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1. 发明授权

US4845176A Preparation of homopolymers and copolymers of ethene using a chromium trioxide catalyst 失效
标题翻译：使用三氧化铬催化剂制备乙烯的均聚物和共聚物
公开(公告)号：US4845176A
公开(公告)日：1989-07-04
申请号：US105542
申请日：1987-10-08
申请人： Rainer Konrad , Rainer Hemmerich , Rudolf Mueller-Mall , Guenther Schweier
发明人： Rainer Konrad , Rainer Hemmerich , Rudolf Mueller-Mall , Guenther Schweier
IPC分类号： C08F4/02 , C08F4/24 , C08F4/48 , C08F4/62 , C08F10/02
CPC分类号： C08F10/02 , Y10S526/908 , Y10S526/909
摘要： Ethene homopolymers and ethene copolymers with minor amounts of higher .alpha.-monoolefins are prepared by polymerization of the monomer or monomers using a chromium trioxide catalyst which is obtained by a method in which (1) a finely divided, porous, silicate carrier is laden with (2) chromium trioxide or a chromium compound which is converted to chromium trioxide under the conditions of stage (3), and then (3) the intermediate resulting from stage (2) is heated in an oxygen-containing gas stream. In this process, a cocatalyst which consists of a lithiumalkyl used in addition to the chromium trioxide catalyst.
摘要翻译：通过使用三氧化铬催化剂聚合单体或单体来制备具有少量较高级α-单烯烃的乙烯均聚物和乙烯共聚物，该三氧化铬催化剂通过以下方法获得，其中（1）细分多孔硅酸盐载体载有（ 2）三氧化铬或在阶段（3）的条件下转化为三氧化铬的铬化合物，然后（3）将由步骤（2）得到的中间体在含氧气体流中加热。在该方法中，除了三氧化铬催化剂之外，还使用由使用的烷基锂组成的助催化剂。

2. 发明授权

US4970184A Catalyst for the polymerization of ethylene, its preparation and the use of the resulting ethylene polymers for the production of films exhibiting little blocking 失效
标题翻译：用于乙烯聚合的催化剂，其制备和使用所得的乙烯聚合物用于生产几乎没有阻塞的膜
公开(公告)号：US4970184A
公开(公告)日：1990-11-13
申请号：US346899
申请日：1989-05-03
申请人： Eckard Schauss , Heinz Vogt , Rainer Hemmerich , Guenther Schweier , Rudolf Mueller-Mall
发明人： Eckard Schauss , Heinz Vogt , Rainer Hemmerich , Guenther Schweier , Rudolf Mueller-Mall
IPC分类号： C08F4/658 , C08F2/34 , C08F4/58 , C08F4/60 , C08F4/64 , C08F4/649 , C08F10/00 , C08F10/02 , C08F210/02
CPC分类号： C08F210/02
摘要： A catalyst for the copolymerization of ethylene by the gas-phase fluidized-bed method is prepared by a process in which a titanium-containing and magnesium-containing active component, reacted with an alcohol as a complexing agent, is applied to a finely divided silica from homogeneous solution, in the presence of a polysiloxane, by evaporating the solvent, and the resulting homogeneous catalyst intermediate is then preactivated by treatment with the alkylaluminum compound and the Lewis base in an inert hydrocarbon solution, and the copolymers prepared using the above catalyst are employed for the production of films exhibiting little blocking.
摘要翻译：通过气相流化床法共聚乙烯的催化剂通过以下方法制备：使含钛和镁的活性组分与醇作为络合剂反应的方法被加到细分二氧化硅从均匀溶液中，在聚硅氧烷的存在下，通过蒸发溶剂，然后通过用惰性烃溶液中的烷基铝化合物和路易斯碱处理预先活化所得均匀的催化剂中间体，并且使用上述催化剂制备的共聚物是用于生产几乎没有阻塞的薄膜。

3. 发明授权

US4814308A Preparation of homopolymers and copolymers of ethene by Phillips catalysis 失效
标题翻译：通过菲利普斯催化制备乙烯的均聚物和共聚物
公开(公告)号：US4814308A
公开(公告)日：1989-03-21
申请号：US110872
申请日：1987-10-21
申请人： Rainer Konrad , Guido Funk , Juergen Schmidt-Thuemmes , Rudolf Mueller-Mall , Guenther Schweier
发明人： Rainer Konrad , Guido Funk , Juergen Schmidt-Thuemmes , Rudolf Mueller-Mall , Guenther Schweier
IPC分类号： C08F4/02 , C08F4/24 , C08F4/48 , C08F4/62 , C08F10/02
CPC分类号： C08F10/02
摘要： Ethene polymerization by Phillips catalysis is carried out using (1) a supported catalyst, which is laden with chromium, phosphorus and aluminum, and (2) a cocatalyst, (1) being obtained by a method in which (1.1) a catalyst intermediate laden with chromium, phosphorus and aluminum is prepared from a silicate carrier, a selected chromium compound, a selected phosphorus compound and a selected aluminum compound, and then (1.2) the catalyst intermediate is heated in an oxygen-containing gas stream. In this process, the component (1) used is one which is obtained by a method in which, in each case in a specific manner, (1.1) in a first stage, (1.1.1) first a suspension is prepared from (1.1.1.1) a finely divided silicate carrier and (1.1.1.2) an inert organic solvent, (1.1.2) then, (1.1.2.1) in an inert organic solvent, (1.1.2.2) an organic chromium compound is combined with (1.1.2.3) an aluminum trialkyl, (1.1.3) then (1.1.3.1) the suspension resulting from (1.1.1) is combined with (1.1.3.2) a phosphoric acid or phosphite and (1.1.3.3) the product obtained from (1.1.2), (1.1.4) finally, the suspension obtained in (1.1.3) is evaporated to dryness, and then (1.2) in a second stage, first (1.2.1) the intermediate obtained from (1.1) is treated with a stream of nitrogen, then (1.2.2) the intermediate obtained from (1.2.1) is heated in an oxygen-containing gas stream, and finally (1.2.3) the intermediate obtained from (1.2.2) is treated with a stream of nitrogen, and both a lithiumalkyl and a boronalkyl are used as (2).
摘要翻译：通过菲利普斯催化进行的乙烯聚合使用（1）负载催化剂，其载有铬，磷和铝，和（2）助催化剂，（1）通过以下方法获得：（1）将载体催化剂中间体由硅酸盐载体，选择的铬化合物，选择的磷化合物和选择的铝化合物制备铬，磷和铝，然后（1.2）在含氧气流中加热催化剂中间体。在该方法中，所使用的组分（1）是通过在每种情况下以具体方式（1.1）在第一阶段（1.1.1）中首先从（1.1）制备悬浮液的方法获得的组分 .1.1）精细分散的硅酸盐载体和（1.1.1.2）惰性有机溶剂（1.1.2）然后，（1.1.2.1）在惰性有机溶剂（1.1.2.2）中将有机铬化合物与（ 1.1.2.3）三烷基铝（1.1.3）然后（1.1.3.1）将由（1.1.1）得到的悬浮液与（1.1.3.2）磷酸或亚磷酸酯和（1.1.3.3）得到的产物从（1.1.2），（1.1.4）最终得到的（1.1.3）中得到的悬浮液蒸发至干，然后在第二阶段（1.2）中，首先（1.2.1）从（1.1 ）用氮气流处理，然后（1.2.2）从（1.2.1）获得的中间体在含氧气流中加热，最后（1.2.3）从（1.2.2）得到的中间体用氮气流和二氧化钛处理和硼烷基用作（2）。

4. 发明授权

US4727124A Preparation of homopolymers and copolymers of ethene by Phillips catalysis 失效
标题翻译：通过菲利普斯催化制备乙烯的均聚物和共聚物
公开(公告)号：US4727124A
公开(公告)日：1988-02-23
申请号：US047116
申请日：1987-05-08
申请人： Rainer Konrad , Rudolf Mueller-Mall , Guenther Schweier
发明人： Rainer Konrad , Rudolf Mueller-Mall , Guenther Schweier
IPC分类号： C08F2/06 , C08F4/02 , C08F4/22 , C08F4/24 , C08F4/62 , C08F4/64 , C08F10/00 , C08F10/02 , C08F2/24
CPC分类号： C08F10/00 , C08F2410/01
摘要： Ethane polymers are prepared by Phillips catalysis using (1) a supported catalyst which is laden with chromium, phosphorus and titanium and (2) a cocatalyst, (1) being obtained by a procedure in which (1.1) a catalyst intermediate laden with chromium, phosphorus and titanium is prepared from a silicate carrier, a selected chromium compound, a selected phosphorus compound and a selected titanium compound, and (1.2) the catalyst intermediate is then heated in an oxygen-containing gas stream. In the process, the supported catalyst (1) used is one which is obtained (using specific methods and substances in each case) by a procedure in which (1.1) in a first stage (1.1.1), a suspension is first prepared from (1.1.1.1) a finely divided silicate carrier and (1.1.1.2) an inert organic solvent, (1.1.2) a suspension is then prepared from (1.1.2.1) a finely divided chromium trioxide and (1.1.2.2) an inert organic solvent, (1.1.3) thereafter (1.1.3.1) the suspension resulting from (1.1.2) is combined with (1.1.3.2) a phosphate or phosphite, (1.1.4) then (1.1.4.1) the suspension obtained from (1.1.1) is combined with (1.1.4.2) the reaction product obtained in (1.1.3), (1.1.5) thereafter (1.1.5.1) the suspension formed in (1.1.4) is combined with (1.1.5.2) a titanate, (1.1.6) finally the suspension obtained in (1.1.5) is evaporated to dryness and then (1.2) in a second stage, (1.2.1) the intermediate obtained in (1.1) is first treated with a nitrogen stream, (1.2.2) an intermediate obtained in (1.2.1) is then heated in an oxygen-containing gas stream and finally (1.2.3) the intermediate obtained in (1.2.2) is treated with a nitrogen stream, and a lithiumalkyl is used as (2).
摘要翻译：通过使用（1）载有铬，磷和钛的载体催化剂和（2）助催化剂的菲尼普斯催化剂制备乙烷聚合物，（1）通过以下程序获得，其中（1.1）载有铬的催化剂中间体，磷和钛由硅酸盐载体，选择的铬化合物，选择的磷化合物和选择的钛化合物制备，然后在含氧气流中加热催化剂中间体。在该方法中，使用的负载催化剂（1）是通过第一阶段（1.1.1）中的（1.1）的步骤获得的（使用具体方法和每种情况下的物质），悬浮液首先由（1.1.1.1）细碎的硅酸盐载体和（1.1.1.2）惰性有机溶剂，（1.1.2）悬浮液然后由（1.1.2.1）细碎的三氧化铬和（1.1.2.2）惰性的有机溶剂（1.1.3）（1.1.3.1）将得自（1.1.2）的悬浮液与（1.1.3.2）磷酸酯或亚磷酸酯（1.1.4）然后（1.1.4.1）合并得到的悬浮液（1.1.1）与（1.1.4）中得到的反应产物（1.1.3），（1.1.5）（1.1.5.1）中合并（1.1.4），将（1.1.4）中形成的悬浮液与（1.1 0.5.2）钛酸盐（1.1.6）最后，将（1.1.5）中得到的悬浮液在第二阶段蒸发至干，然后（1.2）（1.2.1），首先处理（1.1）中获得的中间体用氮气流（1.2.2）中间体然后在含氧气流中加热（1.2.1），最后（1.2.3）用氮气流处理（1.2.2）中得到的中间体，使用烷基锂作为（2）。

5. 发明授权

US4977210A Preparation of propylene/ethylene polymers of the toughened polypropylene type 失效
标题翻译：制备增韧聚丙烯类型的丙烯/乙烯聚合物
公开(公告)号：US4977210A
公开(公告)日：1990-12-11
申请号：US389818
申请日：1989-08-04
申请人： Juergen Kerth , Rainer A. Werner , Ralf Zolk , Klaus-Dieter Ruempler , Guenther Schweier , Rudolf Mueller-Mall , Wolfgang Gruber
发明人： Juergen Kerth , Rainer A. Werner , Ralf Zolk , Klaus-Dieter Ruempler , Guenther Schweier , Rudolf Mueller-Mall , Wolfgang Gruber
IPC分类号： C08F2/34 , C08F4/02 , C08F4/58 , C08F4/60 , C08F4/64 , C08F4/642 , C08F297/08
CPC分类号： C08F297/083
摘要： Propylene/ethylene block copolymers are prepared by a continuous process in which, in each case in an agitated fixed bed of finely divided polymer from the gas phase, first (I) in a first polymerization zone, propylene is homopolymerized by feeding in a Ziegler-Natta catalyst system consisting of (1) a titanium component which contains titanium, magnesium, chlorine and a phthalic acid derivative, (2) an aluminumalkyl component and (3) a silane component, and (II) in a second polymerization zone, a mixture of propylene and ethylene is polymerized with the propylene homopolymer present in the reaction mixture obtained in the first polymerization zone by feeding in the said reaction mixture. In the process, (A) a titanium component (1) is used which is obtained by a method in which (1.1) first, (1.1.1) in a liquid hydrocarbon, (1.1.2) a finely divided magnesium halide, (1.1.3) an alkanol, (1.1.4) a certain phthalic acid derivative and (1.1.5) titanium tetrachloride are reacted with one another under certain conditions, (1.2) the solid intermediate obtained from (1.1) is extracted with titanium tetrachloride or a liquid alkylbenzene until the remaining solid substance has become substantially richer in magnesium, and (1.3) finally, the solid substance remaining in (1.2) is washed with an alkane in a certain manner, (B) a specific silane is used as (3), and (C) specifically selected polymerization parameters are employed, with relationships between the first and second polymerization zones.
摘要翻译：丙烯/乙烯嵌段共聚物通过连续方法制备，其中在每种情况下，在来自气相的搅动的细分散聚合物的固定床中，在第一聚合区中的第一（I），丙烯通过进料齐格勒 - 纳塔催化剂体系（1）钛，镁，氯和邻苯二甲酸衍生物的钛成分，（2）铝烷基成分和（3）硅烷成分，（II）在第二聚合区中的混合物的丙烯和乙烯通过在所述反应混合物中进料而与在第一聚合区中获得的反应混合物中存在的丙烯均聚物聚合。在该方法中，（A）使用通过以下方法获得的钛组分（1）：（1.1）第一，（1.1.1）在液体烃中，（1.1.2）细碎的卤化镁， 1.1.3）链烷醇（1.1.4）某些邻苯二甲酸衍生物和（1.1.5）四氯化钛在一定条件下彼此反应，（1.2）从（1.1）得到的固体中间体用四氯化钛或液态烷基苯，直到残留的固体物质变得更加富镁，（1.3）最后，以（某种）方式用烷烃洗涤残留在（1.2）中的固体，（B）使用特定的硅烷作为（ 3），和（C）具体选择的聚合参数，与第一和第二聚合区之间的关系。

6. 发明授权

US4900798A Preparation of ethene polymers using a ziegler catalyst system 失效
标题翻译：使用齐格勒催化剂体系制备乙烯聚合物
公开(公告)号：US4900798A
公开(公告)日：1990-02-13
申请号：US97068
申请日：1987-09-16
申请人： Juergen Kerth , Rudolf Mueller-Mall , Guenther Schweier
发明人： Juergen Kerth , Rudolf Mueller-Mall , Guenther Schweier
IPC分类号： C08F4/60 , C08F4/64 , C08F10/02
CPC分类号： C08F10/02 , Y10S526/901 , Y10S526/903 , Y10S526/904
摘要： Finely divided ethane polymers are prepared using a Ziegler catalyst system consisting of (1) a titanium-containing catalyst component which has been obtained by (1.1) precipitation in an organic liquid comprising (1.1.1) a solution of titanium tetrachloride in a hydrocarbon, (1.1.2) a solution of a certain organoaluminum compound in a hydrocarbon and (1.1.3) an alpha-monoalkene, and (2) an aluminum-containing catalyst component. In this process, the component (1) used is a component where (1.1) precipitation has been carried out at relatively low temperatures in an organic liquid which has a relatively high viscosity at the precipitation temperature and conists of (1) a liquid hydrocarbon an (b) small amounts of a polymer of an alpha-monoalkene dissolved therein, with the provisos that (i) specific amounts of the organic liquid, of the organoaluminum compound and of the alpha-monoalkene are used per g mol of the titanium tetrachloride used in total, and (ii) per molar unit of the titanium tetrachloride used in total, specific amounts per minute are precipitated and specific amounts per minute of the alpha-monoalkene are introduced, and (1.2) the substance precipitated according to (1.1) has been reacted with a lithiumalkyl.
摘要翻译：使用齐格勒催化剂体系制备精细分散的乙烷聚合物，该齐格勒催化剂体系由（1）通过（1.1）在有机液体中沉淀得到的含钛催化剂组分，所述有机液体包含（1.1.1）四氢化钛在烃中的溶液，（1.1.2）某些有机铝化合物在烃中的溶液和（1.1.3）α-单链烯烃，和（2）含铝催化剂组分。在该方法中，使用的组分（1）是在相对低的温度下在沉淀温度下具有较高粘度的有机液体中进行沉淀的组分，（1）液体烃（b）少量其中溶解有α-单链烯烃的聚合物，条件是（i）有机铝化合物和α-单链烯烃的特定量的有机铝化合物与每摩尔所用的四氯化钛相比使用和（ii）每摩尔单位使用的四氯化钛，每分钟的特定量被沉淀，并且每分钟的特定量的α-单链烯烃被引入，（1.2）根据（1.1）沉淀的物质具有与烷基锂反应。

7. 发明授权

US4794151A Preparation of finely divided homopolymers and copolymers of ethene using a liquid alkane as reaction medium 失效
标题翻译：使用液体烷烃作为反应介质制备细碎的乙烯均聚物和共聚物
公开(公告)号：US4794151A
公开(公告)日：1988-12-27
申请号：US035919
申请日：1987-04-08
申请人： Rudolf Mueller-Mall , Guido Funk , Robert Bachl , Peter Hennenberger , Erich Kolk
发明人： Rudolf Mueller-Mall , Guido Funk , Robert Bachl , Peter Hennenberger , Erich Kolk
IPC分类号： C08F2/06 , C08F2/14 , C08F2/18 , C08F10/02 , C08F210/16 , C08F10/08
CPC分类号： C08F10/02 , C08F210/16 , Y10S526/909 , Y10S526/922
摘要： A process for the continuous preparation of finely divided homopolymers and copolymers of ethene by catalytic polymerization in a circular tube reactor using a liquid alkane as reaction medium in which the ethene or ethene/comonomer mixture to be polymerized is present in dissolved form and the polymer formed is present in suspended form and running the reaction mixture as a cycle stream to which the feed materials are added by bleeding in and from which the polymer formed is withdrawn by bleeding out reaction mixture, comprising (a) maintaining the mean concentration C.sub.m of polymer in the cycle stream at a value within a certain range and (b) effecting the bleeding out of reaction mixture at a point of the cycle stream at which the concentration of polymer has a value which is lower than the mean concentration C.sub.m by a distinct and definite amount.
摘要翻译：通过催化聚合在圆管反应器中连续制备乙烯的均匀聚合物和共聚物的方法，其中使用液体烷烃作为反应介质，其中待聚合的乙烯或乙烯/共聚单体混合物以溶解形式存在并形成聚合物以悬浮形式存在，并以作为循环流的方式运行反应混合物，通过渗出反应混合物，通过渗出所形成的聚合物而将原料加入到该循环流中，通过渗出反应混合物排出，其包括（a）将聚合物的平均浓度Cm保持在循环流在一定范围内的值，和（b）在聚合物浓度具有低于平均浓度C m的值的循环流的点处，通过不同的和明确的方式实现反应混合物的渗出量。

8. 发明授权

US4654397A Preparation of polymer dispersions which form block-resistant films 失效
标题翻译：制备形成阻挡层的聚合物分散体
公开(公告)号：US4654397A
公开(公告)日：1987-03-31
申请号：US803164
申请日：1985-12-02
申请人： Rudolf Mueller-Mall , Michael Melan , Eckehardt Wistuba , Lothar Matthaei
发明人： Rudolf Mueller-Mall , Michael Melan , Eckehardt Wistuba , Lothar Matthaei
IPC分类号： C08F2/00 , C08F2/22 , C08F2/24 , C08F2/26 , C08F2/28 , C08F20/52 , C08F220/04 , C08F220/10 , C08F220/54 , C08F285/00 , C09D5/00 , C09D5/02 , C09D151/00 , C08F265/02
CPC分类号： C09D151/00 , C08F2/26 , C08F285/00
摘要： A process for the preparation of aqueous polymer dispersions which have a low film-forming temperature but still give films having a high block resistance, and the use of these polymer dispersions as binders for coating materials.
摘要翻译：制备具有低成膜温度但仍得到具有高阻块性的膜的水性聚合物分散体的方法，以及这些聚合物分散体作为涂料的粘合剂的用途。

9. 发明授权

US4265796A Preparation of aqueous polyacrylate dispersions having improved flow characteristics 失效
标题翻译：具有改善的流动特性的聚丙烯酸酯水分散体的制备
公开(公告)号：US4265796A
公开(公告)日：1981-05-05
申请号：US73300
申请日：1979-09-07
申请人： Rudolf Mueller-Mall , Kurt Wendel , Hans J. Geelhaar , Michael Melan
发明人： Rudolf Mueller-Mall , Kurt Wendel , Hans J. Geelhaar , Michael Melan
IPC分类号： C08F2/00 , C08F2/22 , C08F2/24 , C08F2/38 , C08F20/12 , C08L33/08 , C08L33/10
CPC分类号： C08F20/12
摘要： Aqueous polyacrylate dispersions having improved flow characteristics are prepared by polymerizing esters of acrylic acid and/or methacrylic acid and alkanols of 1 to 10 carbon atoms, with or without admixture of styrene and/or vinyl esters and/or water-soluble monoolefinically unsaturated comonomers (the monomer feed being in the form of an emulsion), in aqueous emulsion in the presence of a free radical polymerization initiator, a protective colloid, a nonionic emulsifier and a regulator, at least a part of the protective colloid being introduced into an aqueous initial charge, and a water-soluble regulator being employed in the initial charge and in the feed.
摘要翻译：具有改善的流动特性的聚丙烯酸酯水分散体通过聚合丙烯酸和/或甲基丙烯酸和具有1-10个碳原子的链烷醇的酯来制备，具有或不包含苯乙烯和/或乙烯基酯和/或水溶性单烯属不饱和共聚单体的混合物（单体进料为乳液形式），在自由基聚合引发剂，保护胶体，非离子乳化剂和调节剂的存在下，在水乳液中，将至少一部分保护胶体引入水性初始电荷和在初始充电和饲料中使用的水溶性调节剂。

10. 发明授权

US4777265A Preparation of acrylates and methacrylates 失效
标题翻译：丙烯酸酯和甲基丙烯酸酯的制备
公开(公告)号：US4777265A
公开(公告)日：1988-10-11
申请号：US22110
申请日：1987-03-05
申请人： Franz Merger , Hans-Martin Hutmacher , Wolfgang Schwarz , Gerhard Nestler , Maria G. Szucsanyi , Rudolf Mueller-Mall
发明人： Franz Merger , Hans-Martin Hutmacher , Wolfgang Schwarz , Gerhard Nestler , Maria G. Szucsanyi , Rudolf Mueller-Mall
IPC分类号： B01J31/00 , B01J31/02 , B01J31/20 , B01J31/22 , C07B61/00 , C07D233/32 , C07D239/10 , C07D239/36 , C07D243/04 , C07D245/02
CPC分类号： C07D239/10 , C07D233/32 , C07D243/04 , C07D245/02
摘要： Acrylates or methacrylates I ##STR1## (A and B=C.sub.2 -C.sub.5 -alkylene, R.sup.1 =H, CH.sub.3) are prepared by reacting an acrylate or methacrylate II ##STR2## (R.sup.2 =C.sub.1 -C.sub.4 -alkyl) with a heterocycle III ##STR3## in the presence of titanium alcoholates chelate compounds of the metals titanium, zirconium, iron and zinc with 1,3-dicarbonyl compounds.
摘要翻译：丙烯酸酯或甲基丙烯酸酯I（A和B = C 2 -C 5亚烷基，R 1 = H，CH 3）是通过使丙烯酸酯或甲基丙烯酸酯II（R2 = C1-C4-烷基）与杂环在钛醇化物存在下，III，III，Ⅲ族金属螯合钛，锆，铁和锌与1,3-二羰基化合物的化合物。

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