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    • 10. 发明授权
    • Filament winding compositions for fiber/resin composites
    • 纤维/树脂复合材料的丝卷绕组合物
    • US5585414A
    • 1996-12-17
    • US478893
    • 1995-06-07
    • Philip T. KlemarczykYoshihisa OkamotoJames P. Moran, Jr.
    • Philip T. KlemarczykYoshihisa OkamotoJames P. Moran, Jr.
    • C08F2/50C08F283/10C08J3/24C08J5/04B29C35/10C08L63/00
    • C08J5/24C08F283/10C08J3/243C08J5/04C08J2363/00Y10T428/1314Y10T428/1321Y10T428/1362Y10T428/1369Y10T428/2936
    • Resin compositions useful for filament winding applications comprising an epoxy component including at least one polyepoxide resin curable by heat, an olefinicially unsaturated monomer component including at least one polyolefinically unsaturated monomer curable by actinic radiation, at least one photoinitiator, at least one organic peroxide, and a heat activated curing agent for epoxides. The compositions have a viscosity less than about 2000 centipoise (cps) and are capable of retaining this viscosity for at least about 2 hours at a temperature of from about ambient temperature to about 60.degree. C. The resins are capable of being immobilized by actinic radiation exposure and further heat cured without substantial resin drip. One or more organic peroxides are employed, selected from the group of organic peroxides having 10 hour decomposition half lives at temperatures of from about 50.degree. C. to less than about 104.degree. C. Also, fiber resin composites comprising fiber substrates impregnated with the dual-curing resin compositions. Also the process for coating fiber substrates with the dual-curing resin compositions is disclosed.
    • 用于长丝缠绕应用的树脂组合物包括包含至少一种可热固化的聚环氧树脂的环氧组分,包含至少一种可通过光化辐射固化的聚烯烃不饱和单体的烯属不饱和单体组分,至少一种光引发剂,至少一种有机过氧化物和 用于环氧化物的热活化固化剂。 该组合物的粘度小于约2000厘泊(cps),并且能够在约环境温度至约60℃的温度下保持该粘度至少约2小时。树脂能够通过光化辐射固定 暴露并进一步加热固化,而没有实质的树脂滴落。 使用一种或多种有机过氧化物,选自在约50℃至小于约104℃的温度下具有10分钟分解半衰期的有机过氧化物。此外,包含浸渍有双重的纤维基材的纤维树脂复合材料 固化树脂组合物。 还公开了用双重固化树脂组合物涂布纤维基材的方法。