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    • 1. 发明申请
    • PRECOATED FIN MATERIAL FOR HEAT EXCHANGERS AND HEAT EXCHANGER
    • 热交换器和热交换器的预制金属材料
    • US20140231052A1
    • 2014-08-21
    • US14117207
    • 2012-03-21
    • Reiko TakasawaToru Ishii
    • Reiko TakasawaToru Ishii
    • F28F3/02
    • F28F3/02B32B15/20B32B2255/06B32B2255/26B32B2307/728B32B2307/73C08G59/4261C08L61/20C08L61/28C09D5/00C09D163/00F28F17/005F28F19/04F28F2215/00F28F2245/02F28F2245/04
    • Provided is a precoated fin material for heat exchangers that allows the construction of a fin structure in which frost formation at the time of heater operation can be prevented to the extent possible, and under such a condition that condensation is liable to occur on a fin surface, a water droplet of condensed water can be quickly removed by bringing the water droplet into contact with a hydrophilic film, and as a result, a favorable heat exchange function can be maintained without any increase in ventilation resistance. Also provided is a heat exchanger including such fin structure. The precoated fin material for heat exchangers includes: a fin substrate formed of an aluminum plate material; a crosslinked hydrophobic film having a frost formation-suppressing effect, the crosslinked hydrophobic film being formed on one surface of the fin substrate and being formed of an aqueous hydrophobic coating composition containing a resin (A) having a fluorine atom-containing group, a quaternary ammonium salt group-containing modified epoxy resin (B), and an amino resin (C) at predetermined ratios; and a hydrophilic film having a condensed water-removing effect, the hydrophilic film being formed on another surface of the fin substrate. The heat exchanger includes a fin structure in which a hydrophobic surface having a frost formation-suppressing effect and a hydrophilic surface having a condensed water-removing effect are opposite to each other.
    • 提供一种用于热交换器的预涂布翅片材料,其允许构造翅片结构,其中可以在可能的程度上防止加热器操作时的结霜,并且在翅片表面上容易发生冷凝的条件下 通过使水滴与亲水膜接触,可以快速除去冷凝水的水滴,结果,可以保持良好的热交换功能而不会增加通气阻力。 还提供了包括这种翅片结构的热交换器。 用于热交换器的预涂布翅片材料包括:由铝板材料形成的散热片基板; 具有霜冻抑制效果的交联的疏水性膜,所述交联疏水性膜形成在所述散热片基板的一个表面上,并且由含有含氟原子的基团的树脂(A),含有氟原子的基团的四氢呋喃 含铵盐基团的改性环氧树脂(B)和氨基树脂(C); 以及具有冷凝除水效果的亲水性膜,所述亲水膜形成在散热片基板的另一表面上。 热交换器包括翅片结构,其中具有霜冻抑制效果的疏水性表面和具有冷凝除水效果的亲水性表面彼此相反。
    • 2. 发明授权
    • Water-based hydrophilic coatings and a process for manufacturing
precoated fin materials for heat exchangers with use of said coatings
    • 水性亲水涂料以及使用所述涂料制造用于热交换器的预涂翅片材料的方法
    • US5916635A
    • 1999-06-29
    • US894812
    • 1998-03-26
    • Toru IshiiKazuhiko YamazakiReiko Takasawa
    • Toru IshiiKazuhiko YamazakiReiko Takasawa
    • C09D5/00F28F13/18B05D3/02
    • F28F13/18C09D5/00F28F2245/02
    • This invention relates to water-based hydrophilic coatings suitable for giving hydrophilicity primarily to the surface of aluminum and to a process for manufacturing precoated fin materials for heat exchangers with use of said coatings. The coatings are composed of colloidal silica with a dispersed particle diameter of 5 to 100 nm, water-soluble polymers containing at least carboxylic acid polymers, anionic surfactants and water; the colloidal silica and the water-soluble polymers are present at a weight ratio of 30:70 to 70:30 on a solid basis in a combined content of 4 to 20% by weight, the content of carboxyl group in the carboxylic acid polymers contained in the water-soluble polymers is 20 to 63% by weight, the anionic surfactants are alkali salts of sulfosuccinic acid monoalkyl esters with alkyl groups containing 1 to 18 carbon atoms and present in an amount of 5 to 20% by weight of the combined solid content of the colloidal silica and the water-soluble polymers, and the pH is 1 to 5 as a whole. The process for manufacturing precoated fin materials for heat exchangers comprises applying the water-based hydrophilic coatings to the surface of aluminum fin materials to a solid weight of 0.3 to 1.5 g/m.sup.2 and drying under heat.
    • PCT No.PCT / JP97 / 01024 Sec。 371日期:1998年3月26日 102(e)1998年3月26日PCT 1997年3月26日PCT公布。 公开号WO97 / 35938 日期1997年10月2日本发明涉及适用于主要给予铝的亲水性的水性亲水性涂料以及使用所述涂层制造用于热交换器的预涂翅片材料的方法。 涂层由分散粒径为5-100nm的胶态二氧化硅组成,至少含有羧酸聚合物,阴离子表面活性剂和水的水溶性聚合物; 胶体二氧化硅和水溶性聚合物的重量比为30:70至70:30,固体含量为4至20重量%,羧酸聚合物中的羧基含量为 在水溶性聚合物中为20〜63重量%,阴离子表面活性剂为含有1〜18个碳原子的烷基的磺基琥珀酸单烷基酯的碱金属盐,其含量为组合固体重量的5〜20重量% 胶体二氧化硅和水溶性聚合物的含量,pH为1〜5。 用于制造用于热交换器的预涂翅片材料的方法包括将水性亲水涂层施加到铝翅片材料的表面至0.3-1.5g / m 2的固体重量,并在加热下进行干燥。