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1. 发明授权

US4491585A Combating pests with novel phenoxypyridylmethyl esters 失效
标题翻译：用新的苯氧基吡啶甲基酯来防治害虫
公开(公告)号：US4491585A
公开(公告)日：1985-01-01
申请号：US355044
申请日：1982-03-05
申请人： Rainer Fuchs , Ingeborg Hammann , Bernhard Homeyer , Wilhelm Stendel
发明人： Rainer Fuchs , Ingeborg Hammann , Bernhard Homeyer , Wilhelm Stendel
IPC分类号： A01N53/04 , A01N43/40 , A01N53/00 , A01N53/08 , C07D213/64 , C07D213/643 , C07D213/647
CPC分类号： C07D213/643 , A01N43/40 , A01N53/00 , C07D213/647
摘要： New phenoxypyridylmethyl esters of the general formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 have the meaning given in the description andR represents the radical ##STR2## wherein R.sup.4 and R.sup.5 have the meaning given in the description, and represents the radical ##STR3## wherein R.sup.6 and R.sup.7 have the meaning given in the description, are obtained by a process in which carboxylic acids of the general formulaR--COOH (II)wherein R has the meaning given previously, or reactive derivatives of these acids, are reacted with phenoxypyridyl alcohols of the general formula ##STR4## wherein R.sup.1, R.sup.2 and R.sup.3 have the meaning given above, or with reactive derivatives of these alcohols, if appropriate in the presence of acid acceptors, if appropriate in the presence of catalysts and if appropriate in the presence of diluents. The new phenoxypyridylmethyl esters of the formula (I) are distinguished by a high pesticidal, particularly insecticidal and acardicidal activity.
摘要翻译：新颖的通式（I）的苯氧基吡啶甲基酯其中R1，R2和R3具有说明书中给出的含义，R代表基团，其中R4和R5具有说明书中给出的含义，并且表示基团其中R6和R7具有说明书中给出的含义，通过其中R具有以前给出的含义或这些酸的反应性衍生物的通式为R-COOH（II）的羧酸为与式（III）的苯氧基吡啶醇反应，其中R 1，R 2和R 3具有上述含义，或与这些醇的活性衍生物反应，如果合适，在酸受体存在下，如果合适的话，在催化剂存在下并在适当的情况下在稀释剂存在下进行。式（I）的新的苯氧基吡啶基甲基酯的特征在于高杀虫性，特别是杀虫和杀虫活性。

2. 发明授权

US4423066A Combating arthropods with perfluorobenzyl 2,2-dimethyl-3-vinyl-cyclopropane carboxylates 失效
标题翻译：将节肢动物与全氟苄基2,2-二甲基-3-乙烯基 - 环丙烷羧酸酯结合
公开(公告)号：US4423066A
公开(公告)日：1983-12-27
申请号：US13660
申请日：1979-02-21
申请人： Rainer Fuchs , Klaus Naumann , Wolfgang Behrenz , Ingeborg Hammann , Bernhard Homeyer , Wilhelm Stendel
发明人： Rainer Fuchs , Klaus Naumann , Wolfgang Behrenz , Ingeborg Hammann , Bernhard Homeyer , Wilhelm Stendel
IPC分类号： C07C69/747 , A01N53/06 , A01N53/10 , C07C67/11 , C07C69/753 , A01N53/00 , A61K31/215
CPC分类号： C07C69/753
摘要： A pentafluorobenzyl 2,2-dimethyl-3-vinylcyclopropane carboxylate of the formula ##STR1## in which R is hydrogen or halogen, andR.sup.1 is optionally substituted phenyl, orR and R.sup.1 together constitute an alkylene chain with at least two carbon atoms,which possess arthropodicidal properties.
摘要翻译：式“IMAGE”的五氟苄基2,2-二甲基-3-乙烯基环丙烷羧酸酯，其中R是氢或卤素，R 1是任选取代的苯基，或R和R 1一起构成具有至少两个碳原子的亚烷基链，其中具有节肢动物特性。

3. 发明授权

US4344960A Combating insects and acarids with 3-(2-chloro-3,3,4,4,4-pentafluoro-1-butenyl)-2,2-dimethyl-cyclopropaneca rboxylic acid esters 失效
标题翻译：将昆虫和螨与3-（2-氯-3,3,4,4,4-五氟-1-丁烯基）-2,2-二甲基 - 环丙烷甲酸酯
公开(公告)号：US4344960A
公开(公告)日：1982-08-17
申请号：US259645
申请日：1981-05-01
申请人： Rainer Fuchs , Klaus Naumann , Reinhard Lantzsch , Hermann Hagemann , Ingeborg Hammann , Bernhard Homeyer , Wolfgang Behrenz , Wilhelm Stendel
发明人： Rainer Fuchs , Klaus Naumann , Reinhard Lantzsch , Hermann Hagemann , Ingeborg Hammann , Bernhard Homeyer , Wolfgang Behrenz , Wilhelm Stendel
IPC分类号： C07C69/747 , A01N53/00 , A01N53/04 , A01N53/08 , A01N53/10 , B01J31/02 , C07C61/40 , C07C67/00 , C07C253/00 , C07C255/39 , C07D317/62 , A01N43/30 , C07C121/75 , C07D317/44
CPC分类号： A01N53/00 , C07C61/40 , C07D317/62
摘要： A 3-(2,chloro-3,3,4,4,4-pentafluoro-1-butenyl)-2,2-dimethyl-cycloproanecarboxylic acid ester of the formula ##STR1## in which R.sup.1 represents hydrogen, cyano or an alkyl, alkenyl or alkynyl radical with in each case up to 4 carbon atoms, andR.sup.2 represents a phenyl radical which is substituted by fluorine and/or by optionally fluorine-substituted C.sub.1 -C.sub.2 -alkylenedioxy and/or by optionally fluorine-substituted phenoxy, with the proviso that the radical R.sup.2 contains a total of at least one fluorine-substituent which possesses insecticidal and acaricidal activity.
摘要翻译：式（I）的3-（2，氯-3,3,4,4,4-五氟-1-丁烯基）-2,2-二甲基 - 环丙烷羧酸酯，其中R 1表示氢，氰基或烷基，烯基或炔基，其中每种情况最多可达4个碳原子，R2表示被氟取代的苯基和/或任选氟取代的C1-C2-亚烷基二氧基和/或任选氟 - 取代的苯氧基，条件是基团R2含有总共至少一个具有杀虫和杀螨活性的氟取代基。

4. 发明授权

US4276306A Combating arthropods with 3-phenoxybenzyl 2,2-dimethyl-3-vinyl-cyclopropane carboxylates 失效
标题翻译：将节肢动物与2,2-二甲基-3-乙烯基 - 环丙烷羧酸3-苯氧基苄酯反应
公开(公告)号：US4276306A
公开(公告)日：1981-06-30
申请号：US916163
申请日：1978-06-16
申请人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
发明人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： C07C61/39 , A01N53/00 , A01N53/08 , C07C61/40 , C07C67/00 , C07C67/08 , C07C67/10 , C07C67/14 , C07C69/743 , C07C69/747 , C07C253/00 , C07C255/39 , C07C313/00 , C07C323/55 , C07C69/75 , C07C121/75
CPC分类号： A01N53/00
摘要： 3-Phenoxybenzyl 2,2-dimethyl-3-vinyl-cyclopropane carboxylates of the formula ##STR1## in which R, R.sup.1 and R.sup.2 each independently is hydrogen or halogen,R.sup.3 is phenyl, phenylthio, or phenyl or phenylthio carrying at least one alkyl group or halogen atom,Y is hydrogen or cyano,n is 1, 2, 3, 4 or 5, andm is 1, 2, 3 or 4,which possess arthropodicidal properties.
摘要翻译：其中R 1，R 2和R 2各自独立地为氢或卤素，R 3为苯基，苯硫基或苯基或苯硫基，其具有至少一个烷基基团或卤原子，Y为氢或氰基，n为1,2,3,4或5，m为1,2,3或4，具有节肢动物学特性。

5. 发明授权

US4318922A Combating pests with fluorine-substituted 2,2,3,3-tetramethylcyclopropane-1-carboxylic acid benzyl esters 失效
标题翻译：防治害虫与氟取代的2,2,3,3-四甲基环丙烷-1-羧酸苄酯
公开(公告)号：US4318922A
公开(公告)日：1982-03-09
申请号：US198039
申请日：1980-10-17
申请人： Rainer Fuchs , Klaus Naumann , Hans-Jochem Riebel , Wolfgang Behrenz , Ingeborg Hammann , Wilhelm Stendel
发明人： Rainer Fuchs , Klaus Naumann , Hans-Jochem Riebel , Wolfgang Behrenz , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： C07C69/74 , A01N53/00 , A01N53/06 , A01N53/08 , B01J31/00 , C07C67/00 , C07C67/14 , C07C69/743 , C07C253/00 , C07C255/39 , C07C121/75
CPC分类号： A01N53/00
摘要： 2,2,3,3-Tetramethylcyclopropanecarboxylic acid fluorine-substituted-benzyl esters of the formula ##STR1## in which R.sup.1 is hydrogen, cyano, or alkyl, alkenyl or alkynyl each with up to 4 carbon atoms, andR.sup.2 is a phenyl radical which is substituted by halogen and/or by optionally halogen-substituted phenoxy, with the proviso that the radical R.sup.2 in total contains at least one fluorine substituent,which possess insecticidal and acaricidal properties.
摘要翻译：其中R 1是氢，氰基或各自具有至多4个碳原子的烷基，链烯基或炔基，R 2是苯基的2,2,3,3-四甲基环丙烷甲酸氟取代的苄基酯，其被卤素和/或任选被卤素取代的苯氧基取代，条件是基团R2总共含有至少一个具有杀虫和杀螨性质的氟取代基。

6. 发明授权

US4317834A Combating arthropods with fluorine-substituted spiro-carboxylic acid benzyl esters 失效
标题翻译：将节肢动物与氟取代的螺 - 羧酸苄酯相结合
公开(公告)号：US4317834A
公开(公告)日：1982-03-02
申请号：US203032
申请日：1980-11-03
申请人： Rainer Fuchs , Klaus Naumann , Ingeborg Hammann , Bernhard Homeyer , Wolfgang Behrenz , Wilhelm Stendel
发明人： Rainer Fuchs , Klaus Naumann , Ingeborg Hammann , Bernhard Homeyer , Wolfgang Behrenz , Wilhelm Stendel
IPC分类号： C07C69/753 , A01N53/00 , A01N53/06 , A01N53/08 , C07C67/00 , C07C253/00 , C07C255/39 , C07C121/75
CPC分类号： A01N53/00
摘要： Fluorine-substituted spirocarboxylic acid benzyl esters of the formula ##STR1## in which R.sup.1 represents hydrogen, cyano or alkyl, alkenyl or alkynyl, with in each case up to 4 carbon atoms,R.sup.2 represents a phenyl radical which is substituted by halogen and/or by optionally halogen-substituted phenoxy, with the proviso that the radical R.sup.2 contains in total at least one fluorine substituent, andR.sup.3, R.sup.4, R.sup.5 and R.sup.6 each represent hydrogen, halogen or alkyl, orR.sup.3 and R.sup.4, taken together, and/or R.sup.5 and R.sup.6, taken together, represent alkanediyl (alkylene) or a fused-on benzo radical,and the C atoms of the 5-member spirocyclic ring are linked to one another either by double bonds or by single bonds, which possess arthropodicidal properties.
摘要翻译：氟取代的式“IMAGE”的螺羧酸苄基酯，其中R 1表示氢，氰基或烷基，烯基或炔基，在每种情况下最多4个碳原子，R 2表示被卤素和/或通过任选的卤素取代的苯氧基，条件是基团R 2总共含有至少一个氟取代基，并且R 3，R 4，R 5和R 6各自代表氢，卤素或烷基，或者R 3和R 4一起，和/或 R 5和R 6一起代表烷二基（亚烷基）或稠合的苯并基，5元螺环的C原子通过具有节肢动物特性的双键或单键彼此连接。

7. 发明授权

US4316913A Arthropodicidally active styrylcyclopropanecarboxylic acid esters 失效
标题翻译：节肢动物活性苯乙烯基环丙烷羧酸酯
公开(公告)号：US4316913A
公开(公告)日：1982-02-23
申请号：US136023
申请日：1980-03-31
申请人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
发明人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： C07C67/08 , A01N53/00 , A01N53/08 , A01N53/10 , B01J31/00 , C07B61/00 , C07C62/34 , C07C67/00 , C07C69/743 , C07C69/757 , C07C253/00 , C07C255/39 , C07C255/53 , C07C313/00 , C07C323/62 , C07D317/46 , C07D317/60 , C07D319/20 , C07F9/40 , C07C121/75
CPC分类号： C07F9/4056 , A01N53/00 , C07C323/00 , C07C62/34 , C07D317/46 , C07D317/60 , C07D319/20
摘要： Substituted styrylcyclopropanecarboxylic acid esters of the formula ##STR1## in which R represents C.sub.1-4 -alkyl or an alcohol radical customary in pyrethroids,R.sup.1 represents alkoxy or alkylthio, either of which is optionally substituted by halogen andR.sup.2 represents hydrogen or alkoxy, orR.sup.1 and R.sup.2 together represent optionally halogen-substituted alkylenedioxy, andR.sup.3 represents hydrogen or chlorine,exhibit arthropodicidal activity. A novel synthesis is shown involving reaction of ##STR2## in the presence of an alkali metal cyanide to produce an end product wherein R is an .alpha.-cyano-3-phenoxybenzyl ester. ##STR3## is reacted with ##STR4## in the presence of a base to produce certain novel intermediates.
摘要翻译：取代的苯甲酰基环丙烷羧酸酯，其中R表示C1-4烷基或拟除虫菊酯中通常的醇基，R1表示烷氧基或烷硫基，其任一个任选被卤素取代，R 2表示氢或烷氧基，或R 1 并且R 2一起代表卤素取代的亚烷基二氧基，并且R 3表示氢或氯，表现出节肢动物杀伤活性。显示了一种新的合成，其涉及在碱金属氰化物存在下的反应，以产生最终产物，其中R是α-氰基-3-苯氧基苄基酯。在一个碱的存在下，与反应产生某些新的中间体。

8. 发明授权

US4279923A Combating pests with 3-(2,3-dichloro-3,3-difluoro-prop-1-en-1-yl)-2,2-dimethyl-cyclo-propanec arboxylic acid fluoro-benzyl esters 失效
标题翻译：将害虫与3-（2,3-二氯-3,3-二氟 - 丙-1-烯-1-基）-2,2-二甲基 - 环丙烷羧酸氟代苄酯
公开(公告)号：US4279923A
公开(公告)日：1981-07-21
申请号：US185836
申请日：1980-09-10
申请人： Rainer Fuchs , Klaus Naumann , Reinhard Lantzsch , Hermann Hagemann , Ingeborg Hammann , Bernhard Homeyer , Wolfgang Behrenz , Wilhelm Stendel
发明人： Rainer Fuchs , Klaus Naumann , Reinhard Lantzsch , Hermann Hagemann , Ingeborg Hammann , Bernhard Homeyer , Wolfgang Behrenz , Wilhelm Stendel
IPC分类号： C07C69/747 , A01N53/00 , A01N53/06 , A01N53/08 , B01J31/02 , C07C61/40 , C07C67/00 , C07C67/08 , C07C67/14 , C07C253/00 , C07C255/39 , C07C69/743 , C07C121/75
CPC分类号： C07C61/40 , A01N53/00
摘要： 3-(2,3-Dichloro-3,3-difluoro-prop-1-en-1-yl)-2,2-dimethyl-cyclo-propanecarboxylic acid fluoro-benzyl esters of the formula ##STR1## in which R.sup.1 represents hydrogen, cyano, alkyl with up to 4 carbon atoms, alkenyl with up to 4 carbon atoms or alkynyl with up to 4 carbon atoms, andR.sup.2 represents a phenyl radical which is substituted by fluorine and/or optionally fluorine-substituted phenoxy, with the proviso that the radical R.sup.2 in total contains at least one fluorine substituent,which possess pesticidal activity.
摘要翻译：具有式“IMAGE”的3-（2,3-二氯-3,3-二氟 - 丙-1-烯-1-基）-2,2-二甲基 - 环丙烷 - 羧酸氟 - 苄基酯，其中R1 表示氢，氰基，具有至多4个碳原子的烷基，具有至多4个碳原子的烯基或具有至多4个碳原子的炔基，R 2表示被氟和/或任选氟取代的苯氧基取代的苯基，条件是基团R2总计含有至少一个具有杀虫活性的氟取代基。

9. 发明授权

US4215141A Combating insects and acarids with 4,4,5,5-tetrachloro-2,2-dimethyl-spiropentane-1-carboxylic acid 3-phenoxy-benzyl esters 失效
标题翻译：用4,4,5,5-四氯-2,2-二甲基 - 异丙基-1-羧酸3-苯氧基 - 苄基酯与昆虫和螨虫相结合
公开(公告)号：US4215141A
公开(公告)日：1980-07-29
申请号：US41222
申请日：1979-05-21
申请人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
发明人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： C07C69/753 , A01N53/00 , A01N53/08 , C07C61/15 , C07C67/00 , C07C253/00 , C07C255/39 , A01N9/20 , A01N9/24 , C07C69/74 , C07C121/66
CPC分类号： C07C61/15 , A01N53/00
摘要： 4,4,5,5-tetrachloro-2,2-dimethyl-spiropentane-1-carboxylic acid 3-phenoxy-benzyl esters of the formula ##STR1## in which R and R.sup.1 each independently is hydrogen or halogen, andR.sup.2 is hydrogen, cyano or ethynyl,which possess insecticidal and acaricidal properties.
摘要翻译：具有式“IMAGE”的4,4,5,5-四氯-2,2-二甲基 - 异丙烷-1-羧酸3-苯氧基 - 苄基酯，其中R和R 1各自独立地是氢或卤素，R 2是氢，氰基或乙炔基，其具有杀虫和杀螨性质。

10. 发明授权

US4611009A Combating arthropods with 3-phenoxybenzyl 2,2-dimethyl-3-vinylcyclopropane carboxylates 失效
标题翻译：将节肢动物与2,2-二甲基-3-乙烯基环丙烷羧酸3-苯氧基苄酯反应
公开(公告)号：US4611009A
公开(公告)日：1986-09-09
申请号：US391732
申请日：1982-06-24
申请人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
发明人： Rainer Fuchs , Ingeborg Hammann , Wilhelm Stendel
IPC分类号： C07C61/39 , A01N53/00 , A01N53/08 , C07C61/40 , C07C67/00 , C07C67/08 , C07C67/10 , C07C67/14 , C07C69/743 , C07C69/747 , C07C253/00 , C07C255/39 , C07C313/00 , C07C323/55 , C07C121/60 , A01N43/36
CPC分类号： A01N53/00
摘要： 3-Phenoxybenzyl 2,2-dimethyl-3-vinyl-cyclopropane carboxylates of the formula ##STR1## in which R, R.sup.1 and R.sup.2 each independently is hydrogen or halogen,R.sup.3 is phenyl, phenylthio, or phenyl or phenylthio carrying at least one alkyl group or halogen atom,Y is hydrogen or cyano,n is 1, 2, 3, 4 or 5, andm is 1, 2, 3 or 4,which possess arthropodicidal properties.
摘要翻译：其中R 1，R 2和R 2各自独立地为氢或卤素，R 3为苯基，苯硫基或苯基或苯硫基，其具有至少一个烷基基团或卤原子，Y为氢或氰基，n为1,2,3,4或5，m为1,2,3或4，具有节肢动物学特性。

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