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    • 4. 发明申请
    • METHOD FOR PRODUCING POLYACRYLIC ACID (SALT)-BASED WATER ABSORBENT RESIN POWDER
    • 生产聚丙烯酸(盐) - 水吸收树脂粉末的方法
    • US20130102750A1
    • 2013-04-25
    • US13643682
    • 2011-04-27
    • Yusuke WatanabeKazushi ToriiKozo NogiKunihiko IshizakiReiko NakatsuruShigeru Sakamoto
    • Yusuke WatanabeKazushi ToriiKozo NogiKunihiko IshizakiReiko NakatsuruShigeru Sakamoto
    • C08J3/12C08F122/10
    • C08J3/12C08F6/008C08F122/105C08F220/06C08J3/122C08J3/245C08J2333/02C08L33/02
    • A water absorbent resin having less fine powder or powdery dust and a controlled particle size is provided, and the water absorption rate of the water absorbent resin is increased by a simple method at low cost, while maintaining or improving other physical properties such as liquid permeability. Disclosed is a method for producing a polyacrylic acid (salt)-type water absorbent resin powder, which includes, in sequence, a step of polymerizing an aqueous solution of acrylic acid (salt)-type monomer; a step of gel-crushing a gel of a water-containing gel-like crosslinked polymer during polymerization or after polymerization; a step of drying the water-containing gel-like crosslinked polymer; and a step of pulverizing and classifying the dried polymer, wherein water absorbent resin fine particles having a particle size of less than 150 μm or a hydrated-particles thereof is added to a step prior to the drying step, and in the drying step, hot air drying is carried out with a hot air having an average flow velocity of 1.0 to 3.0 [m/s], a dew point of 30° C. to 100° C., and a hot air temperature of 140° C. to 235° C.
    • 提供具有较少粉末或粉末粉尘和受控粒度的吸水性树脂,并且通过简单的方法以低成本提高吸水性树脂的吸水率,同时保持或改善其它物理性质如液体渗透性 。 公开了一种聚丙烯酸(盐)型吸水性树脂粉末的制造方法,其中,依次包括使丙烯酸(盐)型单体的水溶液聚合的工序; 在聚合过程中或聚合后凝胶化凝胶状凝胶状交联聚合物凝胶的步骤; 干燥含水凝胶状交联聚合物的工序; 以及将干燥聚合物粉碎分级的步骤,其中将粒径小于150μm的吸水性树脂细颗粒或其水合物颗粒加入到干燥步骤之前的步骤中,并且在干燥步骤中,热 使用平均流速为1.0〜3.0 [m / s],露点为30℃〜100℃,热风温度为140℃〜235℃的热风进行空气干燥 C。
    • 5. 发明授权
    • Method for producing polyacrylic acid (salt) type water absorbent resin powder
    • 聚丙烯酸(盐)型吸水性树脂粉末的制造方法
    • US08765906B2
    • 2014-07-01
    • US13643682
    • 2011-04-27
    • Yusuke WatanabeKazushi ToriiKozo NogiKunihiko IshizakiReiko NakatsuruShigeru Sakamoto
    • Yusuke WatanabeKazushi ToriiKozo NogiKunihiko IshizakiReiko NakatsuruShigeru Sakamoto
    • C08G63/02C08G63/00
    • C08J3/12C08F6/008C08F122/105C08F220/06C08J3/122C08J3/245C08J2333/02C08L33/02
    • A water absorbent resin having less fine powder or powdery dust and a controlled particle size is provided, and the water absorption rate of the water absorbent resin is increased by a simple method at low cost, while maintaining or improving other physical properties such as liquid permeability. Disclosed is a method for producing a polyacrylic acid (salt)-type water absorbent resin powder, which includes, in sequence, a step of polymerizing an aqueous solution of acrylic acid (salt)-type monomer; a step of gel-crushing a gel of a water-containing gel-like crosslinked polymer during polymerization or after polymerization; a step of drying the water-containing gel-like crosslinked polymer; and a step of pulverizing and classifying the dried polymer, wherein water absorbent resin fine particles having a particle size of less than 150 μm or a hydrated-particles thereof is added to a step prior to the drying step, and in the drying step, hot air drying is carried out with a hot air having an average flow velocity of 1.0 to 3.0 [m/s], a dew point of 30° C. to 100° C., and a hot air temperature of 140° C. to 235° C.
    • 提供具有较少粉末或粉末粉尘和受控粒度的吸水性树脂,并且通过简单的方法以低成本提高吸水性树脂的吸水率,同时保持或改善其它物理性质如液体渗透性 。 公开了一种聚丙烯酸(盐)型吸水性树脂粉末的制造方法,其中,依次包括使丙烯酸(盐)型单体的水溶液聚合的工序; 在聚合过程中或聚合后凝胶化凝胶状凝胶状交联聚合物凝胶的步骤; 干燥含水凝胶状交联聚合物的工序; 将干燥聚合物粉碎并分级的步骤,其中在干燥步骤之前的步骤中加入粒径小于150μm的吸水性树脂微粒或其水合颗粒,并且在干燥步骤中,热 使用平均流速为1.0〜3.0 [m / s],露点为30℃〜100℃,热风温度为140℃〜235℃的热风进行空气干燥 C。
    • 7. 发明申请
    • Aqueous-Liquid-Absorbing Agent and its Production Process
    • 水性吸液剂及其制备方法
    • US20070207924A1
    • 2007-09-06
    • US10593706
    • 2005-03-11
    • Hiroyuki IkeuchiKazushi ToriiShigeru SakamotoTaku IwamuraSayaka Machida
    • Hiroyuki IkeuchiKazushi ToriiShigeru SakamotoTaku IwamuraSayaka Machida
    • B01J20/26
    • C08J3/245
    • An object of the present invention is to provide an aqueous-liquid-absorbing agent which comprises water-absorbent resin particles as essential components and is suitable for uses in sanitary materials. As a means of achieving this object, an aqueous-liquid-absorbing agent according to the present invention is an aqueous-liquid-absorbing agent comprising water-absorbent resin particles as essential components, wherein the water-absorbent resin particles are obtained by a process including the step of polymerizing a water-soluble ethylenically unsaturated monomer and have a crosslinked structure in their inside; with the aqueous-liquid-absorbing agent exhibiting an absorption rate (FSR) of not less than 0.2 g/g/s, a water absorption capacity (CRC) of 5 to 25 g/g, a saline flow conductivity (SFC) of not less than 400×10−7 cm3·s/g, and a wet porosity of not less than 20%. A process according to the present invention for obtaining such an aqueous-liquid-absorbing agent is characterized by comprising the steps of: obtaining a hydrogel from an aqueous monomer solution including a water-soluble ethylenically unsaturated monomer and an internal-crosslinking agent of not less than 0.2 mol % in ratio to the monomer; and then extruding this hydrogel from a perforated structure having perforation diameters in the range of 0.3 to 6.4 mm to thereby pulverize the hydrogel.
    • 本发明的目的是提供一种含水吸收剂,其包含作为必需成分的吸水性树脂粒子,适用于卫生材料。 作为实现该目的的手段,本发明的水性液体吸收剂是以吸水性树脂粒子为必须成分的水性液体吸收剂,其中吸水性树脂粒子是通过 包括聚合水溶性烯键式不饱和单体并在其内部具有交联结构的步骤; 吸水率(FSR)为0.2g / g / s以上,吸水容量(CRC)为5〜25g / g,盐水流动电导率(SFC)不为 小于400×10 -3 cm 3 / g,湿气孔率不小于20%。 根据本发明的用于获得这种水性液体吸收剂的方法的特征在于包括以下步骤:从包含水溶性烯键式不饱和单体和不少于少量的内部交联剂的单体水溶液获得水凝胶 与单体的比例为0.2摩尔%以上; 然后从穿孔直径在0.3至6.4mm范围内的穿孔结构体挤出该水凝胶,从而粉碎水凝胶。