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1. 发明授权

US07910640B2 Polycondensation product based on aromatic or heteroaromatic compounds, method for the production thereof, and use thereof 有权
标题翻译：基于芳族或杂芳族化合物的缩聚产物，其制备方法及其用途
公开(公告)号：US07910640B2
公开(公告)日：2011-03-22
申请号：US11665424
申请日：2005-10-14
申请人： Philipp Wieland , Alexander Kraus , Gerhard Albrecht , Kerstin Becher , Harald Grassl
发明人： Philipp Wieland , Alexander Kraus , Gerhard Albrecht , Kerstin Becher , Harald Grassl
IPC分类号： C04B24/12 , C04B24/28 , C08G8/18
CPC分类号： C08G12/40 , C04B24/243 , C04B24/30 , C04B24/32 , C04B2103/30 , C08G8/28
摘要： Disclosed is a polycondensation product that is a reaction product of A) an aromatic or heteroaromatic compound containing 5 to 10 C atoms or heteroatoms and is provided with an average of 1 to 300 oxyethylene groups and/or oxypropylene groups per molecule which are linked to the aromatic or heteroaromatic compound via an O atom or N atoms, and B) an aromatic compound and C) an aldehyde selected among the group of formaldehyde, glyoxylic acid, and benzaldehyde or mixtures thereof. Surprisingly, the inventive polycondensation product causes very good liquefaction of hydraulic binding agents, eg. Cement, resulting in substantially improved liquefaction of the construction material at a lower dose while pourability can be maintained over a longer period of time as opposed to naphthalene sulfonates or melamine sulfonates.
摘要翻译：公开了一种缩聚产物，其是A）含有5至10个C原子或杂原子的芳族或杂芳族化合物与每个分子平均具有1至300个氧化乙烯基团和/或氧代丙烯基团的反应产物，芳族或杂芳族化合物，以及B）芳族化合物和C）选自甲醛，乙醛酸和苯甲醛或其混合物的醛。令人惊奇的是，本发明的缩聚产物导致非常好的液压粘合剂的液化，例如。水泥，导致较低剂量的建筑材料的液化显着改善，而与萘磺酸盐或三聚氰胺磺酸盐相比，可以在更长的时间内保持可倾倒性。

2. 发明授权

US08053498B2 Pulverulent polycondensation products 有权
标题翻译：粉末缩聚产物
公开(公告)号：US08053498B2
公开(公告)日：2011-11-08
申请号：US12084212
申请日：2006-12-18
申请人： Philipp Wieland , Alexander Kraus , Gerhard Albrecht , Harald Grassl , Kerstin Becher
发明人： Philipp Wieland , Alexander Kraus , Gerhard Albrecht , Harald Grassl , Kerstin Becher
IPC分类号： C04B24/26
CPC分类号： C04B40/0042 , C04B24/166 , C04B24/246 , C04B24/30 , C04B35/63476 , C04B35/63488 , C04B2235/3217 , C04B2235/3418 , C04B2235/5409 , C04B2235/5436 , Y02W30/97 , C04B7/00 , C04B14/02 , C04B16/06 , C04B40/0028 , C04B18/24
摘要： Pulverulent polycondensation products are described, consisting of a) 5 to 95% by weight of a polycondensation product based on an aromatic or heteroaromatic compound (A) having 5 to 10 C atoms or heteroatoms having at least one oxyethylene or oxypropylene radical and one aldehyde (C) selected from the group consisting of formaldehyde, glyoxylic acid and benzaldehyde or mixtures thereof, and b) 5 to 95% by weight of a finely divided mineral carrier material having a specific surface area of 0.5 to 500 m2/g (according to BET as specified in DIN 66 131). The pulverulent polycondensation products according to the invention are outstandingly suitable in construction material mixtures in an amount of from 0.1 to 5% by weight, based on the weight of the construction material. The pulverulent polycondensation products have a number of advantages here, such as, for example, excellent storage stability, good liquefying action at low dosage and industrially simple production.
摘要翻译：描述了由以下组成的粉末缩聚产物：a）5至95重量％的基于具有5至10个碳原子的芳族或杂芳族化合物（A）的缩聚产物或具有至少一个氧乙烯或氧丙烯基和一个醛的杂原子（ C）选自甲醛，乙醛酸和苯甲醛或其混合物，和b）5至95重量％的细分矿物载体材料，其比表面积为0.5-500m2 / g（根据BET 如DIN 66 131中所规定）。根据本发明的粉状缩聚产物，以建筑材料的重量为基准，优选为0.1-5重量％的建筑材料混合物。粉状缩聚产物在这里具有许多优点，例如，优异的储存稳定性，低剂量的液化作用和工业上简单的生产。

3. 发明申请

US20090054558A1 Pulverulent Polycondensation Products 有权
标题翻译：粉末缩聚产品
公开(公告)号：US20090054558A1
公开(公告)日：2009-02-26
申请号：US12084212
申请日：2006-12-18
申请人： Philipp Wieland , Alexander Kraus , Gerhard Albrecht , Harald Grassl , Kerstin Becher
发明人： Philipp Wieland , Alexander Kraus , Gerhard Albrecht , Harald Grassl , Kerstin Becher
IPC分类号： C08L61/00 , C08L61/06 , C08K5/13 , C04B14/00 , C04B16/00 , C08K5/521 , C08K3/00 , C08K5/17 , C08K5/42 , C08K5/18 , C08K5/20 , C08K5/1535 , C08K5/3492 , C08K5/21 , C08K3/26 , C08K3/34 , C08K3/22 , C08K3/30
CPC分类号： C04B40/0042 , C04B24/166 , C04B24/246 , C04B24/30 , C04B35/63476 , C04B35/63488 , C04B2235/3217 , C04B2235/3418 , C04B2235/5409 , C04B2235/5436 , Y02W30/97 , C04B7/00 , C04B14/02 , C04B16/06 , C04B40/0028 , C04B18/24
摘要： Pulverulent polycondensation products are described, consisting of a) 5 to 95% by weight of a polycondensation product based on an aromatic or heteroaromatic compound (A) having 5 to 10 C atoms or heteroatoms having at least one oxyethylene or oxypropylene radical and one aldehyde (C) selected from the group consisting of formaldehyde, glyoxylic acid and benzaldehyde or mixtures thereof, and b) 5 to 95% by weight of a finely divided mineral carrier material having a specific surface area of 0.5 to 500 m2/g (according to BET as specified in DIN 66 131). The pulverulent polycondensation products according to the invention are outstandingly suitable in construction material mixtures in an amount of from 0.1 to 5% by weight, based on the weight of the construction material. The pulverulent polycondensation products have a number of advantages here, such as, for example, excellent storage stability, good liquefying action at low dosage and industrially simple production.
摘要翻译：描述了由以下组成的粉末缩聚产物：a）5至95重量％的基于具有5至10个碳原子的芳族或杂芳族化合物（A）的缩聚产物或具有至少一个氧乙烯或氧丙烯基和一个醛的杂原子（ C）选自甲醛，乙醛酸和苯甲醛或其混合物，和b）5至95重量％的细分矿物载体材料，其比表面积为0.5-500m2 / g（根据BET 如DIN 66 131中所规定）。根据本发明的粉状缩聚产物，以建筑材料的重量为基准，优选为0.1-5重量％的建筑材料混合物。粉状缩聚产物在这里具有许多优点，例如，优异的储存稳定性，低剂量的液化作用和工业上简单的生产。

4. 发明申请

US20080108732A1 Polycondensation Product Base on Aromatic or Heteroaromatic Compounds, Method for the Production Thereof, and Use Thereof 有权
标题翻译：芳基或杂芳族化合物的缩聚产物，其生产方法及其用途
公开(公告)号：US20080108732A1
公开(公告)日：2008-05-08
申请号：US11665424
申请日：2005-10-14
申请人： Philipp Wieland , Alexander Kraus , Gerhard Albrecht , Kerstin Becher , Harald Grassl
发明人： Philipp Wieland , Alexander Kraus , Gerhard Albrecht , Kerstin Becher , Harald Grassl
IPC分类号： C08K3/26
CPC分类号： C08G12/40 , C04B24/243 , C04B24/30 , C04B24/32 , C04B2103/30 , C08G8/28
摘要： Disclosed is a polycondensation product comprising A) an aromatic or heteroaromatic compound containing 5 to 10 C atoms or heteroatoms, said compound being provided with an average of 1 to 300 oxyethylene groups and/or oxypropylene groups per molecule which are linked to the aromatic or heteroaromatic compound via an O atom or N atom, and optionally B) an aromatic compound selected among the group comprising phenols, phenol ether, naphthols, naphthol ether, anilines, furfuryl alcohols, and/or an aminoplast former selected among the group comprising melamine (derivatives), urea (derivatives), and carboxylic acid amides, and C) an aldehyde selected among the group comprising formaldehyde, glyoxylic acid, and benzaldehyde or mixtures thereof, the benzaldehyde optionally containing acid groups in the form of COOMa, SO3Ma, and PO3Ma, wherein M=H, akali metal or alkaline earth metal, ammonium, or organic amine radicals and a=½, 1, or 2. Surprisingly, the inventive polycondensation product causes very good liquefaction of hydraulic binding agents, e.g. cement, resulting in substantially improved liquefaction of the construction material at a lower dose while pourability can be maintained over a longer period of time as opposed to naphthalene sulfonates or melamine sulfonates.
摘要翻译：公开了一种缩聚产物，其包含A）含有5至10个C原子的芳族或杂芳族化合物或杂原子，所述化合物每分子平均提供1至300个氧化乙烯基团和/或氧代丙烯基团，其与芳族或杂芳族化合物通过O原子或N原子的化合物，以及任选地B）选自苯酚，酚醚，萘酚，萘酚醚，苯胺，糠醇和/或选自三聚氰胺（衍生物）），脲（衍生物）和羧酸酰胺，和C）选自包括甲醛，乙醛酸和苯甲醛或其混合物的组中的醛，所述苯甲醛任选地含有COOM的形式的酸基，其中M = H，碱金属或碱土金属，或者其中M = H，碱金属或碱土金属，铵或有机胺基，a =½，1或2。令人惊奇的是，本发明的缩聚产物导致非常好的液压粘合剂的液化，例如水泥，导致较低剂量的建筑材料的液化显着改善，而与萘磺酸盐或三聚氰胺磺酸盐相比，可以在更长的时间内保持可倾倒性。

5. 发明授权

US08835535B2 Aqueous dispersions of silica for increasing early strength in cementitious preparations 有权
标题翻译：二氧化硅水分散体，用于增加水泥制剂中的早期强度
公开(公告)号：US08835535B2
公开(公告)日：2014-09-16
申请号：US12446333
申请日：2007-10-16
申请人： Ulrich Fischer , Philipp Wieland , Christian Huebsch , Harald Grassl , Kerstin Becher , Stefanie Scheul , Eva Jetzlsperger
发明人： Ulrich Fischer , Philipp Wieland , Christian Huebsch , Harald Grassl , Kerstin Becher , Stefanie Scheul , Eva Jetzlsperger
IPC分类号： C08J3/00 , C04B14/06 , C04B40/00
CPC分类号： C04B14/062 , C04B40/0039 , C04B24/2647 , C04B14/04
摘要： Dispersion which is free of binders and which contains silica and at least one superplasticizer, the silica being a precipitated silica having a surface area greater than 50 m2/g, the aggregates and/or agglomerates in the dispersion having a median diameter of less than 1 μm and the proportion of silica being from 5 to 50% by weight, based on the total amount of the dispersion, and a process for the preparation thereof and the use thereof as a concrete admixture in cement-containing preparations.
摘要翻译：不含粘合剂并且含有二氧化硅和至少一种超增塑剂的分散体，二氧化硅是表面积大于50m 2 / g的沉淀二氧化硅，分散体中的聚集体和/或附聚物的中值直径小于1 μm，二氧化硅的比例为5〜50重量％，基于分散体的总量，其制备方法及其作为混凝土外加剂在水泥制剂中的用途。

6. 发明申请

US20100324173A1 AQUEOUS DISPERSIONS OF SILICA FOR INCREASING EARLY STRENGTH IN CEMENTITIOUS PREPARATIONS 有权
标题翻译：二氧化硅的水分散度在生化准备中提高早期强度
公开(公告)号：US20100324173A1
公开(公告)日：2010-12-23
申请号：US12446333
申请日：2007-10-16
申请人： Ulrich Fischer , Philipp Wieland , Christian Huebsch , Harald Grassl , Kerstin Becher , Stefanie Scheul , Eva Jetzlsperger
发明人： Ulrich Fischer , Philipp Wieland , Christian Huebsch , Harald Grassl , Kerstin Becher , Stefanie Scheul , Eva Jetzlsperger
IPC分类号： C04B24/26 , C08J3/22 , C08K3/36 , C08L33/10
CPC分类号： C04B14/062 , C04B40/0039 , C04B24/2647 , C04B14/04
摘要： Dispersion which is free of binders and which contains silica and at least one superplasticizer, the silica being a precipitated silica having a surface area greater than 50 m2/g, the aggregates and/or agglomerates in the dispersion having a median diameter of less than 1 μm and the proportion of silica being from 5 to 50% by weight, based on the total amount of the dispersion, and a process for the preparation thereof and the use thereof as a concrete admixture in cement-containing preparations.
摘要翻译：不含粘合剂并且含有二氧化硅和至少一种超增塑剂的分散体，二氧化硅是表面积大于50m 2 / g的沉淀二氧化硅，分散体中的聚集体和/或附聚物的中值直径小于1 μm，二氧化硅的比例为5〜50重量％，基于分散体的总量，其制备方法及其作为混凝土外加剂在水泥制剂中的用途。

7. 发明申请

US20110313083A1 Two-component mortar compound and its use 有权
标题翻译：双组份砂浆化合物及其用途
公开(公告)号：US20110313083A1
公开(公告)日：2011-12-22
申请号：US12932305
申请日：2011-02-23
申请人： Philipp Wieland
发明人： Philipp Wieland
IPC分类号： C04B24/24
CPC分类号： C04B28/02 , C04B40/065 , C04B2111/00715 , C04B14/06 , C04B14/066 , C04B22/0013 , C04B24/282 , C04B14/303 , C04B22/068 , C04B14/042 , C04B14/10 , C04B14/22 , C04B14/28 , C04B22/06 , C04B22/08 , C04B22/124 , C04B22/165 , C04B24/281 , C04B40/0658 , C04B2103/44
摘要： A two-component mortar compound including a curable resin component (A) that contains 30% to 45% by weight of at least one radically polymerizable resin, 30% to 45% by weight of fillers, 15% to 25% by weight of cement and 1% to 8% of a thickeners, and including a separately arranged so as to inhibit reaction curing component (B) that contains 1% to 20% by weight of a peroxide, 10% to 35% by weight of water, 40% to 80% by weight of fillers and 0.5% to 5% by weight of thickeners, with the proviso that the sum of the quantities of the constituents of the resin component or of the curing component is always 100% by weight, which is characterized in that the resin component (A) contains 0.01% to 5% by weight of an organic and/or inorganic acid and/or salts and esters thereof, and the invention also describes its use to fasten anchoring means into drilled holes in mineral substrates by means of the chemical reaction of the resin component (A) with the curing component (B).
摘要翻译：包含含有30重量％至45重量％的至少一种可自由基聚合树脂，30重量％至45重量％的填料，15重量％至25重量％的水泥的可固化树脂组分（A）的双组分砂浆化合物和1％至8％的增稠剂，并且包括单独布置以便抑制含有1重量％至20重量％的过氧化物，10重量％至35重量％的水，40重量％的反应固化组分（B）至80重量％的填料和0.5重量％至5重量％的增稠剂，条件是树脂组分或固化组分的组分的总量总计为100重量％，其特征在于树脂组分（A）含有0.01重量％至5重量％的有机和/或无机酸和/或其盐和酯，本发明还描述了其用于将锚固装置固定在矿物基底中的钻孔中，的树脂组分（A）与固化组分（B）的化学反应。

8. 发明授权

US08304474B2 Two-component mortar compound and its use 有权
标题翻译：双组份砂浆化合物及其用途
公开(公告)号：US08304474B2
公开(公告)日：2012-11-06
申请号：US12932305
申请日：2011-02-23
申请人： Philipp Wieland
发明人： Philipp Wieland
IPC分类号： C08K3/00 , C08K3/34
CPC分类号： C04B28/02 , C04B40/065 , C04B2111/00715 , C04B14/06 , C04B14/066 , C04B22/0013 , C04B24/282 , C04B14/303 , C04B22/068 , C04B14/042 , C04B14/10 , C04B14/22 , C04B14/28 , C04B22/06 , C04B22/08 , C04B22/124 , C04B22/165 , C04B24/281 , C04B40/0658 , C04B2103/44
摘要： A two-component mortar compound including a curable resin component (A) that contains 30% to 45% by weight of at least one radically polymerizable resin, 30% to 45% by weight of fillers, 15% to 25% by weight of cement and 1% to 8% of a thickeners, and including a separately arranged so as to inhibit reaction curing component (B) that contains 1% to 20% by weight of a peroxide, 10% to 35% by weight of water, 40% to 80% by weight of fillers and 0.5% to 5% by weight of thickeners, with the proviso that the sum of the quantities of the constituents of the resin component or of the curing component is always 100% by weight, which is characterized in that the resin component (A) contains 0.01% to 5% by weight of an organic and/or inorganic acid and/or salts and esters thereof.
摘要翻译：包含含有30重量％至45重量％的至少一种可自由基聚合树脂，30重量％至45重量％的填料，15重量％至25重量％的水泥的可固化树脂组分（A）的双组分砂浆化合物和1％至8％的增稠剂，并且包括单独布置以便抑制含有1重量％至20重量％的过氧化物，10重量％至35重量％的水，40重量％的反应固化组分（B）至80重量％的填料和0.5重量％至5重量％的增稠剂，条件是树脂组分或固化组分的组分的总量总计为100重量％，其特征在于树脂组分（A）含有0.01重量％至5重量％的有机和/或无机酸和/或其盐和酯。

9. 发明授权

US06790909B2 Graft copolymers, their preparation and their use 失效
标题翻译：接枝共聚物，它们的制备及其用途
公开(公告)号：US06790909B2
公开(公告)日：2004-09-14
申请号：US10617860
申请日：2003-07-14
申请人： Yvonne Heischkel , Nicolas Stöckel , Philipp Wieland , Marcus Schäfer , Oskar Nuyken
发明人： Yvonne Heischkel , Nicolas Stöckel , Philipp Wieland , Marcus Schäfer , Oskar Nuyken
IPC分类号： C08G8102
CPC分类号： C09J151/006 , C08F212/32 , C08F287/00 , C08F293/005 , C08F297/00 , C08K5/01 , C08L51/006 , C09D151/006 , C08L51/00
摘要： The invention relates to a process for preparing a reaction product (RP) which is functionalized by groups containing halogen or sulfonyl chloride by reaction of at least one free-radically polymerizable monomer, at least one compound of the formula (I), at least one free-radical initiator and at least one free-radically polymerizable monomer containing halogen or sulfonyl chloride groups under free-radical conditions, and to a reaction product (RP) which can be prepared by the process of the present invention and to the use of the reaction product (RP) as macroinitiator for the preparation of graft copolymers. Furthermore the invention relates to a process for preparing graft copolymers by reaction of the reaction product (RP) with at least one suitable monomer and to graft copolymers which can be prepared by the process of the present invention and also to the use of the graft copolymers of the present invention.
摘要翻译：本发明涉及一种通过至少一种可自由基聚合的单体，至少一种式（I）化合物，至少一种可自由基聚合的单体，至少一种自由基引发剂和在自由基条件下含有卤素或磺酰氯基团的至少一种可自由基聚合的单体，以及可通过本发明的方法制备的反应产物（RP）反应产物（RP）作为制备接枝共聚物的大分子引发剂。此外，本发明涉及通过反应产物（RP）与至少一种合适的单体反应制备接枝共聚物的方法以及可通过本发明的方法制备的接枝共聚物，以及使用接枝共聚物的本发明。

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