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    • 6. 发明授权
    • Random propylene copolymers
    • 无规丙烯共聚物
    • US5744567A
    • 1998-04-28
    • US763839
    • 1996-12-04
    • Stephan HufferMeinolf KerstingFranz LanghauserRainer Alexander WernerPatrik MullerJurgen Kerth
    • Stephan HufferMeinolf KerstingFranz LanghauserRainer Alexander WernerPatrik MullerJurgen Kerth
    • C08F4/658C08F4/02C08F4/64C08F4/654C08F210/06C08F210/16D01F6/06C08F10/06
    • C08F210/16C08F210/06
    • Random propylene copolymers containing copolymerized C.sub.2 -C.sub.10 -alk-1-enes are obtainable by polymerization of propylene and C.sub.2 -C.sub.10 -alk-1-enes in the presence of a Ziegler-Natta catalyst system comprising a titanium-containing solid component a) comprising a compound of magnesium, a halogen, silica gel as support and a carboxylic ester as electron donor compound, and also, as cocatalysts, an aluminum compound b) and a further electron donor compound c), where propylene and the C.sub.2 -C.sub.10 -alk-1-enes are polymerized with one another at from 50.degree. to 100.degree. C. at pressures in the range from 15 to 40 bar and mean residence times of from 0.5 to 5 hours and the support used in the titanium-containing solid component is a silica gel which has a mean particle diameter of from 5 to 200 .mu.m, a mean particle diameter of the primary particles of from 1 to 10 .mu.m and voids or channels having a mean diameter of from 1 to 10 .mu.m, which voids or channels have a macroscopic proportion by volume based on the total particle in the range from 5 to 20%.
    • 含有共聚的C 2 -C 10 - 烷-1-烯的无规丙烯共聚物可通过丙烯和C 2 -C 10 - 烯-1-烯的齐聚反应获得,该齐格勒 - 纳塔催化剂体系包含含钛的固体组分a) 镁,卤素,硅胶作为载体的化合物和作为电子给体化合物的羧酸酯,以及作为助催化剂的铝化合物b)和另外的电子给体化合物c),其中丙烯和C 2 -C 10 - 烷基 -1-烯烃在50至100℃的压力下彼此聚合,并且平均停留时间为0.5至5小时,并且在含钛固体组分中使用的载体为 平均粒径为5〜200μm,一次粒子的平均粒径为1〜10μm,平均粒径为1〜10μm的空隙或通道的硅胶,其空隙 或通道基于t的体积的宏观比例 他的总粒子在5〜20%的范围内。
    • 8. 发明申请
    • Method for Treating Fibrous Substrates
    • 纤维底物处理方法
    • US20080249230A1
    • 2008-10-09
    • US10572449
    • 2004-09-18
    • Stephan HufferDarijo MijolovicKarl VillMatthias KlugleinGerhard Wolf
    • Stephan HufferDarijo MijolovicKarl VillMatthias KlugleinGerhard Wolf
    • C08L33/02
    • C14C9/02C08F290/042C14C3/22D06M15/227D06M15/27D21H17/35D21H17/43D21H17/72D21H21/16
    • Fibrous substrates are treated with (a) at least one oligomer of branched or straight-chain C3-C10-alkene having an average molecular weight Mn of up to 1200 g/mol, (b) at least one emulsifier which is obtainable by copolymerization of (A) at least one ethylenically unsaturated dicarboxylic anhydride, derived from at least one dicarboxylic acid of 4 to 8 carbon atoms, (B) at least one oligomer of branched or straight-chain C3-C10-alkene, at least one oligomer having an average molecular weight Mn of up to 1200 g/mol, (C) at least one α-olefin of up to 16 carbon atoms and (D) optionally at least one ethylenically unsaturated comonomer, and optionally reaction with (E) at least one compound of the formula I a, I b, I c or I d and, if appropriate, subsequent contact with water, where, in formulae I a to I d, A1 are identical or different C2-C20-alkylene, R1 is linear or branched C1-C30-alkyl, phenyl or hydrogen, and n is an integer from 1 to 200.
    • 纤维底物用(a)至少一种具有平均分子量M N n的支链或直链C 3 -C 10 - 亚烯基的低聚物处理, (a)至少一种烯键式不饱和二羧酸酐,其由至少一种4-8个碳原子的二羧酸共聚得到(A)至少一种乙烯基不饱和二羧酸酐, B)至少一种支链或直链C 3 -C 10 - 烯烃的低聚物,至少一种平均分子量为M < (C)至少一种至多16个碳原子的α-烯烃和(D)任选的至少一种烯键式不饱和共聚单体,并且任选地与(E)至少一种式 式I a,I b,I c或I d,并且如果适用,随后与水接触,其中在式I a至I d中,A 1至A 1相同或不同C 2 C 20 - 亚烷基,R 1是直链或支链的 C 1 -C 30烷基,苯基或氢,n是1至200的整数。
    • 10. 发明授权
    • Process for producing improved random propylene copolymers
    • 制备改进的无规丙烯共聚物的方法
    • US6013742A
    • 2000-01-11
    • US969278
    • 1997-11-13
    • Stephan HufferMeinolf KerstingFranz LanghauserRainer Alexander WernerPatrik MullerJurgen Kerth
    • Stephan HufferMeinolf KerstingFranz LanghauserRainer Alexander WernerPatrik MullerJurgen Kerth
    • C08F4/658C08F4/02C08F4/64C08F4/654C08F210/06C08F210/16D01F6/06C08F4/18
    • C08F210/16C08F210/06
    • A process for preparing random propylene copolymers containing copolymerized C.sub.2 -C.sub.10 -alk-1-enes by polymerization of propylene and C.sub.2 -C.sub.10 -alk-1-enes in the presence of a Ziegler-Natta catalyst system comprising a titanium-containing solid component a) comprising a compound of magnesium, a halogen, silica gel as support and a carboxylic ester as electron donor compound, and also, as cocatalysts, an aluminum compound b) and a further electron donor compound c), where propylene and the C.sub.2 -C.sub.10 -alk-1-enes are polymerized with one another at from 50 to 100.degree. C. at pressures in the range from 15 to 40 bar and mean residence times of from 0.5 to 5 hours and the support used in the titanium-containing solid component is a silica gel which has a mean particle diameter of from 5 to 200 .mu.m, a mean particle diameter of the primary particles of from 1 to 10 .mu.m and voids or channels having a mean diameter of from 1 to 10 .mu.m, which voids or channels have a macroscopic proportion by volume based on the total particle in the range from 5 to 20%.
    • 在含有含钛固体组分a的齐格勒 - 纳塔催化剂体系存在下,通过丙烯和C 2 -C 10 - 烷-1-烯的聚合制备含共聚的C 2 -C 10 - 烷-1-烯的无规丙烯共聚物的方法 ),其包含镁,卤素,硅胶作为载体的化合物和作为电子给体化合物的羧酸酯,以及作为助催化剂的铝化合物b)和另外的电子给体化合物c),其中丙烯和C 2 -C 10 α-烷-1-烯在50至100℃下以15至40巴的压力和0.5至5小时的平均停留时间彼此聚合,并且在含钛固体组分中使用的载体 是平均粒径为5〜200μm,一次粒子的平均粒径为1〜10μm,平均粒径为1〜10μm的通道的硅胶,其中, 空隙或通道具有基于体积的宏观比例 总颗粒在5至20%的范围内。