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1. 发明授权

US5292931A Carrier catalyst, process for its preparation, and its use for the preparation of vinyl acetate 失效
标题翻译：载体催化剂，其制备方法及其用于制备乙酸乙烯酯的用途
公开(公告)号：US5292931A
公开(公告)日：1994-03-08
申请号：US44212
申请日：1993-04-07
申请人： Peter Wirtz , Karl-Fred Worner , Friedrich Wunder , Klaus Eichler , Gunter Roscher , Ioan Nicolau
发明人： Peter Wirtz , Karl-Fred Worner , Friedrich Wunder , Klaus Eichler , Gunter Roscher , Ioan Nicolau
IPC分类号： B01J23/44 , B01J23/06 , B01J23/48 , B01J23/52 , B01J23/58 , B01J23/60 , B01J23/66 , B01J23/89 , B01J35/10 , B01J37/00 , B01J37/02 , C07B61/00 , C07C67/05 , C07C67/055 , C07C69/15
CPC分类号： B01J37/0205 , B01J23/58 , B01J23/60 , C07C67/055
摘要： The invention relates to a process for the preparation of a catalyst which contains palladium and/or compounds thereof and alkali metal compounds, and additionally cadmium compounds and/or gold and/or compounds thereof, on support particles which have been pressed from SiO.sub.2 or an iO.sub.2 -Al.sub.2 O.sub.3 mixture with the aid of a binder which comprisesa) washing the roasted support particles with an acid which does not react with SiO.sub.2 or SiO.sub.2 -Al.sub.2 O.sub.3 mixtures, until no further cations of the binder employed during pressing of the support particles are released from the support particles;b) then impregnating the support particles with palladium, and gold or cadmium;c) then bringing the impregnated support particles into contact with a solution of a base at least until the thickness of the nobel metal shell generated in this way on the support particles no longer changes substantially; andd) then impregnating the support particles with an alkali metal compound.A shell-like distribution of the palladium and if appropriate of the gold in the support particles is generated in this manner.Furthermore, the invention relates to a catalyst prepared in this way and to its use for the preparation of vinyl acetate.
摘要翻译：本发明涉及一种制备催化剂的方法，该催化剂包含钯和/或其化合物和碱金属化合物，以及另外的镉化合物和/或金和/或其化合物，其在从SiO 2或 iO 2 -Al 2 O 3混合物，其包括a）用不与SiO 2或SiO 2 -Al 2 O 3混合物反应的酸洗涤焙烧的载体颗粒，直到在压制载体颗粒期间不再使用粘合剂的阳离子释放从支撑颗粒; b）然后用钯和金或镉浸渍载体颗粒; c）然后使浸渍的载体颗粒与碱的溶液接触，至少直到以这种方式在载体颗粒上产生的诺贝尔金属壳的厚度不再显着变化; 和d）然后用碱金属化合物浸渍载体颗粒。以这种方式产生钯的壳状分布和如果合适的支撑颗粒中的金。此外，本发明涉及以这种方式制备的催化剂及其用于制备乙酸乙烯酯的用途。

2. 发明授权

US5250487A Carrier catalyst, process for its preparation, and its use for the preparation of vinyl acetate 失效
标题翻译：载体催化剂，其制备方法及其用于制备乙酸乙烯酯的用途
公开(公告)号：US5250487A
公开(公告)日：1993-10-05
申请号：US900839
申请日：1992-06-18
申请人： Peter Wirtz , Karl-Fred Worner , Friedrich Wunder , Klaus Fichler , Gunter Roscher , Ioan Nicolau
发明人： Peter Wirtz , Karl-Fred Worner , Friedrich Wunder , Klaus Fichler , Gunter Roscher , Ioan Nicolau
IPC分类号： B01J23/44 , B01J23/06 , B01J23/48 , B01J23/52 , B01J23/58 , B01J23/60 , B01J23/66 , B01J23/89 , B01J35/10 , B01J37/00 , B01J37/02 , C07B61/00 , C07C67/05 , C07C67/055 , C07C69/15 , B01J37/06
CPC分类号： B01J37/0205 , B01J23/58 , B01J23/60 , C07C67/055
摘要： The invention relates to a process for the preparation of a catalyst which contains palladium and/or compounds thereof and alkali metal compounds, and additionally cadmium compounds and/or gold and/or compounds thereof, on support particles which have been pressed from SiO.sub.2 or an iO.sub.2 -Al.sub.2 O.sub.3 mixture with the aid of a binder which comprisesa) washing the roasted support particles with an acid which does not react with SiO.sub.2 or SiO.sub.2 -Al.sub.2 O.sub.3 mixtures, until no further cations of the binder employed during pressing of the support particles are released from the support particles;b) then impregnating the support particles with palladium, and gold or cadmium;c) then bringing the impregnated support particles into contact with a solution of a base at least until the thickness of the nobel metal shell generated in this way on the support particles no longer changes substantially; andd) then impregnating the support particles with an alkali metal compound.A shell-like distribution of the palladium and if appropriate of the gold in the support particles is generated in this manner.Furthermore, the invention relates to a catalyst prepared in this way and to its use for the preparation of vinyl acetate.
摘要翻译：本发明涉及一种制备催化剂的方法，该催化剂包含钯和/或其化合物和碱金属化合物，以及另外的镉化合物和/或金和/或其化合物，其在从SiO 2或 iO 2 -Al 2 O 3混合物，其包括a）用不与SiO 2或SiO 2 -Al 2 O 3混合物反应的酸洗涤焙烧的载体颗粒，直到在压制载体颗粒期间不再使用粘合剂的阳离子释放从支撑颗粒; b）然后用钯和金或镉浸渍载体颗粒; c）然后使浸渍的载体颗粒与碱的溶液接触，至少直到以这种方式在载体颗粒上产生的诺贝尔金属壳的厚度不再显着变化; 和d）然后用碱金属化合物浸渍载体颗粒。以这种方式产生钯的壳状分布和如果合适的支撑颗粒中的金。此外，本发明涉及以这种方式制备的催化剂及其用于制备乙酸乙烯酯的用途。

3. 发明授权

US5225388A Method for making a catalyst 失效
标题翻译：制造催化剂的方法
公开(公告)号：US5225388A
公开(公告)日：1993-07-06
申请号：US808443
申请日：1991-12-16
申请人： Friedrich Wunder , Peter Wirtz , Gunter Roscher , Klaus Eichler
发明人： Friedrich Wunder , Peter Wirtz , Gunter Roscher , Klaus Eichler
IPC分类号： B01J23/52 , B01J23/58 , B01J23/60 , B01J35/10 , C07C67/055
CPC分类号： C07C67/055 , B01J23/58 , B01J23/52 , B01J23/60 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/108
摘要： The invention relates to a method for making a catalyst which contains palladium and/or its compounds and, if desired, additionally gold and/or gold compounds and which contains as activators alkali metal compounds and, if desired, additionally cadmium compounds on a support which is composed of SiO.sub.2 or an SiO.sub.2 -Al.sub.2 O.sub.3 mixture having a surface area of 50-250 m.sup.2 /g and a pore volume of 0.4-1.2 ml/g and whose particles have a particle size of 4 to 9 mm, 5 to 20% of the pore volume of the support being formed of pores having radii of 200 to 3000 .ANG. and 50 to 90% of the pore volume being formed of pores having radii of 70 to 100 .ANG.. The support particles are compressed with the aid of an Li, Mg, Al, Zn or Mn salt of a C.sub.2 -C.sub.20 carboxylic acid or a mixture of such salts as binder.
摘要翻译：本发明涉及一种制备含有钯和/或其化合物的催化剂的方法，并且如果需要，还需要金和/或金化合物，并且其包含作为活化剂的碱金属化合物，并且如果需要，在载体上另外含有镉化合物由SiO 2或SiO 2 -Al 2 O 3混合物组成，其表面积为50-250m2 / g，孔体积为0.4-1.2ml / g，其颗粒的粒度为4〜9mm，5〜20％载体的孔体积由半径为200至3000的孔形成，孔体积的50至90％由半径为70至100的孔形成。借助于C2-C20羧酸的Li，Mg，Al，Zn或Mn盐或这些盐的混合物作为粘合剂，将载体颗粒压缩。

4. 发明授权

US5476963A Supported catalyst, process for its preparation and its use for the preparation of vinyl acetate 失效
标题翻译：负载催化剂，其制备方法及其用于制备乙酸乙烯酯的用途
公开(公告)号：US5476963A
公开(公告)日：1995-12-19
申请号：US394840
申请日：1995-02-27
申请人： Peter Wirtz , Friedrich Wunder , Karl-Fred Worner
发明人： Peter Wirtz , Friedrich Wunder , Karl-Fred Worner
IPC分类号： B01J23/58 , B01J23/60 , B01J23/66 , B01J37/02 , B01J37/34 , C07B61/00 , C07C67/055 , C07C69/15 , C07C67/05
CPC分类号： B01J37/343 , B01J23/58 , B01J23/60 , B01J23/66 , C07C67/055
摘要： Supported catalyst, process for its preparation and its use for the preparation of vinyl acetateThe invention relates to improved Pd/K/Au, Pd/K/Ba and Pd/K/Cd supported catalysts, their preparation and their use for the preparation of vinyl acetate from ethylene, acetic acid and oxygen in the gas phase. The stated catalysts are prepared by atomizing a solution of corresponding metal salts by means of ultrasonics and then applying them in such limited amounts and within such a limited time to the carrier particles, and beginning to dry them, so that the catalytically active metal salts cannot penetrate into the carrier particles as far as the core but only into a larger or smaller outer part.
摘要翻译：负载催化剂及其制备方法及其在制备乙酸乙烯酯中的应用本发明涉及改进的Pd / K / Au，Pd / K / Ba和Pd / K / Cd载体催化剂，其制备及其在制备来自乙烯的乙酸乙烯酯，乙酸和氧气在气相中。所述催化剂是通过用超声波雾化相应金属盐溶液制备的，然后以有限的量和在有限的时间内将它们施加到载体颗粒上，并开始将它们干燥，使得催化活性金属盐不能渗透到载体颗粒直到芯部，但仅进入更大或更小的外部部分。

5. 发明授权

US5422329A Supported catalyst, process for its preparation and its use for the preparation of vinyl acetate 失效
标题翻译：负载催化剂，其制备方法及其用于制备乙酸乙烯酯的用途
公开(公告)号：US5422329A
公开(公告)日：1995-06-06
申请号：US43567
申请日：1993-04-07
申请人： Peter Wirtz , Friedrich Wunder , Karl-Fred Worner
发明人： Peter Wirtz , Friedrich Wunder , Karl-Fred Worner
IPC分类号： B01J23/58 , B01J23/60 , B01J23/66 , B01J37/02 , B01J37/34 , C07B61/00 , C07C67/055 , C07C69/15 , B01J23/04 , B01J23/06 , B01J23/44
CPC分类号： B01J37/343 , B01J23/58 , B01J23/60 , B01J23/66 , C07C67/055
摘要： The invention relates to improved Pd/K/Au, Pd/K/Ba and Pd/K/Cd supported catalysts, their preparation and their use for the preparation of vinyl acetate from ethylene, acetic acid and oxygen in the gas phase. The stated catalysts are prepared by atomizing a solution of corresponding metal salts by means of ultrasonics and then applying them in such limited amounts and within such a limited time to the carrier particles, and beginning to dry them, so that the catalytically active metal salts cannot penetrate into the carrier particles as far as the core but only into a larger or smaller outer part.
摘要翻译：本发明涉及改进的Pd / K / Au，Pd / K / Ba和Pd / K / Cd载体催化剂，它们的制备及其在气相中由乙烯，乙酸和氧气制备乙酸乙烯酯的用途。所述催化剂是通过用超声波雾化相应金属盐溶液制备的，然后以有限的量和在有限的时间内将它们施加到载体颗粒上，并开始将它们干燥，使得催化活性金属盐不能渗透到载体颗粒直到芯部，但仅进入更大或更小的外部部分。

6. 发明授权

US08841424B2 Humanized AXL antibodies 有权
标题翻译：人源化AXL抗体
公开(公告)号：US08841424B2
公开(公告)日：2014-09-23
申请号：US13320060
申请日：2010-05-11
申请人： Peter Wirtz , Jens Ruhe , Takeshi Takizawa , Tomoko Takayama
发明人： Peter Wirtz , Jens Ruhe , Takeshi Takizawa , Tomoko Takayama
IPC分类号： C07K16/40 , C07K16/00 , A61K39/395
CPC分类号： C07K16/40 , A61K39/3955 , A61K2039/505 , C07K16/2863 , C07K2317/24 , C07K2317/30 , C07K2317/56 , C07K2317/565 , C07K2317/73 , C07K2317/77 , C07K2317/92 , G01N33/573
摘要： The present invention refers to monoclonal humanized antibodies, which bind to the extracellular domain of the AXL receptor tyrosine kinase and which at least partially inhibit AXL activity.
摘要翻译：本发明涉及与AXL受体酪氨酸激酶的细胞外结构域结合并且至少部分抑制AXL活性的单克隆人源化抗体。

7. 发明授权

US5303601A Torque wrench 失效
标题翻译：扭力扳手
公开(公告)号：US5303601A
公开(公告)日：1994-04-19
申请号：US806903
申请日：1991-12-12
申请人： Heinz Schonberger , Frank Humme , Peter Wirtz
发明人： Heinz Schonberger , Frank Humme , Peter Wirtz
IPC分类号： B25B23/142 , B25B23/144 , G01L5/00
CPC分类号： B25B23/1425
摘要： The present invention relates to a torque wrench (1, 2) having an electronic measuring device which detects a prevailing torque by means of strain gauges, having a memory for the storing of measured values and an indicating device which indicates the minimum and maximum values reached by means of light-emitting diodes (5, 6, 7) of different color. In order to be able to use the torque wrench advantageously, in particular in routine work where the precise maintaining of a torque is of importance, the invention proposes that a measured value be stored by actuating an actuating button (8) which also serves to activate the torque wrench (1, 2).
摘要翻译：本发明涉及一种具有电子测量装置的扭矩扳手（1,2），该电子测量装置通过应变计检测主要扭矩，具有用于存储测量值的存储器和指示达到的最小值和最大值的指示装置通过不同颜色的发光二极管（5,6,7）。为了能够有利地使用扭矩扳手，特别是在转矩的精确维持是重要的日常工作中，本发明提出通过致动执行按钮（8）来存储测量值，该致动按钮（8）也用于激活扭矩扳手（1,2）。

8. 发明授权

US5296027A Single-component alkali metal silicate cement composition 失效
标题翻译：单组分碱金属硅酸盐水泥组合物
公开(公告)号：US5296027A
公开(公告)日：1994-03-22
申请号：US8733
申请日：1993-01-25
申请人： Josef Ernst , Hans J. Semmler , Peter Wirtz
发明人： Josef Ernst , Hans J. Semmler , Peter Wirtz
IPC分类号： C04B22/16 , C04B28/26 , C09D1/02 , C09J1/02 , C04B12/02 , C04B12/04
CPC分类号： C04B22/16 , C04B28/26 , C09D1/02 , C09J1/02
摘要： The invention relates to a dry, surfactant-free single-component alkali metal silicate cement composition containing as hardening agent condensed aluminum phosphate and at least one compound from the group comprising the ortho- and pyrophosphates of manganese, zinc, cobalt, iron(III) and chromium(III) and in addition containing the conventional components rounded quartz sand, clay, kieselguhr, mineral oil and solid powdered sodium water glass or potassium water glass.
摘要翻译：本发明涉及一种干燥的无表面活性剂的单组分碱金属硅酸盐水泥组合物，其包含作为硬化剂的浓缩磷酸铝和至少一种包含锰，锌，钴，铁（III）的邻 - 和焦磷酸盐的化合物，和铬（III），另外含有常规成分为圆形石英砂，粘土，硅藻土，矿物油和固体粉末钠水玻璃或钾水玻璃。

9. 外观设计

USD274991S Electronic scale 失效
公开(公告)号：USD274991S
公开(公告)日：1984-08-07
申请号：US357871
申请日：1982-03-15
申请人： Peter Wirtz
设计人： Peter Wirtz

10. 发明授权

US4165313A Process for deodorizing foaming agents for the manufacture of air foams 失效
标题翻译：用于制造空气泡沫的除臭发泡剂的方法
公开(公告)号：US4165313A
公开(公告)日：1979-08-21
申请号：US792909
申请日：1977-05-02
申请人： Albert Schlegel , Peter Wirtz
发明人： Albert Schlegel , Peter Wirtz
IPC分类号： B01F17/30 , A62D1/00 , A62D1/02 , A23J1/10 , C07G7/06
CPC分类号： A62D1/0078
摘要： A process is disclosed for deodorizing protein hydrolysates which are used for making air foam. Protein is hydrolyzed by known methods in the absence of heavy metal salts. Then an epoxide is added until blackening occurs when a spot-test is carried out with lead acetate paper.
摘要翻译：公开了用于制造空气泡沫的蛋白质水解产物的除臭方法。在不存在重金属盐的情况下，蛋白质通过已知方法水解。然后加入环氧化物，直到当用乙酸铅纸进行点测试时发生黑化。

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