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1. 发明申请

US20130237640A1 Process for preparing a vinylidene chloride polymer latex 审中-公开
标题翻译：制备偏二氯乙烯聚合物胶乳的方法
公开(公告)号：US20130237640A1
公开(公告)日：2013-09-12
申请号：US13988319
申请日：2011-11-10
申请人： Pierre-Emmanuel Dufils , Patrick Lacroix-Desmazes , Jerome Garnier , Yves Vanderveken , Jerome Vinas
发明人： Pierre-Emmanuel Dufils , Patrick Lacroix-Desmazes , Jerome Garnier , Yves Vanderveken , Jerome Vinas
IPC分类号： C08L37/00 , C09D137/00
CPC分类号： C08L37/00 , B29K2027/08 , C08F214/22 , C09D137/00
摘要： A process for preparing a seed latex of an epoxy-containing polymer by radical polymerization in aqueous emulsion of at least one epoxy-containing monomer and optionally at least one comonomer is disclosed.Also disclosed are a process for preparing a vinylidene chloride polymer latex either by radical polymerization in aqueous emulsion of vinylidene chloride and optionally at least one comonomer in the presence of the epoxy-containing polymer seed latex obtained by the process according to the invention; or by mixing the epoxy-containing polymer seed latex with a vinylidene chloride polymer latex obtained separately by radical polymerization in aqueous emulsion.
摘要翻译：公开了一种通过在至少一种含环氧基的单体和任选的至少一种共聚单体的水乳液中自由基聚合来制备含环氧基聚合物的种子胶乳的方法。还公开了通过在通过本发明的方法获得的含环氧基的聚合物种子胶乳存在下，通过在偏二氯乙烯的水性乳液和任选的至少一种共聚单体中的自由基聚合来制备偏二氯乙烯聚合物胶乳的方法; 或通过将含环氧基的聚合物种子胶乳与通过自由基聚合在水乳液中分别获得的偏二氯乙烯聚合物胶乳混合。

2. 发明申请

US20090292071A1 Free-radical polymerization process in aqueous dispersion for the preparation of a block copolymer at least one block of which is a block of a halogenated polymer 有权
标题翻译：用于制备嵌段共聚物的水分散体中的自由基聚合方法，其中至少一个嵌段是卤代聚合物的嵌段
公开(公告)号：US20090292071A1
公开(公告)日：2009-11-26
申请号：US12305255
申请日：2007-07-04
申请人： Christophe Fringant , Yves Vanderveken , Patrick Lacroix-Desmazes , Jeff Tonnar
发明人： Christophe Fringant , Yves Vanderveken , Patrick Lacroix-Desmazes , Jeff Tonnar
IPC分类号： C08F2/16
CPC分类号： C08F2/18 , C08F2/22 , C08F2/38 , C08F4/04 , C08F4/40 , C08F214/06 , C08F220/14 , C08F293/00 , C08F293/005 , C08F2220/1825
摘要： Process of controlled free-radical polymerization in aqueous dispersion for the preparation of a block copolymer at least one block of which is a block of a halogenated polymer using molecular iodine and at least one oxidant whose solubility in water is at least 10 g/l for the synthesis of the first block of the block copolymer.
摘要翻译：在水性分散体中控制自由基聚合的方法，用于制备嵌段共聚物，其至少一个嵌段是使用分子碘的卤代聚合物的嵌段和至少一种氧化剂，其在水中的溶解度为至少10g / l，对于合成嵌段共聚物的第一嵌段。

3. 发明授权

US08541524B2 Free-radical polymerization process in aqueous dispersion for the preparation of a block copolymer at least one block of which is a block of a halogenated polymer 有权
公开(公告)号：US08541524B2
公开(公告)日：2013-09-24
申请号：US12305255
申请日：2007-07-04
申请人： Christophe Fringant , Yves Vanderveken , Patrick Lacroix-Desmazes , Jeff Tonnar
发明人： Christophe Fringant , Yves Vanderveken , Patrick Lacroix-Desmazes , Jeff Tonnar
IPC分类号： C08F2/16
CPC分类号： C08F2/18 , C08F2/22 , C08F2/38 , C08F4/04 , C08F4/40 , C08F214/06 , C08F220/14 , C08F293/00 , C08F293/005 , C08F2220/1825
摘要： Process of controlled free-radical polymerization in aqueous dispersion for the preparation of a block copolymer at least one block of which is a block of a halogenated polymer using molecular iodine and at least one oxidant whose solubility in water is at least 10 g/l for the synthesis of the first block of the block copolymer.

4. 发明申请

US20060258798A1 Methods for the dispersion of water-soluble of hydrophilic substances in a supercritically pressurized fluid 审中-公开
标题翻译：在超临界加压流体中分散亲水物质的水溶性的方法
公开(公告)号：US20060258798A1
公开(公告)日：2006-11-16
申请号：US10554281
申请日：2004-04-23
申请人： Joel Richard , Frantz Deschamps , Patrick Lacroix-Desmazes , Bernard Boutevin
发明人： Joel Richard , Frantz Deschamps , Patrick Lacroix-Desmazes , Bernard Boutevin
IPC分类号： C08L27/12
CPC分类号： C08L53/00 , A61K9/2018 , A61K9/2054 , A61K9/2866 , A61K9/2886 , C08F293/005 , C08L53/005 , Y02P20/544 , C08L2666/02
摘要： A method for the dispersion of water-soluble or hydrophilic substances in a supercritically pressurized fluid by adding a surfactant said surfactant being a block copolymer comprising at least one CO2-philic block and at least one nonionic hydrophilic block.
摘要翻译：一种通过添加表面活性剂将水溶性或亲水性物质分散在超临界加压流体中的方法，所述表面活性剂是包含至少一个CO 2 - 2嵌段和至少一个非离子亲水嵌段的嵌段共聚物。

5. 发明授权

US08324322B2 Polymer composition 有权
标题翻译：聚合物组成
公开(公告)号：US08324322B2
公开(公告)日：2012-12-04
申请号：US10572944
申请日：2004-09-22
申请人： Christophe Fringant , Vincent Bodart , Berengere Rixens , Romain Severac , Yves Hervaud , Patrick Lacroix-Desmazes , Bernard Boutevin
发明人： Christophe Fringant , Vincent Bodart , Berengere Rixens , Romain Severac , Yves Hervaud , Patrick Lacroix-Desmazes , Bernard Boutevin
IPC分类号： C08L27/08 , C08L33/08 , C08L27/12 , B05D7/02 , B05D7/16 , B05D7/10 , C08F230/02 , C08F214/08
CPC分类号： C09D127/08 , C08L27/08 , C08L43/02 , C08L51/003 , C08L2666/04 , C08L2666/24
摘要： Polymer composition comprising: 1) a polymer (P1) comprising at least 50% by weight of monomeric units derived from an ethylenically unsaturated monomer (M1), and 2) at least one co-oligomer (O1) comprising at least: a) a component (A) comprising at least one monomeric unit identical to that derived from the monomer (M1) on which the polymer (P1) is based, and b) a component (B) comprising at least one monomeric unit (m2), derived from an ethylenically unsaturated monomer, carrying at least one group chosen from the following groups: —CaH2a+1 with a between 6 and 30; —(CH2)b—CcF2c+1 with b between 1 and 11 and c greater than or equal to 5; —(CH2)d—(Si(CH3)2—O)e—Si(CH3)3 with d between 1 and 11 and e between 1 and 1000; —COOH; —SO3H, and the phosphonate groups —PO(OH)(OR1) with R1 being a hydrogen atom or an alkyl radical containing from 1 to 11 carbon atoms.
摘要翻译：聚合物组合物，包括：1）包含至少50重量％衍生自烯键式不饱和单体（M1）的单体单元的聚合物（P1），和2）至少包含至少一个共低聚物（O1）：a）组分（A），其包含至少一种与聚合物（P1）所基于的单体（M1）相同的单体单元，和b）包含至少一种单体单元（m2）的组分（A），衍生自带有至少一个选自以下基团的烯属不饱和单体：-CaH2a + 1，其中6至30; - （CH2）b-CcF2c + 1，其中b在1和11之间，c大于或等于5; - （CH 2）d - （Si（CH 3）2 -O）e-Si（CH 3）3，d为1至11，e为1至1000; -COOH; -SO 3 H和膦酸酯基-PO（OH）（OR 1），其中R 1为氢原子或含有1至11个碳原子的烷基。

6. 发明申请

US20090191135A1 METHODS FOR THE DISPERSION OF WATER-SOLUABLE OR HYDROPHILIC SUBSTANCES IN A SUPERCRITICALLY PRESSURIZED FLUID 审中-公开
标题翻译：在超临界加压流体中分散水溶性或水解物质的方法
公开(公告)号：US20090191135A1
公开(公告)日：2009-07-30
申请号：US12355696
申请日：2009-01-16
申请人： Joel RICHARD , Frantz Deschamps , Patrick Lacroix-Desmazes , Bernard Boutevin
发明人： Joel RICHARD , Frantz Deschamps , Patrick Lacroix-Desmazes , Bernard Boutevin
IPC分类号： A61K9/12
CPC分类号： C08L53/00 , A61K9/2018 , A61K9/2054 , A61K9/2866 , A61K9/2886 , C08F293/005 , C08L53/005 , Y02P20/544 , C08L2666/02
摘要： A method for encapsulating an active principle by dispersing the active principle in a supercritical fluid by adding a surfactant to the fluid. The surfactant is a block copolymer having at least one CO2-philic block and at least one nonionic hydrophilic block.
摘要翻译：一种通过向流体中加入表面活性剂将活性成分分散在超临界流体中来包封活性成分的方法。表面活性剂是具有至少一个CO 2亲和嵌段和至少一个非离子亲水嵌段的嵌段共聚物。

7. 发明申请

US20070218207A1 Polymer Composition 有权
标题翻译：聚合物组成
公开(公告)号：US20070218207A1
公开(公告)日：2007-09-20
申请号：US10572944
申请日：2004-09-22
申请人： Christophe Fringant , Vincent Bodart , Berengere Rixens , Romain Severac , Yves Hervaud , Patrick Lacroix-Desmazes , Bernard Boutevin
发明人： Christophe Fringant , Vincent Bodart , Berengere Rixens , Romain Severac , Yves Hervaud , Patrick Lacroix-Desmazes , Bernard Boutevin
IPC分类号： C08L27/08 , C09D127/08
CPC分类号： C09D127/08 , C08L27/08 , C08L43/02 , C08L51/003 , C08L2666/04 , C08L2666/24
摘要： Polymer composition comprising: 1) a polymer (P1) comprising at least 50% by weight of monomeric units derived from an ethylenically unsaturated monomer (M1), and 2) at least one co-oligomer (01) comprising at least: a) a component (A) comprising at least one monomeric unit identical to that derived from the monomer (Ml) on which the polymer (P1) is based, and b) a component (B) comprising at least one monomeric unit (m2), derived from an ethylenically unsaturated monomer, carrying at least one group chosen from the following groups: —CaH2a+1 with a between 6 and 30; —(CH2)b—CeF26+1 with b between 1 and 11 and c greater than or equal to 5; —(CH2)d—(Si(CH3)2—O)e—Si(CH3)3 with d between 1 and 11 and e between 1 and 1000; —COOH; —SO3H, and the phosphonate groups —PO(OH)(OR1) with RI being a hydrogen atom or an alkyl radical containing from 1 to 11 carbon atoms.
摘要翻译：聚合物组合物包括：1）包含至少50重量％的衍生自烯属不饱和单体（M1）的单体单元的聚合物（P1），和2）至少包含至少一个共低聚物（01）：a）组分（A）包含至少一种与聚合物（P1）所基于的单体（M1）相同的单体单元，和b）包含至少一种单体单元（m2）的组分（B），衍生自带有至少一个选自以下基团的烯键式不饱和单体：具有介于6和30之间的-C≡AH 2a + - （CH 2 - ） - - - - - - - - - - - - - （2）其中b在1和11之间，c更大超过或等于5; - （CH 2）2 - （Si（CH 3）2-O） - （CH 2）2 - 其中d在1和11之间，e在1和1000之间; -COOH; -SO 3 H，以及R 1为氢原子或含有1至11个碳原子的烷基的膦酸酯基-PO（OH）（OR 1）。

8. 发明申请

US20090306302A1 Process of free-radical polymerization in aqueous disperasion for the preparation of polymers 审中-公开
标题翻译：用于制备聚合物的水分散中的自由基聚合方法
公开(公告)号：US20090306302A1
公开(公告)日：2009-12-10
申请号：US12308977
申请日：2007-07-04
申请人： Patrick Lacroix-Desmazes , Jeff Tonnar
发明人： Patrick Lacroix-Desmazes , Jeff Tonnar
IPC分类号： C08F271/02 , C08F4/04 , C08F4/34 , C08F265/02 , C08F279/02 , C08F265/04 , C08F261/06 , C08F273/00 , C08F275/00
CPC分类号： C08F2/18 , C08F2/22 , C08F2/38 , C08F4/04 , C08F4/40 , C08F214/06 , C08F220/14 , C08F293/00 , C08F293/005 , C08F2220/1825
摘要： Process of free-radical polymerization in aqueous dispersion for the preparation of polymers, employing (A) at least one ethylenically unsaturated monomer, one of which is employed as the principal monomer and is selected from styrene and its derivatives, acrylic acid and its derivatives, methacrylic acid and its derivatives, dienes, vinyl esters, vinyl ethers, vinylic pyridine derivatives, vinylsulphonic acid and its derivatives, vinylphosphonic acid and its derivatives, and N-vinyl monomers, (B) at least one free-radical initiator selected from diazo compounds, peroxides and dialkyldiphenylalkanes, (C) molecular iodine, and (D) at least one oxidizing agent whose solubility in water is at least 10 g/l, of which at least one may be the one (B); said process comprising the steps whereby (1) at least one fraction of each of compounds (A), (B), (C) and (D) is introduced into a reactor, and (2) the contents of the reactor are reacted while introducing into the reactor the remainder, where appropriate, of each of compounds (A), (B), (C) and (D). Process of free-radical polymerization in aqueous dispersion for the preparation of block copolymers starting from polymers prepared by the abovementioned process.
摘要翻译：使用（A）至少一种烯键式不饱和单体，其中一种作为主要单体使用并选自苯乙烯及其衍生物，丙烯酸及其衍生物的方法，用于制备聚合物的水性分散体中的自由基聚合方法，甲基丙烯酸及其衍生物，二烯，乙烯基酯，乙烯基醚，乙烯基吡啶衍生物，乙烯基磺酸及其衍生物，乙烯基膦酸及其衍生物和N-乙烯基单体，（B）至少一种选自重氮化合物的自由基引发剂，过氧化物和二烷基二苯基烷烃，（C）分子碘，和（D）至少一种在水中的溶解度至少为10g / l的氧化剂，其中至少一种可以是（B）。所述方法包括以下步骤：（1）将化合物（A），（B），（C）和（D）中的每一种的至少一部分引入反应器中，和（2）使反应器的内容物反应，同时在合适的情况下，将化合物（A），（B），（C）和（D）中的每一种引入反应器中。在通过上述方法制备的聚合物开始制备嵌段共聚物的水分散体中的自由基聚合方法。

9. 发明申请

US20090056742A1 Process for Decontaminating an Organic Solid Substrate Contaminated by Solid Radioactive Particulate Inorganic Contaminants, Using Dense Pressurized CO2 有权
标题翻译：用固体放射性微粒无机污染物污染有机固体基质去除污染的方法，使用密集加压的CO2
公开(公告)号：US20090056742A1
公开(公告)日：2009-03-05
申请号：US12280205
申请日：2007-02-23
申请人： Bruno Fournel , Julien Galy , Frederic Barth , Patrick Lacroix-Desmazes , Serge Lagerge , Sophie Dussolliet , Jerome Blancher
发明人： Bruno Fournel , Julien Galy , Frederic Barth , Patrick Lacroix-Desmazes , Serge Lagerge , Sophie Dussolliet , Jerome Blancher
IPC分类号： B08B3/12 , B08B7/00 , B08B3/10
CPC分类号： B01D11/0203 , B08B3/02 , B08B3/045 , B08B3/102 , B08B3/104 , B08B3/12 , B08B7/0021 , B08B2203/0288 , G21F9/125
摘要： Process for decontaminating, cleaning a solid organic substrate contaminated by solid radioactive particulate inorganic contaminants, in which: the said solid substrate is brought into contact with an extraction medium, devoid of water, comprising: dense pressurized CO2; at least one nonhalogenated surface-active compound chosen from block copolymers of poly(ethylene oxide) PEO and poly(propylene oxide) PPO, such as (EO)x-(PO)y diblock copolymers, (EO)x-(PO)y-(EO)x triblock copolymers and (PO)x-(EO)y-(PO), triblock copolymers, where x and y are integers from 2 to 80 with x other than y; and polydi(1 to 6C)alkylsiloxanes, such as polydimethylsiloxane (PDMS); and at least one complexing agent chosen from tributyl phosphate (TBP), crown ethers, tributylphosphine oxide, triphenylphosphine oxide and tri(n-octyl)phosphine oxide; the solid substrate and/or the extraction medium is/are subjected, simultaneously with the contacting operation, to a mechanical action.
摘要翻译：用于净化，清洁被固体放射性颗粒无机污染物污染的固体有机基质的方法，其中：使所述固体基质与无水的萃取介质接触，所述提取介质包含：加压的CO 2; 至少一种选自聚（环氧乙烷）PEO和聚（环氧丙烷）PPO的嵌段共聚物的非卤代表面活性化合物，例如（EO）x-（PO）y二嵌段共聚物，（EO）x-（PO）y - （EO）x三嵌段共聚物和（PO）x-（EO）y-（PO），三嵌段共聚物，其中x和y是2至80的整数，x不是y; 和聚二（1至6C）烷基硅氧烷，如聚二甲基硅氧烷（PDMS）; 和至少一种选自磷酸三丁酯（TBP），冠醚，三丁基氧化膦，三苯基氧化膦和三（正辛基）氧化膦的络合剂; 固体基质和/或提取介质在接触操作的同时受到机械作用。

10. 发明授权

US07208558B2 Radical polymerization processes for preparing halogenated polymers, and halogenated polymers 有权
公开(公告)号：US07208558B2
公开(公告)日：2007-04-24
申请号：US11431836
申请日：2006-05-11
申请人： Patrick Lacroix-Desmazes , Romain Severac , Bernard Boutevin , Vincent Bodart , Vincent Kurowski
发明人： Patrick Lacroix-Desmazes , Romain Severac , Bernard Boutevin , Vincent Bodart , Vincent Kurowski
IPC分类号： C08F14/08 , C08F293/00
CPC分类号： C08F293/005 , C08F8/22 , C08F14/00 , C08F214/18 , C08F214/186 , C08F293/00 , C08L53/00 , C08L2666/02 , C08L2666/24
摘要： Radical polymerization process for the preparation of halogenated polymers employing one or more ethylenically unsaturated monomers, at least one of which is chosen from halogenated monomers, molecular iodine and one or more radical-generating agents chosen from diazo compounds, peroxides and dialkyl diphenylalkanes Radical polymerization process for the preparation, starting from the halogenated polymers prepared by the process as described above, of block copolymers, at least one block of which is a halogenated polymer block. Halogenated polymers which have a number-average molecular mass Mn of greater than 1.0×104 and an Mz/Mw ratio of less than 1.65. Block copolymers, at least one block of which is a block of halogenated polymer identical to the halogenated polymers described above. Block copolymers comprising at least one halogenated polymer block which have a number-average molecular mass Mn of greater than 1.5×104 and a polydispersity index Mw/Mn of less than 1.60.

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