the catalyst, a liquid fraction F containing at least solvent, catalyst, sulfur and the solid by-products resulting from degradation of the catalyst is extracted from after the contacting stage. The liquid fraction F is sent to a processing stage distinct from the contacting stage where the liquid fraction F is heated to a temperature at least partially crystallizing the by-products, and the at least partially crystallized by-products separated from the rest of the liquid fraction F containing at least solvent. At least a stream F1 comprising solvent, catalyst and sulfur and substantially free of the by-products and a stream F2 mostly comprising the by-products are recovered.
    • 一种用于处理至少包含硫化氢(H 2 S)和至少二氧化硫(SO 2)的气体的方法,包括以下步骤:在接触阶段使气体与含有至少一种催化剂的液体溶剂接触,回收基本上不含 硫化氢和来自接触阶段的二氧化硫,并且在接触阶段下游的倾析区中将液体硫与液体溶剂分离。 为了除去由催化剂的降解引起的副产物,从接触阶段后提取至少含有溶剂,催化剂,硫和由催化剂降解引起的固体副产物的液体馏分F. 液体馏分F被送至不同于液体馏分F被加热至至少部分使副产物结晶的温度的接触阶段的处理阶段,并且至少部分结晶的副产物与其余液体分离 含有至少溶剂的馏分F. 回收至少包含溶剂,催化剂和硫并基本上不含副产物的流F1和主要包含副产物的料流F2。