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    • 8. 发明授权
    • Impact-reinforced acrylic material
    • 冲击强化丙烯酸材料
    • US09546268B2
    • 2017-01-17
    • US14009346
    • 2012-04-05
    • Jean-Marc BoutillierJean-Pierre Disson
    • Jean-Marc BoutillierJean-Pierre Disson
    • C08L53/00C08F220/14C08F220/18
    • C08L53/00C08F220/14C08F2220/1825C08L2205/22Y10T428/2495Y10T428/31855Y10T428/31928C08L33/12
    • The subject of the present invention is a semi-rigid or flexible and low-gloss impact-reinforced acrylic material. The acrylic material according to the invention comprises a nanostructured matrix constituted of at least one thermoplastic acrylic block copolymer and at least one highly crosslinked acrylic copolymer. The matrix comprises at least one thermoplastic acrylic block copolymer. The highly crosslinked acrylic copolymer comprises, as sole monomer or as predominate monomer, MMA, that is to say that it comprises, by weight, more than 50%, advantageously more than 65% of MMA. The acrylic material according to the invention comprises from 60% to 99% by weight of matrix for 40% to 1% by weight of crosslinked copolymer. These materials may be converted by injection molding, extrusion, co-extrusion, extrusion-blow molding for producing parts, profiles, sheets or films for example.
    • 本发明的主题是半刚性或柔性和低光泽的冲击强化丙烯酸材料。 根据本发明的丙烯酸材料包含由至少一种热塑性丙烯酸嵌段共聚物和至少一种高度交联的丙烯酸共聚物构成的纳米结构基质。 该基质包含至少一种热塑性丙烯酸嵌段共聚物。 高度交联的丙烯酸共聚物包含作为唯一单体或作为主要单体的MMA,也就是说,其含有按重量计超过50%,有利地大于65%的MMA。 根据本发明的丙烯酸材料包含60重量%至99重量%的基质,40重量%至1重量%的交联共聚物。 这些材料可以通过例如注射成型,挤出,共挤出,挤出吹塑来生产部件,型材,片材或薄膜来转化。
    • 9. 发明申请
    • NOVEL IMPACT-REINFORCED ACRYLIC MATERIAL
    • 新型冲击强化丙烯酸酯材料
    • US20140030538A1
    • 2014-01-30
    • US14009346
    • 2012-04-05
    • Jean-Marc BoutillierJean-Pierre Disson
    • Jean-Marc BoutillierJean-Pierre Disson
    • C08L53/00
    • C08L53/00C08F220/14C08F2220/1825C08L2205/22Y10T428/2495Y10T428/31855Y10T428/31928C08L33/12
    • The subject of the present invention is a semi-rigid or flexible and low-gloss impact-reinforced acrylic material. The acrylic material according to the invention comprises a nanostructured matrix constituted of at least one thermoplastic acrylic block copolymer and at least one highly crosslinked acrylic copolymer. The matrix comprises at least one thermoplastic acrylic block copolymer. The highly crosslinked acrylic copolymer comprises, as sole monomer or as predominate monomer, MMA, that is to say that it comprises, by weight, more than 50%, advantageously more than 65% of MMA. The acrylic material according to the invention comprises from 60% to 99% by weight of matrix for 40% to 1% by weight of crosslinked copolymer. These materials may be converted by injection molding, extrusion, co-extrusion, extrusion-blow molding for producing parts, profiles, sheets or films for example.
    • 本发明的主题是半刚性或柔性和低光泽的冲击强化丙烯酸材料。 根据本发明的丙烯酸材料包含由至少一种热塑性丙烯酸嵌段共聚物和至少一种高度交联的丙烯酸共聚物构成的纳米结构基质。 该基质包含至少一种热塑性丙烯酸嵌段共聚物。 高度交联的丙烯酸共聚物包含作为唯一单体或作为主要单体的MMA,也就是说,其含有按重量计超过50%,有利地大于65%的MMA。 根据本发明的丙烯酸材料包含60重量%至99重量%的基质,40重量%至1重量%的交联共聚物。 这些材料可以通过例如注射成型,挤出,共挤出,挤出吹塑来生产部件,型材,片材或薄膜来转化。
    • 10. 发明申请
    • THERMOPLASTIC POLYMER SYSTEMS MODIFIED BY COPOLYMERS WITH FUNCTIONALISED BLOCKS
    • 具有功能块的共聚物改性的热塑性聚合物体系
    • US20110245422A1
    • 2011-10-06
    • US13121781
    • 2009-10-02
    • Jean-Pierre DissonThomas Fine
    • Jean-Pierre DissonThomas Fine
    • C08L53/00
    • C08L75/06C08L33/00C08L35/00C08L75/04C08L2666/06
    • The present invention relates to thermoplastic polymers modified by means of acrylic block copolymers functionalized by hydrophilic monomers. The subject matter of the invention is a blend of polymers comprising, as matrix polymer, a thermoplastic material which comprises flexible segments of polyether or polyester type and comprising at least one acrylic block copolymer dispersed in said matrix polymer and miscible with the latter, said block copolymer comprising at least one hydrophilic monomer. The modified thermoplastic materials according to the invention maintain very good properties of transparency and, in addition, acquire new properties, in particular mechanical properties, such as a better mechanical strength in the molten state during conversion operations specific to thermoplastic materials, such as extrusion, blow molding or calendering operations.
    • 本发明涉及通过由亲水性单体官能化的丙烯酸嵌段共聚物改性的热塑性聚合物。 本发明的主题是聚合物的混合物,其包含作为基质聚合物的热塑性材料,其包含聚醚或聚酯类型的柔性链段,并且包含至少一种分散在所述基质聚合物中并与其混溶的丙烯酸嵌段共聚物,所述嵌段 共聚物包含至少一种亲水性单体。 根据本发明的改性热塑性材料保持非常好的透明性质,并且另外获得新的性能,特别是机械性能,例如在热塑性材料特定的转化操作期间在熔融状态下更好的机械强度,例如挤出, 吹塑或压延操作。