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    • 4. 发明申请
    • MIXTURE OF SURFACE-ACTIVE COMPOUNDS FOR USE IN CLEANING PREPARATIONS
    • 表面活性化合物的混合物用于清洁制剂
    • US20070082836A1
    • 2007-04-12
    • US11531320
    • 2006-09-13
    • Sabine BothCorinna BoehmeRainer EskuchenMelanie MaikHans-Christian Raths
    • Sabine BothCorinna BoehmeRainer EskuchenMelanie MaikHans-Christian Raths
    • C11D1/72
    • C11D1/825C11D1/40C11D1/44C11D1/662C11D1/72C11D1/721C11D1/722C11D1/74C11D1/835C11D1/90C11D1/94
    • The disclosed invention relates to mixtures of at least two structurally different surface-active compounds, one surface-active compound a) being selected from an hydroxyl mixed ether compound of formula (I): R1O[CH2CH2O]xCH2CH(OM)R2  (I) in which R1 is a linear or branched alkyl and/or alkenyl group containing 4 to 22 carbon atoms or an R2—CH(OH)CH2 group, where R2 is a linear or branched alkyl and/or alkenyl group containing 8 to 16 carbon atoms, x is a number from 40 to 80 and M is a hydrogen atom or a saturated alkyl group containing 1 to 18 carbon atoms. The second surface-active compound b) is preferably selected from a structurally different hydroxy mixed ether compound of formula (II): R3O[CH2CH2O]y[CH2CHCH3O]zCH2CH(OH)R4  (II) These mixtures are capable of improving the drying of hard surfaces after washing and, at the same time, also positively influence clear-rinse performance.
    • 所公开的发明涉及至少两种结构不同的表面活性化合物的混合物,一种表面活性化合物a)选自式(I)的羟基混合醚化合物:<β在线式描述=“In- 线式“end =”lead“?> R 1 O 2 CH 2 CH 2 O 2 CH 2 CH 2 (I)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中R < SUP> 1是含有4至22个碳原子的直链或支链烷基和/或烯基或R 2 -CH(OH)CH 2 - 基团 其中R 2是含有8至16个碳原子的直链或支链烷基和/或烯基,x是40至80的数,M是氢原子或含有1的饱和烷基 至18个碳原子。 第二表面活性化合物b)优选选自结构不同的式(II)的羟基混合醚化合物:<?in-line-formula description =“In-line formula”end =“lead”?> R SUP > 3 O 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 (O)CH 2 CH 2 OH(CH 2)2(2) 在线配方“end =”tail“?>这些混合物能够改善洗涤后硬表面的干燥,同时也对清洗性能有积极的影响。
    • 5. 发明授权
    • Alkyl and/or alkenyloligoglycoside preparations having reduced magnesium salt concentrations
    • 具有降低的镁盐浓度的烷基和/或烯醇降糖苷制剂
    • US07045494B2
    • 2006-05-16
    • US10481841
    • 2002-06-12
    • Thomas AlbersKarl Heinz SchmidRainer EskuchenMichael Koehler
    • Thomas AlbersKarl Heinz SchmidRainer EskuchenMichael Koehler
    • C11D3/22C11D11/00C11D13/00C07H15/04
    • C07H15/04C07H1/06
    • A process for making an alkyl and/or alkenyl oligoglycoside preparation having a magnesium salt concentration of less than about 10 ppm involving the steps of: (a) providing an alkyl and/or alkenyl oligoglycoside preparation having an active substance content of from about 10 to 70% by weight, based on the weight of the preparation; (b) providing an acid component; (c) adjusting the pH of the alkyl and/or alkenyl oligoglycoside preparation to from about 4 to 9.5 by combining the acid component with the alkyl and/or alkenyl oligoglycoside preparation to form a pH-modified alkyl and/or alkenyl oligoglycoside preparation; (d) providing a column charged with an ion exchange resin; and (e) purifying the pH-modified alkyl and/or alkenyl oligoglycoside preparation by passing it through the column of step (d) at a viscosity of from about 20 to 6,000 mPas, and at a temperature of from about 20 to 90° C. to form the alkyl and/or alkenyl oligoglycoside preparation having a magnesium salt concentration of less than about 10 ppm.
    • 制备镁盐浓度小于约10ppm的烷基和/或烯基低聚糖苷制剂的方法,包括以下步骤:(a)提供活性物质含量为约10至10重量%的烷基和/或烯基低聚糖苷制剂, 70重量%,基于制剂的重量; (b)提供酸组分; (c)通过将酸组分与烷基和/或链烯基低聚糖苷制剂组合以形成pH-改性的烷基和/或烯基低聚糖苷制剂,将烷基和/或链烯基低聚糖苷制剂的pH调节至约4至9.5; (d)提供带有离子交换树脂的柱; 和(e)通过使pH值为约20至6,000mPa·s的粘度和约20至90℃的温度通过步骤(d)的柱来纯化pH-改性的烷基和/或烯基低聚糖苷制剂 形成镁盐浓度小于约10ppm的烷基和/或烯基低聚糖苷制剂。
    • 7. 发明授权
    • Modified process for the direct production of alkyl glycosides
    • 直接生产烷基糖苷的改良方法
    • US5559219A
    • 1996-09-24
    • US952535
    • 1992-02-09
    • Willi WuestJoseph WollmannRainer Eskuchen
    • Willi WuestJoseph WollmannRainer Eskuchen
    • C07H15/04C07H1/00C07H3/02
    • C07H15/04
    • Alkyl glycosides are produced by direct synthesis from higher monofunctional alcohols and powder-form glycoses, particularly anhydrous glucose and/or glucose monohydrate, in the presence of acidic catalysts at elevated temperatures, the interior of the reactor being kept under reduced pressure and the glycose being introduced with delay into the alcohol reactants present in excess therein, the alcohol reactants containing the acidic catalyst and being heated to the reaction temperature, while water released in the reaction mixture is removed from the reaction zone via the gas phase. A partial stream is run off from the liquid reaction mixture and delivered to a premixing zone into which the powder-form reactant is simultaneously introduced and is converted with the liquid partial stream into a paste which is delivered to the interior of the reactor via a following intensive mixer. The premixing zone is in direct pressure equalization with the reduced pressure of the reactor interior via the intensive mixer on the one hand and, at the same time, with the ambient pressure via the feed unit used for the powder-form glycose on the other hand, the consistency of the paste formed in the premixing zone being selected so that the paste serves as a pressure-equalizing sealing compound and, hence, as a so-called "living seal".
    • PCT No.PCT / EP91 / 01010 Sec。 371日期1992年2月9日 102(e)1992年2月9日PCT PCT 1991年5月31日PCT公布。 出版物WO91 / 19722 日期1991年12月26日烷基糖苷通过在高温下在酸性催化剂存在下由高级单官能醇和粉末形糖糖,特别是无水葡萄糖和/或葡萄糖一水合物进行直接合成来制备,反应器内部保持减少 压力,并且将糖类延迟引入其中存在的醇反应物中,醇反应物含有酸性催化剂并被加热至反应温度,同时通过气相将反应混合物中释放的水从反应区除去。 部分物流从液体反应混合物中流出并且被输送到预混合区,粉末形式的反应物同时被引入到该预混合区中,并且用液体部分流转化成糊状物,该浆料经由下列物质被输送到反应器的内部 密集搅拌机 一方面,预混合区域通过强化混合器在反应器内部的压力下进行直接均压,另一方面,通过用于粉末形式的糖的进料单元的环境压力 选择在预混合区中形成的糊状物的稠度,使得糊状物用作均压密封剂,因此作为所谓的“活性密封”。