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1. 发明申请

US20060074158A1 Flexible semicrystalline polyamides 有权
标题翻译：柔性半结晶聚酰胺
公开(公告)号：US20060074158A1
公开(公告)日：2006-04-06
申请号：US11243532
申请日：2005-10-05
申请人： Philippe Blondel , Thibaut Montanari , Annett Linemann , Nicolas Amouroux , Henri Decraemer
发明人： Philippe Blondel , Thibaut Montanari , Annett Linemann , Nicolas Amouroux , Henri Decraemer
IPC分类号： C08K5/43
CPC分类号： C08K5/435 , C08L2205/02 , Y10T428/31725 , Y10T428/31728 , Y10T428/31732 , Y10T428/31739 , Y10T428/31743 , Y10T428/31746 , C08L77/00
摘要： The invention relates to a composition, and structures having a layer made of said composition, in which the composition is, by weight, the total being 100%: 50 to 100% of at least one polyamide Al of formula X.Y/Z or 6.Y2/Z in which: X denotes the residues of an aliphatic diamine having from 6 to 10 carbon atoms, Y denotes the residues of an aliphatic dicarboxylic acid having from 10 to 14 carbon atoms, Y2 denotes the residues of an aliphatic dicarboxylic acid having from 15 to 20 carbon atoms and Z denotes at least one unit chosen from the residues of a lactam, the residues of an α,ω-aminocarboxylic acid, the unit X1, Y1 in which X1 denotes the residues of an aliphatic diamine and Y1 denotes the residues of an aliphatic dicarboxylic acid, the weight ratios Z/(X+Y+Z) and Z/(6+Y2+Z) being between 0 and 15%; 0 to 40% of a plasticizer; 0 to 50% of an impact modifier; and 0 to 50% of a polyamide A2.
摘要翻译：本发明涉及一种组合物和具有由所述组合物制成的层的结构，其中所述组合物的总重量为100％：50至100％的至少一种式XY / Z或6的聚酰胺Al。 Y2 / Z，其中：X表示具有6至10个碳原子的脂族二胺的残基，Y表示具有10至14个碳原子的脂族二羧酸的残基，Y2表示具有 15〜20个碳原子，Z表示选自内酰胺残基中的至少一个单元，α，ω-氨基羧酸的残基，单元X1，Y1，其中X1表示脂族二胺的残基，Y1表示脂肪族二羧酸的残基，Z /（X + Y + Z）和Z /（6 + Y2 + Z）的重量比在0〜15％之间; 0〜40％的增塑剂; 0至50％的抗冲改性剂; 和0〜50％的聚酰胺A2。

2. 发明授权

US07750110B2 Flexible semicrystalline polyamides 有权
标题翻译：柔性半结晶聚酰胺
公开(公告)号：US07750110B2
公开(公告)日：2010-07-06
申请号：US11243532
申请日：2005-10-05
申请人： Philippe Blondel , Thibaut Montanari , Annett Linemann , Nicolas Amouroux , Henri Decraemer
发明人： Philippe Blondel , Thibaut Montanari , Annett Linemann , Nicolas Amouroux , Henri Decraemer
IPC分类号： C08G69/08
CPC分类号： C08K5/435 , C08L2205/02 , Y10T428/31725 , Y10T428/31728 , Y10T428/31732 , Y10T428/31739 , Y10T428/31743 , Y10T428/31746 , C08L77/00
摘要： The invention relates to a composition, and structures having a layer made of said composition, in which the composition is, by weight, the total being 100%: 50 to 100% of at least one polyamide A1 of formula X.Y/Z or 6.Y2/Z in which: X denotes the residues of an aliphatic diamine having from 6 to 10 carbon atoms, Y denotes the residues of an aliphatic dicarboxylic acid having from 10 to 14 carbon atoms, Y2 denotes the residues of an aliphatic dicarboxylic acid having from 15 to 20 carbon atoms and Z denotes at least one unit chosen from the residues of a lactam, the residues of an α,ω-aminocarboxylic acid, the unit X1, Y1 in which X1 denotes the residues of an aliphatic diamine and Y1 denotes the residues of an aliphatic dicarboxylic acid, the weight ratios Z/(X+Y+Z) and Z/(6+Y2+Z) being between 0 and 15%; 0 to 40% of a plasticizer; 0 to 50% of an impact modifier; and 0 to 50% of a polyamide A2.
摘要翻译：本发明涉及一种组合物和具有由所述组合物制成的层的结构，其中所述组合物的总重量为100％：50至100％的至少一种式XY / Z或6的聚酰胺A1。 Y2 / Z，其中：X表示具有6至10个碳原子的脂族二胺的残基，Y表示具有10至14个碳原子的脂族二羧酸的残基，Y2表示具有 15至20个碳原子，Z表示选自内酰胺残基中的至少一个单元，α，ω-氨基羧酸的残基，单元X1，Y1，其中X1表示脂族二胺的残基，Y1表示脂肪族二羧酸的残基，Z /（X + Y + Z）和Z /（6 + Y2 + Z）的重量比在0〜15％之间; 0〜40％的增塑剂; 0至50％的抗冲改性剂; 和0〜50％的聚酰胺A2。

3. 发明授权

US08293372B2 Flexible semicrystalline polyamides 有权
标题翻译：柔性半结晶聚酰胺
公开(公告)号：US08293372B2
公开(公告)日：2012-10-23
申请号：US12783862
申请日：2010-05-20
申请人： Philippe Blondel , Thibaut Montanari , Annett Linemann , Nicolas Amouroux , Henri Decraemer
发明人： Philippe Blondel , Thibaut Montanari , Annett Linemann , Nicolas Amouroux , Henri Decraemer
IPC分类号： B32B27/06
CPC分类号： C08K5/435 , C08L2205/02 , Y10T428/31725 , Y10T428/31728 , Y10T428/31732 , Y10T428/31739 , Y10T428/31743 , Y10T428/31746 , C08L77/00
摘要： The invention relates to a multilayer structure in which the inner layer is in contact with petrol or diesel fuel and comprising, in succession from the outside inwards: an outer layer made of, 50 to 100% of at least one polyamide A1 of formula X.Y/Z or 6.Y2/Z in which: “6” represents the residues of hexamethylene diamine, X denotes the residues of a C6-10 aliphatic, Y denotes the residues of an aliphatic C10-14 dicarboxylic acid, Y2 denotes the residues of an aliphatic C15-20 dicarboxylic acid, and Z denotes at least one unit chosen from the residues of a lactam, the residues of an α,ω-aminocarboxylic acid, the unit X1,Y1 in which X1 denotes the residues of an aliphatic diamine and Y1 denotes the residues of an aliphatic dicarboxylic acid, the weight ratios Z/(X+Y+Z) and Z/(6+Y2+Z) being between 0 and 15%, an inner PA-6 layer or a layer of a PA-6/polyolefin blend having a PA-6 matrix and optionally containing a conductor.
摘要翻译：本发明涉及一种多层结构，其中内层与汽油或柴油燃料接触，并且从外部连续地包括：外层，其由50-100％的至少一种式XY / Z或6.Y2 / Z，其中：6表示六亚甲基二胺的残基，X表示C6-10脂族的残基，Y表示脂肪族C 10-14二羧酸的残基，Y2表示脂肪族C15的残基 -20二羧酸，Z表示选自内酰胺残基中的至少一个单元，α，ω-氨基羧酸的残基，单元X1，Y1，其中X1表示脂族二胺的残基，Y1表示脂肪族二羧酸的残基，Z /（X + Y + Z）和Z /（6 + Y2 + Z）的重量比为0〜15％，内部PA-6层或PA-6层 /具有PA-6基质并任选地含有导体的聚烯烃共混物。

4. 发明申请

US20110031155A1 FLEXIBLE SEMICRYSTALLINE POLYAMIDES 有权
标题翻译：柔性半结晶聚酰胺
公开(公告)号：US20110031155A1
公开(公告)日：2011-02-10
申请号：US12783862
申请日：2010-05-20
申请人： Philippe Blondel , Thibaut Montanari , Annett Linemann , Nicolas Amouroux , Henri Decraemer
发明人： Philippe Blondel , Thibaut Montanari , Annett Linemann , Nicolas Amouroux , Henri Decraemer
IPC分类号： B65D85/00 , B32B27/34
CPC分类号： C08K5/435 , C08L2205/02 , Y10T428/31725 , Y10T428/31728 , Y10T428/31732 , Y10T428/31739 , Y10T428/31743 , Y10T428/31746 , C08L77/00
摘要： The invention relates to a multilayer structure in which the inner layer is in contact with petrol or diesel fuel and comprising, in succession from the outside inwards: an outer layer made of, 50 to 100% of at least one polyamide A1 of formula X.Y/Z or 6.Y2/Z in which: “6” represents the residues of hexamethylene diamine, X denotes the residues of a C6-10 aliphatic, Y denotes the residues of an aliphatic C10-14 dicarboxylic acid, Y2 denotes the residues of an aliphatic C15-20 dicarboxylic acid, and Z denotes at least one unit chosen from the residues of a lactam, the residues of an α,ω-aminocarboxylic acid, the unit X1,Y1 in which X1 denotes the residues of an aliphatic diamine and Y1 denotes the residues of an aliphatic dicarboxylic acid, the weight ratios Z/(X+Y+Z) and Z/(6+Y2+Z) being between 0 and 15%, an inner PA-6 layer or a layer of a PA-6/polyolefin blend having a PA-6 matrix and optionally containing a conductor.
摘要翻译：本发明涉及一种多层结构，其中内层与汽油或柴油燃料接触，并且从外部连续地包括：外层，其由50-100％的至少一种式XY / Z或6.Y2 / Z，其中：“6”表示六亚甲基二胺的残基，X表示C6-10脂肪族的残基，Y表示脂肪族C 10-14二羧酸的残基，Y2表示脂族C 15-20二羧酸，Z表示选自内酰胺残基中的至少一个单元，α，ω-氨基羧酸的残基，单元X1，Y1，其中X1表示脂族二胺的残基和Y1 表示脂肪族二羧酸的残基，Z /（X + Y + Z）和Z /（6 + Y2 + Z）的重量比在0〜15％之间，内部PA-6层或PA层 -6 /聚烯烃共混物，其具有PA-6基体并且任选地含有导体。

5. 发明授权

US09664312B2 Polyamide hose for compressed air 有权
公开(公告)号：US09664312B2
公开(公告)日：2017-05-30
申请号：US12161578
申请日：2007-01-22
申请人： Gaelle Bellet , Nicolas Amouroux , Thibaut Montanari
发明人： Gaelle Bellet , Nicolas Amouroux , Thibaut Montanari
IPC分类号： F16L11/08 , F16L11/12 , B32B1/08 , B32B27/34 , F16L11/04 , B32B27/08 , B32B27/36
CPC分类号： F16L11/12 , B32B1/08 , B32B27/08 , B32B27/285 , B32B27/34 , B32B27/36 , B32B27/365 , B32B2250/24 , B32B2307/546 , F16L11/04 , Y10T428/1393
摘要： The present invention relates to a multilayer hose for compressed air comprising, in this order:an outer layer (1) made of polyamide,optionally an intermediate layer (2) of a polymer having a flexural modulus of less than 500 MPa,an inner layer (3) of a polymer having a flexural modulus of greater than 1100 MPa, the inner layer (3) being in contact with the compressed air.

6. 发明申请

US20090017247A1 POLYAMIDE HOSE FOR COMPRESSED AIR 有权
标题翻译：用于压缩空气的聚氨酯软管
公开(公告)号：US20090017247A1
公开(公告)日：2009-01-15
申请号：US12161578
申请日：2007-01-22
申请人： Gaelle Bellet , Nicolas Amouroux , Thibaut Montanari
发明人： Gaelle Bellet , Nicolas Amouroux , Thibaut Montanari
IPC分类号： F16L11/04
CPC分类号： F16L11/12 , B32B1/08 , B32B27/08 , B32B27/285 , B32B27/34 , B32B27/36 , B32B27/365 , B32B2250/24 , B32B2307/546 , F16L11/04 , Y10T428/1393
摘要： The present invention relates to a multilayer hose for compressed air comprising, in this order: an outer layer (1) made of polyamide, optionally an intermediate layer (2) of a polymer having a flexural modulus of less than 500 MPa, an inner layer (3) of a polymer having a flexural modulus of greater than 1100 MPa, the inner layer (3) being in contact with the compressed air.
摘要翻译：本发明涉及一种用于压缩空气的多层软管，其包括以下顺序：由聚酰胺制成的外层（1），任选地具有弯曲模量小于500MPa的聚合物的中间层（2），内层（3）具有大于1100MPa的挠曲模量的聚合物，内层（3）与压缩空气接触。

7. 发明申请

US20050058845A1 Multilayer structure that includes an impact-modified EVOH layer 审中-公开
标题翻译：包括冲击改性EVOH层的多层结构
公开(公告)号：US20050058845A1
公开(公告)日：2005-03-17
申请号：US10909505
申请日：2004-08-02
申请人： Gaelle Bellet , Nicolas Amouroux , Thibaut Montanari , Benoit Brule , Anthony Bonnet , Fabrice Chopinez
发明人： Gaelle Bellet , Nicolas Amouroux , Thibaut Montanari , Benoit Brule , Anthony Bonnet , Fabrice Chopinez
IPC分类号： B32B1/08 , B32B27/08 , C08L23/12 , C08L23/16 , C08L25/08 , C08L25/10 , C08L25/14 , C08L29/04 , C08L53/02
CPC分类号： B32B27/08 , B32B27/306 , B32B27/32 , B32B27/34 , B32B2307/21 , B32B2323/00 , B32B2329/04 , B32B2377/00 , B32B2439/00 , C08L7/00 , C08L23/16 , C08L29/04 , C08L33/062 , C08L51/00 , C08L53/00 , C08L53/02 , C08L77/00 , Y10T428/3175 , C08L2666/24 , C08L2666/20 , C08L2666/06 , C08L2666/08 , C08L2666/04 , C08L2666/02
摘要： The present invention relates to a multilayer structure comprising the following successive layers: a polyamide or HDPE (high-density polyethylene) layer; a tie layer; an impact-modified EVOH layer; optionally, a tie layer; and a polyamide or polyamide/polyolefin blend or polyolefin layer, the latter layer possibly containing fillers in order to make it antistatic; and such that the impact-modified EVOH layer is a blend based on EVOH and at least one modifier chosen from: a) functionalized ethylene/alkyl (meth)acrylate copolymers; b) products resulting from the reaction of (i) a copolymer of ethylene and of an unsaturated monomer X grafted or copolymerized with (ii) a polyamide; c) blends of a) and b); d) polyamides, preferably PA-6; e) blends of a) and d); f) elastomers, preferably EPR, EPDM and NBR, these elastomers possibly being functionalized; g) S-B-M triblocks; h) triblocks formed from a poly(butyl acrylate) block between two PMMA blocks; and i) linear or star S-B-S block copolymers, these optionally being hydrogenated (they are then denoted by S-EB-S).
摘要翻译：本发明涉及包含以下连续层的多层结构：聚酰胺或HDPE（高密度聚乙烯）层; 一个领带; 冲击改性EVOH层; 可选地，连接层; 聚酰胺或聚酰胺/聚烯烃共混物或聚烯烃层，后一层可能含有填料以使其抗静电; 并且使得冲击改性的EVOH层是基于EVOH的共混物和选自以下的至少一种改性剂：a）官能化的乙烯/（甲基）丙烯酸烷基酯共聚物; b）由（i）乙烯和与（ii）聚酰胺接枝或共聚的不饱和单体X的共聚物的反应产生的产物; c）a）和b）的共混物; d）聚酰胺，优选PA-6; e）a）和d）的混合物; f）弹性体，优选EPR，EPDM和NBR，这些弹性体可能被官能化; g）S-B-M三嵌段; h）由两个PMMA嵌段之间的聚（丙烯酸丁酯）嵌段形成的三嵌段; 和i）线性或星形S-B-S嵌段共聚物，它们任选被氢化（然后用S-EB-S表示）。

8. 发明申请

US20090188578A1 MULTILAYER TUBE BASED ON A POLYAMIDE AND A FLUOROPOLYMER FOR TRANSFERRING FLUIDS 审中-公开
标题翻译：基于聚酰胺的多层管和用于转移流体的氟聚合物
公开(公告)号：US20090188578A1
公开(公告)日：2009-07-30
申请号：US11577559
申请日：2005-10-18
申请人： Anthony Bonnet , Nicolas Amouroux , Gaelle Bellet
发明人： Anthony Bonnet , Nicolas Amouroux , Gaelle Bellet
IPC分类号： F16L11/04 , F16L11/20
CPC分类号： B32B27/28 , B32B1/08 , B32B27/08 , B32B27/18 , B32B27/304 , B32B27/32 , B32B27/34 , B32B2250/24 , B32B2270/00 , B32B2307/202 , B32B2307/714 , B32B2597/00 , C08L23/0815 , C08L23/30 , C08L27/12 , C08L27/16 , Y10T428/1393 , C08L2666/24 , C08L2666/04
摘要： The present invention relates to a multilayer tube comprising, in its radial direction from the outside inwards: a polyamide outer layer (1); an inner layer (2) of a composition comprising, the total being 100%, 5 to 30% by weight of a blend (A) comprising: a polyethylene carrying epoxy functional groups, an impact modifier chosen from elastomers and very low-density polyethylenes, the said impact modifier being completely or partly functionalized; 95 to 70% by weight of a blend (B) comprising: a fluoropolymer (B1), a functionalized fluoropolymer (B2), the proportion of (B2) being between 1 and 80% by weight of (A)+(B), the layers being successive and adhering to one another in their respective contact region. The inner layer is the layer in contact with the fluid being transported. The layer (2) may be conductive. It is also possible to place a polyamide layer (3) beside the layer (2), which layer becomes the inner layer. The tube of the present invention has a very low permeability to petrol, particularly to hydrocarbons and to their additives, in particular alcohols such as methanol and ethanol, or even ethers such as MTBE or ITBE. These tubes also exhibit good resistance to fuels and to lubricating oils for engines. This tube exhibits very good mechanical properties at low temperature and at high temperature. The invention also relates to the use of these tubes for transporting petrol.
摘要翻译：本发明涉及一种多层管，其从径向向外包括：聚酰胺外层（1）; 组合物的内层（2），其包含总共为100％，5至30重量％的共混物（A），其包含：携带环氧官能团的聚乙烯，选自弹性体和非常低密度聚乙烯的抗冲改性剂所述抗冲改性剂完全或部分官能化; 95重量％至70重量％的共混物（B），其包含：含氟聚合物（B1），官能化含氟聚合物（B2），（B2）的比例为（A）+（B）的1-80重量％这些层是连续的并且在各自的接触区域中彼此附着。内层是与被输送流体接触的层。层（2）可以是导电的。也可以在层（2）旁边放置聚酰胺层（3），该层成为内层。本发明的管具有非常低的汽油渗透性，特别是烃和它们的添加剂，特别是醇如甲醇和乙醇，甚至醚如MTBE或ITBE。这些管也表现出良好的燃料抵抗性和发动机润滑油。该管在低温和高温下表现出非常好的机械性能。本发明还涉及这些管用于运输汽油的用途。

9. 发明授权

US09169392B2 Composite material based on polyamide and on poly(lactic acid), manufacturing process and use thereof 有权
标题翻译：基于聚酰胺和聚（乳酸）的复合材料，其制造方法和用途
公开(公告)号：US09169392B2
公开(公告)日：2015-10-27
申请号：US12524691
申请日：2008-01-29
申请人： Maho Yasuda , Nicolas Amouroux , Benoit Brule , Nadine Decraemer , Jean-Jacques Flat
发明人： Maho Yasuda , Nicolas Amouroux , Benoit Brule , Nadine Decraemer , Jean-Jacques Flat
IPC分类号： C08L77/00 , C08L67/04 , C08L23/08 , B29C43/00 , B29C45/00 , B29C47/00 , B29C51/00 , C08L77/02 , C08J5/10 , C08L77/06 , C08K7/14
CPC分类号： C08L77/02 , C08J5/10 , C08J2377/00 , C08J2377/02 , C08J2377/06 , C08K7/14 , C08L23/0869 , C08L23/0884 , C08L67/04 , C08L77/00 , C08L77/06 , C08L2666/02 , C08L2666/20 , C08L2666/18
摘要： The invention relates to a composite obtained from a composition comprising: 50 (excluded) to 90% by weight of at least one polyamide; 10 to 50% by weight of polylactic acid (PLA); and 0 to 30% by weight of at least one compatibilizing agent. The invention also relates to a process for manufacturing this composite and its use.
摘要翻译：本发明涉及一种由组合物获得的复合材料，所述组合物包含：50（不包括）至90重量％的至少一种聚酰胺; 10〜50重量％的聚乳酸（PLA）; 和0〜30重量％的至少一种相容剂。本发明还涉及这种复合材料的制造方法及其用途。

10. 发明申请

US20070059469A1 Polyamide-based multilayer tube for transferring fluids 有权
标题翻译：用于转移流体的聚酰胺基多层管
公开(公告)号：US20070059469A1
公开(公告)日：2007-03-15
申请号：US11413245
申请日：2006-04-28
申请人： Nicolas Amouroux , Michaela Steng
发明人： Nicolas Amouroux , Michaela Steng
IPC分类号： B32B1/08
CPC分类号： C08L77/02 , B32B1/08 , B32B27/08 , B32B27/18 , B32B27/34 , B32B2250/24 , B32B2270/00 , B32B2307/202 , B32B2307/206 , B32B2307/308 , B32B2307/546 , B32B2307/558 , B32B2307/56 , B32B2307/714 , B32B2509/00 , B32B2597/00 , B32B2605/08 , C08G69/265 , C08G69/36 , C08L77/00 , C08L77/06 , F16L11/04 , F16L11/127 , Y10T428/1393 , C08L2666/20
摘要： The present invention relates to a multilayer tube comprising, in its radial direction from the outside inwards: an optional layer (1) made of nylon-11 or nylon-12 polyamide; an intermediate layer (2) comprising by weight, the total being 100%: 50 to 100% of at least one polyamide A1 of formula X,Y/Z or 6,Y2/Z, in which X denotes residues of an aliphatic diamine having from 6 to 10 carbon atoms, Y denotes residues of an aliphatic dicarboxylic acid having from 10 to 14 carbon atoms, Y2 denotes residues of an aliphatic dicarboxylic acid having from 15 to 20 carbon atoms, Z denotes at least one unit chosen from residues of a lactam, residues of an α,Ω-aminocarboxylic acid, the unit X1,Y1, in which X1 denotes residues of a diamine and Y1 denotes residues of a diacid, the weight ratios Z/(X+Y+Z) and Z/(6+Y2+Z) being between 0 and 15%, and 0 to 50% of nylon-11 or nylon-12 polyamide; an optional layer (3) made of nylon-11 or nylon-12 polyamide, with the condition that at least one of the layers (1) and (3) is present; the layers being successive and adhering to one another, the inner layer being the layer in contact with the fluid transported.
摘要翻译：本发明涉及一种多层管，其从径向向外包括：由尼龙-11或尼龙-12聚酰胺制成的任选的层（1）中间层（2），其总重量为100％：50至100％的至少一种式X的聚酰胺A1，Y / Z或6，Y2 / Z，其中X表示具有 6至10个碳原子，Y表示具有10至14个碳原子的脂肪族二羧酸的残基，Y2表示具有15至20个碳原子的脂肪族二羧酸的残基，Z表示至少一个选自内酰胺，α，ω-氨基羧酸的残基，单元X1，Y1，其中X1表示二胺的残基，Y1表示二酸的残基，重量比Z /（X + Y + Z）和Z /（ 6 + Y2 + Z）为0〜15％，0〜50％为尼龙-11或尼龙-12聚酰胺; （3）由尼龙-11或尼龙-12聚酰胺制成的可选层（3），条件是至少存在一层（1）和（3）层; 这些层是连续的并且彼此粘附，内层是与所输送的流体接触的层。

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