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1. 发明授权

US4952654A Heat distortion resistant, transparent thermoplastic molding material, its preparation and its use 失效
标题翻译：耐热变形，透明热塑性成型材料，其制备及其用途
公开(公告)号：US4952654A
公开(公告)日：1990-08-28
申请号：US324015
申请日：1989-03-16
申请人： Rainer Bueschl , Adolf Echte , Juergen Mertes
发明人： Rainer Bueschl , Adolf Echte , Juergen Mertes
IPC分类号： C08F20/52 , C08F220/10 , C08F220/14 , C08F220/54 , C08F220/56
CPC分类号： C08F220/14 , C08F220/54
摘要： A heat distortion resistant, transparent thermoplastic molding material contains a copolymer of the monomers(a) methyl methacrylate and(b) an N-substituted amide of methacrylic acid.The molding material contains from 5 to 95% by weight of monomer (a) and from 95 to 5% by weight of monomer or monomers (b), the percentages being based on (a)+(b), and furthermore, as monomer (b), and N-substituted amide of the formula ##STR1## where R is a primary, secondary or tertiary alkyl radical, cycloalkyl, aryl or aralkyl of 2 to 12 carbon atoms.The molding material is used for the production of heat distortion resistant moldings or laminates.
摘要翻译：耐热变形，透明的热塑性成型材料包含单体（a）甲基丙烯酸甲酯和（b）甲基丙烯酸的N-取代酰胺的共聚物。成型材料含有5至95重量％的单体（a）和95至5重量％的单体或单体（b），其百分比基于（a）+（b），此外，作为单体（b）和式“IMAGE”的N-取代酰胺，其中R是2至12个碳原子的伯，仲或叔烷基，环烷基，芳基或芳烷基。成型材料用于生产耐热变形模制品或层压材料。

2. 发明授权

US4839418A Thermoplastic molding materials and their preparation 失效
标题翻译：热塑性成型材料及其制备
公开(公告)号：US4839418A
公开(公告)日：1989-06-13
申请号：US141098
申请日：1988-01-05
申请人： Hans-Dieter Schwaben , Adolf Echte , Rainer Bueschl , Rainer Schlichtmann , Peter Klaerner , Hubert Kindler
发明人： Hans-Dieter Schwaben , Adolf Echte , Rainer Bueschl , Rainer Schlichtmann , Peter Klaerner , Hubert Kindler
IPC分类号： C08F287/00 , C08L25/06 , C08L51/00
CPC分类号： C08F287/00 , C08L25/06 , C08L51/00
摘要： A thermoplastic molding material contains, in each case based on the molding material comprising A+B,A from 80 to 60% by weight of a hard matrix composed of polystyrene andB from 20 to 40% by weight of a soft phase which is obtainable by polymerization of styrene in the presence of a linear styrene/butadienne block copolymer which has an ill defined transition, contains from 35 to 45% by weight of styrene and from 65 to 55% by weight of butadiene and has a block polystyrene content of from 25 to 35% by weight, the soft phase being uniformly distributed in the hard matrix and having a particle diameter of less than 0.8 .mu.m.The typical features of the said molding material are that the median particle diameter d.sub.50 (volume average of the soft phase B is from 0.25 to 0.38 .mu.m, the width of the particle size distribution, (d.sub.95 14 d.sub.5), is from 0.2 to 0.6 .mu.m, the d.sub.60 value is from 0.26 to 0.40 .mu.m and the d.sub.90 value is from 0.40 to 0.75.
摘要翻译：在各种情况下，热塑性成型材料基于包含A + B的成型材料，80-60重量％的由聚苯乙烯和B组成的硬质基质的A含有20-40重量％的软相，在具有不规则转变的线性苯乙烯/丁二烯嵌段共聚物的存在下苯乙烯的聚合包含35-45％（重量）的苯乙烯和65-55％（重量）的丁二烯，并且具有 25〜35重量％，软相均匀分布在硬质基质中，粒径小于0.8μm。所述成型材料的典型特征是中值粒径d50（软相B的体积平均值为0.25至0.38μm，粒度分布的宽度（d9514d5））为0.2至0.6μm m，d60值为0.26〜0.40μm，d90为0.40〜0.75。

3. 发明授权

US5011871A Impact resistant thermoplastic molding composition and use thereof 失效
标题翻译：耐冲击热塑性成型用组合物及其用途
公开(公告)号：US5011871A
公开(公告)日：1991-04-30
申请号：US323753
申请日：1989-03-15
申请人： Rainer Bueschl , Adolf Echte , Konrad Schulte , Hans Mittnacht
发明人： Rainer Bueschl , Adolf Echte , Konrad Schulte , Hans Mittnacht
IPC分类号： C08F279/02
CPC分类号： C08F279/02
摘要： An impact resistance thermoplastic molding composition contains, each percentage being based on A+B, from 80 to 55% by weight of a hard matrix A of a copolymer containing at least 95% by weight of an aromatic vinyl monomer a.sub.11 of from 8 to 10 carbon atoms and at least one comonomer a.sub.12 in a proportion of 0.1 to 5% by weight, based on A, and from 45 to 20% by weight of a soft phase B which, uniformly dispersed in the hard matrix, has an average particle diameter d.sub.50 (volume average) of from 3.5 to 9 .mu.m and is obtainable by polymerization of the mixture of monomers a.sub.11 and a.sub.12 in the presence of an elastomer (rubber) and subsequent isolation of the useful product, wherein the comonomer a.sub.12 has the general formula I ##STR1## where X is --OR.sup.2, --COOR.sup.2 or --CONHR.sup.3,R.sup.1 is hydrogen or methyl andR.sup.2 and R.sup.3 are each alkyl of from 1 or 2 to 10 carbon atoms with at least one OH or epoxy group or at least one other polar group.
摘要翻译：抗冲击性热塑性成型组合物含有以百分比为基准的A + B，80〜55重量％的含有至少95重量％的芳族乙烯基单体a11为8〜10的共聚物的硬质基质A 碳原子和至少一种共聚单体a 12，其比例为0.1至5重量％，基于A，和45至20重量％的均匀分散在硬质基质中的软相B具有平均粒径 d50（体积平均）为3.5至9μm，可通过在弹性体（橡胶）存在下聚合单体a11和a12的混合物，随后分离有用的产物而获得，其中共聚单体a12具有通式（I）其中X是-OR2，-COOR2或-CONHR3，R1是氢或甲基，R2和R3各自为具有1或2至10个碳原子的烷基，具有至少一个OH或环氧基团或在至少另一个极地组。

4. 发明授权

US5166270A Thermoplastic molding materials based on vinyl chloride 失效
标题翻译：基于氯乙烯的热塑性模塑材料
公开(公告)号：US5166270A
公开(公告)日：1992-11-24
申请号：US500932
申请日：1990-03-29
申请人： Klaus-Dieter Hungenberg , Rainer Bueschl
发明人： Klaus-Dieter Hungenberg , Rainer Bueschl
IPC分类号： C08L27/06 , C08L33/06
CPC分类号： C08L27/06 , C08L33/06
摘要： Thermoplastic molding materials obtained from polymers based on vinyl chloride contain from 2 to 80% by weight of a polymer ofa) from 2 to 100% by weight of a monomer of the general formula I ##STR1## where R.sup.1 is hydrogen or C.sub.1 -C.sub.4 -alkyl and Ar is an isoaromatic group, or of a mixture of these monomers, andb) from 0 to 98% by weight of a monomer of the general formula II ##STR2## where R.sup.2 is C.sub.1 -C.sub.4 -alkyl and Alk is C.sub.1 -C.sub.8 -alkyl, or of a mixture of these monomers, andc) from 0 to 5% by weight of further monomers capable of undergoing free radical polymerization (monomers III).The molding materials have a high heat distortion resistance.
摘要翻译：由基于氯乙烯的聚合物获得的热塑性成型材料含有2至80重量％的a）2至100重量％的通式I单体的聚合物，其中R 1为氢或C1- C 4 - 烷基和Ar是这些单体的混合物的异构基团，和b）0至98重量％的通式II的单体II，其中R 2是C 1 -C 4烷基和Alk 是C 1 -C 8烷基或这些单体的混合物，和c）0至5重量％的能够进行自由基聚合的其它单体（单体III）。成型材料具有高耐热变形性。

5. 发明授权

US5008341A Transparent thermoplastic blends 失效
标题翻译：透明热塑性混合物
公开(公告)号：US5008341A
公开(公告)日：1991-04-16
申请号：US401239
申请日：1989-08-31
申请人： Rainer Bueschl , Peter Klaerner
发明人： Rainer Bueschl , Peter Klaerner
IPC分类号： C08L25/04 , C08L25/12 , C08L27/06 , C08L33/00 , C08L33/04 , C08L33/06 , C08L101/00
CPC分类号： C08L25/12 , C08L27/06 , C08L33/06 , C08L2205/02
摘要： A transparent polyblend is formed from(a1) 99.9-0.1% by weight of a methyl (meth)acrylate homopolymer or of a copolymer thereof with up to 20% by weight of units of alkyl (meth)acrylate having an alkyl radical of from 2 to 10 carbon atoms and up to 10% by weight of further comonomers or(a2) 99.9-0.1% by weight of a styrene or .alpha.-methylstyrene and acrylonitrile copolymer containing from 5 to 30% by weight of units of acrylonitrile or(a3) 99.9-0.1% by weight of a possibly impact-modified polyvinyl chloride homopolymer or copolymer with up to 20% by weight of comonomers and(b) 0.1-99.9% by weight of a cycloalkyl (meth)acrylate homopolymer or copolymer with up to 99.9% by weight of units of methyl methacrylate.
摘要翻译：透明聚合物由（a1）99.9-0.1重量％的（甲基）丙烯酸甲酯均聚物或其共聚物与至多20重量％的具有烷基自由基的（甲基）丙烯酸烷基酯的单元形成至少10重量％的另外的共聚单体或（a2）99.9-0.1重量％的苯乙烯或α-甲基苯乙烯和丙烯腈共聚物，其含有5-30重量％的丙烯腈单元或（a3） 99.9〜0.1重量％的可能具有高达20重量％共聚单体的抗冲改性聚氯乙烯均聚物或共聚物，和（b）0.1-99.9重量％的（甲基）丙烯酸环烷基酯均聚物或共聚物，其高达99.9 重量百分比的甲基丙烯酸甲酯单位。

6. 发明授权

US4948832A Reinforced thermoplastic molding materials based on polyphenylene ether 失效
标题翻译：基于聚苯醚的增强热塑性成型材料
公开(公告)号：US4948832A
公开(公告)日：1990-08-14
申请号：US281755
申请日：1988-12-09
申请人： Bertram Ostermayer , Ehrenfried Baumgartner , Rainer Bueschl , Hermann Brandt , Klaus Boehlke , Erhard Seiler , Graham E. McKee
发明人： Bertram Ostermayer , Ehrenfried Baumgartner , Rainer Bueschl , Hermann Brandt , Klaus Boehlke , Erhard Seiler , Graham E. McKee
IPC分类号： C08L51/04 , C08L71/12 , C08L77/00
CPC分类号： C08L51/04 , C08L71/123 , C08L77/00
摘要： Reinforced thermoplastic molding materials containing, as essential components,(A) from 40 to 94 parts by weight of a polymer component of(a.sub.1) from 10 to 90% by weight of polyphenylene ether and(a.sub.2) from 10 to 90% by weight, based in each case on A, of a styrene polymer toughened with an acrylate rubber or with an unhydrogenated or hydrogenated polymer of a conjugated diene,(B) from 1 to 20 parts by weight of a copolymer of(b.sub.1) from 70 to 99.9% by weight of a monomer from the group consisting of styrene, .alpha.-methylstyrene and styrene alkylated in the nucleus or a mixture of these monomers,(b.sub.2) from 0.1 to 30% by weight of one or more compounds from the group consisting of tert-butyl acrylate and tert-butyl methacrylate, or one or more compounds from the group of compounds of the general formula I ##STR1## where R.sup.1 is hydrogen or methyl and R.sup.2, R.sup.3 and R.sup.4 are each an alkyl or alkoxy group of not more than 4 carbon atoms, or of the general formula II ##STR2## where n is an integer from 1 to 4 and R.sup.5, R.sup.6 and R.sup.7 are each one of the radicals stated for R.sup.2 or are each --O(CH.sub.2 --CH.sub.2 --O).sub.m R.sup.8, where R.sup.8 is C.sub.1 -C.sub.4 -alkyl and m is 1, 2, 3 or 4, and(b.sub.3) from 0 to 10% by weight, based on the copolymer, of a further ethylenically unsaturated monomer which is copolymerizable with b.sub.1 and b.sub.2, and(C) from 5 to 50 parts by weight of a reinforcing agent, the number of parts by weight being based on 100 parts by weight of the sum of A, B and C,are prepared and used for the production of moldings.
摘要翻译：作为必要成分的增强热塑性成型材料含有（A）40〜94重量份聚合物成分（a1），10〜90重量％聚苯醚和（a2）10〜90重量％基于A的每种情况，使用丙烯酸酯橡胶或共轭二烯的未氢化或氢化的聚合物增韧的苯乙烯聚合物，（B）1至20重量份的（b1）70至99.9重量％的共聚物，重量的来自于在核中烷基化的苯乙烯，α-甲基苯乙烯和苯乙烯的单体或这些单体的混合物，（b2）0.1-30％（重量）一种或多种下列化合物：叔 - 丙烯酸丁酯和甲基丙烯酸叔丁酯，或一种或多种通式Ⅰ化合物的化合物，其中R1是氢或甲基，R2，R3和R4分别是烷基或烷氧基不大于 4个碳原子，或通式II其中n是一个整数 1至4的取代基和R 5，R 6和R 7各自为R 2所示的基团之一或分别为-O（CH 2 -CH 2 -O）m R 8，其中R 8为C 1 -C 4 - 烷基且m为1,2,3 或（4）和（b3）0〜10重量％，基于共聚物，可与b1和b2共聚的另外的烯属不饱和单体和（C）5〜50重量份的增强剂，制备基于100重量份的A，B和C之和的重量份数，并用于制造模制品。

7. 发明授权

US4939201A Glass fiber reinforced thermoplastic molding compositions based on polyesters and graft polymers 失效
标题翻译：基于聚酯和接枝聚合物的玻璃纤维增强热塑性模塑组合物
公开(公告)号：US4939201A
公开(公告)日：1990-07-03
申请号：US255028
申请日：1988-10-07
申请人： Erhard Seiler , Karl Ruppmich , Manfred Knoll , Walter Heckmann , Dietrich Lausberg , Rainer Bueschl
发明人： Erhard Seiler , Karl Ruppmich , Manfred Knoll , Walter Heckmann , Dietrich Lausberg , Rainer Bueschl
IPC分类号： C08L67/00 , C08K7/14 , C08L67/02
CPC分类号： C08L67/02
摘要： Thermoplastic molding compositions based on thermoplastic polyesters (a.sub.1), graft polymers incorporating acrylate rubbers as grafting bases (a.sub.2), copolymers of aromatic vinyl monomers and acrylonitrile or methacrylonitrile (a.sub.3) which contain a polymeric component (B) having carboxyl, carboxyl derivative, hydroxyl or epoxy groups or, alternatively, where graft polymers (a.sub.2) or copolymers (a.sub.3) carry such groups have a balanced range of properties.
摘要翻译：基于热塑性聚酯（a1）的热塑性成型组合物，将丙烯酸酯橡胶作为接枝基（a2）的接枝聚合物，含有具有羧基，羧基衍生物，羟基的聚合物组分（B）的芳族乙烯基单体和丙烯腈或甲基丙烯腈（a3）的共聚物或环氧基，或者，接枝聚合物（a2）或共聚物（a3）携带这些基团具有平衡的性质范围。

8. 发明授权

US5475055A Thermoplastic molding material with a matt effect 失效
标题翻译：热塑性成型材料具有无光泽的效果
公开(公告)号：US5475055A
公开(公告)日：1995-12-12
申请号：US327880
申请日：1994-10-24
申请人： Andreas Deckers , Norbert Guentherberg , Rainer Bueschl , Ekkehard Jahns
发明人： Andreas Deckers , Norbert Guentherberg , Rainer Bueschl , Ekkehard Jahns
IPC分类号： C08L9/02 , C08L25/12 , C08L33/12 , C08L51/04 , C08L55/02
CPC分类号： C08L25/12 , C08L51/04 , C08L55/02 , C08L33/12 , C08L9/02
摘要： A thermoplastic molding material containing, based on the sum of its constituents A, B and C,A: 70 to 99% by weight of a thermoplastic resin A comprising, based on A,A1: 50 to 100% by weight of a hard matrix A1 comprising, based on A1,A11: 50 to 95% by weight of units of an aromatic vinyl compound or methyl methacrylate or their mixtures (A11) andA12: 5 to 50% by weight of units of acrylonitrile A12;A2: up to 50% by weight of a rubber-elastic particulate graft copolymer A2 comprising, based on A2,A21: 30 to 80% by weight of at least one elastomeric graft base A21 having a median particle size of from 30 to 1000 nm comprising, based on A21,A211: 50 to 100% by weight of units of a 1,3-diene or a C.sub.4 -C.sub.8 alkyl acrylate forming rubber-elastic polymers (A211),A212: up to 50% by weight of units of at least one vinyl monomer A212;andA22: 15 to 85% by weight of a graft shell A22 comprising, based on A22,A221: 50 to 90% by weight of units of an aromatic vinyl monomer A221 andA222: 10 to 50% by weight of units of acrylonitrile A222;B: 0.5 to 15% by weight of a nitrile rubber B comprising, based on B,B1: 10 to 40% by weight of units of acrylonitrile, andB2: 60 to 90% by weight of units of butadiene;andC: 0.5 to 15% by weight of a particulate polymer C distributed in the hard matrix A and comprising, based on C,C1: 80 to 99% by weight of units of methyl methacrylate,C2: 0.5 to 15% by weight of units of an ester of acrylic acid,C3: 0.5 to 5% by weight of units of a crosslinking monomer copolymerizable with C1 and C2, andC4: up to 10% by weight of units of a polar monomer selected from (meth)acrylic acid, hydroxyethyl (meth)acrylate and dimethylaminoethyl (meth)acrylate,the median particle size of C being from 50 to 50,000 nm.
摘要翻译：一种热塑性成型材料，其基于其成分A，B和C的总和，A：70-99重量％的热塑性树脂A，其包含基于A的Al：50至100重量％的硬质基质 A1包含基于A1，A11：50至95重量％的芳族乙烯基化合物或甲基丙烯酸甲酯或其混合物（A11）和A12：5-50重量％的丙烯腈A12的单元; A2：高达50重量％的橡胶弹性颗粒接枝共聚物A2，其包含基于A2的A21：30至80重量％的至少一种中值粒径为30至1000nm的弹性体接枝基质A21 包括基于A21的A211：50至100重量％的1,3-二烯或丙烯酸C 4 -C 8烷基酯的单元形成橡胶弹性聚合物（A211），A212：至多50重量％的至少一种乙烯基单体A212; 和A22：15至85重量％的接枝壳A22，其包含基于A22的A221：50至90重量％的芳族乙烯基单体A221和A222的单元：10至50重量％的丙烯腈A222的单元 ; B：以B为基准的丁腈橡胶B的0.5〜15重量％B1：10〜40重量％的丙烯腈单元，B2：60〜90重量％的丁二烯单元; 和C：0.5至15重量％的分散在硬质基质A中的颗粒状聚合物C，其基于C包含：C：80至99重量％的甲基丙烯酸甲酯单元，C2：0.5至15重量％丙烯酸酯的单元，C3：0.5至5重量％的可与C1和C2共聚的交联单体的单元和C4：至多10重量％的选自（甲基）丙烯酸的极性单体的单元，（甲基）丙烯酸羟乙酯和（甲基）丙烯酸二甲基氨基乙酯，C的中值粒径为50〜50000nm。

9. 发明授权

US5091477A Thermoplastic molding materials 失效
标题翻译：热塑性材料
公开(公告)号：US5091477A
公开(公告)日：1992-02-25
申请号：US494316
申请日：1990-03-16
申请人： Rainer Bueschl , Peter Klaerner
发明人： Rainer Bueschl , Peter Klaerner
IPC分类号： C08L25/08 , C08L25/02 , C08L33/00 , C08L33/06 , C08L55/02
CPC分类号： C08L25/02 , C08L55/02 , C08L33/06 , Y10S525/905
摘要： Molding materials of high impact polystyrene (HIPS) and one or more further polymers as essential components contain, as a third or further compatibility-imparting component, a polymer or copolymer containing not less than 45% by weight of units of cyclohexyl (meth)acrylate.
摘要翻译：作为必要成分的高抗冲聚苯乙烯（HIPS）和一种或多种其它聚合物的成型材料，含有不少于45重量％的（甲基）丙烯酸环己酯单元的聚合物或共聚物作为第三或其它相容性赋予组分，。

10. 发明授权

US5304591A Blends of styrene-acrylonitrile polymer, styrene-methyl methacrylate-maleic anhydride terpolymer and glass filler 失效
标题翻译：苯乙烯 - 丙烯腈聚合物，苯乙烯 - 甲基丙烯酸甲酯 - 马来酸酐三元共聚物和玻璃填料的共混物
公开(公告)号：US5304591A
公开(公告)日：1994-04-19
申请号：US876166
申请日：1992-04-30
申请人： Bernhard H. Nowakowsky , Rainer Theysohn , Rainer Bueschl , Klaus Muehlbach , Graham E. McKee
发明人： Bernhard H. Nowakowsky , Rainer Theysohn , Rainer Bueschl , Klaus Muehlbach , Graham E. McKee
IPC分类号： C08K3/40 , C08L25/12 , C08L51/04 , C08J5/08 , C08L51/06
CPC分类号： C08K3/40 , C08L25/12 , C08L51/04
摘要： A thermoplastic molding composition composed of, based on the total of A, B, C and D,40-95% by weight of a copolymer A of, based on A,90-95% by weight of styrene and/or its derivatives and 10-50% by weight of acrylonitrile, optionally up to 50% by weight of a graft copolymer B of 20-80% by weight of a monomer mixture of either styrene/acrylonitrile in the ration from 9:1 to 4:6 or styrene/acrylonitrile/methylacrylate in the ration from 19:1:1 to 8:6:6 onto 80-20% by weight of an elastomer based on butadiene or acrylic ester as grafting base, graft copolymerization being effected in either emulsion or solution, 1-50% by weight of a reinforcing glass fiber material C and 0.1-50% by weight of a terpolymer D of styrene, methyl methacrylate and maleic anhydride composed of 1-15% by weight each of styrene and maleic anhydride and a styrene/maleic anhydride ratio of from 5:1 to 1:5, and methyl methacrylate.
摘要翻译：基于A，B，C和D的总和，40-95重量％的基于A的共聚物A，基于90-95重量％的苯乙烯和/或其衍生物的热塑性模塑组合物和 10-50重量％的丙烯腈，任选最多50重量％的接枝共聚物B，其中20-80重量％的苯乙烯/丙烯腈在9:1至4:6的比例中的单体混合物或苯乙烯 /丙烯腈/甲基丙烯酸酯的比例为19:1:1至8:6:6的80-20重量％的基于丁二烯或丙烯酸酯作为接枝基的弹性体，接枝共聚在乳液或溶液中进行，1 -50重量％的增强玻璃纤维材料C和0.1-50重量％的苯乙烯，甲基丙烯酸甲酯和马来酸酐的三元共聚物D，其组成为苯乙烯和马来酸酐的1-15重量％，苯乙烯/马来酸酐酸酐比为5:1至1:5，和甲基丙烯酸甲酯。

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