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    • 1. 发明授权
    • Aluminum-silicon alloy having reduced microporosity
    • 具有降低微孔的铝硅合金
    • US07666353B2
    • 2010-02-23
    • US11042252
    • 2005-01-25
    • Raymond J. DonahueTerrance M. ClearyKevin R. Anderson
    • Raymond J. DonahueTerrance M. ClearyKevin R. Anderson
    • C22C21/04
    • C22C21/04C22C21/02
    • An aluminum silicon die cast alloy having a very low iron content and relatively high strontium content that prevents soldering to dies into die casting process. The alloys of the present invention also have a modified eutectic silicon and modified iron morphology, when iron is present, resulting in low microporosity and high impact properties. The alloy comprises 6-22% by weight silicon, 0.05 to 0.20% by weight strontium and the balance aluminum. Preferably, the alloy of the present invention contains in weight percent: 6-20% silicon, 0.05-0.10% strontium, 0.40% maximum iron and most preferably 0.20% maximum iron, 4.5% maximum copper, 0.50% maximum manganese, 0.60% maximum magnesium, 3.0% maximum zinc, balance aluminum. On cooling from the solution temperature, the strontium serves to modify the eutectic silicon structure as well as create an iron phase morphology change if iron is present, facilitating feeding through the aluminum interdendritic matrix. This, in turn, creates a finished die cast product with extremely low levels of microporosity defects. The strontium content also appears to create a non-wetting monolayer of strontium atoms on the surface of a molten casting, preventing die soldering, even at very low iron contents. The alloy may be used to cast any type of object and is particularly suited for casting outboard marine propellers, driveshaft housings, gear case housings, Gimbel rings and engine blocks.
    • 铝硅压铸合金,具有非常低的铁含量和相对较高的锶含量,防止模具焊接到压铸过程中。 当存在铁时,本发明的合金还具有改性的共晶硅和改性的铁形态,导致低微孔性和高冲击性。 该合金包含6-22重量%的硅,0.05-0.20重量%的锶和余量的铝。 优选地,本发明的合金优选含有6-20%硅,0.05-0.10%锶,0.40%最大铁,最优选0.20%最大铁,4.5%最大铜,最大锰0.50%,最大0.60% 镁,3.0%最大锌,余量铝。 在从溶液温度冷却时,锶用于改变共晶硅结构,并且如果存在铁,则产生铁相形态变化,促进通过铝树枝状间质基质进料。 这又产生了具有极低水平的微孔缺陷的成品压铸产品。 锶含量也似乎在熔融铸件的表面上产生锶原子的非润湿单层,即使在非常低的铁含量下也能防止模具焊接。 该合金可用于铸造任何类型的物体,特别适用于铸造船外螺旋桨,传动轴壳体,齿轮箱壳体,Gimbel环和发动机缸体。
    • 3. 发明授权
    • Aluminum-silicon alloy having reduced microporosity and method for casting the same
    • 具有降低的微孔的铝硅合金及其铸造方法
    • US07347905B1
    • 2008-03-25
    • US11174764
    • 2005-07-05
    • Raymond J. DonahueTerrance M. ClearyKevin R. Anderson
    • Raymond J. DonahueTerrance M. ClearyKevin R. Anderson
    • C22C21/04
    • C22C21/04C22C21/02
    • An aluminum-silicon lost foam casting alloy having reduced microporosity and a method for casting the same is herein disclosed. A preferred lost foam cast alloy consists essentially of 6 to 12% by weight silicon and preferably 9.0 to 9.5% by weight silicon, 0.035-0.30% strontium, 0.40% maximum iron, 0.45% maximum copper, 0.49% maximum manganese, 0.60% maximum magnesium, 3.0% maximum zinc, and the balance aluminum. Most preferably, the lost foam alloy is free from iron, titanium and boron. However, such elements may exist at trace levels. Most preferably, the alloy is lost foam cast with the process that applies at least 10 atmospheres of pressure during solidification. However, the range may be 5 to 60 atmospheres. The strontium addition is greater than 0.005% by weight and most preferably greater than 0.05% by weight. In accordance with the present disclosure, alloys having substantially decreased tensile liquid failure defects and substantially decreased surface puncture defects in comparison to conventional lost foam cast aluminum silicon alloys are obtained. Further, hydrogen porosity formation is substantially completely suppressed and surface porosity defects are substantially decreased in comparison to conventional lost foam silicon alloys when casting lost foam cast alloys in accordance with the claims of the instant disclosure. The instant disclosure further discloses aluminum silicon alloys that may be utilized in both the lost foam with pressure and the die casting processes.
    • 本文公开了具有降低的微孔性的铝硅损失泡沫铸造合金及其铸造方法。 优选的失去泡沫铸造合金基本上由6-12重量%的硅组成,优选的是硅,9.0- 9.5重量%的硅,0.035-0.30%的锶,0.40%的最大铁,最大铜的0.45%,最大锰的0.49%,最大的0.60% 镁,3.0%最大锌,余量为铝。 最优选地,失去的泡沫合金不含铁,钛和硼。 然而,这些元素可以以痕量水平存在。 最优选的是,合金是在熔化过程中至少施加至少10个大气压的过程而失去的泡沫铸造。 然而,该范围可以是5至60个大气压。 锶添加量大于0.005重量%,最优选大于0.05重量%。 根据本公开,获得了与常规的失去泡沫铸造铝硅合金相比,具有显着降低的拉伸液体破坏缺陷和显着降低的表面穿孔缺陷的合金。 此外,根据本公开的权利要求,当铸造失去泡沫的铸造合金时,与常规的失去泡沫硅合金相比,基本上完全抑制了氢气孔隙形成,并且表面孔隙率缺陷显着降低。 本公开进一步公开了可以用于压力失去的泡沫和压铸工艺中的铝硅合金。
    • 4. 发明授权
    • Hypoeutectic aluminum-silicon alloy having reduced microporosity
    • 低共晶铝硅合金具有降低的微孔
    • US06923935B1
    • 2005-08-02
    • US10429098
    • 2003-05-02
    • Raymond J. DonahueTerrance M. ClearyKevin R. Anderson
    • Raymond J. DonahueTerrance M. ClearyKevin R. Anderson
    • C22C21/02C22C21/04
    • C22C21/04C22C21/02
    • A hypoeutectic aluminum silicon casting alloy having a refined primary silicon particle size and a modified iron morphology. The alloy includes 10 to 11.5% by weight silicon, 0.10 to 0.70% by weight magnesium and also contains 0.05 to 0.07% by weight strontium. On cooling from the solution temperature, the strontium serves to modify the silicon eutectic structure as well as create an iron phase morphology change. Such changes facilitate feeding through the aluminum interdendritic matrix. This, in turn, creates a finished die cast product with extremely low levels of microporosity defects. The alloy may be used to cast engine blocks for marine outboard and stern drive motors. Furthermore, when the magnesium levels are adjusted to approximately 0.10 to 0.20% by weight magnesium, propellers having a highly advantageous ductility may be obtained.
    • 具有精制一次硅粒径和改性铁形态的亚共晶铝硅铸造合金。 该合金包括10〜11.5重量%的硅,0.10〜0.70重量%的镁,还含有0.05〜0.07重量%的锶。 在从溶液温度冷却时,锶用于改变硅共晶结构以及产生铁相形态变化。 这种变化有助于通过铝树枝状间质基体进料。 这又产生了具有极低水平的微孔缺陷的成品压铸产品。 该合金可用于铸造船用舷外驱动电机的发动机缸体。 此外,当将镁水平调节至约0.10至0.20重量%的镁时,可以获得具有高有利延展性的螺旋桨。