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1. 发明授权

US4937256A Thiophene compounds 失效
标题翻译：噻吩化合物
公开(公告)号：US4937256A
公开(公告)日：1990-06-26
申请号：US356552
申请日：1989-05-25
申请人： Reiner Kober , Joachim Leyendecker , Rainer Seele , Stefan Karbach , Norbert Meyer , Karl-Otto Westphalen , Bruno Wuerzer , Gerhard Wagenblast
发明人： Reiner Kober , Joachim Leyendecker , Rainer Seele , Stefan Karbach , Norbert Meyer , Karl-Otto Westphalen , Bruno Wuerzer , Gerhard Wagenblast
IPC分类号： A01N43/10 , C07D333/22 , C07D333/28 , C07D333/38 , C07D409/14 , C07D413/14
CPC分类号： C07D409/14 , A01N43/10 , C07D333/22 , C07D333/28
摘要： Thiophene compounds of the formula I ##STR1## where the substituents and the index have the following meanings: n is 0 or 1;R.sup.1 is hydrogen, halogen, C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.8 -haloalkyl or C.sub.1 -C.sub.6 -haloalkoxy;R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are cyano, nitro or the groups given for R.sup.1 ;A is hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.8 -alkoxy, C.sub.1 -C.sub.6 -haloalkoxy, substituted or unsubstituted aryl or heteroaryl, a radical OR.sup.6, whereR.sup.6 is hydrogen, C.sub.1 -C.sub.8 -alkyl, substituted C.sub.1 -C.sub.4 -alkyl, substituted or unsubstituted C.sub.2 -C.sub.8 -alkenyl, substituted or unsubstituted C.sub.3 -C.sub.7 -alkynyl, C.sub.4 -C.sub.9 -cycloalkyl, or a radical NR.sup.7 R.sup.8, where R.sup.7 and R.sup.8 are hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -haloalkoxy, substituted or unsubstituted aryl or hetaryl, substituted or unsubstituted C.sub.1 -C.sub.12 -alkylcarbonyl, C.sub.1 -C.sub.12 -haloalkylcarbonyl, substituted or unsubstituted aryl or hetaryl,and their environmentally acceptable salts, processes for their manufacture, and their use.
摘要翻译：式I的噻吩化合物（I）其中取代基和指数具有以下含义：n为0或1; R 1是氢，卤素，C 1 -C 8 - 烷基，C 1 -C 6 - 烷氧基，C 1 -C 8 - 卤代烷基或C 1 -C 6 - 卤代烷氧基; R2，R3，R4和R5是氰基，硝基或R1给出的基团; A是氢，C 1 -C 8 - 烷基，C 1 -C 6 - 卤代烷基，C 1 -C 8 - 烷氧基，C 1 -C 6 - 卤代烷氧基，取代或未取代的芳基或杂芳基，基团OR 6，其中R 6是氢，C 1 -C 8烷基，取代或未取代的C 2 -C 8 - 烯基，取代或未取代的C 3 -C 7 - 炔基，C 4 -C 9 - 环烷基或NR 7 R 8基团，其中R 7和R 8为氢，C 1 -C 8 - 烷基，C 1 -C 8 - C 1-8 - 烷氧基，C 1 -C 6 - 卤代烷基，C 1 -C 6 - 卤代烷氧基，取代或未取代的芳基或杂芳基，取代或未取代的C 1 -C 12烷基羰基，C 1 -C 12 - 卤代烷基羰基，取代或未取代的芳基或杂芳基，盐，其制造方法及其用途。

2. 发明授权

US5158598A Bithienyl derivatives, and herbicidal use for agents containing them 失效
标题翻译：二氯甲烷衍生物及其除草剂用于含有它们的物质
公开(公告)号：US5158598A
公开(公告)日：1992-10-27
申请号：US389820
申请日：1989-08-04
申请人： Reiner Kober , Joachim Leyendecker , Rainer Seele , Klaus Fischer , Hans Theobald , Bruno Wuerzer , Karl-Otto Westphalen , Norbert Meyer
发明人： Reiner Kober , Joachim Leyendecker , Rainer Seele , Klaus Fischer , Hans Theobald , Bruno Wuerzer , Karl-Otto Westphalen , Norbert Meyer
IPC分类号： A01N43/10 , A01N43/36 , A01N43/40 , A01N43/42 , A01N43/52 , A01N43/74 , A01N43/80 , C07D333/16 , C07D333/28 , C07D333/34 , C07D333/38 , C07D333/42 , C07D409/14 , C07D413/14 , C07D417/14
CPC分类号： C07D409/14 , A01N43/10 , A01N43/36 , A01N43/40 , A01N43/42 , A01N43/52 , A01N43/74 , A01N43/80 , C07D333/16 , C07D333/28 , C07D333/34 , C07D333/38 , C07D333/42 , C07D413/14 , C07D417/14
摘要： Bithienyl derivatives of the formula Ia ##STR1## where the substituents have the following meanings: R.sup.1, R.sup.2 hydrogen, halogen, nitro, formyl, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.3 -C.sub.8 -cycloalkoxy, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkylthio, substituted or unsubstituted C.sub.1 -C.sub.6 -alkylcarbonyl, substituted or unsubstituted C.sub.3 -C.sub.6 -cycloalkylcarbonyl, substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxycarbonyl and/or phenylcarbonyl;R.sup.3 hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl or C.sub.1 -C.sub.4 -haloalkoxy;A --CSNH.sub.2 ;substituted or unsubstituted oxazol-2-yl, oxazol-5-yl, isoxazol-3-yl, pyrazol-3-yl, pyrazol-5-yl, thiazol-2-yl or a corresponding benzofused radical;methods of manufacturing compounds Ia and agents containing a bithienyl derivative of the general formula I ##STR2## where B is --CSNH.sub.2 ;substituted or unsubstituted pyridyl, quinolinyl, phenyl, naphthyl, furyl, pyrrolyl, pyrazolyl, imidazolyl, oxazolyl, isoxazolyl, thiazolyl or a corresponding benzofused radical.
摘要翻译：式Ia Ia的双噻吩基衍生物其中取代基具有以下含义：R 1，R 2氢，卤素，硝基，甲酰基，C 1 -C 6 - 烷基，C 1 -C 6 - 卤代烷基，C 3 -C 8环烷基，C 3 -C 8 取代或未取代的C 1 -C 6 - 烷基羰基，取代或未取代的C 3 -C 6 - 环烷基羰基，取代或未取代的C 1 -C 6 - 烷氧基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 卤代烷氧基， C6烷氧基羰基和/或苯基羰基; R3，卤素，C1-C4烷基，C1-C4-烷氧基，C1-C4-烷硫基，C1-C4-卤代烷基或C1-C4-卤代烷氧基; A -CSNH2; 取代或未取代的恶唑-2-基，恶唑-5-基，异恶唑-3-基，吡唑-3-基，吡唑-5-基，噻唑-2-基或相应的苯并稠合基; 制备化合物Ia的方法和含有通式I的二噻吩基衍生物的试剂，其中B是-CSNH 2; 取代或未取代的吡啶基，喹啉基，苯基，萘基，呋喃基，吡咯基，吡唑基，咪唑基，恶唑基，异恶唑基，噻唑基或相应的苯并稠合基团。

3. 发明授权

US4963690A N-aminotriazole derivatives 失效
标题翻译： N-氨基三唑衍生物
公开(公告)号：US4963690A
公开(公告)日：1990-10-16
申请号：US418090
申请日：1989-10-06
申请人： Rainer Seele , Stefan Karbach , Reiner Kober , Matthias Zipplies , Hubert Sauter , Barbara A. Moore , Dale R. Carlson , Paul S. Zorner , Karl-Otto Westphalen , Bruno Wuerzer
发明人： Rainer Seele , Stefan Karbach , Reiner Kober , Matthias Zipplies , Hubert Sauter , Barbara A. Moore , Dale R. Carlson , Paul S. Zorner , Karl-Otto Westphalen , Bruno Wuerzer
IPC分类号： A01N43/64 , A01N43/653 , C07D249/08 , C07D521/00
CPC分类号： C07D231/12 , A01N43/653 , C07D233/56 , C07D249/08
摘要： N-aminotriazole derivatives of the general formulae Ia and Ib ##STR1## wherein R.sup.1 and R.sup.2 are each C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.5 -C.sub.8 -cycloalkenyl, tetrahydropyranyl or norbornyl, or phenyl, biphenyl, naphthyl or pyridyl, and the aromatic radicals may carry from one to five halogen atoms and/or from one to three of the following groups: hydroxyl, phenoxy, nitro, amino, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy and/or C.sub.1 -C.sub.4 -alkylthio, and their salts which are environmentally compatible and tolerated by crops.
摘要翻译：通式Ia和Ib的N-氨基三唑衍生物其中R 1和R 2各自为C 1 -C 8 - 烷基，C 3 -C 8 - 环烷基，C 5 -C 8 - 环烯基，四氢吡喃基或降冰片基或苯基，联苯基，萘基或吡啶基，芳基可以带有1-5个卤素原子和/或1-3个以下基团：羟基，苯氧基，硝基，氨基，氰基，C 1 -C 4 - 烷基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 卤代烷氧基和/或C 1 -C 4 - 烷硫基，以及它们与农作物环境相容和耐受的它们的盐。

4. 发明授权

US5034049A Thiophene-2-carboxylic acid derivatives, their preparation and their use for controlling undesirable plant growth 失效
标题翻译：噻吩-2-羧酸衍生物，其制备及其用于控制不期望的植物生长的用途
公开(公告)号：US5034049A
公开(公告)日：1991-07-23
申请号：US463163
申请日：1990-01-09
申请人： Reiner Kober , Rainer Seele , Hans-Juergen Neubauer , Thomas Saupe , Bruno Wuerzer , Norbert Meyer , Karl-Otto Westphalen
发明人： Reiner Kober , Rainer Seele , Hans-Juergen Neubauer , Thomas Saupe , Bruno Wuerzer , Norbert Meyer , Karl-Otto Westphalen
IPC分类号： A01N43/10 , C07D333/38 , C07D333/40 , C07D333/42
CPC分类号： C07D333/38 , A01N43/10
摘要： Thiophene-2-carboxylic acid derivatives of the general formula I ##STR1## where R.sup.1 to R.sup.3 are each hydrogen, halogen, branched or straight-chain C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.8 -alkoxy, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -haloalkoxy, nitro, cyano, unsubstituted phenyl or phenyl which is mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, halogen, C.sub.1 -C.sub.5 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.5 -haloalkoxy;X is --OR.sup.4 or --NH--OR.sup.5,R.sup.4 being branched or straight-chain C.sub.3 -C.sub.10 -alkynylalkyl which is unsubstituted or substituted by halogen; andR.sup.5 being branched or straight-chain C.sub.1 -C.sub.5 -alkyl which is unsubstituted or substituted by halogen, or branched or straight-chain C.sub.3 -C.sub.10 -alkynylalkyl which is unsubstituted or substituted by halogen;with the proviso that R.sup.4 is not propargyl when R.sup.2 and R.sup.3 are both hydrogen or when R.sup.2 is halogen or R.sup.3 is chlorine, methyl or methoxy.The compounds I are suitable for combating the growth of unwanted plants.
摘要翻译：通式I的噻吩-2-羧酸衍生物其中R 1至R 3各自为氢，卤素，支链或直链C 1 -C 6 - 烷基，C 1 -C 8 - 烷氧基，C 1 -C 6 - 卤代烷基，C 1 C 1-6卤代烷氧基，硝基，氰基，未取代的苯基或被C 1 -C 4 - 烷基，卤素，C 1 -C 5 - 卤代烷基，C 1 -C 4 - 烷氧基或C 1 -C 5 - 卤代烷氧基单 - X为-OR4或-NH-OR5，R4为未取代或被卤素取代的支链或直链C 3 -C 10 - 炔基烷基; 并且R 5是未被取代或被卤素取代的支链或直链C 1 -C 5 - 烷基，或未被取代或被卤素取代的支链或直链C 3 -C 10 - 炔基烷基; 条件是当R 2和R 3均为氢时或R 2为卤素或R 3为氯，甲基或甲氧基时，R 4不是炔丙基。化合物I适用于对抗不想要的植物的生长。

5. 发明授权

US5062879A 8-azolylmethylquinolines and herbicidal use thereof 失效
标题翻译： 8-AZOLYLMETHYLQUINOLINES及其除草剂
公开(公告)号：US5062879A
公开(公告)日：1991-11-05
申请号：US520810
申请日：1990-05-09
申请人： Rainer Seele , Gunter Brill , Reiner Kober , Thomas Saupe , Karl-Otto Westphalen , Bruno Wuerzer
发明人： Rainer Seele , Gunter Brill , Reiner Kober , Thomas Saupe , Karl-Otto Westphalen , Bruno Wuerzer
IPC分类号： A01N43/42 , A01N43/50 , A01N43/56 , A01N43/653 , C07D401/06
CPC分类号： C07D401/06 , A01N43/50 , A01N43/56 , A01N43/653
摘要： 8-Azolylmethylquinolines I ##STR1## (R=H, halogen, CN, C.sub.1 -C.sub.4 -alkyl; X=halogen; A=the 1-yl radical of a 5-membered, aromatic heterocycle with 2 or 3 nitrogen atoms in the ring, which may also bear further substituents; B=Cl, Br, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, an amine radical which may be mono- or disubstituted, a radical ZR.sup.4 where R.sup.4 =phenyl which may bear further substituents, and Z=oxygen, sulfur or an amine radical which may be alkylated) and the acid addition salts and metal complexes of I.The compounds I and the salts and metal complexes thereof are suitable as herbicides.
摘要翻译： 8-吡唑基甲基喹啉I（I）（R = H，卤素，CN，C 1 -C 4 - 烷基; X =卤素; A =具有2或3个氮原子的5元芳族杂环的1-基在环中，其还可以具有其它取代基; B = Cl，Br，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，可以被单取代或二取代的胺基，其中R 4 =可以承载的苯基进一步的取代基，Z =氧，硫或可被烷基化的胺基）和I的酸加成盐和金属络合物。化合物I及其盐和金属络合物适用作除草剂。

6. 发明授权

US5133799A N-aryltetrahydrophthalimides and herbicidal compositions thereof 失效
标题翻译： N-三氟甲磺酰嘧啶及其除草剂组合物
公开(公告)号：US5133799A
公开(公告)日：1992-07-28
申请号：US697036
申请日：1991-05-08
申请人： Rainer Seele , Lothar Rueb , Reiner Kober , Karl Eicken , Karl-Otto Westphalen , Bruno Wuerzer
发明人： Rainer Seele , Lothar Rueb , Reiner Kober , Karl Eicken , Karl-Otto Westphalen , Bruno Wuerzer
IPC分类号： A01N43/50 , A01N43/56 , A01N43/653 , C07D403/10 , C07D403/14 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/56 , A01N43/653 , C07D233/56 , C07D249/08 , C07D403/10 , C07D403/14
摘要： R.sup.1 is C.sub.1 -C.sub.4 -alkyl which may carry from one to five halogen atoms or one of the groups stated for X;R.sup.2 is a heteroaromatic structure bonded via a nitrogen atom, which has a 5-membered ring and contains, in addition to carbon ring members, from one to three nitrogen atoms, andR.sup.3 is halogen, C.sub.1 -C.sub.4 -alkylthio, one of the groups stated for R.sup.2 or phenylthio which in turn may carry from one to three of the following radicals: halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy or C.sub.1 -C.sub.4 -alkylthio, and where the phenylthio group may also carry halogen atoms such that the total number of radicals is 4 or 5,and salts thereof which can be used in agriculture, are suitable as herbicides. 2
摘要翻译：其中X是氢或卤素; R 1是可以携带1至5个卤素原子的C1-C4-烷基或为X表示的基团之一; R2是通过氮原子键合的杂芳族结构，其具有5元环，并且除了碳环成员之外还含有一个至三个氮原子，并且R 3是卤素，C 1 -C 4 - 烷硫基，其中一个基团对于R2或苯硫基，其又可以携带1-3个以下基团：卤素，C 1 -C 4 - 烷基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 卤代烷氧基或C 1 -C 4 - 烷硫基并且苯硫基也可以携带卤素原子使得基团的总数为4或5，并且其可用于农业的盐适用作除草剂。

7. 发明授权

US4940717A Fungicidal imidazolylmethyloxiranes 失效
标题翻译：杀真菌咪唑甲基环氧乙烷
公开(公告)号：US4940717A
公开(公告)日：1990-07-10
申请号：US319318
申请日：1989-03-06
申请人： Rainer Seele , Stefan Karbach , Bernd Janssen , Reiner Kober , Eberhard Ammermann , Gisela Lorenz
发明人： Rainer Seele , Stefan Karbach , Bernd Janssen , Reiner Kober , Eberhard Ammermann , Gisela Lorenz
IPC分类号： C07D405/06 , A01N43/50 , C07D405/14 , C07D521/00
CPC分类号： C07D249/08 , A01N43/50 , C07D231/12 , C07D233/56
摘要： Imidazolylmethyloxiranes of the general formula I ##STR1## where R is phenyl, pyridyl, tetrahydropyranyl, norbornyl, C.sub.3 -C.sub.12 -cycloalkyl or C.sub.5 -C.sub.8 -cycloalkenyl, these radicals being unsubstituted or substituted, and their plant-tolerated acid addition salts and metal complexes, and fungicides containing these compounds.
摘要翻译：其中R是苯基，吡啶基，四氢吡喃基，降冰片基，C 3 -C 12 - 环烷基或C 5 -C 8 - 环烯基的咪唑基甲基环氧乙烷，这些基团是未取代的或取代的，以及它们的植物耐受的酸加成盐和金属复合物和含有这些化合物的杀真菌剂。

8. 发明授权

US5006152A Azolylmethylcyclopropanes and their use as crop protection agents 失效
标题翻译：唑基甲基环丙烷及其作为农作物保护剂的用途
公开(公告)号：US5006152A
公开(公告)日：1991-04-09
申请号：US409310
申请日：1989-09-19
申请人： Rainer Seele , Reiner Kober , Stefan Karbach , Hubert Sauter , Eberhard Ammermann , Gisela Lorenz , Wilhelm Rademacher , Johann Jung
发明人： Rainer Seele , Reiner Kober , Stefan Karbach , Hubert Sauter , Eberhard Ammermann , Gisela Lorenz , Wilhelm Rademacher , Johann Jung
IPC分类号： A01N43/50 , A01N43/653 , A01N43/836 , C07D233/56 , C07D233/60 , C07D233/61 , C07D249/08 , C07D401/10 , C07D405/10 , C07D521/00
CPC分类号： C07D231/12 , A01N43/50 , A01N43/653 , C07D233/56 , C07D249/08 , C07D401/10
摘要： Azolylmethylcyclopropanes of the formula ##STR1## where R is alkyl, cycloalkyl, cycloalkenyl, tetrahydropyranyl, norbornyl, pyridyl, naphthyl, biphenyl or phenyl, and these radicals are substituted or unsubstituted, A is H, F, Cl or Br, and X is CH or N, their plant-tolerated acid addition salts and metal complexes, and fungicides and growth-regulating agents containing these compounds.
摘要翻译：其中R是烷基，环烷基，环烯基，四氢吡喃基，降冰片基，吡啶基，萘基，联苯基或苯基，并且这些基团是取代或未取代的，A是H，F，Cl或Br，X是 CH或N，其植物耐受酸加成盐和金属络合物，以及含有这些化合物的杀真菌剂和生长调节剂。

9. 发明授权

US5110829A 2,2'-thienylbenzothiophenes, their preparation and their use for controlling pests 失效
标题翻译： 2,2'-三苯并噻吩，其制备及其用于控制PESTS的用途
公开(公告)号：US5110829A
公开(公告)日：1992-05-05
申请号：US737738
申请日：1991-07-30
申请人： Reiner Kober , Hans Theobald , Uwe Kardorff , Christoph Kuenast , Peter Hofmeister , Rainer Seele , Gerhard Wagenblast
发明人： Reiner Kober , Hans Theobald , Uwe Kardorff , Christoph Kuenast , Peter Hofmeister , Rainer Seele , Gerhard Wagenblast
IPC分类号： A01N43/12 , C07D333/54 , C07D333/62 , C07D333/64
CPC分类号： C07D333/54 , A01N43/12
摘要： 2,2'-Thienylbenzothiophenes of the general formula I ##STR1## where R.sup.1 and R.sup.3 independently of one another are each halogen, alkyl, haloalkyl, alkoxy or haloalkoxy, R.sup.2 is hydrogen, halogen, alkyl, haloalkyl, alkoxy or haloalkoxy, n is 0, 1 or 2, and the radicals may be different when n is 2, and m is 0, 1, 2, 3 or 4, and the radicals may be different when m is 2, 3 or 4, processes for their preparation, pesticides containing them and the use thereof.
摘要翻译：其中R 1和R 3彼此独立地为卤素，烷基，卤代烷基，烷氧基或卤代烷氧基，R 2为氢，卤素，烷基，卤代烷基，烷氧基或卤代烷氧基，n为0,1,2'-噻吩基苯并噻吩，是0,1或2，当n为2时，基团可以不同，m为0,1,2,3或4，当m为2,3或4时，基团可以不同，其制备方法，含有它们的农药及其用途。

10. 发明授权

US5159117A Preparation of .alpha.,.alpha.-dialkoxy ketones 失效
标题翻译：（ALPHA），（ALPHA） - 二羟基酮的制备
公开(公告)号：US5159117A
公开(公告)日：1992-10-27
申请号：US747575
申请日：1991-08-20
申请人： Guenter Wegner , Stefan Karbach , Hubert Smuda , Eckhard Hickmann , Reiner Kober , Rainer Seele , Thomas Zierke
发明人： Guenter Wegner , Stefan Karbach , Hubert Smuda , Eckhard Hickmann , Reiner Kober , Rainer Seele , Thomas Zierke
IPC分类号： C07C45/68 , C07C45/71 , C07C49/175 , C07C49/255 , C07C49/517 , C07C49/84 , C07D307/46 , C07D333/22
CPC分类号： C07D333/22 , C07C45/68 , C07C45/71 , C07C49/175 , C07C49/255 , C07C49/517 , C07C49/84 , C07D307/46
摘要： A process for preparing .alpha.,.alpha.-dialkoxy ketones of the formula I ##STR1## where R.sup.1 and R.sup.2 are each, independently of one another, hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.3 -C.sub.20 -cycloalkyl, C.sub.4 -C.sub.30 -cycloalkylakyl, C.sub.9 -C.sub.30 -alkylcycloalkyl, unsubstituted or C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy-, halogen-, C.sub.1 -C.sub.4 -haloalkyl-, C.sub.1 -C.sub.4 -haloalkoxy-, phenyl-, phenoxy-, halophenyl-, halophenoxy- and/or cyano-substituted aryl, C.sub.7 -C.sub.20 -aralkyl or heterocyclyl,R.sup.2 is also ##STR2## R.sup.3 and R.sup.4 are each, independently of one another, C.sub.1 -C.sub.20 -alkyl, C.sub.3 -C.sub.20 -cycloalkyl, aryl, C.sub.7 -C.sub.20 -arylalkyl, or together are an unsubstituted or C.sub.1-C.sub.4 -alkyl- substituted C.sub.2 -C.sub.7 -alkylene chain andR.sup.5 is R.sup.1 or together with R.sup.1 is an unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted C.sub.2 -C.sub.7 -alkylene chain,which entails reacting ketones or aldehydes of the formula II ##STR3## with nitrites of the formula IIIR.sup.3/4 --(NO.sub.2).sub.n (III)where n is 1 or 2, and n is 2 when R.sup.3 and R.sup.4 together are an unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted C.sub.2 -C.sub.7 -alkylene chain, with the proviso that the nitrite radicals are located at the termini, or with a mixture of alcohol of the formula IVR.sup.3/4 --(OH).sub.n IVwhere n is 1 or 2, and n is 2 when R.sup.3 and R.sup.4 together are an unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted C.sub.2 -C.sub.7 -alkylene chain, with the proviso that the hydroxyl group is located at the terminus, and dinitrogen trioxide in a molar ratio of 2:1 in the presence of an acid catalyst at from 0.degree. to 170.degree. C.
摘要翻译：制备式I的α，α-二烷氧基酮的方法，其中R 1和R 2各自独立地为氢，C 1 -C 20 - 烷基，C 3 -C 20 - 环烷基，C 4 -C 30 - 环烷基，C 9 -C 30 - 烷基环烷基，未取代的或C 1 -C 8 - 烷基，C 1 -C 8 - 烷氧基 - ，卤素 - ，C 1 -C 4卤代烷基 - ，C 1 -C 4 - 卤代烷氧基 - ，苯基 - ，苯氧基 - ，卤代苯基 - ，卤代苯氧基 - 和/或氰基取代的芳基，C 7 -C 20 - 芳烷基或杂环基，R 2也是R 3和R 4彼此独立地为C 1 -C 20 - 烷基，C 3 -C 20 - 环烷基，芳基，或者一起是未取代的或C 1 -C 4烷基取代的C 2 -C 7亚烷基链，R 5是R 1或与R 1一起是未取代的或C 1 -C 4烷基取代的C 2 -C 7亚烷基链，其中需要使式II（II）的酮或醛与式III R3 / 4-（NO2）n（III）的亚硝酸盐反应，其中n为1或2，n为2，当R3和R4一起为未取代的或C 1 -C 4烷基取代的C 2 -C 7 - 亚烷基链条件是亚硝酸根自由基位于末端，或与式IV R3 / 4-（OH）n IV的醇的混合物，其中n为1或2，n为2，当R 3和R 4一起为未取代的或 C1-C4烷基取代的C2-C7-亚烷基链，条件是羟基位于末端，二氧化二氮在摩尔比为2:1的酸催化剂存在下，0℃至 170℃

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