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1. 发明申请

US20100024134A1 STRETCH FABRICS WITH IMPROVED CHEMICAL RESISTANCE 失效
标题翻译：具有改善耐化学性的织物
公开(公告)号：US20100024134A1
公开(公告)日：2010-02-04
申请号：US12472739
申请日：2009-08-05
申请人： Rona L. Reid , Thoi H. Ho , Selim Bensason , Rajen M. Patel , Antonio Batistini
发明人： Rona L. Reid , Thoi H. Ho , Selim Bensason , Rajen M. Patel , Antonio Batistini
IPC分类号： D06M11/40 , D06M11/38 , D06M11/30 , D06M11/50
CPC分类号： D04B21/16 , D06M11/30 , D06M11/40 , D06M11/50 , D06M13/08 , G01N33/36 , Y10T442/2861
摘要： Durable stretch fabrics are made and processed from one or more crosslinked, heat-resistant olefin elastic fibers, e.g., a substantially linear, homogeneously branched ethylene polymer. The fabrics can be made by any process, e.g., weaving, knitting, etc., and from any combination of crosslinked, heat-resistant olefin elastic and inelastic (“hard”) fibers, e.g., cotton and wool. These fabrics exhibit excellent chemical, e.g., chlorine, resistance and durability, e.g., they retain their shape and feel (“hand”) over repeated exposure to processing conditions, e.g., stone-washing, dye-stripping, PET-dyeing and the like, and service conditions, e.g., washing, drying, etc.
摘要翻译：耐久的拉伸织物由一种或多种交联的耐热烯烃弹性纤维制成和加工，例如基本上线性均匀支化的乙烯聚合物。织物可以通过任何方法制造，例如编织，编织等，以及交联，耐热烯烃弹性和非弹性（“硬”）纤维如棉和羊毛的组合。这些织物表现出优异的化学性质，例如氯，耐性和耐久性，例如，它们在反复暴露于加工条件（例如石洗，染料剥离，PET染色等）中保持其形状和手感（“手”）和服务条件，如洗涤，干燥等

2. 发明授权

US07727286B2 Stretch fabrics with improved chemical resistance 失效
标题翻译：具有改善耐化学性的拉伸织物
公开(公告)号：US07727286B2
公开(公告)日：2010-06-01
申请号：US12472739
申请日：2009-08-05
申请人： Rona L. Reid , Thoi H. Ho , Selim Bensason , Rajen M. Patel , Antonio Batistini
发明人： Rona L. Reid , Thoi H. Ho , Selim Bensason , Rajen M. Patel , Antonio Batistini
IPC分类号： D06L3/08 , D06L3/00
CPC分类号： D04B21/16 , D06M11/30 , D06M11/40 , D06M11/50 , D06M13/08 , G01N33/36 , Y10T442/2861
摘要： Durable stretch fabrics are made and processed from one or more crosslinked, heat-resistant olefin elastic fibers, e.g., a substantially linear, homogeneously branched ethylene polymer. The fabrics can be made by any process, e.g., weaving, knitting, etc., and from any combination of crosslinked, heat-resistant olefin elastic and inelastic (“hard”) fibers, e.g., cotton and wool. These fabrics exhibit excellent chemical, e.g., chlorine, resistance and durability, e.g., they retain their shape and feel (“hand”) over repeated exposure to processing conditions, e.g., stone-washing, dye-stripping, PET-dyeing and the like, and service conditions, e.g., washing, drying, etc.
摘要翻译：耐久的拉伸织物由一种或多种交联的耐热烯烃弹性纤维制成和加工，例如基本上线性均匀支化的乙烯聚合物。织物可以通过任何方法制造，例如编织，编织等，以及交联，耐热烯烃弹性和非弹性（“硬”）纤维如棉和羊毛的组合。这些织物表现出优异的化学性质，例如氯，耐性和耐久性，例如，它们在反复暴露于加工条件（例如石洗，染料剥离，PET染色等）中保持其形状和手感（“手”）和服务条件，如洗涤，干燥等

3. 发明授权

US07955539B2 Reversible, heat-set, elastic fibers, and method of making and article made from same 有权
标题翻译：可逆，热定型，弹性纤维，以及制造方法和由其制成的制品
公开(公告)号：US07955539B2
公开(公告)日：2011-06-07
申请号：US10507230
申请日：2003-03-11
申请人： Rajen M. Patel , Rona L Reid , Antonio Batistini , Selim Bensason , Thoi H. Ho
发明人： Rajen M. Patel , Rona L Reid , Antonio Batistini , Selim Bensason , Thoi H. Ho
IPC分类号： B29C45/14 , B29C41/00 , D06C3/00 , D03D15/04 , D04H1/00 , D06B1/02
CPC分类号： D03D15/08 , D01F6/30 , D01F6/70 , D02G3/32 , D02G3/328 , D02J1/22 , D03D15/00 , D03D15/0027 , D04B1/16 , D04H1/4291 , D04H1/4358 , D10B2201/02 , D10B2201/06 , D10B2211/02 , D10B2211/04 , D10B2321/02 , D10B2321/021 , D10B2321/022 , D10B2331/02 , D10B2331/04 , D10B2401/041 , D10B2401/061 , D10B2401/14 , D10B2501/00 , D10B2505/08 , D10B2509/00 , Y10T442/601
摘要： A reversible, heat-set covered fiber is described, the covered fiber comprising: A. A core comprising an elastic fiber comprising a substantially crosslinked, temperature-stable, olefin polymer, and B. A cover comprising an inelastic fiber. The fiber is heat-set by a method comprising: (a) Stretching the covered fiber by applying a stretching force to the covered fiber; (b) Heating the stretched covered fiber of (a) to a temperature in excess of the crystalline melting point of the olefin polymer for a period of time sufficient to at least partially melt the olefin polymer; (c) Cooling the stretched and heated covered fiber of (b) to a temperature below the crystalline melting point of the olefin polymer for a period of time sufficient to solidify the polymer; and (d) Removing the stretching force from the covered fiber.
摘要翻译：描述了可逆的热固覆盖纤维，所述被覆纤维包括：A.包含包含基本交联的温度稳定的烯烃聚合物的弹性纤维的芯，以及B.包含非弹性纤维的覆盖物。纤维通过以下方法进行热定形，该方法包括：（a）通过向被覆纤维施加拉伸力来拉伸被覆纤维; （b）将（a）的拉伸的被覆纤维加热到超过烯烃聚合物的结晶熔点的温度足以至少部分地熔化烯烃聚合物的时间; （c）将（b）的拉伸和加热的被覆纤维冷却至低于烯烃聚合物的结晶熔点的温度足以固化聚合物的时间; 和（d）从被覆纤维上去除拉伸力。

4. 发明授权

US06803014B2 Method of making elastic articles having improved heat-resistance 有权
标题翻译：制造具有改善的耐热性的弹性制品的方法
公开(公告)号：US06803014B2
公开(公告)日：2004-10-12
申请号：US10192223
申请日：2002-07-10
申请人： Thoi H. Ho , Selim Bensason , Rajen M. Patel , Kimberly S. Houchens , Rona L. Reid , Pak-Wing S. Chum , Leonie K. Walsh
发明人： Thoi H. Ho , Selim Bensason , Rajen M. Patel , Kimberly S. Houchens , Rona L. Reid , Pak-Wing S. Chum , Leonie K. Walsh
IPC分类号： B29C3508
CPC分类号： D04B1/18 , C08L51/06 , C08L53/025 , C08L2666/24 , C08L2666/04 , C08L2666/02
摘要： The present invention relates to a method for making a heat-resistant elastic article and a heat-resistant elastic article. The invention especially relates to a method of making elastic fibers and polymeric elastic fibers wherein the elastic fibers are capable of withstanding dyeing and heat-setting processes that typically are conducted at elevated temperatures (such as 110-230° C. and especially at greater than or equal to 130° C. for minutes). The inventive method comprises radiation crosslinking an article (or plurality of articles) under an inert or oxygen limited atmosphere (for example, in N2, argon, helium, carbon dioxide, xenon and/or a vacuum) wherein the article (or articles) comprises at least one amine stabilizer and preferably another optional stabilizer additive. More preferably, the radiation crosslinking is performed at a low temperature (−50 to 40° C.). The elastic article (or articles) comprises a homogeneously branched ethylene interpolymer (preferably a substantially linear ethylene interpolymer), a substantially hydrogenated block polymer, or a combination of the two. The heat-resistant elastic articles (especially fibers) are useful in various durable or repeated-use fabric applications such as, but not limited to, clothing, under-garments, and sports apparel. The heat-resistant elastic fibers can be conveniently formed into fabrics using well-known techniques such as, for example, by using co-knitting techniques with cotton, nylon, and/or polyester fibers.
摘要翻译：本发明涉及一种制造耐热弹性制品和耐热弹性制品的方法。本发明特别涉及一种制造弹性纤维和聚合物弹性纤维的方法，其中弹性纤维能够耐受染色和热定型过程，其通常在升高的温度（例如110-230℃，特别是大于或等于130℃，分钟）。本发明的方法包括在惰性或氧气限制的气氛（例如，在N 2，氩气，氦气，二氧化碳，氙气和/或真空中）中辐射交联物品（或多个制品），其中制品（或制品）包含至少一种胺稳定剂，优选另一种任选的稳定剂添加剂。更优选地，辐射交联在低温（-50至40℃）下进行。弹性制品（或制品）包含均匀支化的乙烯互聚物（优选基本上为线性的乙烯互聚物），基本上氢化的嵌段聚合物或两者的组合。耐热弹性制品（特别是纤维）可用于各种耐用或重复使用的织物应用，例如但不限于衣服，衣服和运动服装。耐热弹性纤维可以使用众所周知的技术方便地形成织物，例如通过使用与棉，尼龙和/或聚酯纤维的共同编织技术。

5. 发明授权

US06437014B1 Method of making elastic articles having improved heat-resistance 失效
标题翻译：制造具有改善的耐热性的弹性制品的方法
公开(公告)号：US06437014B1
公开(公告)日：2002-08-20
申请号：US09627534
申请日：2000-07-28
申请人： Thoi H. Ho , Selim Bensason , Rajen M. Patel , Kimberly S. Houchens , Rona L. Reid , Pak-Wing S. Chum , Leonie K. Walsh
发明人： Thoi H. Ho , Selim Bensason , Rajen M. Patel , Kimberly S. Houchens , Rona L. Reid , Pak-Wing S. Chum , Leonie K. Walsh
IPC分类号： C08K513
CPC分类号： D04B1/18 , C08L51/06 , C08L53/025 , C08L2666/24 , C08L2666/04 , C08L2666/02
摘要： The present invention relates to a method for making a heat-resistant elastic article and a heat-resistant elastic article. The invention especially relates to a method of making elastic fibers and polymeric elastic fibers wherein the elastic fibers are capable of withstanding dyeing and heat-setting processes that typically are conducted at elevated temperatures (such as 110-230° C. and especially at greater than or equal to 130° C. for minutes). The inventive method comprises radiation crosslinking an article (or plurality of articles) under an inert or oxygen limited atmosphere (for example, in N2, argon, helium, carbon dioxide, xenon and/or a vacuum) wherein the article (or articles) comprises at least one amine stabilizer and preferably another optional stabilizer additive. More preferably, the radiation crosslinking is performed at a low temperature (−50 to 40° C.). The elastic article (or articles) comprises a homogeneously branched ethylene interpolymer (preferably a substantially linear ethylene interpolymer), a substantially hydrogenated block polymer, or a combination of the two. The heat-resistant elastic articles (especially fibers) are useful in various durable or repeated-use fabric applications such as, but not limited to, clothing, under-garments, and sports apparel. The heat-resistant elastic fibers can be conveniently formed into fabrics using well-known techniques such as, for example, by using co-knitting techniques with cotton, nylon, and/or polyester fibers.
摘要翻译：本发明涉及一种制造耐热弹性制品和耐热弹性制品的方法。本发明特别涉及一种制造弹性纤维和聚合物弹性纤维的方法，其中弹性纤维能够耐受染色和热定型过程，其通常在升高的温度（例如110-230℃，特别是大于或等于130℃，分钟）。本发明的方法包括在惰性或氧气限制的气氛（例如，在N 2，氩气，氦气，二氧化碳，氙气和/或真空中）中辐射交联物品（或多个制品），其中制品（或制品）包含至少一种胺稳定剂，优选另一种任选的稳定剂添加剂。更优选地，辐射交联在低温（-50至40℃）下进行。弹性制品（或制品）包含均匀支化的乙烯互聚物（优选基本上为线性的乙烯互聚物），基本上氢化的嵌段聚合物或两者的组合。耐热弹性制品（特别是纤维）可用于各种耐用或重复使用的织物应用，例如但不限于衣服，衣服和运动服装。耐热弹性纤维可以使用众所周知的技术方便地形成织物，例如通过使用与棉，尼龙和/或聚酯纤维的共同编织技术。

6. 发明授权

US06777082B2 Hydrogenated block copolymers having elasticity and articles made therefrom 有权
标题翻译：具有弹性的氢化嵌段共聚物和由其制成的制品
公开(公告)号：US06777082B2
公开(公告)日：2004-08-17
申请号：US10006082
申请日：2001-12-06
申请人： Rajen M. Patel , Pak-Wing S. Chum , Stephen F. Hahn , Leonie K. Walsh , Rexford A. Maugans , Selim Bensason , Thoi H. Ho , Calvin P. Esneault
发明人： Rajen M. Patel , Pak-Wing S. Chum , Stephen F. Hahn , Leonie K. Walsh , Rexford A. Maugans , Selim Bensason , Thoi H. Ho , Calvin P. Esneault
IPC分类号： C08L5300
CPC分类号： C08L51/06 , A61F13/4902 , C08L53/025 , D01F6/42 , D01F6/56 , D02G3/32 , D03D15/08 , Y10T428/2913 , Y10T428/2915 , Y10T428/2933 , C08L2666/24 , C08L2666/04 , C08L2666/02
摘要： The present invention relates to a fiber produced form a composition comprising at least one hydrogenated block copolymer and, optionally, at least one other polymer selected from the group consisting of a reactive tailored liquid polyurethane, an elastomeric or sulfonated ethylene/vinyl aromatic interpolymer, an elastomeric ethylene/C3-C20 &agr;-olefin interpolymer, an C3-C20 &agr;-olefin/conjugated diene interpolymer, an elastic polypropylene polymer, an enhanced polypropylene polymer, an elastomeric thermoplastic polyurethane, an elastic copolyester, a partially hydrogenated block copolymer, an elastic polyamide, a hydroxyl functionalized polyether (or polyetheramine), a styrene/conjugated diene interpolymer, and an elastomeric metallocene-catalyzed synthetic polymer or a blend or formulated system thereof.
摘要翻译：本发明涉及由包含至少一种氢化嵌段共聚物和任选的至少一种其它聚合物制备的纤维，所述其它聚合物选自反应性定制的液体聚氨酯，弹性体或磺化乙烯/乙烯基芳族互聚物，弹性体乙烯/ C 3 -C 20α-烯烃互聚物，C 3 -C 20α-烯烃/共轭二烯互聚物，弹性聚丙烯聚合物，增强聚丙烯聚合物，弹性体热塑性聚氨酯，弹性共聚酯，部分氢化嵌段共聚物，弹性体聚酰胺，羟基官能化聚醚（或聚醚胺），苯乙烯/共轭二烯互聚物和弹性体茂金属催化的合成聚合物或其共混物或配制体系。

7. 发明授权

US06500540B1 Articles having elevated temperature elasticity made from irradiated and crosslinked ethylene polymers and method for making the same 有权
公开(公告)号：US06500540B1
公开(公告)日：2002-12-31
申请号：US09313740
申请日：1999-05-18
申请人： Michael F. Langohr , Selim Bensason , Rajen M. Patel , Jill M. Martin , Thoi H. Ho , Nancy J. Schrock
发明人： Michael F. Langohr , Selim Bensason , Rajen M. Patel , Jill M. Martin , Thoi H. Ho , Nancy J. Schrock
IPC分类号： D02G300
CPC分类号： A61F13/4902 , C08L23/04 , C08L23/0815 , C08L23/0838 , C08L23/10 , D01F6/30 , D01F6/46 , D01F8/06 , D04B21/18 , Y10T428/2913 , Y10T428/2967 , C08L2666/04
摘要： The present invention relates to elastic articles comprising a crosslinked or crosslinkable ethylene polymer and a method for making the same. In particular, the invention relates to a shaped article (e.g. film or fiber) characterized by improved elasticity at elevated temperatures and comprising a substantially cured, irradiated, or crosslinked (or curable, irradiated or crosslinkable) homogeneously branched ethylene polymer. The improved elastic article of the present invention is particularly suitable for use in applications where good elasticity must be maintained at elevated temperatures such as, for example, personal hygiene items and disposable infection-control garments at body temperatures of about 100° F. (38° C.).

8. 发明授权

US06667351B2 Articles having elevated temperature elasticity made from irradiated and crosslinked ethylene polymers and method for making the same 有权
公开(公告)号：US06667351B2
公开(公告)日：2003-12-23
申请号：US10086057
申请日：2002-02-28
申请人： Michael F. Langohr , Rajen M. Patel , Selim Bensason , Jill M. Martin , Thoi H. Ho , Nancy J. Schrock
发明人： Michael F. Langohr , Rajen M. Patel , Selim Bensason , Jill M. Martin , Thoi H. Ho , Nancy J. Schrock
IPC分类号： C08J328
CPC分类号： A61F13/4902 , C08L23/04 , C08L23/0815 , C08L23/0838 , C08L23/10 , D01F6/30 , D01F6/46 , D01F8/06 , D04B21/18 , Y10T428/2913 , Y10T428/2967 , C08L2666/04
摘要： The present invention relates to elastic articles comprising a crosslinked or crosslinkable ethylene polymer and a method for making the same. In particular, the invention relates to a shaped article (e.g. film or fiber) characterized by improved elasticity at elevated temperatures and comprising a substantially cured, irradiated, or crosslinked (or curable, irradiated or crosslinkable) homogeneously branched ethylene polymer. The improved elastic article of the present invention is particularly suitable for use in applications where good elasticity must be maintained at elevated temperatures such as, for example, personal hygiene items and disposable infection-control garments at body temperatures of about 100° F. (38° C.).

9. 发明授权

US06184291B2 Block copolymer compositions containing substantially inert thermoelastic extenders 失效
公开(公告)号：US06184291B2
公开(公告)日：2001-02-06
申请号：US08980141
申请日：1997-11-26
申请人： Wasif K. Ahmed , Antonio Batistini , Stephen R. Betso , Martin J. Guest , Thoi H. Ho , George W. Knight , Deepak R. Parikh , Rajen M. Patel
发明人： Wasif K. Ahmed , Antonio Batistini , Stephen R. Betso , Martin J. Guest , Thoi H. Ho , George W. Knight , Deepak R. Parikh , Rajen M. Patel
IPC分类号： C08L4700
CPC分类号： C09D153/02 , C08L23/0815 , C08L53/02 , C08L2314/06 , C08L2666/02 , C08L2666/04 , C09J153/02
摘要： The present invention is at least a two-component thermoplastic elastomeric composition comprising at least one block copolymer wherein the composition has essentially the same comparative elasticity, high temperature serviceability and hardness as the unmodified, undiluted (neat) block copolymer portion of the composition. The composition also shows enhanced thermal stability and processibility and is well suited for fabricating elastic moldings, films and fibers as well as for formulating with asphalts, adhesives and sealants. The novel thermoplastic elastomeric composition comprises (a) from about 50 to about 99 percent by weight of at least one block copolymer and (b) about 1 to about 50 percent by weight of at least one ethylene interpolymer having a density from about 0.855 g/cc to about 0.905 g/cc, wherein the ethylene interpolymer in the amount employed is a substantially inert extender of the block copolymer and the composition is further characterized as having: i. storage moduli throughout the range of −26° C. to 24° C. of less than about 3.5×109 dynes/cm2, ii. a ratio of storage modulus at −26° C. to storage modulus at 24° C. of less than about 4, and iii. storage moduli at −26° C. and 24° C. about 0.2 to about 3 times higher than the storage moduli at −26° C. and 24° C., respectively, of the neat block copolymer portion of the composition.

10. 发明授权

US06403710B1 Block copolymer compositions containing substantially inert thermoelastic extenders 有权
标题翻译：含有基本上惰性的热弹性增量剂的嵌段共聚物组合物
公开(公告)号：US06403710B1
公开(公告)日：2002-06-11
申请号：US09690039
申请日：2000-10-16
申请人： Wasif K. Ahmed , Stephen R. Betso , Antonio Batistini , Martin J. Guest , Thoi H. Ho , Deepak R. Parikh , George W. Knight , Rajen M. Patel
发明人： Wasif K. Ahmed , Stephen R. Betso , Antonio Batistini , Martin J. Guest , Thoi H. Ho , Deepak R. Parikh , George W. Knight , Rajen M. Patel
IPC分类号： C08L900
CPC分类号： C09D153/02 , C08L23/0815 , C08L53/02 , C08L2314/06 , C08L2666/02 , C08L2666/04 , C09J153/02
摘要： The present invention is at least a two-component thermoplastic elastomeric composition comprising at least one block copolymer wherein the composition has essentially the same comparative elasticity, high temperature serviceability and hardness as the unmodified, undiluted (neat) block copolymer portion of the composition. The composition also shows enhanced thermal stability and processibility and is well suited for fabricating elastic moldings, films and fibers as well as for formulating with asphalts, adhesives and sealants. The novel thermoplastic elastomeric composition comprises (a) from about 50 to about 99 percent by weight of at least one block copolymer and (b) about 1 to about 50 percent by weight of at least one ethylene interpolymer having a density from about 0.855 g/cc to about 0.905 g/cc, wherein the ethylene interpolymer in the amount employed is a substantially inert extender of the block copolymer and the composition is further characterized as having: i. storage moduli throughout the range of −26° C. to 24° C. of less than about 3.5×109 dynes/cm2, ii. a ratio of storage modulus at −26° C. to storage modulus at 24° C. of less than about 4, and iii. storage moduli at −26° C. and 24° C. about 0.2 to about 3 times higher than the storage moduli at −26° C. and 24° C., respectively, of the neat block copolymer portion of the composition.
摘要翻译：本发明是至少一种包含至少一种嵌段共聚物的双组分热塑性弹性体组合物，其中组合物与组合物未未改性的未稀释（纯）嵌段共聚物部分具有基本上相同的比较弹性，高温可使用性和硬度。该组合物还显示出增强的热稳定性和加工性，并且非常适用于制造弹性模制品，薄膜和纤维，以及用沥青，粘合剂和密封剂配制。新型热塑性弹性体组合物包含（a）约50至约99重量％的至少一种嵌段共聚物和（b）约1至约50重量％的至少一种乙烯互聚物，其密度约为0.855克/ cc至约0.905g / cc，其中所用量的乙烯互聚物是嵌段共聚物的基本惰性的增量剂，组合物进一步表征为具有：在-26℃至24℃的范围内的储存模量小于约3.5×10 9达因/厘米2，ii。在-26℃下的储能模量与24℃下的储能模量的比小于约4，和iii。在-26℃和24℃下的储存模量分别比组合物的纯嵌段共聚物部分的-26℃和24℃下的储存模量高约0.2至约3倍。

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