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    • 10. 发明授权
    • Double layer electrode and barrier system on hemispherical grain silicon for use with high dielectric constant materials and methods for fabricating the same
    • 用于高介电常数材料的半球形晶粒硅上的双层电极和屏障系统及其制造方法
    • US06399459B2
    • 2002-06-04
    • US09892594
    • 2001-06-27
    • Husam N. Al-ShareefScott DeBoerRandhir Thakur
    • Husam N. Al-ShareefScott DeBoerRandhir Thakur
    • H01L2120
    • H01L28/84H01L27/10814H01L28/55
    • A high surface area capacitor comprising a double metal layer (an electrode metal and barrier material) deposited on hemispherical grain (HSG) silicon, wherein a high dielectric constant (HDC) material is deposited over the double metal layer. The high surface area capacitor is complete with an upper cell plate electrode deposited over the HDC material. The double metal layer preferably comprises one noble metal, such as platinum or palladium, for the electrode metal and an oxidizable metal, such as ruthenium, iridium, or molybdenum, for the barrier material. The noble metal, such as platinum metal, alone would normally allow oxygen to diffuse into and oxidize any adhesion layer (making the adhesion layer less conductive) and/or undesirably oxidize any silicon-containing material during the deposition of the HDC material. Thus, the barrier metal is used to form a conducting oxide layer or a conducting layer which stops the oxygen diffusion. The HSG polysilicon provides an enhanced surface roughness that boosts cell capacitance. The HDC material, preferably BST or the like, is also used to boost cell capacitance.
    • 包括沉积在半球形晶粒(HSG)硅上的双金属层(电极金属和阻挡材料)的高表面积电容器,其中在双金属层上沉积高介电常数(HDC)材料。 高表面积电容器完成了沉积在HDC材料上的上电池板电极。 双金属层优选包含用于电极金属的一种贵金属,例如铂或钯,以及用于阻挡材料的可氧化金属,例如钌,铱或钼。 单独的贵金属,例如铂金属,通常会允许氧气在HDC材料的沉积过程中扩散并氧化任何粘附层(使粘合层导电性差)和/或不期望地氧化任何含硅材料。 因此,阻挡金属用于形成阻止氧扩散的导电氧化物层或导电层。 HSG多晶硅提供增强的表面粗糙度,提高电池电容。 HDC材料,优选BST等,也用于提高电池电容。