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1. 发明授权

US4880472A Organic pigments coated with metal oxides 失效
标题翻译：涂有金属氧化物的有机颜料
公开(公告)号：US4880472A
公开(公告)日：1989-11-14
申请号：US202865
申请日：1988-06-06
申请人： Philippe Bugnon , Arnold Grubenmann , Bernhard Medinger , Jean Schaefle
发明人： Philippe Bugnon , Arnold Grubenmann , Bernhard Medinger , Jean Schaefle
IPC分类号： C08K9/02 , C09B67/08
CPC分类号： C09B67/0007
摘要： Compositions containing an organic pigment coated with metal oxides, wherein the pigment particles are provided with a tenacious, dense, highly crosslinked coating of silica and/or alumina which is fixed by polycondensation of a silicate and/or aluminate with the free hydroxyl groups of a layer that densely coats the surface of the pigment particles and which consists substantially of partially hydrolyzed compounds of elements of group 4A or 4B of the Periodic Table selected from the group consisting of chelates of formula ##STR1## wherein R is methyl, ethyl, methoxy or ethoxy, R.sup.1 is methyl or ethyl and X is halogen or C.sub.1 -C.sub.4 alkoxy, and M is Ti or Sn, and of esters of formulaQ(OR.sup.2).sub.4 (III),wherein Q is an element of group 4A or 4B of the Periodic Table and R.sup.2 is C.sub.1 -C.sub.4 alkyl.Pigment compositions of this kind are distinguished in particular by excellent rheological properties in varnish and printing ink systems, by high gloss of the finishes obtained therewith, and by substantial non-deformation of the plastic mouldings pigmented therewith.
摘要翻译：包含涂覆有金属氧化物的有机颜料的组合物，其中所述颜料颗粒设置有坚固，致密，高度交联的二氧化硅和/或氧化铝的涂层，其通过硅酸盐和/或铝酸盐与一种硅酸盐和/或铝酸盐的游离羟基的缩聚固定层，其密集地涂覆颜料颗粒的表面，并且其基本上由元素周期表中的4A或4B族元素的部分水解化合物组成，其选自由式（I）或（IMAGE）（II）的螯合物组成的组）其中R是甲基，乙基，甲氧基或乙氧基，R1是甲基或乙基，X是卤素或C1-C4烷氧基，M是Ti或Sn，和式Q（OR2）4（Ⅲ）的酯，其中Q是元素周期表的4A或4B族元素，R2是C1-C4烷基。这种颜料组合物特别是通过在清漆和印刷油墨体系中的优异的流变性能，通过其获得的表面光泽的高光泽度和通过其着色的塑料模制品的基本不变形来区分。

2. 发明授权

US4504404A Lubricant compositions containing chlorinated organic compounds 失效
标题翻译：含有氯化有机化合物的润滑剂组合物
公开(公告)号：US4504404A
公开(公告)日：1985-03-12
申请号：US631510
申请日：1984-07-16
申请人： Rolf Schumacher , Arnold Grubenmann
发明人： Rolf Schumacher , Arnold Grubenmann
IPC分类号： C10M137/04 , C10M131/00 , C10M131/06 , C10M131/10 , C10M133/38 , C10M135/00 , C10M135/10 , C10M135/34 , C10N10/02 , C10N10/04 , C10N20/02 , C10N30/06 , C10M1/54
CPC分类号： C10M135/00 , C10M131/00 , C10M133/38 , C10M2203/06 , C10M2205/026 , C10M2207/023 , C10M2207/024 , C10M2207/025 , C10M2207/026 , C10M2207/027 , C10M2207/028 , C10M2207/123 , C10M2207/129 , C10M2207/16 , C10M2207/22 , C10M2207/289 , C10M2209/084 , C10M2211/00 , C10M2211/024 , C10M2211/042 , C10M2211/044 , C10M2211/06 , C10M2211/08 , C10M2215/06 , C10M2215/064 , C10M2215/065 , C10M2215/066 , C10M2215/08 , C10M2215/082 , C10M2215/086 , C10M2215/14 , C10M2215/18 , C10M2215/182 , C10M2215/202 , C10M2215/22 , C10M2215/221 , C10M2215/222 , C10M2215/223 , C10M2215/224 , C10M2215/225 , C10M2215/226 , C10M2215/227 , C10M2215/28 , C10M2215/30 , C10M2217/028 , C10M2217/06 , C10M2219/024 , C10M2219/044 , C10M2219/046 , C10M2219/064 , C10M2219/068 , C10M2219/082 , C10M2219/085 , C10M2219/086 , C10M2219/09 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10M2219/108 , C10M2223/04 , C10M2223/041 , C10M2223/042 , C10M2223/043 , C10M2223/045 , C10M2223/047 , C10M2223/065 , C10M2227/00 , C10N2210/01 , C10N2210/02 , C10N2210/04 , C10N2210/05 , C10N2210/06 , C10N2210/08
摘要： The load-carrying capacity of liquid lubricants having a kinematic viscosity of 2 to 1500 mm.sup.2 /s at 40.degree. C. can be substantially improved by the addition of oil-insoluble, dispersible aromatic compounds which are chlorine-substituted in the nucleus. The compounds, which consist of 1 to 4 completely unsaturated or partially saturated aromatic moieties which may contain hetero-atoms and are linked to one another through a simple direct bond, a double bond or through --O--, --S--, --N(R)--, --N.dbd., alkylene, --NHCO--, --N.dbd.CH--, --N.dbd.N--, --N.dbd.NCH(COCH.sub.3)CONH, --CH.dbd.N--N.dbd.CH-- or .dbd.N--(Y)--N.dbd., contain from 2 to 24 aromatic chlorine atoms. The combination of the additives of the invention with conventional antiwear additives has been found to be particularly advantageous.
摘要翻译：在40℃下运动粘度为2〜1500mm 2 / s的液体润滑剂的承载能力可以通过加入在核中被氯取代的不溶于油的可分散的芳族化合物而大大提高。该化合物由1至4个完全不饱和或部分饱和的芳族部分组成，其可含有杂原子并通过简单的直接键相互连接，双键或通过-O - ， - S - ， - N（（CH 3）CONH，-CH = NN = CH-或= N-（Y） - ，-N =亚烷基，-NHCO-，-N = CH-，-N = N =，含有2至24个芳族氯原子。已经发现本发明的添加剂与常规抗磨添加剂的组合是特别有利的。

3. 发明授权

US5776657A Wet-chemical developable, etch-stable photoresist for UV radiation with a wavelength below 200 NM 失效
标题翻译：湿化学可显影，蚀刻稳定的光致抗蚀剂，其波长低于200NM
公开(公告)号：US5776657A
公开(公告)日：1998-07-07
申请号：US614613
申请日：1996-03-14
申请人： Ulrich Schaedeli , Manfred Hofmann , Norbert Muenzel , Arnold Grubenmann
发明人： Ulrich Schaedeli , Manfred Hofmann , Norbert Muenzel , Arnold Grubenmann
IPC分类号： G03F7/004 , G03F7/023 , G03F7/029 , G03F7/033 , G03F7/038 , G03F7/039 , G03F7/40 , H01L21/027
CPC分类号： G03F7/039 , G03F7/0045 , G03F7/40
摘要： Photoresist compositions are described, which are sufficiently transparent in the solvent-free state for radiation of a wavelength of approximately 193 nm, and which contain nonaromatic chemical groups, which can be converted into groups with aromatic structural elements (latent aromatic groups) under process conditions, for which an image structure comprised of the resist material is not disrupted. A preferred component with latent aromatic groups is bicyclo�3.2.2!nona-6,8-dien-3-one Resist coatings, which are produced with these compositions, show a stability in plasma etching, which is comparable with the stability of conventional resists based on phenolic resins.
摘要翻译：描述了光致抗蚀剂组合物，其在无溶剂状态下对于约193nm的波长的辐射是足够透明的，并且其含有非芳族化学基团，其可以在加工条件下转化成具有芳族结构元素（潜芳族基团）的基团由抗蚀剂材料构成的图像结构不被破坏。具有潜在芳族基团的优选组分是双环[3.2.2]壬-6,8-二烯-3-酮用这些组合物制备的抗蚀涂层显示出在等离子体蚀刻中的稳定性，其与传统的基于酚醛树脂。

4. 发明授权

US6063549A Wet-chemical, developable, etch-stable photoresist for UV radiation with a wavelength below 200 nm 失效
标题翻译：湿化学，可显影，蚀刻稳定的光致抗蚀剂，其波长低于200nm
公开(公告)号：US6063549A
公开(公告)日：2000-05-16
申请号：US86006
申请日：1998-05-27
申请人： Ulrich Schadeli , Manfred Hofmann , Norbert Muenzel , Arnold Grubenmann
发明人： Ulrich Schadeli , Manfred Hofmann , Norbert Muenzel , Arnold Grubenmann
IPC分类号： G03F7/004 , G03F7/023 , G03F7/029 , G03F7/033 , G03F7/038 , G03F7/039 , G03F7/40 , H01L21/027
CPC分类号： G03F7/039 , G03F7/0045 , G03F7/40
摘要： Photoresist compositions are described, which are sufficiently transparent in the solvent-free state for radiation of a wavelength of approximately 193 nm, and which contain nonaromatic chemical groups, which can be converted into groups with aromatic structural elements (latent aromatic groups) under process conditions, for which an image structure comprised of the resist material is not disrupted. A preferred component with latent aromatic groups is bicyclo[3.2.2]nona-6,8-dien-3-one. Resist coatings, which are produced with these compositions, show a stability in plasma etching, which is comparable with the stability of conventional resists based on phenolic resins.
摘要翻译：描述了光致抗蚀剂组合物，其在无溶剂状态下对于约193nm的波长的辐射是足够透明的，并且其含有非芳族化学基团，其可以在加工条件下转化成具有芳族结构元素（潜芳族基团）的基团由抗蚀剂材料构成的图像结构不被破坏。具有潜芳族基团的优选组分是双环[3.2.2]壬-6,8-二烯-3-酮。用这些组合物生产的抗蚀涂层表现出等离子体蚀刻中的稳定性，其与基于酚醛树脂的常规抗蚀剂的稳定性相当。

5. 发明授权

US4980458A Mixed sodium, ammonium and/or calcium salt crystals of laked monoazo disulfonated pyrazolone pigments 失效
标题翻译：浸渍的单偶氮二磺化吡唑啉酮颜料的混合的钠，铵和/或钙盐晶体
公开(公告)号：US4980458A
公开(公告)日：1990-12-25
申请号：US349907
申请日：1989-05-08
申请人： Stefan Hari , Arnold Grubenmann , Andreas Burkhard
发明人： Stefan Hari , Arnold Grubenmann , Andreas Burkhard
IPC分类号： C09B67/48 , C08K5/22 , C08K5/23 , C08K5/41 , C08K5/42 , C09B63/00 , C09B67/22 , C09B69/02
CPC分类号： C09B67/0051 , C09B69/02 , Y10S534/01
摘要： Mixed crystals of at least two different compounds of formula I ##STR1## wherein R is --CH.sub.3, phenyl, --COOCH.sub.3, --COOCH.sub.3, --COOC.sub.2 H.sub.5, --NHCO--C.sub.1 -C.sub.4 alkyl or --CONH--C.sub.1 -C.sub.4 alkyl, M.sup.+ and M.sub.1.sup.+ are each independently of the other an alkali metal cation, an alkaline earth metal cation or a heavy metal cation or NH.sub.4.sup.+ ; wherein X, Y, X' and Y' are each independently hydrogen, halogen, --CH.sub.3, --C.sub.2 H.sub.5, --OCH.sub.3, --OC.sub.2 H.sub.5, --NO.sub.2 or the group of formula --NHCO--C.sub.1 -C.sub.4 alkyl, wherein at least two of the cations M.sup.+ and M.sub.1.sup.+ in the compounds forming the mixed crystals of formula I are different and the X-ray diffraction patterns of the mixed crystals differ from the X-ray diffraction patterns of the individual components and of their sum. Such mixed crystals are most suitable as pigments for coloring high molecular organic material and are distinguished in particular by surprisingly high color strength and pure shade.
摘要翻译：至少两种不同的式I化合物的混合晶体（I）其中R是-CH 3，苯基，-COOCH 3，-COOCH 3，-COOC 2 H 5，-NHCO-C 1 -C 4烷基或-CONH-C 1 -C 4烷基， M +和M1 +各自独立地为碱金属阳离子，碱土金属阳离子或重金属阳离子或NH4 +; 其中X，Y，X'和Y'各自独立地为氢，卤素，-CH 3，-C 2 H 5，-OCH 3，-OC 2 H 5，-NO 2或式-NHCO-C 1 -C 4烷基的基团，其中至少两个形成式I的混合晶体的化合物中的阳离子M +和M1 +是不同的，并且混晶的X射线衍射图与各个组分的X射线衍射图和它们的和不同。这种混合晶体最适合作为着色高分子有机材料的颜料，特别是出人意料地高的着色强度和纯净的色调。

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