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    • 6. 发明授权
    • Process for preparing aluminophosphate compounds and substituted
derivatives of the structural type VFI
    • 制备结构型VFI的氨基磷酸酯化合物和取代衍生物的方法
    • US5241093A
    • 1993-08-31
    • US822852
    • 1992-01-21
    • Jean-Francois JolyHerve CauffriezJean-Louis Guth
    • Jean-Francois JolyHerve CauffriezJean-Louis Guth
    • B01J29/83C01B37/04C01B37/08
    • B01J29/83C01B37/04C01B37/08
    • A process for preparing aluminophosphate compounds (and substituted derivatives) of the structural type VFI. This preparation process is characterized in that the speed of increase in temperature of the reaction mixture is greater than 250.degree. C./hour, the total time of heating of the reaction mixture, including the rise in temperature and the plateau heating, being less than one hour. The temperature of the plateau heating is between 100.degree. and 200.degree. C.The synthetic compounds in accordance with the invention possess(a) a general formula approximating to the following:1 Al.sub.2 O.sub.3 0.75-1.25 P.sub.2 O.sub.5 0-0.5 XO.sub.n/2 0-0.05 R y H.sub.2 OwhereX represents a heteroatom chosen from the group consisting of silicon, cobalt, magnesium and zinc;n is the degree of oxidation of the heteroatom X;y, the number of water molecules contained in the said compound, is greater than 0.001; andR is an organic compound chosen from the group consisting of secondary amines, tertiary amines, and quaternary ammonium salts and hydroxides;(b) an X-ray diffraction diagram as represented in Table I of the description.
    • 制备结构型VFI的磷酸铝化合物(和取代的衍生物)的方法。 该制备方法的特征在于,反应混合物的温度升高速度大于250℃/小时,反应混合物的总加热时间(包括温度升高和平台加热)小于 一小时。 平台加热的温度为100至200℃。根据本发明的合成化合物具有(a)接近于以下的通式:1 Al 2 O 3 0.75-1.25 P 2 O 5 0-0.5 XOn / 2 0-0.05 其中X表示选自硅,钴,镁和锌的杂原子; n是杂原子X的氧化度; y,所述化合物中含有的水分子数目大于0.001; 并且R是选自仲胺,叔胺和季铵盐和氢氧化物的有机化合物; (b)如说明书的表I所示的X射线衍射图。