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1. 发明申请

US20110257334A1 Switchable Hydrophilicity Solvents and Methods of Use Thereof 有权
标题翻译：可切换的亲水性溶剂及其使用方法
公开(公告)号：US20110257334A1
公开(公告)日：2011-10-20
申请号：US12914948
申请日：2010-10-28
申请人： Philip G. Jessop , Lam N. Phan , Andrew J. Carrier , Rui Resendes , Dominik Wechsler
发明人： Philip G. Jessop , Lam N. Phan , Andrew J. Carrier , Rui Resendes , Dominik Wechsler
IPC分类号： C08F112/08 , B01D11/00 , B01J19/00 , C08L101/00 , B01D11/04 , C07C257/10 , C07C211/09 , C07C211/01 , C02F1/26 , B08B3/08
CPC分类号： C08K5/17 , B01D11/0492 , C07C257/14 , C08J11/08 , C08J2325/06 , C10G1/04 , C10G2300/1011 , C10G2300/44 , C11D3/30 , C11D3/43 , Y02P30/20 , Y02W30/701 , Y10S516/924
摘要： A solvent that reversibly converts from a hydrophobic liquid form to hydrophilic liquid form upon contact with water and a selected trigger, e.g., contact with CO2, is described. The hydrophilic liquid form is readily converted back to the hydrophobic liquid form and water. The hydrophobic liquid is an amidine or amine. The hydrophilic liquid form comprises an amidinium salt or an ammonium salt.
摘要翻译：描述了当与水接触并且选择的触发器例如与CO 2接触时可逆地从疏水性液体形式转化为亲水性液体的溶剂。亲水性液体形式容易转化回疏水性液体形式和水。疏水性液体是脒或胺。亲水性液体形式包括脒鎓盐或铵盐。

2. 发明授权

US08580124B2 Switchable hydrophilicity solvents and methods of use thereof 有权
标题翻译：可切换的亲水溶剂及其使用方法
公开(公告)号：US08580124B2
公开(公告)日：2013-11-12
申请号：US12914948
申请日：2010-10-28
申请人： Philip G. Jessop , Lam N. Phan , Andrew J. Carrier , Rui Resendes , Dominik Wechsler
发明人： Philip G. Jessop , Lam N. Phan , Andrew J. Carrier , Rui Resendes , Dominik Wechsler
IPC分类号： C02F1/20
CPC分类号： C08K5/17 , B01D11/0492 , C07C257/14 , C08J11/08 , C08J2325/06 , C10G1/04 , C10G2300/1011 , C10G2300/44 , C11D3/30 , C11D3/43 , Y02P30/20 , Y02W30/701 , Y10S516/924
摘要： A solvent that reversibly converts from a hydrophobic liquid form to hydrophilic liquid form upon contact with water and a selected trigger, e.g., contact with CO2, is described. The hydrophilic liquid form is readily converted back to the hydrophobic liquid form and water. The hydrophobic liquid is an amidine or amine. The hydrophilic liquid form comprises an amidinium salt or an ammonium salt.
摘要翻译：描述了当与水接触并且选择的触发器例如与CO 2接触时可逆地从疏水性液体形式转化为亲水性液体的溶剂。亲水性液体形式容易转化回疏水性液体形式和水。疏水性液体是脒或胺。亲水性液体形式包括脒鎓盐或铵盐。

3. 发明申请

US20140076810A1 Systems and Methods for Use of Water with Switchable Ionic Strength 审中-公开
标题翻译：使用水可切换离子强度的系统和方法
公开(公告)号：US20140076810A1
公开(公告)日：2014-03-20
申请号：US13993890
申请日：2011-12-15
申请人： Philip G. Jessop , Sean M. Mercer , Tobias Robert , R. Stephen Brown , Timothy James Clark , Brian Ernest Mariampillai , Rui Resendes , Dominik Wechsler
发明人： Philip G. Jessop , Sean M. Mercer , Tobias Robert , R. Stephen Brown , Timothy James Clark , Brian Ernest Mariampillai , Rui Resendes , Dominik Wechsler
IPC分类号： C02F1/68 , C02F1/44
CPC分类号： C02F1/68 , B01D61/002 , B01D61/005 , B01D61/025 , B01D61/027 , B01D61/58 , C02F1/001 , C02F1/26 , C02F1/38 , C02F1/44 , C02F1/441 , C02F1/442 , C02F1/445 , C02F1/52 , C02F1/5236 , C02F1/5272 , C02F1/682 , C02F2101/10 , C02F2101/32 , C02F2101/325 , C02F2103/001 , C02F2103/08 , C02F2103/10 , C02F2103/365 , C02F2209/05 , C02F2209/09 , C02F2303/12 , C02F2303/16 , C02F2305/14 , C08F8/32 , C08F22/14 , Y02A20/128 , Y02A20/131
摘要： Methods and systems for use of switchable water, which is capable of reversibly switching between an initial ionic strength and an increased ionic strength, is described. The disclosed methods and systems can be used, for example, in distillation-free removal of water from solvents, solutes, or solutions, desalination, clay settling, viscosity switching, etc. Switching from lower to higher ionic strength is readily achieved using low energy methods such as bubbling with C02, CS2 or COS or treatment with Bronsted acids. Switching from higher to lower ionic strength is readily achieved using low energy methods such as bubbling with air, inert gas, heating, agitating, introducing a vacuum or partial vacuum, or any combination or thereof.
摘要翻译：描述了使用可切换水的方法和系统，其能够在初始离子强度和增加的离子强度之间可逆地切换。所公开的方法和系统可以用于例如从溶剂，溶质或溶液中蒸馏除去水，脱盐，粘土沉降，粘度转换等。使用低能量容易地实现从较低离子强度到较高离子强度的切换方法如用CO 2，CS 2或COS鼓泡或用布朗斯台德酸处理。使用低能量方法（例如用空气鼓泡，惰性气体，加热，搅拌，引入真空或部分真空或其任何组合）容易地实现从较高离子强度到较低离子强度的切换。

4. 发明授权

US10377647B2 Systems and methods for use of water with switchable ionic strength 有权
公开(公告)号：US10377647B2
公开(公告)日：2019-08-13
申请号：US13993890
申请日：2011-12-15
申请人： Philip G. Jessop , Sean M. Mercer , Tobias Robert , R. Stephen Brown , Timothy James Clark , Brian Ernest Mariampillai , Rui Resendes , Dominik Wechsler
发明人： Philip G. Jessop , Sean M. Mercer , Tobias Robert , R. Stephen Brown , Timothy James Clark , Brian Ernest Mariampillai , Rui Resendes , Dominik Wechsler
IPC分类号： B01D39/00 , B01D61/00 , C02F1/68 , C02F1/26 , C02F1/44 , C02F1/52 , C08F8/32 , C08F22/14 , B01D61/58 , C02F1/00 , C02F1/38 , C02F101/10 , C02F101/32 , C02F103/00 , C02F103/08 , C02F103/10 , C02F103/36 , B01D61/02
摘要： Methods and systems for use of switchable water, which is capable of reversibly switching between an initial ionic strength and an increased ionic strength, is described. The disclosed methods and systems can be used, for example, in distillation-free removal of water from solvents, solutes, or solutions, desalination, clay settling, viscosity switching, etc. Switching from lower to higher ionic strength is readily achieved using low energy methods such as bubbling with C02, CS2 or COS or treatment with Bronsted acids. Switching from higher to lower ionic strength is readily achieved using low energy methods such as bubbling with air, inert gas, heating, agitating, introducing a vacuum or partial vacuum, or any combination or thereof.

5. 发明申请

US20110274994A1 Catalyst and Liquid Combination for a Thermally Regenerative Fuel Cell 审中-公开
标题翻译：催化剂和液体组合用于热再生燃料电池
公开(公告)号：US20110274994A1
公开(公告)日：2011-11-10
申请号：US13102840
申请日：2011-05-06
申请人： Andrew J. Carrier , Boyd R. Davis , Philip G. Jessop , Keith Hao-Kiet Huynh
发明人： Andrew J. Carrier , Boyd R. Davis , Philip G. Jessop , Keith Hao-Kiet Huynh
IPC分类号： H01M8/18 , C01B3/32
CPC分类号： C01B3/22 , C01B2203/0277 , C01B2203/1217 , C01B2203/84 , H01M8/182 , Y02E60/528 , Y02P20/129
摘要： Combinations of catalyst and compound are described that are suitable for use in a thermally regenerative fuel cell. Such combinations offer greater than 99% selectivity and accordingly they cycle through a reversible dehydrogenation process with substantially no loss due to byproduct formation. Combinations of secondary benzylic alcohols and Pd/SiO2 catalysts offer levels of by-products that are undetectable by NMR and GC analysis. With such TRFC, thermal energy can be converted into electric energy in a moving vehicle without the requirement of storage of H2, and its safety issues. Instead, a catalytic amount of H2 is cycled through the system and used to generate electric energy.
摘要翻译：描述了适用于热再生燃料电池的催化剂和化合物的组合。这样的组合提供大于99％的选择性，因此它们循环通过可逆脱氢过程，由于副产物形成基本上没有损失。二级苄醇和Pd / SiO2催化剂的组合提供了通过NMR和GC分析检测不到的副产物水平。使用这种TRFC，热能可以在移动的车辆中转化为电能，而不需要储存H2及其安全问题。相反，催化量的H 2循环通过该系统并用于产生电能。

6. 发明授权

US07982069B2 Switchable solvents and methods of use thereof 有权
标题翻译：可切换溶剂及其使用方法
公开(公告)号：US07982069B2
公开(公告)日：2011-07-19
申请号：US11717172
申请日：2007-03-13
申请人： Philip G. Jessop , Charles A. Eckert , Charles L. Liotta , David J. Heldebrant
发明人： Philip G. Jessop , Charles A. Eckert , Charles L. Liotta , David J. Heldebrant
IPC分类号： C07C279/00
CPC分类号： B01D11/0492 , B01D17/047 , B01D17/048 , C07B63/00
摘要： A solvent that reversibly converts from a nonionic liquid mixture to an ionic liquid upon contact with a selected trigger, e.g., contact with CO2, is described. In preferred embodiments, the ionic solvent is readily converted back to the nonionic liquid mixture. The nonionic liquid mixture includes an amidine or guanidine or both, and water, alcohol, or a combination thereof. Single component amine solvents that reversibly convert between ionic and non-ionic states are also described. Some embodiments require increased pressure to convert; others convert at 1 atmosphere.
摘要翻译：描述了当与所选择的触发器接触时，从非离子液体混合物可逆地转化为离子液体的溶剂，例如与CO 2接触。在优选的实施方案中，离子溶剂容易转化回非离子液体混合物。非离子液体混合物包括脒或胍或二者，以及水，醇或它们的组合。还描述了在离子和非离子状态之间可逆转化的单组分胺溶剂。一些实施例需要增加的压力来转换; 其他人转换为1个大气。

7. 发明申请

US20130087072A1 Reversibly Switchable Surfactants and Methods of Use Thereof 审中-公开
标题翻译：可逆切换表面活性剂及其使用方法
公开(公告)号：US20130087072A1
公开(公告)日：2013-04-11
申请号：US13616900
申请日：2012-09-14
申请人： Philip G. Jessop
发明人： Philip G. Jessop
IPC分类号： C08K5/29
CPC分类号： C08K5/29 , B01D17/047 , B01D21/01 , B01F17/0042 , B03D1/01 , C07B63/02 , C07C257/14 , C08F2/24 , Y02W10/37
摘要： Reversible switchable surfactants are provided. A surfactant is the salt of an amidine or guanidine having at least one R group that is a hydrophobic moiety selected from the group consisting of higher aliphatic moiety, higher siloxyl moiety, higher aliphatic/siloxyl moiety, aliphatic/aryl moiety, siloxyl/aryl moiety, and aliphatic/siloxyl/aryl moiety. The other R groups are smaller moieties such as H, C1 to C4 aliphatic or the like. The surfactant is turned on by a gas that liberates hydrogen ions, such as, for example, carbon dioxide, which liberates hydrogen ions in the presence of water. The surfactant is turned off by exposure to a flushing gas and/or heating. When “on” the surfactants are useful to stabilize emulsions, and when “off” they are useful to separate immiscible liquids or a liquid and a solid. The surfactants find uses in polymerization and in the oil industry.
摘要翻译：提供可逆切换表面活性剂。表面活性剂是具有至少一个R基团的脒或胍的盐，所述R基团是选自高级脂族部分，高级甲硅烷氧基部分，高级脂族/甲硅烷氧基部分，脂族/芳基部分，硅氧烷/芳基部分，和脂族/硅氧基/芳基部分。其它R基团是较小的部分，例如H，C 1至C 4脂族基等。表面活性剂通过释放氢离子的气体导通，例如二氧化碳，二氧化碳在水存在下释放出氢离子。通过暴露于冲洗气体和/或加热来关闭表面活性剂。当表面活性剂可用于稳定乳液时，并且当它们脱离时它们可用于分离不混溶的液体或液体和固体。表面活性剂用于聚合和石油工业。

8. 发明授权

US08283385B2 Reversibly switchable surfactants and methods of use thereof 有权
标题翻译：可逆切换的表面活性剂及其使用方法
公开(公告)号：US08283385B2
公开(公告)日：2012-10-09
申请号：US11599623
申请日：2006-11-15
申请人： Philip G. Jessop
发明人： Philip G. Jessop
IPC分类号： B01F17/16 , B01F17/04 , B01F17/22 , B01F3/08 , C07B63/02 , B01D17/04 , B01D17/05 , C07C257/10 , C07C279/02 , C07D233/06 , C07D239/06 , C07F7/10 , C08F2/22 , C08F2/32
CPC分类号： C08K5/29 , B01D17/047 , B01D21/01 , B01F17/0042 , B03D1/01 , C07B63/02 , C07C257/14 , C08F2/24 , Y02W10/37
摘要： Reversible switchable surfactants are provided. A surfactant is the salt of an amidine or guanidine: having at least one R group that is a hydrophobic moiety selected from the group consisting of higher aliphatic moiety, higher siloxyl moiety, higher aliphatic/siloxyl moiety, aliphatic/aryl moiety, siloxyl/aryl moiety, and aliphatic/siloxyl/aryl moiety. The other R groups are smaller moieties such as H, C1 to C4 aliphatic or the like. The surfactant is turned on by a gas that liberates hydrogen ions, such as, for example, carbon dioxide, which liberates hydrogen ions in the presence of water. The surfactant is turned off by exposure to a flushing gas and/or heating. When “on” the surfactants are useful to stabilize emulsions, and when “off” they are useful to separate immiscible liquids or a liquid and a solid. The surfactants find uses in polymerization and in the oil industry.
摘要翻译：提供可逆切换表面活性剂。表面活性剂是脒或胍的盐：具有至少一个R基团，其是疏水部分，其选自高级脂族部分，高级甲硅烷氧基部分，高级脂族/硅氧烷基部分，脂族/芳基部分，硅氧烷/芳基部分和脂肪族/酪醇酰/芳基部分。其它R基团是较小的部分，例如H，C 1至C 4脂族基等。表面活性剂通过释放氢离子的气体导通，例如二氧化碳，二氧化碳在水存在下释放出氢离子。通过暴露于冲洗气体和/或加热来关闭表面活性剂。当表面活性剂可用于稳定乳液时，并且当它们脱离时它们可用于分离不混溶的液体或液体和固体。表面活性剂用于聚合和石油工业。

9. 发明授权

US08513464B2 Switchable solvents and methods of use thereof 有权
标题翻译：可切换溶剂及其使用方法
公开(公告)号：US08513464B2
公开(公告)日：2013-08-20
申请号：US13172090
申请日：2011-06-29
申请人： Philip G. Jessop , Charles A. Eckert , Charles L. Liotta , David J. Heldebrant
发明人： Philip G. Jessop , Charles A. Eckert , Charles L. Liotta , David J. Heldebrant
IPC分类号： C07C257/00
CPC分类号： B01D11/0492 , B01D17/047 , B01D17/048 , C07B63/00
摘要： A solvent that reversibly converts from a nonionic liquid mixture to an ionic liquid upon contact with a selected trigger, e.g., contact with CO2, is described. In preferred embodiments, the ionic solvent is readily converted back to the nonionic liquid mixture. The nonionic liquid mixture includes an amidine or guanidine or both, and water, alcohol, or a combination thereof. Single component amine solvents that reversibly convert between ionic and non-ionic states are also described. Some embodiments require increased pressure to convert; others convert at 1 atmosphere.
摘要翻译：描述了当与所选择的触发器接触时，从非离子液体混合物可逆地转化为离子液体的溶剂，例如与CO 2接触。在优选的实施方案中，离子溶剂容易转化回非离子液体混合物。非离子液体混合物包括脒或胍或二者，以及水，醇或它们的组合。还描述了在离子和非离子状态之间可逆转化的单组分胺溶剂。一些实施例需要增加的压力来转换; 其他人转换为1个大气。

10. 发明申请

US20130105377A1 Water with Switchable Ionic Strength 审中-公开
标题翻译：水可切换离子强度
公开(公告)号：US20130105377A1
公开(公告)日：2013-05-02
申请号：US13578290
申请日：2011-02-10
申请人： Philip G. Jessop , Sean M. Mercer , R. Stephen Brown , Tobias Robert
发明人： Philip G. Jessop , Sean M. Mercer , R. Stephen Brown , Tobias Robert
IPC分类号： C02F1/44
摘要： A method and system for reversibly converting water between an initial ionic strength and an increased ionic strength, using a switchable additive, is described. The disclosed method and system can be used, for example, in distillation-free removal of water from solvents, solutes, or solutions. Following extraction of a solute from a medium by dissolving it in water, the solute can then be isolated from the aqueous solution or “salted-out” by converting the water to a solution having an increased ionic strength. The solute then separates from the increased ionic strength solution as a separate phase. Once the solute is, for example, decanted off, the increased ionic strength aqueous solution can be converted back to water having its original ionic strength and reused. Switching from lower to higher ionic strength is readily achieved using low energy methods such as bubbling with CO2, CS2 or COS. Switching from higher to lower ionic strength is readily achieved using low energy methods such as bubbling with air, heating, agitating, introducing a vacuum or partial vacuum, or any combination or thereof.
摘要翻译：描述了使用可切换添加剂在初始离子强度和增加的离子强度之间可逆地转化水的方法和系统。所公开的方法和系统可以用于例如从溶剂，溶质或溶液中蒸馏除去水。在通过将溶解在水中从介质中提取溶质后，可以通过将水转化为具有增加的离子强度的溶液，从溶液中分离溶质或“盐析”。然后，溶质作为分离相与增加的离子强度溶液分离。例如，一旦溶质脱出，增加的离子强度水溶液可以转化回具有其原始离子强度的水并重复使用。使用低能量方法（例如用CO 2，CS 2或COS起泡）容易地实现从低到高的离子强度的切换。使用低能量方法容易地实现从较高离子强度到较低离子强度的切换，例如用空气鼓泡，加热，搅拌，引入真空或部分真空，或其任何组合。

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