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    • 2. 发明授权
    • Process of producing relief structures using polyamide ester resins
    • 使用聚酰胺酯树脂生产浮雕结构的方法
    • US4369247A
    • 1983-01-18
    • US334163
    • 1981-12-24
    • David L. GoffEdward L. YuanStephen Proskow
    • David L. GoffEdward L. YuanStephen Proskow
    • C08F290/14G03F7/037H01L21/312G03C5/00
    • C08F290/145G03F7/037H01L21/312
    • An improved process for forming relief structures on electrical devices such as capacitors, integrated circuits, printed circuits and semiconductors; a solution of a composition a polymeric heat resistant photopolymerizable composition of a polyamide ester resin containing photopolymerizable groups is applied to substrate such as a coated silicon wafer, which forms the base an electrical device, and is dried to form a film, the film is exposed to radiation through a pattern and photopolymerized; the unexposed and unpolymerized part of the film is dissolved off and the resulting relief structure is converted to a polyimide structure having a sharp definition and good mechanical, chemical and electrical properties; to reduce radiation exposure time and increase the rate of photopolymerization the following constituents are used in the composition:a radiation sensitive polymerizable polyfunctional acrylate compound and a photopolymerization initiator of an aromatic biimidazole.
    • 用于在诸如电容器,集成电路,印刷电路和半导体的电气装置上形成浮雕结构的改进方法; 将包含可光聚合基团的聚酰胺酯树脂的聚合物耐热可光聚合组合物的组合物溶液施加到基底上,例如形成基底的电子器件的被覆硅晶片,并干燥以形成膜,该膜暴露 通过图案辐射和光聚合; 将未曝光和未聚合的薄膜部分溶解掉,将得到的浮雕结构转变成具有清晰清晰度和良好机械,化学和电学性能的聚酰亚胺结构; 为了减少辐射暴露时间并增加光聚合速率,在组合物中使用以下成分:辐射敏感的可聚合多官能丙烯酸酯化合物和芳族联咪唑的光聚合引发剂。
    • 4. 发明授权
    • Electrical device formed from polymeric heat resistant
photopolymerizable composition
    • 由聚合物耐热光聚合组合物形成的电器件
    • US4410612A
    • 1983-10-18
    • US334166
    • 1981-12-24
    • David L. GoffEdward L. YuanStephen Proskow
    • David L. GoffEdward L. YuanStephen Proskow
    • C08F290/14G03F7/037H01L21/312G03C5/00
    • C08F290/145G03F7/037H01L21/312Y10S428/901
    • An electrical device formed from a polymeric heat resistant photopolymerizable composition of a polyamide ester, resin containing photopolymerizable groups which forms a relief structures on electrical devices such as capacitors, integrated circuits, printed circuits, multilayer circuits or semiconductors; a solution of the composition is applied to a substrate such as a coated silicon wafer, dried to form a film, the film is exposed to radiation through a pattern and photopolymerized; the unexposed and unpolymerized part of the film is dissolved off and the resulting relief structure is converted to a polyimide structure with sharp definition and has good mechanical, chemical and electrical properties; to reduce radiation exposure time and increase the rate of photopolymerization the following constituents are used in the composition: a radiation sensitive polymerizable polyfunctional acrylate compound and a photopolymerization initiator of an aromatic biimidazole.
    • 由聚酰胺酯的聚合物耐热可光聚合组合物形成的电气装置,包含在诸如电容器,集成电路,印刷电路,多层电路或半导体的电气装置上形成浮雕结构的可光聚合基团的树脂; 将组合物的溶液施加到诸如涂覆的硅晶片的基材上,干燥以形成膜,通过图案将膜暴露于辐射并进行光聚合; 将未曝光和未聚合的薄膜部分溶解掉,得到的浮雕结构转变为具有清晰清晰度的聚酰亚胺结构,具有良好的机械,化学和电学性能; 为了减少辐射暴露时间并增加光聚合速率,在组合物中使用以下成分:辐射敏感的可聚合多官能丙烯酸酯化合物和芳族联咪唑的光聚合引发剂。
    • 8. 发明授权
    • Electrical device containing a radiation-sensitive polyimide precursor
composition derived from a diaryl fluoro compound
    • 含有衍生自二芳基氟化合物的辐射敏感性聚酰亚胺前体组合物的电气装置
    • US4454220A
    • 1984-06-12
    • US427416
    • 1982-09-29
    • David L. Goff
    • David L. Goff
    • C08F290/14C08G73/10C08L79/08G03F7/037G03C5/00
    • C08F290/14C08G73/1039C08L79/08G03F7/037Y10S430/117Y10S430/12
    • An electrical device coated with a polymerized polyimide structure resulting from a radiation-sensitive polyimide precursor composition which comprises a polymer of the formula ##STR1## wherein n is a positive integer corresponding to the number of units in the polymer and is sufficiently large to provide the polymer with a number average molecular weight of about 1500-15,000 as determined by vapor pressure osmometry, and wherein for any particular unit in the polymer:.fwdarw.denotes isomerism; R.sup.1 is a divalent aromatic, aliphatic or cycloaliphatic radical containing at least 2 carbon atoms; R.sup.2 and R.sup.3 are selected from the group consisting of a hydrogen radical and any organic radical containing a photopolymerizable olefinic double bond; and R.sup.4 and R.sup.5 are selected from the group consisting of perfluoro and perhalofluoro aliphatic hydrocarbons having 1 to 8 carbons.
    • 涂覆有由辐射敏感的聚酰亚胺前体组合物产生的聚合的聚酰亚胺结构的电气装置,其包含下式的聚合物:其中n是对应于聚合物中的单元数目的正整数,并且足够大以提供 通过蒸气压渗透压测定的数均分子量为约1500-15,000的聚合物,并且其中对于聚合物中的任何特定单元: - >表示异构体; R1是含有至少2个碳原子的二价芳族,脂族或脂环族基团; R2和R3选自氢基团和含有可光聚合的烯属双键的任何有机基团; 并且R 4和R 5选自具有1至8个碳的全氟和全氟氟脂族烃。
    • 9. 发明授权
    • Radiation-sensitive polyimide precursor composition derived from a
diaryl fluoronated diamine compound
    • 衍生自二芳基氟化二胺化合物的辐射敏感聚酰亚胺前体组合物
    • US4430418A
    • 1984-02-07
    • US430856
    • 1982-09-30
    • David L. Goff
    • David L. Goff
    • C08F290/14C08G73/10C08L79/08G03F7/037G03C1/68
    • G03F7/037C08F290/14C08G73/1039C08L79/08Y10S430/117Y10S430/12
    • A radiation-sensitive polyimide precursor composition, comprising a polymer of the formula ##STR1## wherein n is a positive integer corresponding to the number of units in the polymer and is sufficiently large to provide the polymer with a number average molecular weight of about 1500-15,000 as determined by vapor pressure osmometry, and wherein for any particular unit in the polymer:.fwdarw.denotes isomerism;R.sup.1 is a tetravalent aromatic non-halogen containing organic radical containing at least one ring of six carbon atoms, said ring characterized by benzenoid unsaturation, the four carbonyl groups being attached directly to separate carbon atoms in a ring of the R.sup.1 radical;R.sup.2 and R.sup.3 are selected from the group consisting of a hydrogen radical and any organic radical containing a photopolymerizable olefinic double bond, at least one of R.sup.2 and R.sup.3 being said organic radical;R.sup.4 and R.sup.5 are selected from the group consisting of perfluoro and perhalofluoro aliphatic hydrocarbons having 1 to 8 carbons; and A and A' are selected from the group consisting of H, Cl, Br, and NO.sub.2.
    • 一种辐射敏感的聚酰亚胺前体组合物,其包含下式的聚合物,其中n是对应于聚合物中单元数的正整数,并且足够大以提供数均分子量为约1500〜 通过蒸气压渗透测定法测定,其中对于聚合物中的任何特定单位: - >表示异构体; R1是含有至少一个具有6个碳原子的环的四价芳族不含卤素的有机基团,所述环的特征在于苯不饱和键,四个羰基直接连接在R1基团的环上分开的碳原子; R2和R3选自氢基团和含有可光聚合的烯属双键的任何有机基团,R 2和R 3中的至少一个是所述有机基团; R4和R5选自具有1至8个碳的全氟和全氟氟脂族烃; A和A'选自H,Cl,Br和NO 2。
    • 10. 发明授权
    • Photopolymerizable polyamide ester resin compositions containing an
oxygen scavenger
    • 含有除氧剂的可光聚合的聚酰胺酯树脂组合物
    • US4414312A
    • 1983-11-08
    • US334164
    • 1981-12-24
    • David L. GoffEdward L. YuanStephen Proskow
    • David L. GoffEdward L. YuanStephen Proskow
    • C08F290/14G03F7/037H01L21/312G03C1/68
    • H01L21/312C08F290/145G03F7/037
    • A polymeric heat resistant photopolymerizable composition of a polyamide ester resin containing photopolymerizable groups useful for forming relief structures on electrical devices such as capacitors, integrated circuits, printed circuits and semiconductors; a solution of the composition is applied to a substrate such as a coated silicon wafer which is the base for an electrical device, dried to form a film, the film is exposed to radiation through a pattern and photopolymerized; the unexposed and unpolymerized part of the film is dissolved off and the resulting relief structure is converted to a polyimide structure with sharp definition and has good mechanical, chemical and electrical properties; to reduce radiation exposure time and increase the rate of photopolymerization the following constituents are used in the composition:radiation sensitive polymerizable polyfunctional acrylate compound and photopolymerization initiators containing hydrogen donor initiator and aromatic biimidazole, and an oxygen scavenger.
    • 含有用于在诸如电容器,集成电路,印刷电路和半导体的电气装置上形成浮雕结构的可光聚合基团的聚酰胺酯树脂的聚合物耐热可光聚合组合物; 将组合物的溶液施加到诸如作为电气装置的基底的涂覆硅晶片的基板上,干燥以形成膜,通过图案将膜暴露于辐射并进行光聚合; 将未曝光和未聚合的薄膜部分溶解掉,得到的浮雕结构转变为具有清晰清晰度的聚酰亚胺结构,具有良好的机械,化学和电学性能; 为了减少辐射暴露时间并增加光聚合速率,组合物中使用以下组分:辐射敏感的可聚合多官能丙烯酸酯化合物和含氢供体引发剂和芳族联咪唑的光聚合引发剂和除氧剂。