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    • 3. 发明申请
    • ELECTROCHEMICAL GAS GENERATOR FOR CARBON MONOXIDE
    • 一氧化碳电化学气体发生器
    • US20080041730A1
    • 2008-02-21
    • US11835603
    • 2007-08-08
    • Kerstin CAROPeter TschunckyHerbert Kiesele
    • Kerstin CAROPeter TschunckyHerbert Kiesele
    • C25B9/00C25B1/00
    • G01N33/0006C25B1/00
    • An electrochemical gas generator is provided including an electrolysis cell (1) with a gas-impermeable housing, which is closed by a gas-permeable membrane (2) for the discharge of the test gas or calibrating gas CO. A chemically inert cathode (5) formed of a noble metal, a mixture of noble metals or a material containing carbon, is in direct contact with an electrolyte (7). An anode (4) formed of a noble metal, a mixture of noble metals or a material containing carbon, is in direct contact with a mesoxalic acid salt, the mesoxalic acid salt being in direct contact with the electrolyte (7). A control unit (6) is provided that also acts as a power source and is connected to the electrodes (4, 5).
    • 提供一种电化学气体发生器,其包括具有气体不可渗透壳体的电解池(1),其由用于排出测试气体或校准气体CO的透气膜(2)封闭。化学惰性阴极(5 )由贵金属,贵金属或含碳材料的混合物形成,与电解质(7)直接接触。 由贵金属形成的阳极(4),贵金属或含碳材料的混合物与中草酸盐直接接触,所述中草酸盐与电解质(7)直接接触。 还提供控制单元(6),其也用作电源并且连接到电极(4,5)。
    • 4. 发明授权
    • Electrochemical gas generator for combustible gases
    • 用于可燃气体的电化学气体发生器
    • US08007642B2
    • 2011-08-30
    • US11839071
    • 2007-08-15
    • Kerstin CaroPeter TschunckyHerbert Kiesele
    • Kerstin CaroPeter TschunckyHerbert Kiesele
    • C25B9/00C25B1/00
    • C25B3/04C25B9/06
    • An electrochemical gas generator is provided with an electrolysis cell (1) with a housing, which is closed by a gas-permeable membrane (2) for the escape of the test or calibrating gas. A cathode (5) is provided formed of a noble metal, a mixture of noble metals or a material containing carbon. The cathode is in direct contact with an electrolyte (7) disposed in the housing. An anode (4) is provided formed of a noble metal, a mixture of noble metals or a material containing carbon. The anode is in direct contact with an electrolyte (7). The electrolyte (7) contains a carboxylic acid salt. A control unit (6) is provided that acts as a current source and which is connected to the electrodes (4, 5).
    • 电化学气体发生器设置有具有壳体的电解池(1),该壳体由用于测试或校准气体逸出的透气膜(2)封闭。 提供由贵金属,贵金属或含碳材料的混合物形成的阴极(5)。 阴极与设置在壳体中的电解质(7)直接接触。 提供由贵金属,贵金属或含碳材料的混合物形成的阳极(4)。 阳极与电解质(7)直接接触。 电解质(7)含有羧酸盐。 提供控制单元(6),其用作电流源并连接到电极(4,5)。
    • 5. 发明授权
    • Electrochemical gas generator for carbon monoxide
    • 一氧化碳气化发生器
    • US07951273B2
    • 2011-05-31
    • US11835603
    • 2007-08-08
    • Kerstin CaroPeter TschunckyHerbert Kiesele
    • Kerstin CaroPeter TschunckyHerbert Kiesele
    • C25B1/00
    • G01N33/0006C25B1/00
    • An electrochemical gas generator is provided including an electrolysis cell (1) with a gas-impermeable housing, which is closed by a gas-permeable membrane (2) for the discharge of the test gas or calibrating gas CO. A chemically inert cathode (5) formed of a noble metal, a mixture of noble metals or a material containing carbon, is in direct contact with an electrolyte (7). An anode (4) formed of a noble metal, a mixture of noble metals or a material containing carbon, is in direct contact with a mesoxalic acid salt, the mesoxalic acid salt being in direct contact with the electrolyte (7). A control unit (6) is provided that also acts as a power source and is connected to the electrodes (4, 5).
    • 提供一种电化学气体发生器,其包括具有气体不可渗透壳体的电解池(1),其由用于排出测试气体或校准气体CO的透气膜(2)封闭。化学惰性阴极(5 )由贵金属,贵金属或含碳材料的混合物形成,与电解质(7)直接接触。 由贵金属形成的阳极(4),贵金属或含碳材料的混合物与中草酸盐直接接触,所述中草酸盐与电解质(7)直接接触。 还提供控制单元(6),其也用作电源并且连接到电极(4,5)。
    • 7. 发明授权
    • Flow gap gas distribution adapter for an electrochemical gas sensor
    • 用于电化学气体传感器的流隙气体分配适配器
    • US06793786B2
    • 2004-09-21
    • US10109477
    • 2002-03-28
    • Herbert KieseleUwe KühnRainer KunzFrank Mett
    • Herbert KieseleUwe KühnRainer KunzFrank Mett
    • G01N27404
    • G01N27/404G01N33/0009
    • An adapter (1) and electrochemical gas sensor (2) is provided with an electrochemical gas sensor housing (14) accommodating an electrolyte (13), with at least one measuring electrode (12) arranged therein and with a membrane (11), which screens the measuring electrode (12) from a measured gas and is permeable to the measured gas. The measuring sensitivity of an electrochemical gas sensor is increased by the adapter (1) having a gas-impermeable surface (15) extending in parallel to and at a spaced location from the membrane (11). The adapter (1) and the membrane (11) form a flow gap (10) for the measured gas delivered by a pump. The adapter (1) may be plugged onto the electrochemical sensor (2) at its outer edge (1a). The measured gas enters through a central opening (17), expands in the flow gap (10) radially to the outside and leaves same via the ring-shaped gap (16).
    • 适配器(1)和电化学气体传感器(2)设置有容纳电解质(13)的电化学气体传感器壳体(14),其中布置有至少一个测量电极(12)和膜(11),其中 从测量的气体中筛选测量电极(12)并且对测得的气体是可渗透的。电化学气体传感器的测量灵敏度由具有气体不可渗透表面(15)的适配器(1)增加,所述气体不可渗透表面(15)平行延伸并在 与膜(11)的间隔开的位置。 适配器(1)和膜(11)形成用于由泵输送的测量气体的流动间隙(10)。 适配器(1)可以在其外边缘(1a)处被插入到电化学传感器(2)上。 测量的气体通过中心开口(17)进入,在流动间隙(10)中径向扩张到外部并经由环形间隙(16)离开。
    • 9. 发明授权
    • Process and device for monitoring the hydrogen concentration
    • 用于监测氢浓度的过程和装置
    • US07175753B2
    • 2007-02-13
    • US10349276
    • 2003-01-22
    • Herbert KieselePeter Tschuncky
    • Herbert KieselePeter Tschuncky
    • G01N27/26
    • G01N27/4045G01N27/4163G01N33/005
    • A process and a device are provided for monitoring the hydrogen concentration in a gas with at least one device, which comprises an electrochemical gas sensor and a bipotentiostat, e.g., for use in internal combustion engines with hydrogen, in fuel cells and in the petrochemical industry. The electrochemical gas sensor used has two working electrodes (3) and (4), with which the hydrogen and oxygen concentrations are determined in the gas in different steps due to the application of a voltage by a bipotentiostat (5-18). In an additional, optional step, a voltage in the range of −1,100 mV to −800 mV is applied to a working electrode (4), so that hydrogen is formed at the working electrode (4) and the functional surface of the working electrode (4) as well as the sensitivity of the working electrode (3) to hydrogen can be checked. A cyclic repetition of the process steps, preferably offset in time, with two devices makes possible the continuous monitoring of the hydrogen and oxygen concentrations with regular checking of the working electrodes (3, 4) for their readiness to function.
    • 提供了一种方法和装置,用于利用至少一个装置监测气体中的氢浓度,所述装置包括电化学气体传感器和双重定位器,例如用于燃料电池和石化工业中的氢气内燃机 。 所使用的电化学气体传感器具有两个工作电极(3)和(4),由于通过双恒电位仪施加电压(5-18),气体中的氢气和氧气浓度在不同的步骤中被确定。 在额外的可选步骤中,将-1,100mV至-800mV范围内的电压施加到工作电极(4),从而在工作电极(4)和工作电极的功能表面上形成氢 (4)以及工作电极(3)对氢的敏感性。 通过两个装置对工艺步骤的循环重复(优选时间偏移)使得可以通过定期检查工作电极(3,4)来准备工作来连续监测氢和氧浓度。