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    • 4. 发明授权
    • Distillate hydrofining catalyst and a process for the preparation of the
same
    • 馏分加氢精制催化剂及其制备方法
    • US5914290A
    • 1999-06-22
    • US884814
    • 1997-06-30
    • Yahua ShiDadong LiXuefen LiuHong NieXiaodong GaoYibing Ying
    • Yahua ShiDadong LiXuefen LiuHong NieXiaodong GaoYibing Ying
    • B01J23/888B01J27/132C10G45/08B01J23/30B01J23/755B01J27/12
    • C10G45/08B01J23/888B01J27/132
    • The present invention discloses a hydrofining catalyst. The catalyst has the following composition based on the total weight of the entire catalyst composition: 1-5%(wt.) nickel oxide, 12-35% (wt.) tungsten oxide, 1-9% (wt.) fluorine, and the balancing amount of composite alumina. Said composite alumina is composed of one or several kinds of micropore alumina and one or several kinds of macropore alumina, wherein the weight ratio of micropore alumina to macropore alumina is 75:25 to 50:50. The term "micropore alumina" in the context means the alumina in which the volume of the proe of diameter less than 80 angstrom occupies more than 95% of its total pore volume, while the term "macropore alumina" in the contest means the alumina in which the volume of the pore of diameter 60-600 angstrom occupies more than 70% of its total pore volume. The pore distribution mentioned above is determined by BET method of nitrogen adsorption at low temperature. This catalyst is especially suitable for the hydrofining of inferior distillates with high sulfur content and boiling range of 80-550.degree. C.
    • 本发明公开了一种加氢精制催化剂。 催化剂具有以下催化剂组合物总重量的组成:1-5%(重量)氧化镍,12-35%(重量)氧化钨,1-9%(重量)氟,和 复合氧化铝的平衡量。 所述复合氧化铝由一种或几种微孔氧化铝和一种或几种大孔氧化铝组成,其中微孔氧化铝与大孔氧化铝的重量比为75:25至50:50。 在本文中,术语“微孔氧化铝”是指直径小于80埃的原型体积占其总孔体积的95%以上的氧化铝,而比较中的术语“大孔氧化铝”是指氧化铝 其直径为60-600埃的孔的体积占其总孔体积的70%以上。 上述孔分布由低温氮吸附的BET法测定。 该催化剂特别适用于高硫含量和沸程为80-550℃的劣质馏分的加氢精制。
    • 5. 发明授权
    • Combined process for hydrotreating and catalytic cracking of residue
    • 渣油加氢处理和催化裂化的综合工艺
    • US08529753B2
    • 2013-09-10
    • US12521346
    • 2007-12-27
    • Chuanfeng NiuLishun DaiYongcan GaoDadong LiYahua ShiHong NieQinghe Yang
    • Chuanfeng NiuLishun DaiYongcan GaoDadong LiYahua ShiHong NieQinghe Yang
    • C10G69/04
    • C10G69/04
    • Disclosed is a combined process for hydrotreating and catalytic cracking of residue, wherein the residue, catalytic cracking heavy cycle oil with acidic solid impurity being removed, optional distillate oil and adistillate of catalytic cracking slurry oil from which the acidic solid impurity is removed are fed into residue hydrotreating unit, the hydrogenated residue obtained and optional vacuum gas oil are fed into catalytic cracking unit to obtain various products; the catalytic cracking heavy cycle oil from which the acidic solid impurity is removed is circulated to the residue hydrotreating unit; the catalytic cracking slurry oil is separated by distilling, the distillate of the catalytic cracking slurry oil after removing off the acidic solid impurity is circulated to the residue hydrotreating unit. This process makes the residue hydrotreating and catalytic cracking being combined together more effectively such that it is not only able to improve product quality of the residue hydrotreating, elongate operation cycle of the residue hydrotreating unit, but also increases the yield of the hydrogenated diesel oil and catalytic cracking light oil, and decreases coking quantity of the catalytic cracking.
    • 公开了一种用于残余物加氢处理和催化裂化的组合方法,其中除去残留物,除去酸性固体杂质的催化裂解重质循环油,任选的馏出油和除去酸性固体杂质的催化裂化浆料油馏出物 进入残渣加氢处理装置,将得到的氢化残渣和任选的减压瓦斯油加入催化裂化装置中得到各种产物; 去除酸性固体杂质的催化裂解重质循环油循环至残渣加氢处理装置; 通过蒸馏分离催化裂化浆料油,除去酸性固体杂质后的催化裂化浆料油的馏出物循环至残渣加氢处理装置。 该方法使残渣加氢处理和催化裂化更有效地结合在一起,使得不仅能够提高残余物加氢处理装置的残余物加氢处理,延长操作循环的产品质量,而且还提高氢化柴油的产率, 催化裂解轻油,降低催化裂化的焦化量。
    • 6. 发明申请
    • COMBINED PROCESS FOR HYDROTREATING AND CATALYTIC CRACKING OF RESIDUE
    • 用于加氢和催化裂化的残留物的组合方法
    • US20100314287A1
    • 2010-12-16
    • US12521346
    • 2007-12-27
    • Chuanfeng NiuLishun DaiYongcan GaoDadong LiYahua ShiHong NieQinghe Yang
    • Chuanfeng NiuLishun DaiYongcan GaoDadong LiYahua ShiHong NieQinghe Yang
    • C10G69/04
    • C10G69/04
    • Disclosed is a combined process for hydrotreating and catalytic cracking of residue, wherein the residue, catalytic cracking heavy cycle oil with acidic solid impurity being removed, optional distillate oil and adistillate of catalytic cracking slurry oil from which the acidic solid impurity is removed are fed into residue hydrotreating unit, the hydrogenated residue obtained and optional vacuum gas oil are fed into catalytic cracking unit to obtain various products; the catalytic cracking heavy cycle oil from which the acidic solid impurity is removed is circulated to the residue hydrotreating unit; the catalytic cracking slurry oil is separated by distilling, the distillate of the catalytic cracking slurry oil after removing off the acidic solid impurity is circulated to the residue hydrotreating unit. This process makes the residue hydrotreating and catalytic cracking being combined together more effectively such that it is not only able to improve product quality of the residue hydrotreating, elongate operation cycle of the residue hydrotreating unit, but also increases the yield of the hydrogenated diesel oil and catalytic cracking light oil, and decreases coking quantity of the catalytic cracking.
    • 公开了一种用于残余物加氢处理和催化裂化的组合方法,其中除去残留物,除去酸性固体杂质的催化裂解重质循环油,任选的馏出油和除去酸性固体杂质的催化裂化浆料油馏出物 进入残渣加氢处理装置,将得到的氢化残渣和任选的减压瓦斯油加入催化裂化装置中得到各种产物; 去除酸性固体杂质的催化裂解重质循环油循环至残渣加氢处理装置; 通过蒸馏分离催化裂化浆料油,除去酸性固体杂质后的催化裂化浆料油的馏出物循环至残渣加氢处理装置。 该方法使残渣加氢处理和催化裂化更有效地结合在一起,使得不仅能够提高残余物加氢处理装置的残余物加氢处理,延长操作循环的产物质量,而且还可以提高氢化柴油的产率, 催化裂解轻油,降低催化裂化的焦化量。