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1. 发明授权

US4613461A Process for preparing esters of thiolcarbamic acids 失效
标题翻译：制备硫代氨基甲酸酯的方法
公开(公告)号：US4613461A
公开(公告)日：1986-09-23
申请号：US687608
申请日：1984-12-31
申请人： Peter Viski , Laszlo Simandi , Ferenc Nagy , Gabor Besenyei , Gyorgy Paszthy , Gyula Pazmandi , Istvan Szita , Gyula Szilagyi , Istvan Toth , Ilona Szigeti nee Kiss
发明人： Peter Viski , Laszlo Simandi , Ferenc Nagy , Gabor Besenyei , Gyorgy Paszthy , Gyula Pazmandi , Istvan Szita , Gyula Szilagyi , Istvan Toth , Ilona Szigeti nee Kiss
IPC分类号： C07C333/02 , C07D211/60 , C07C153/00 , C07C154/00 , C07D207/00
CPC分类号： C07C333/02
摘要： The invention relates to a new process for preparing known thiolcarbamate esters of the general formula (I) ##STR1## wherein R.sup.1 and R.sup.2 stand independently for hydrogen or a straight or branched chain alkyl group containing 1 to 6 carbon atoms or an alkenyl group containing 2 to 6 atoms, or an alkyl group containing 1 to 6 or an alkenyl group containing 2 to 6 carbon atoms and mono- or polysubstituted by halogen, oxygen, sulphur and/or nitrogen; orR.sup.1 and R.sup.2 together may represent an optionally substituted .alpha.,.omega.-alkylene group containing 4 to 6 carbon atoms;R.sup.3 and R.sup.4 stand independently for hydrogen or an alkyl group containing 1 to 4 carbon atoms and optionally substituted by halogen or by a group containing oxygen, sulphur and/or nitrogen; andR.sup.5 and R.sup.6 both stand for hydrogen; orR.sup.5 and R.sup.6 together may represent a chemical bond.The compounds of general formula (I) are prepared by reacting(a) thiolcarbamate salts of the general formula (II) ##STR2## wherein the meanings of R.sup.1 and R.sup.2 are as defined above, andY stands for a primary, secondary or tertiary ammonium ion or an alkaline metal ion; or(b) amines of the general formula (III) ##STR3## wherein the meanings of R.sup.1 and R.sup.2 are as defined above, together with sulphur and carbon monoxide; or(c) amine of the general formula (III) together with carbonyl sulphidewith alkynes of the general formula (IV)R.sup.3 --C.tbd.C--R.sup.4 (IV)wherein the meanings of R.sup.3 and R.sup.4 are as defined above and, if desired, hydrogenating the obtained product of general formula (I), wherein the meanings of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are as defined above and R.sup.5 together with R.sup.6 forms a chemical bond, to a compound of the general formula (I), wherein both R.sup.5 and R.sup.6 stand for hydrogen.
摘要翻译：本发明涉及一种制备通式（I）的已知硫代氨基甲酸酯的新方法，其中R1和R2独立地表示氢或含有1至6个碳原子的直链或支链烷基或烯基含有2至6个原子的基团，或含有1至6个的烷基或含2至6个碳原子的烯基，被卤素，氧，硫和/或氮单取代或多取代; 或者R 1和R 2一起可以表示任选取代的含有4至6个碳原子的α，ω-亚烷基; R3和R4分别独立地表示氢或含有1至4个碳原子的烷基，并且任选被卤素取代或被含氧，硫和/或氮的基团取代; R5和R6均代表氢; 或R5和R6一起可以表示化学键。通式（I）的化合物是通过使（a）通式（II）的硫代氨基甲酸盐与其中R 1和R 2的含义如上所定义的通式（Ⅱ）的化合物反应，Y代表伯，仲或叔铵离子或碱金属离子; 或（b）通式（III）的胺其中R 1和R 2的含义如上所定义，连同硫和一氧化碳; 或（c）通式（III）的胺与羰基硫化物与通式（IV）的炔类反应，其中R3和R4的含义如上所定义，如果需要，氢化得到的通式（I）的产物，其中R 1，R 2，R 3和R 4的含义如上所定义，R 5与R 6一起形成化学键，通式（I）的化合物，其中两者 R5和R6代表氢。

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