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1. 发明授权

US08324305B2 Process for the homogeneous incorporation of polymer particles into polymeric matrices 失效
标题翻译：将聚合物颗粒均匀掺入聚合物基质的方法
公开(公告)号：US08324305B2
公开(公告)日：2012-12-04
申请号：US13002515
申请日：2009-07-03
申请人： Rainer Dyllick-Brenzinger , Alban Glaser , Samira Nozari
发明人： Rainer Dyllick-Brenzinger , Alban Glaser , Samira Nozari
IPC分类号： C08K5/01 , C08K5/16
CPC分类号： C08J3/005 , C08J2323/02 , C08L23/02 , C08L2666/02
摘要： The invention relates to preparations comprising a wax in which polymer particles are present, where the polymer particles comprise at least one effect substance, obtainable by, by means of a miniemulsion polymerization carried out in the presence of a wax-immiscible solvent, distributing at least one effect substance in polymer particles, and incorporating the polymer particle dispersion obtained in this way into a wax by phase transfer.Furthermore, the invention relates to compositions comprising a polymeric matrix in which, in essentially homogeneous distribution, the aforementioned polymer particles are present, obtainable by incorporating the aforementioned polymer-particle-comprising wax as preparation into a polymeric matrix.
摘要翻译：本发明涉及包含其中存在聚合物颗粒的蜡的制剂，其中聚合物颗粒包含至少一种效应物质，其可通过在不溶于蜡的溶剂存在下进行的微乳液聚合获得，至少分布聚合物颗粒中的一种效应物质，并且通过相转移将以这种方式获得的聚合物颗粒分散体掺入蜡中。此外，本发明涉及包含聚合物基质的组合物，其中基本上均匀分布存在上述聚合物颗粒，其通过将上述含聚合物颗粒的蜡作为制剂掺入聚合物基质中而获得。

2. 发明申请

US20110105660A1 PROCESS FOR THE HOMOGENEOUS INCORPORATION OF POLYMER PARTICLES INTO POLYMERIC MATRICES 失效
标题翻译：将聚合物颗粒均匀掺入聚合物基质的方法
公开(公告)号：US20110105660A1
公开(公告)日：2011-05-05
申请号：US13002515
申请日：2009-07-03
申请人： Rainer Dyllick-Brenzinger , Alban Glaser , Samira Nozari
发明人： Rainer Dyllick-Brenzinger , Alban Glaser , Samira Nozari
IPC分类号： C08K5/17
CPC分类号： C08J3/005 , C08J2323/02 , C08L23/02 , C08L2666/02
摘要： The invention relates to preparations comprising a wax in which polymer particles are present, where the polymer particles comprise at least one effect substance, obtainable by, by means of a miniemulsion polymerization carried out in the presence of a wax-immiscible solvent, distributing at least one effect substance in polymer particles, and incorporating the polymer particle dispersion obtained in this way into a wax by phase transfer.Furthermore, the invention relates to compositions comprising a polymeric matrix in which, in essentially homogeneous distribution, the aforementioned polymer particles are present, obtainable by incorporating the aforementioned polymer-particle-comprising wax as preparation into a polymeric matrix.
摘要翻译：本发明涉及包含其中存在聚合物颗粒的蜡的制剂，其中聚合物颗粒包含至少一种效应物质，其可通过在不溶于蜡的溶剂存在下进行的微乳液聚合获得，至少分布聚合物颗粒中的一种效应物质，并且通过相转移将以这种方式获得的聚合物颗粒分散体掺入蜡中。此外，本发明涉及包含聚合物基质的组合物，其中基本上均匀分布存在上述聚合物颗粒，其通过将上述含聚合物颗粒的蜡作为制剂掺入聚合物基质中而获得。

3. 发明授权

US09234098B2 Method for the production of composite materials 有权
标题翻译：复合材料生产方法
公开(公告)号：US09234098B2
公开(公告)日：2016-01-12
申请号：US13262755
申请日：2010-04-01
申请人： Hannah Maria König , Hans-Joachim Hähnle , Arno Lange , Samira Nozari , Gerhard Cox , Rainer Dyllick-Brenzinger , Stefan Spange , Tina Löschner
发明人： Hannah Maria König , Hans-Joachim Hähnle , Arno Lange , Samira Nozari , Gerhard Cox , Rainer Dyllick-Brenzinger , Stefan Spange , Tina Löschner
IPC分类号： B82Y30/00 , C08L83/02 , C08J5/00 , H01B1/04 , C08K3/36
CPC分类号： C08L83/02 , B82Y30/00 , C08J5/005 , C08K3/36
摘要： The present invention relates to a process for producing a nanocomposite material from a) at least one inorganic or organometallic metal phase; and b) an organic polymer phase; comprising the polymerization of at least one monomer M which have at least one first polymerizable monomer unit A which has a metal or semimetal M, and at least one second polymerizable organic monomer unit B which is joined to the polymerizable unit A via a covalent chemical bond, under polymerization conditions under which both the polymerizable monomer unit A and the polymerizable unit B polymerize with breakage of the bond between A and B, the monomers M to be polymerized comprising a first monomer M1 and at least one second monomer M2 which differs at least in one of the monomer units A and B from the monomer M1 (embodiment 1), or the monomers to be polymerized comprising, as well as the at least one monomer M, at least one further monomer other than the monomers M, i.e. a conventional monomer which does not have a monomer unit A and is copolymerizable with the monomer unit B (embodiment 2).
摘要翻译：本发明涉及从a）至少一种无机或有机金属金属相制备纳米复合材料的方法; 和b）有机聚合物相; 包括至少一种单体M的聚合，所述单体M具有至少一个具有金属或半金属M的第一可聚合单体单元A和至少一个第二可聚合有机单体单元B，其通过共价化学键连接到可聚合单元A 在可聚合单体单元A和可聚合单元B两者都聚合并且A和B之间的键断裂聚合的聚合条件下，待聚合的单体M包含第一单体M1和至少一个第二单体M2，其至少不同在单体M1（实施方案1）的单体单元A和B中的一种中，或要聚合的单体以及至少一种单体M至少一种除单体M以外的其它单体，即常规不具有单体单元A并且可与单体单元B共聚的单体（实施方案2）。

4. 发明授权

US08680203B2 Process for producing a particulate nanocomposite material 失效
标题翻译：颗粒状纳米复合材料的制造方法
公开(公告)号：US08680203B2
公开(公告)日：2014-03-25
申请号：US13319414
申请日：2010-05-07
申请人： Samira Nozari , Rainer Dyllick-Brenzinger , Arno Lange , Stefan Spange
发明人： Samira Nozari , Rainer Dyllick-Brenzinger , Arno Lange , Stefan Spange
IPC分类号： C07F7/00 , C07F7/04
CPC分类号： C08F2/14 , B82Y30/00 , C08F2/44 , C08J5/005 , C08J2361/06 , C08K3/36 , Y10T428/2982
摘要： The present invention relates to a process for producing a particulate nanocomposite material, in which the particles of the nanocomposite material comprise a) at least one inorganic or organo(semi)metallic phase which comprises at least one (semi)metal M; and b) at least one organic polymer phase. The invention also relates to the nanocomposite materials obtainable by this process.The process comprises the polymerization of at least one monomer MM which has at least one first cationically polymerizable monomer unit A which has a metal or semimetal M, and at least one second cationically polymerizable organic monomer unit B which is joined to the polymerizable unit A via at least one, e.g. 1, 2, 3, or 4, covalent chemical bond, under cationic polymerization conditions under which both the polymerizable monomer unit A and the polymerizable unit B polymerize with breakage of the bond or bonds between A and B, wherein the polymerization is performed in an aprotic solvent in which the nanocomposite material is insoluble, in the presence of at least one polymerization initiator and of at least one further substance selected from α) at least one surface-active substance and β) at least one particulate material.
摘要翻译：本发明涉及一种制备颗粒状纳米复合材料的方法，其中纳米复合材料的颗粒包含a）至少一种包含至少一种（半）金属M的无机或有机（半）金属相; 和b）至少一个有机聚合物相。本发明还涉及通过该方法可获得的纳米复合材料。该方法包括至少一种单体MM的聚合，所述单体MM具有至少一个具有金属或半金属M的第一阳离子可聚合单体单元A和至少一个第二阳离子可聚合有机单体单元B，其连接到可聚合单元A，经由至少一个，例如 1,2,3或4共价化学键，在阳离子聚合条件下，可聚合单体单元A和可聚合单元B都聚合，其中A和B之间的键或键的断裂，其中聚合在在至少一种聚合引发剂和选自α）至少一种表面活性物质和至少一种表面活性物质和至少一种颗粒物质的至少一种其它物质的存在下，纳米复合材料不溶解的非质子溶剂。

5. 发明申请

US20120091400A1 METHOD FOR THE PRODUCTION OF COMPOSITE MATERIALS 有权
标题翻译：复合材料生产方法
公开(公告)号：US20120091400A1
公开(公告)日：2012-04-19
申请号：US13262755
申请日：2010-04-01
申请人： Hannah Maria König , Hans-Joachim Hähnle , Arno Lange , Samira Nozari , Gerhard Cox , Rainer Dyllick-Brenzinger , Stefan Spange , Tina Löschner
发明人： Hannah Maria König , Hans-Joachim Hähnle , Arno Lange , Samira Nozari , Gerhard Cox , Rainer Dyllick-Brenzinger , Stefan Spange , Tina Löschner
IPC分类号： H01B1/04 , C01B13/00 , C08L83/06 , C01B21/06 , B82Y30/00
CPC分类号： C08L83/02 , B82Y30/00 , C08J5/005 , C08K3/36
摘要： The present invention relates to a process for producing a nanocomposite material from a) at least one inorganic or organometallic metal phase; and b) an organic polymer phase; comprising the polymerization of at least one monomer M which have at least one first polymerizable monomer unit A which has a metal or semimetal M, and at least one second polymerizable organic monomer unit B which is joined to the polymerizable unit A via a covalent chemical bond, under polymerization conditions under which both the polymerizable monomer unit A and the polymerizable unit B polymerize with breakage of the bond between A and B, the monomers M to be polymerized comprising a first monomer M1 and at least one second monomer M2 which differs at least in one of the monomer units A and B from the monomer M1 (embodiment 1), or the monomers to be polymerized comprising, as well as the at least one monomer M, at least one further monomer other than the monomers M, i.e. a conventional monomer which does not have a monomer unit A and is copolymerizable with the monomer unit B (embodiment 2).
摘要翻译：本发明涉及从a）至少一种无机或有机金属金属相制备纳米复合材料的方法; 和b）有机聚合物相; 包括至少一种单体M的聚合，所述单体M具有至少一个具有金属或半金属M的第一可聚合单体单元A和至少一个第二可聚合有机单体单元B，其通过共价化学键连接到可聚合单元A 在可聚合单体单元A和可聚合单元B两者都聚合并且A和B之间的键断裂聚合的聚合条件下，待聚合的单体M包含第一单体M1和至少一个第二单体M2，其至少不同在单体M1（实施方案1）的单体单元A和B中的一种中，或要聚合的单体以及至少一种单体M至少一种除单体M以外的其它单体，即常规不具有单体单元A并且可与单体单元B共聚的单体（实施方案2）。

6. 发明申请

US20120052300A1 PROCESS FOR PRODUCING A PARTICULATE NANOCOMPOSITE MATERIAL 失效
标题翻译：生产颗粒状纳米复合材料的方法
公开(公告)号：US20120052300A1
公开(公告)日：2012-03-01
申请号：US13319414
申请日：2010-05-07
申请人： Samira Nozari , Rainer Dyllick-Brenzinger , Arno Lange , Stefan Spange
发明人： Samira Nozari , Rainer Dyllick-Brenzinger , Arno Lange , Stefan Spange
IPC分类号： C08G77/00 , C01B33/113 , C08L83/00 , B82Y30/00
CPC分类号： C08F2/14 , B82Y30/00 , C08F2/44 , C08J5/005 , C08J2361/06 , C08K3/36 , Y10T428/2982
摘要： The present invention relates to a process for producing a particulate nanocomposite material, in which the particles of the nanocomposite material comprise a) at least one inorganic or organo(semi)metallic phase which comprises at least one (semi)metal M; and b) at least one organic polymer phase. The invention also relates to the nanocomposite materials obtainable by this process.The process comprises the polymerization of at least one monomer MM which has at least one first cationically polymerizable monomer unit A which has a metal or semimetal M, and at least one second cationically polymerizable organic monomer unit B which is joined to the polymerizable unit A via at least one, e.g. 1, 2, 3, or 4, covalent chemical bond, under cationic polymerization conditions under which both the polymerizable monomer unit A and the polymerizable unit B polymerize with breakage of the bond or bonds between A and B, wherein the polymerization is performed in an aprotic solvent in which the nanocomposite material is insoluble, in the presence of at least one polymerization initiator and of at least one further substance selected from α) at least one surface-active substance and β) at least one particulate material.
摘要翻译：本发明涉及一种制备颗粒状纳米复合材料的方法，其中纳米复合材料的颗粒包含a）至少一种包含至少一种（半）金属M的无机或有机（半）金属相; 和b）至少一个有机聚合物相。本发明还涉及通过该方法可获得的纳米复合材料。该方法包括至少一种单体MM的聚合，所述单体MM具有至少一个具有金属或半金属M的第一阳离子可聚合单体单元A和至少一个第二可阳离子聚合的有机单体单元B，其通过至少一个，例如 1,2,3或4共价化学键，在阳离子聚合条件下，可聚合单体单元A和可聚合单元B都聚合，其中A和B之间的键或键的断裂，其中聚合在在至少一种聚合引发剂和选自α）至少一种表面活性物质和至少一种表面活性物质和至少一种颗粒物质的至少一种其它物质的存在下，纳米复合材料不溶解的非质子溶剂。

7. 发明申请

US20080146448A1 Aqueous Polymer Dispersions Comprising Effect Substances, Processes For Preparing Them And Their Use 审中-公开
标题翻译：含水聚合物分散体，包括作用物质，制备方法及其用途
公开(公告)号：US20080146448A1
公开(公告)日：2008-06-19
申请号：US11817712
申请日：2005-03-10
申请人： Rainer Dyllick-Brenzinger , Alban Glaser , Matthias Bratz , Felix Christian Gorth , Christian Kruger , Gunter Oetter
发明人： Rainer Dyllick-Brenzinger , Alban Glaser , Matthias Bratz , Felix Christian Gorth , Christian Kruger , Gunter Oetter
IPC分类号： A01N25/12 , C08F2/16 , A61K8/02 , A01P13/00 , A01P15/00 , A01P3/00 , A61Q99/00 , C08K3/18
CPC分类号： C08F2/22 , C08F2/44 , C08K5/0008 , C08L23/02 , C08L23/22 , C08L33/12
摘要： Aqueous polymer dispersions comprising effect substances with a mean particle size of the dispersed particles of
摘要翻译：包含具有小于1000nm的分散颗粒的平均粒径的效应物质的聚合物水分散体，其中聚合物颗粒包含至少一种烯键式不饱和单体的聚合物基质，至少0.1重量％的（i）至少一种乙烯，丙烯，1-丁烯，2-丁烯，1-戊烯或1-己烯的均聚物，平均摩尔质量百分数为100至10000，（ii ）至少一种在（i）中提及的至少两种单体与平均摩尔质量为100-1000的共聚物和/或（iii）平均摩尔质量百分比的聚异丁烯的至少一种共聚物至少为 100和至少一种可溶于形成聚合物的烯属不饱和单体的效应物质，通过细乳液聚合制备这种分散体的方法，其中至少一种效应物质在至少一种烯键式不饱和单体中的溶液和至少一个聚合物根据（i），（ii）和/或（iii）的r在至少一种表面活性剂的存在下在水中乳化，得到平均液滴尺寸<500nm的细乳液，自由基条件，以及由此获得的聚合物水分散体或由其获得的聚合物粉末，用于稳定聚合物的抗紫外线辐射，氧气和/或热的作用，作为聚合物的润滑剂，在化妆品或药物制剂中的表面涂料，制备纸，皮革或纺织品，用于饲养动物的配方和用于农业和林业的配方。

8. 发明申请

US20100190929A1 USE OF POLYMER POWDER CONTAINING UV ABSORBER FOR THE STABILISATION OF POLYMERS AGAINST THE EFFECTS OF UV RADIATION 失效
标题翻译：包含紫外线吸收剂的聚合物粉末对紫外线辐射效应的聚合物稳定化的应用
公开(公告)号：US20100190929A1
公开(公告)日：2010-07-29
申请号：US12756061
申请日：2010-04-07
申请人： Rainer Dyllick-Brenzinger , Oliver Koch , Dirk Wulff , Alban Glaser
发明人： Rainer Dyllick-Brenzinger , Oliver Koch , Dirk Wulff , Alban Glaser
IPC分类号： C08L23/00
CPC分类号： C08K5/005
摘要： The present invention relates to the use, for stabilizing polymers, in particular polyolefins, with respect to exposure to UV radiation, of fine-particle polymer powders comprising at least one UV absorber. The present invention further relates to stabilizer mixtures for stabilizing polymers with respect to exposure to UV radiation, oxygen and heat, which, inter alia, comprise these polymer powders, and to a process for stabilizing polymers, in particular polyolefins, with respect to exposure to UV radiation, oxygen and heat, which comprises adding, to the polymers, in particular to the polyolefins, an effective amount of these stabilizers. The present invention further relates to polymers, in particular polyolefins, which have been stabilized with respect to exposure to UV radiation or with respect to exposure to UV radiation, oxygen and heat, which comprise an effective amount of these polymer powders or, respectively, stabilizer mixtures, and to articles produced from these stabilized polymers, in particular polyolefins.
摘要翻译：本发明涉及用于稳定聚合物，特别是关于暴露于UV辐射的聚烯烃，包含至少一种UV吸收剂的细颗粒聚合物粉末的用途。本发明还涉及用于稳定聚合物相对于暴露于UV辐射，氧和热的稳定剂混合物，其特别包括这些聚合物粉末，以及用于稳定聚合物，特别是聚烯烃的方法，涉及暴露于 UV辐射，氧气和热量，其包括向聚合物，特别是聚烯烃中加入有效量的这些稳定剂。本发明还涉及聚合物，特别是聚烯烃，其已经相对于暴露于UV辐射或相对于暴露于UV辐射，氧和热而被稳定，其包含有效量的这些聚合物粉末或分别为稳定剂混合物，以及由这些稳定的聚合物，特别是聚烯烃生产的制品。

9. 发明申请

US20090318617A1 POLYMER DISPERSIONS COMPRISING EFFECT SUBSTANCES AND USE THEREOF 审中-公开
标题翻译：包含有效物质的聚合物分散体及其用途
公开(公告)号：US20090318617A1
公开(公告)日：2009-12-24
申请号：US12281154
申请日：2007-03-09
申请人： Rainer Dyllick-Brenzinger , Alban Glaser
发明人： Rainer Dyllick-Brenzinger , Alban Glaser
IPC分类号： C08K5/132 , C08F2/44 , C08L33/20 , C08L33/08 , C08L25/04
CPC分类号： C08F2/44 , C08F2/22 , C08F220/14 , C08F220/40 , C08F222/1006 , C08K5/005 , C08K9/08 , C08L33/12
摘要： Aqueous polymer dispersions, the dispersed particles of which comprise at least one effect substance from the group consisting of UV absorbers, antistatics, antioxidants and antifogging agents and have a mean particle size of at most 500 nm and a glass transition temperature of at least 85° C. and which can be obtained by emulsion polymerization of ethylenically unsaturated monomers in the presence of at least one effect substance, and to the use of the polymer dispersions comprising effect substances or of the polymer powders obtained therefrom for the finishing and for the stabilizing of polymers, in particular for the stabilizing of thermoplastic polymers, against the effect of UV radiation.
摘要翻译：含水聚合物分散体，其分散颗粒包含至少一种由UV吸收剂，抗静电剂，抗氧化剂和防雾剂组成的组的效应物质，并且具有至多500nm的平均粒度和至少85°的玻璃化转变温度并且可以通过在至少一种效应物质的存在下烯键式不饱和单体的乳液聚合获得，以及使用包含效应物质或由其获得的聚合物粉末的聚合物分散体用于整理和稳定聚合物，特别是用于稳定热塑性聚合物，抗紫外线辐射的作用。

10. 发明申请

US20060058430A1 Use of polymer powder containing uv absorber for the stabilisation of polymers against the effects of uv radiation 失效
标题翻译：使用含有紫外吸收剂的聚合物粉末来稳定聚合物以抵抗紫外辐射的影响
公开(公告)号：US20060058430A1
公开(公告)日：2006-03-16
申请号：US10535860
申请日：2003-11-11
申请人： Rainer Dyllick-Brenzinger , Oliver Koch , Dirk Wulff , Alban Glaser
发明人： Rainer Dyllick-Brenzinger , Oliver Koch , Dirk Wulff , Alban Glaser
IPC分类号： C08K5/49
CPC分类号： C08K5/005
摘要： The present invention relates to the use, for stabilizing polymers, in particular polyolefins, with respect to exposure to UV radiation, of fine-particle polymer powders comprising at least one UV absorber. The present invention further relates to stabilizer mixtures for stabilizing polymers with respect to exposure to UV radiation, oxygen and heat, which, inter alia, comprise these polymer powders, and to a process for stabilizing polymers, in particular polyolefins, with respect to exposure to UV radiation, oxygen and heat, which comprises adding, to the polymers, in particular to the polyolefins, an effective amount of these stabilizers. The present invention further relates to polymers, in particular polyolefins, which have been stabilized with respect to exposure to UV radiation or with respect to exposure to UV radiation, oxygen and heat, which comprise an effective amount of these polymer powders or, respectively, stabilizer mixtures, and to articles produced from these stabilized polymers, in particular polyolefins.
摘要翻译：本发明涉及用于稳定聚合物，特别是关于暴露于UV辐射的聚烯烃，包含至少一种UV吸收剂的细颗粒聚合物粉末的用途。本发明还涉及用于稳定聚合物相对于暴露于UV辐射，氧和热的稳定剂混合物，其特别包括这些聚合物粉末，以及用于稳定聚合物，特别是聚烯烃的方法，涉及暴露于 UV辐射，氧气和热量，其包括向聚合物，特别是聚烯烃中加入有效量的这些稳定剂。本发明还涉及聚合物，特别是聚烯烃，其已经相对于暴露于UV辐射或相对于暴露于UV辐射，氧和热而被稳定，其包含有效量的这些聚合物粉末或分别为稳定剂混合物，以及由这些稳定的聚合物，特别是聚烯烃生产的制品。

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