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    • 2. 发明授权
    • Composition with a polymer and an oxidation-catalyst
    • 用聚合物和氧化催化剂组成
    • US08404148B2
    • 2013-03-26
    • US12373113
    • 2007-07-04
    • Pieter GijsmanJohan Franz Gradus Antonius JansenDirk Armand Wim Stanssens
    • Pieter GijsmanJohan Franz Gradus Antonius JansenDirk Armand Wim Stanssens
    • C07C27/22
    • C08K5/1575
    • The present invention relates to a polymer composition with an increased rate of oxygen-uptake by the presence of an oxidation catalyst. The invention further relates to a process to increase the rate of oxygen-uptake by a polymer composition. The invention also relates to a process to increase the oxo-biodegradability of a polymer composition and to the use of such a composition for the preparation of a product having a controlled lifetime. The invention further relates to a process to increase the rate of oxygen-scavenging in a composition containing a carbon-containing polymer, the composition obtained by this method and its use in the preparation of an oxygen-scavenging product. The present invention further relates to objects containing an oxygen scavenging layer containing such a composition.
    • 本发明涉及一种通过存在氧化催化剂而吸收氧吸收速率的聚合物组合物。 本发明还涉及增加聚合物组合物的吸氧速率的方法。 本发明还涉及增加聚合物组合物的氧代 - 生物降解性的方法,以及这种组合物用于制备具有受控寿命的产品的用途。 本发明还涉及提高含有含碳聚合物的组合物中氧气清除率的方法,该方法通过该方法得到的组合物及其在除氧产物的制备中的用途。 本发明还涉及包含含有这种组合物的除氧层的物体。
    • 5. 发明申请
    • COMPOSITION WITH A POLYMER AND AN OXIDATION-CATALYST
    • 与聚合物和氧化催化剂的组合物
    • US20100130695A1
    • 2010-05-27
    • US12373109
    • 2007-07-04
    • Pieter GijsmanJohan Franz Gradus Antonius Jansen
    • Pieter GijsmanJohan Franz Gradus Antonius Jansen
    • C08L23/12C08L67/02
    • C08K5/1575
    • The present invention relates to a polymer composition with an increased rate of oxygen-uptake by the presence of an oxidation catalyst. The invention further relates to a process to increase the rate of oxygen-uptake by a polymer composition. The invention also relates to a process to increase the oxo-biodegradability of a polymer composition and to the use of such a composition for the preparation of a product having a controlled lifetime. The invention further relates to a process to increase the rate of oxygen-scavenging in a composition containing a carbon-containing polymer, the composition obtained by this method and its use in the preparation of an oxygen-scavenging product. The present invention further relates to objects containing an oxygen scavenging layer containing such a composition.
    • 本发明涉及一种通过存在氧化催化剂而吸收氧吸收速率的聚合物组合物。 本发明还涉及增加聚合物组合物的吸氧速率的方法。 本发明还涉及增加聚合物组合物的氧代 - 生物降解性的方法,以及这种组合物用于制备具有受控寿命的产品的用途。 本发明还涉及增加含有含碳聚合物的组合物中的氧清除速率的方法,该方法通过该方法获得的组合物及其在制备氧气清除产物中的用途。 本发明还涉及包含含有这种组合物的除氧层的物体。
    • 10. 发明申请
    • PROCESS FOR PRODUCING HIGH MOLECULAR WEIGHT POLYETHYLENE
    • 生产高分子量聚乙烯的方法
    • US20100331995A1
    • 2010-12-30
    • US12741431
    • 2008-11-06
    • Harold Jan SmeltPieter GijsmanMartin van Duin
    • Harold Jan SmeltPieter GijsmanMartin van Duin
    • A61F2/30A61F2/02C08L23/06A61L2/08C08K5/3435C08K5/3462
    • C08J3/24A61L27/16A61L27/505C08F8/00C08J3/28C08J2323/06C08J2323/36C08K5/3435C08K5/3492C08K5/34926C08L23/06C08L2201/08C08L2203/02C08L2207/068C08L2666/02C08F110/02
    • The invention relates to a process for producing an (ultra) high molecular weight polyethylene (HMWPE) article comprising:—incorporating into the HMWPE resin a Hindered Amine Light Stabilizer (HALS) and—cross-link the (U)HMWPE during or after molding the (U)HMWPE resin. In particular the invention relates to a process comprising the following steps: a) incorporating into (U)HMWPE resin a Hindered Amine Light Stabilizer (HALS) according to one of the following general formulas or combinations hereof: wherein R1 up to and including R5 are herein independent substituents; for example containing hydrogen, ether, ester, amine, amide, alkyl, alkenyl, alkynyl, aralkyl, cycloalkyl and/or aryl groups, which substituents may in turn contain functional groups, for example alcohols, ketones, anhydrides, imines, siloxanes, ethers, carboxyl groups, aldehydes, esters, amides, imides, amines, nitriles, ethers, urethanes and any combination thereof; b) molding the (U)HMWPE resin comprising the HALS, resulting in an article; c) cross-linking and sterilizing the article via gamma radiation or electron beam radiation; d) optionally, if step b results in a stock shape, machining the stock shape into an article; wherein step c and step d can be performed in either order.
    • 本发明涉及一种用于生产(超)高分子量聚乙烯(HMWPE)制品的方法,其包括: - 在成型期间或之后 - 将HMWPE树脂中的受阻胺光稳定剂(HALS)和 - 交联(U)HMWPE (U)HMWPE树脂。 具体而言,本发明涉及一种包括以下步骤的方法:a)根据以下通式或其组合之一将(U)HMWPE树脂掺入到受阻胺光稳定剂(HALS)中:其中R 1直至并包括R 5为 本文独立取代基; 例如含有氢,醚,酯,胺,酰胺,烷基,烯基,炔基,芳烷基,环烷基和/或芳基,该取代基又可包含官能团,例如醇,酮,酸酐,亚胺,硅氧烷,醚 羧基,醛,酯,酰胺,酰亚胺,胺,腈,醚,氨基甲酸酯及其任何组合; b)模制包含HALS的(U)HMWPE树脂,得到制品; c)通过伽马辐射或电子束辐射对制品进行交联和灭菌; d)任选地,如果步骤b导致坯料形状,将坯料加工成制品; 其中步骤c和步骤d可以以任何顺序执行。