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1. 发明授权

US07309441B2 Electrochemical sterilizing and bacteriostatic method 有权
标题翻译：电化学灭菌和抑菌法
公开(公告)号：US07309441B2
公开(公告)日：2007-12-18
申请号：US10895317
申请日：2004-07-21
申请人： Philippe Rychen , Laurent Pupunat , Tsuneto Furuta , Masao Sekimoto , Hozumi Tanaka , Yoshinori Nishiki , Shuhei Wakita
发明人： Philippe Rychen , Laurent Pupunat , Tsuneto Furuta , Masao Sekimoto , Hozumi Tanaka , Yoshinori Nishiki , Shuhei Wakita
IPC分类号： B01D17/06
CPC分类号： C02F1/4674 , C02F2001/46138 , C02F2305/023
摘要： A method is disclosed, which is capable of subjecting microorganisms to sterilizing or bacteriostatic treatment with good efficiency as compared with the conventional sterilizing or bacteriostatic method using a noble metal electrode. Microorganism-containing water to be treated is electrochemically treated using an anode having conductive diamond to bring the microorganism into contact with the anode, thereby undergoing sterilization. Since the conductive diamond has a high oxidation potential as compared with other electrode substances, direct oxidation reaction due to contact between a microorganism in water to be treated, such as Legionella bacteria, and the anode surface occurs strongly as compared with other electrodes, thereby enabling effective sterilization. The conductive diamond has a high ability to generate ozone and has an excellent formation efficiency with respect to the generation of hydrogen peroxide and radicals. Accordingly, an indirect sterilizing effect can also be expected.
摘要翻译：与使用贵金属电极的常规灭菌或抑菌方法相比，公开了能够以高效率对微生物进行灭菌或抑菌处理的方法。使用具有导电金刚石的阳极对待处理的含微生物水进行电化学处理，使微生物与阳极接触，从而进行灭菌。由于与其他电极物质相比，导电金刚石具有高的氧化电位，因此与其他电极相比，由于诸如军团菌等待处理的水中的微生物与微生物之间的接触引起的直接氧化反应强烈地发生，从而使得有效灭菌。导电金刚石具有高的产生臭氧的能力，并且在产生过氧化氢和自由基方面具有优异的形成效率。因此，也可以预期间接杀菌作用。

2. 发明申请

US20050023227A1 Electrochemical sterilizing and bacteriostatic method 有权
标题翻译：电化学灭菌和抑菌法
公开(公告)号：US20050023227A1
公开(公告)日：2005-02-03
申请号：US10895317
申请日：2004-07-21
申请人： Philippe Rychen , Laurent Pupunat , Tsuneto Furuta , Masao Sekimoto , Hozumi Tanaka , Yoshinori Nishiki , Shuhei Wakita
发明人： Philippe Rychen , Laurent Pupunat , Tsuneto Furuta , Masao Sekimoto , Hozumi Tanaka , Yoshinori Nishiki , Shuhei Wakita
IPC分类号： C02F1/46 , C02F1/461 , C02F1/467 , C25B11/06
CPC分类号： C02F1/4674 , C02F2001/46138 , C02F2305/023
摘要： A method is disclosed, which is capable of subjecting microorganisms to sterilizing or bacteriostatic treatment with good efficiency as compared with the conventional sterilizing or bacteriostatic method using a noble metal electrode. Microorganism-containing water to be treated is electrochemically treated using an anode having conductive diamond to bring the microorganism into contact with the anode, thereby undergoing sterilization. Since the conductive diamond has a high oxidation potential as compared with other electrode substances, direct oxidation reaction due to contact between a microorganism in water to be treated, such as Legionella bacteria, and the anode surface occurs strongly as compared with other electrodes, thereby enabling effective sterilization. The conductive diamond has a high ability to generate ozone and has an excellent formation efficiency with respect to the generation of hydrogen peroxide and radicals. Accordingly, an indirect sterilizing effect can also be expected.
摘要翻译：与使用贵金属电极的常规灭菌或抑菌方法相比，公开了能够以高效率对微生物进行灭菌或抑菌处理的方法。使用具有导电金刚石的阳极对待处理的含微生物水进行电化学处理，使微生物与阳极接触，从而进行灭菌。由于与其他电极物质相比，导电金刚石具有高的氧化电位，因此与其他电极相比，由于诸如军团菌等待处理的水中的微生物与微生物之间的接触引起的直接氧化反应强烈地发生，从而使得有效灭菌。导电金刚石具有高的产生臭氧的能力，并且在产生过氧化氢和自由基方面具有优异的形成效率。因此，也可以预期间接杀菌作用。

3. 发明授权

US06767447B2 Electrolytic cell for hydrogen peroxide production and process for producing hydrogen peroxide 有权
标题翻译：用于过氧化氢生产的电解槽和生产过氧化氢的方法
公开(公告)号：US06767447B2
公开(公告)日：2004-07-27
申请号：US10123114
申请日：2002-04-17
申请人： Masaharu Uno , Shuhei Wakita , Masao Sekimoto , Tsuneto Furuta , Yoshinori Nishiki
发明人： Masaharu Uno , Shuhei Wakita , Masao Sekimoto , Tsuneto Furuta , Yoshinori Nishiki
IPC分类号： C25B130
CPC分类号： C25B1/30
摘要： An electrolytic cell and method of electrolysis for producing hydrogen peroxide at a moderate current density while preventing metal deposition on the cathode surface. A feed water from which multivalent metal ions have been removed and in which a salt of a univalent metal, e.g., sodium sulfate, has been dissolved in a given concentration is prepared with an apparatus for removing multivalent metal ions and dissolving a salt in low concentration. The feed water is supplied to an electrolytic cell. Even when electrolysis is continued, almost no deposition of a hydroxide or carbonate occurs on the cathode because multivalent metal ions are not present in the electrolytic solution. Due to the dissolved salt, a sufficient current density is secured to prevent an excessive load from being imposed on the electrodes, etc. Thus, stable production of hydrogen peroxide is possible over a long period of time.
摘要翻译：一种电解槽和电解方法，用于在中等电流密度下生产过氧化氢，同时防止阴极表面上的金属沉积。用一种除去多价金属离子并溶解盐浓度低的装置制备已经除去多价金属离子并且其中以一定浓度的硫酸钠等单价盐溶解的给水的给水。给水供给电解池。即使继续进行电解，因为在电解液中不存在多价金属离子，所以在阴极上几乎不发生氢氧化物或碳酸盐的沉积。由于溶解的盐，确保足够的电流密度以防止对电极等施加过大的负荷。因此，可以长期稳定地生产过氧化氢。

4. 发明申请

US20050072667A1 Apparatus and method for electrolytically treating chemical plating waste liquor 审中-公开
标题翻译：化学镀废液电解处理设备及方法
公开(公告)号：US20050072667A1
公开(公告)日：2005-04-07
申请号：US10947300
申请日：2004-09-23
申请人： Tsuneto Furuta , Masao Sekimoto , Shuhei Wakita , Hozumi Tanaka
发明人： Tsuneto Furuta , Masao Sekimoto , Shuhei Wakita , Hozumi Tanaka
IPC分类号： C02F1/46 , C02F1/461 , C02F1/467 , C23C18/16 , C25B11/04 , C25B11/06 , C25B11/12 , C25B1/22
CPC分类号： C02F1/46109 , C02F1/4672 , C02F2001/46142 , C02F2101/105 , C02F2103/346
摘要： An electrolytic treatment apparatus and method by simply subjecting a chemical plating waste liquor containing phosphorus components and organic compounds to electrolytic treatment, thereby reducing the amount of impurities in the waste liquor to a level at which the waste liquor can be discharged. The chemical plating waste liquor containing hypophosphorous acid, phosphorous acid and organic compounds is subjected to electrolytic treatment in an electrolytic cell having a conductive diamond electrode as an anode. The conductive diamond electrode oxidizes or oxidatively decomposes the phosphorus components and organic compounds in the waste liquor substantially simultaneously, thereby reducing the amount of impurities to a level at which the waste liquor can be discharged.
摘要翻译：一种电解处理装置和方法，通过简单地对含有磷成分和有机化合物的化学镀废液进行电解处理，从而将废液中的杂质量减少至排出废液的水平。将含有次磷酸，亚磷酸和有机化合物的化学镀废液在具有导电金刚石电极作为阳极的电解槽中进行电解处理。导电金刚石电极基本上同时地氧化或氧化废液中的磷成分和有机化合物，从而将杂质的量减少至排出废液的水平。

5. 发明授权

US06666030B2 Ice composition containing hydrogen peroxide and method of storing perishable food 失效
公开(公告)号：US06666030B2
公开(公告)日：2003-12-23
申请号：US10155961
申请日：2002-05-29
申请人： Tsuneto Furuta , Yoshinori Nishiki , Masao Sekimoto , Shyuhei Wakita
发明人： Tsuneto Furuta , Yoshinori Nishiki , Masao Sekimoto , Shyuhei Wakita
IPC分类号： F25C2100
CPC分类号： C09K5/066 , A61L2/035 , A61L2/16 , C02F1/4672 , C02F1/722 , C02F2001/46133 , F25D3/02 , F25D2303/085 , Y02A40/968
摘要： An ice composition obtained by freezing a liquid containing, dissolved therein, hydrogen peroxide produced by electrolysis; and a method of food storage using the composition. Hydrogen peroxide has a lower rate of dissipation into the air and better suitability for long-term storage than ozone. Furthermore, since hydrogen peroxide is electrolytically produced, it eliminates the trouble of transportation, storage, and dissolution. When seawater is used as a feed water for electrolysis, the ice composition thus obtained has a higher cooling effect because it has a melting point lower than 0° C.

6. 发明授权

US5560815A Electrolytic chromium plating method using trivalent chromium 失效
标题翻译：电镀铬法使用三价铬
公开(公告)号：US5560815A
公开(公告)日：1996-10-01
申请号：US495110
申请日：1995-06-27
申请人： Masao Sekimoto , Yukiei Matsumoto , Kyohei Kuroda , Takanobu Hayashi , Akio Nishi , Mitsuo Shibata
发明人： Masao Sekimoto , Yukiei Matsumoto , Kyohei Kuroda , Takanobu Hayashi , Akio Nishi , Mitsuo Shibata
IPC分类号： C25D3/06 , C25D17/10 , C25D17/12 , C25D3/04
CPC分类号： C25D17/10 , C25D3/06
摘要： A chromium plating method using a plating bath comprising trivalent chromium and an electrode which is an anode comprising an electrode substrate of titanium, tantalum, zirconium, niobium or an alloy thereof, coated with an electrode catalyst comprising at least iridium oxide and, optionally, at least one of titanium, tantalum, niobium, zirconium, tin, antimony, ruthenium, platinum, cobalt, molybdenum, tungsten or an oxide thereof. The anode may be placed directly in the chromium plating bath or may be placed in an anode chamber partitioned from the chromium plating bath with an ion-exchange membrane. The chromium plating method may be a barrel plating method.
摘要翻译：使用包含三价铬的电镀浴和作为阳极的电极的镀铬方法，其包含钛，钽，锆，铌或其合金的电极基底，涂覆有至少包含氧化铱的电极催化剂，以及任选地钛，钽，铌，锆，锡，锑，钌，铂，钴，钼，钨或其氧化物中的至少一种。阳极可以直接放置在镀铬浴中，或者可以用离子交换膜置于与镀铬浴分隔的阳极室中。镀铬法可以是滚镀法。

7. 发明授权

US5232576A Anode for chromium plating and processes for producing and using the same 失效
标题翻译：用于生产和使用它的铬镀层和工艺的阳极
公开(公告)号：US5232576A
公开(公告)日：1993-08-03
申请号：US755423
申请日：1991-09-04
申请人： Yukiei Matsumoto , Masao Sekimoto
发明人： Yukiei Matsumoto , Masao Sekimoto
IPC分类号： C25D3/04 , C25D17/10 , C25D17/12
CPC分类号： C25D17/10
摘要： There are described an anode, a process for producing the same, an apparatus for electrolytic chromium plating, and a method for electrolytic chromium plating, using such anode, wherein the anode comprises an electrically conductive substrate comprising a valve metal or an alloy thereof, a first intermediate layer formed on the sustrate and comprising an oxide of tin, a second intermediate layer formed on the first intermediate layer and comprising either (1) platinum metal and an oxide of tin, or (2) platinum metal, an oxide of tin, and iridium oxide, and a surface layer formed on the second intermediate layer and comprising either (1) platinum metal and an oxide of tin, or (2) platinum metal, an oxide of tin, and iridium oxide, the composition of said surface layer being different form that of said second intermediate layer.

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