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1. 发明授权

US5096569A Catalytic hydropyrolysis of carbonaceous material with char recycle 失效
标题翻译：碳质材料的催化加氢热解与焦炭回收
公开(公告)号：US5096569A
公开(公告)日：1992-03-17
申请号：US641328
申请日：1991-01-15
申请人： Peter S. Maa , Russell R. Chianelli
发明人： Peter S. Maa , Russell R. Chianelli
IPC分类号： C10G1/08
CPC分类号： C10G1/086
摘要： Disclosed is a method for catalytically hydropyrolyzing carbonaceous material to produce liquid products boiling under about 550.degree. C. with reduced amounts of methane being formed. The process comprises (a) treating the carbonaceous material with as hydrogenation catalyst; (b) contacting the so-treated carbonaceous material with an effective amount of hydrogen, at an effective residence time, at a temperature below the critical temperature of rapid methane formation; (c) recovering the resulting liquids, gases, and char; and (d) recycling the char.
摘要翻译：公开了一种用于催化加氢热解碳质材料以产生在约550℃下沸腾的液体产物的方法，其中形成的甲烷的量减少。该方法包括（a）用氢化催化剂处理碳质材料; （b）在低于快速形成甲烷的临界温度的温度下，将有效量的氢气在有效的停留时间下接触; （c）回收所得液体，气体和炭; 和（d）回收炭。

2. 发明授权

US4831003A Catalyst composition and process of making 失效
标题翻译：催化剂组成和制备方法
公开(公告)号：US4831003A
公开(公告)日：1989-05-16
申请号：US95942
申请日：1987-09-14
申请人： Robert J. Lang , Peter S. Maa , Veluswamy R. LaVanga
发明人： Robert J. Lang , Peter S. Maa , Veluswamy R. LaVanga
IPC分类号： B01J21/18 , B01J32/00 , B01J37/02 , C10G49/04
CPC分类号： C10G49/04 , B01J21/18 , B01J32/00 , B01J37/0238
摘要： A catalyst composition prepared by depositing a metal or metal compound onto a carbon support formed, in effect, simultaneously with the deposition of the metal or metal compound via partial combustion of an unsaturated hydrocarbon and thereafter converting said metal or metal compound to an oxide or sulfide having hydrogenation activity. The metal is selected from the group of metals consisting of Groups II-B, IV-B, IV-A, V-A, VI-A, VII-A and VIII-A metals of the Periodic Table of the Elements. The catalyst compositions are useful in hydroconversion and hydrotreating processes.
摘要翻译：一种催化剂组合物，其通过将金属或金属化合物沉积在碳载体上而形成，其实际上与通过不饱和烃的部分燃烧沉积金属或金属化合物同时形成，然后将所述金属或金属化合物转化为氧化物或硫化物具有氢化活性。金属选自由元素周期表的II-B族，IV-B族，IV-A族，V-A族，VI-A族，VII-A族和VIII-A族金属组成的金属。催化剂组合物可用于加氢转化和加氢处理。

3. 发明授权

US4092235A Treatment of coal by alkylation or acylation to increase liquid products from coal liquefaction 失效
标题翻译：通过烷基化或酰化处理煤，以增加煤液化产物
公开(公告)号：US4092235A
公开(公告)日：1978-05-30
申请号：US635706
申请日：1975-11-26
申请人： Richard H. Schlosberg , Peter S. Maa , Richard C. Neavel
发明人： Richard H. Schlosberg , Peter S. Maa , Richard C. Neavel
IPC分类号： C10G1/00 , C10G1/06
CPC分类号： C10G1/065 , C10G1/00 , Y10S208/951
摘要： The production of liquid hydrocarbons from coal is significantly enhanced by alkylating or acylating the coal prior to subjecting the coal to liquefaction conditions. The introduction of aliphatic hydrocarbon radicals or acyl radicals, including carbon monoxide, into the coal structure is believed to permit more of the coal to undergo liquefaction at suitable liquefaction conditions. The alkylation or acylation reactions can be conducted in the presence or absence of added or extraneous catalysts.
摘要翻译：在煤经历液化条件之前，通过烷化或酰化煤，显着提高了来自煤的液体烃的生产。据信，在煤结构中引入脂族烃基或酰基，包括一氧化碳，允许更多的煤在合适的液化条件下经历液化。烷基化或酰化反应可以在存在或不存在加入的或外来的催化剂的情况下进行。

4. 发明授权

US4022680A Hydrogen donor solvent coal liquefaction process 失效
标题翻译：氢供体溶剂煤液化过程
公开(公告)号：US4022680A
公开(公告)日：1977-05-10
申请号：US641489
申请日：1975-12-17
申请人： Peter S. Maa
发明人： Peter S. Maa
IPC分类号： C10G1/04 , C10G1/06
CPC分类号： C10G1/042 , C10G1/065
摘要： A process for liquefying a particulate coal feed to produce useful petroleum-like liquid products, particularly by steps which include: (a) contacting, in a liquefaction zone, said coal feed with a hydrogen donor solvent at temperature and pressure sufficient to hydroconvert and liquefy the coal (b) separating the product from the liquefaction zone by distillation into fractions inclusive of a liquid fraction which contains at least 30 weight percent, and preferably at least 50 weight percent hydrogen donor compounds, particularly those fractions boiling within about the 350.degree.-850.degree. F. range, and preferably within about the 400.degree.-700.degree. F. range, (c) hydrogenating said liquid fraction in a hydrogenation zone, (d) adding to said liquid fraction a solvent characterized as a low molecular weight heterocyclic oxygen or heterocyclic sulfur compound containing, within a molecule, from 2 to about 6 fused rings one or more of which is a five- or six-membered heterocyclic ring having 4 to 5 carbon atoms and from 1 to 2 atoms of oxygen or sulfur, and (e) recycling the hydrogenated liquid solvent mixture to said coal liquefaction zone.
摘要翻译：用于液化颗粒状煤进料以产生有用的石油样液体产物的方法，特别是通过以下步骤进行的方法，该方法包括：（a）在液化区使所述煤进料与氢供体溶剂在足以加氢转化和液化的温度和压力下接触煤（b）通过蒸馏将产物与液化区分离成包括含有至少30重量％，优选至少50重量％氢供体化合物的液体馏分，特别是在约350℃沸腾的馏分， 850°F范围内，优选在约400°-700°F范围内，（c）在氢化区中氢化所述液体馏分，（d）向所述液体馏分中加入表征为低分子量杂环氧的溶剂或在分子内含有2至约6个稠合环的杂环硫化合物，其中一个或多个是具有4个或5个的五元或六元杂环至5个碳原子和1至2个原子的氧或硫，和（e）将氢化液体溶剂混合物再循环到所述煤液化区。

5. 发明申请

US20170321125A1 DIRECT COAL LIQUEFACTION PROCESS 审中-公开
公开(公告)号：US20170321125A1
公开(公告)日：2017-11-09
申请号：US15662113
申请日：2017-07-27
申请人： Richard F. Bauman , Peter S. Maa
发明人： Richard F. Bauman , Peter S. Maa
IPC分类号： C10G1/06
CPC分类号： C10G1/065 , C10G1/086 , C10G2300/4081 , C10G2300/44
摘要： A direct coal liquefaction process capable of producing unexpectedly high levels of C5/650° F. product, which process employs a relatively high ratio of solvent plus bottoms product recycle to feed coal.

6. 发明授权

US4485008A Liquefaction process 失效
标题翻译：液化过程
公开(公告)号：US4485008A
公开(公告)日：1984-11-27
申请号：US483076
申请日：1983-04-07
申请人： Peter S. Maa , Lavanga R. Veluswamy , Lonnie W. Vernon
发明人： Peter S. Maa , Lavanga R. Veluswamy , Lonnie W. Vernon
IPC分类号： C10G1/00 , C10G1/08 , C10G1/06
CPC分类号： C10G1/006 , C10G1/083
摘要： An improved liquefaction process for solid carbonaceous materials wherein at least a portion of the liquefaction is accomplished in the presence of an added hydrogenation catalyst and a solvent containing at least 1.25 wt % donatable hydrogen and in the presence of partially liquefied, solid carbonaceous material at liquefaction conditions. In a preferred embodiment, the liquefaction is accomplished in a plurality of stages and a solvent containing at least 1.25 wt % donatable hydrogen is used in at least one stage, most preferably in the second stage. The partially liquefied solid carbonaceous material may be taken from the bottoms fraction of the effluent from any of the liquefaction stages.
摘要翻译：用于固体碳质材料的改进的液化方法，其中至少一部分液化在添加的氢化催化剂和含有至少1.25重量％可供氢的溶剂的存在下进行，并且在液化的部分液化的固体含碳材料存在下完成条件。在优选的实施方案中，液化在多个阶段中完成，并且在至少一个阶段，最优选在第二阶段中使用含有至少1.25wt％可供氢的溶剂。部分液化的固体碳质材料可以从任何液化阶段的流出物的底部馏分中获取。

7. 发明授权

US5795464A Conversion of the organic component from tar sands to lower boiling products 失效
标题翻译：将有机成分从焦油砂转化为较低沸点的产物
公开(公告)号：US5795464A
公开(公告)日：1998-08-18
申请号：US753459
申请日：1996-11-25
申请人： Bruce M. Sankey , Peter S. Maa , Roby Bearden, Jr.
发明人： Bruce M. Sankey , Peter S. Maa , Roby Bearden, Jr.
IPC分类号： C10G1/00 , C10G1/04 , C10G9/00 , C01G1/00 , C01G1/04 , C01G9/34
CPC分类号： C10G9/005 , C10G1/002 , C10G1/047
摘要： A process for the thermal conversion of the organic component associated with tar sands to lower boiling, higher value products. The conversion is achieved by subjecting the organic component containing from about 1 to 20 wt. % native solids to elevated temperatures and pressures. Compared to conventional thermal conversion processes, such as visbreaking, much higher conversion of the organic component can be achieved owing to the presence of native solids on which coke is deposited instead of fouling the process equipment. This higher conversion is also associated with enhanced removal of sulfur and metals.
摘要翻译：将与焦油砂相关的有机成分热转化为较低沸点，更高价值的产品的方法。该转化通过使含有约1至20重量％％天然固体升高温度和压力。与传统的热转化方法（如减粘裂化）相比，由于存在沉淀焦炭而不是污染工艺设备的天然固体，可以实现有机组分的高得多的转化率。这种更高的转化率也与增加硫和金属的去除有关。

8. 发明授权

US4322283A Coal conversion in the presence of added hydrogen sulfide 失效
标题翻译：在加入硫化氢存在下转化煤
公开(公告)号：US4322283A
公开(公告)日：1982-03-30
申请号：US183862
申请日：1980-09-04
申请人： Peter S. Maa , Lavanga R. Veluswamy
发明人： Peter S. Maa , Lavanga R. Veluswamy
IPC分类号： C10G1/06
CPC分类号： C10G1/06 , Y10S208/951
摘要： Coal or similar liquefiable carbonaceous solids are converted into lower molecular weight liquids by contacting the feed solids with molecular hydrogen in the absence of externally added hydrocarbon liquids and in the presence of added hydrogen sulfide under liquefaction conditions in one or more liquefaction zones.
摘要翻译：在不存在外部添加的烃类液体的情况下和在液化条件下在一个或多个液化区中加入的硫化氢存在下，将煤或类似的可液化碳质固体转化为较低分子量的液体。

9. 发明授权

US07160437B2 Method for determining the source of fouling in thermal conversion process units 失效
标题翻译：确定热转换过程单位污染源的方法
公开(公告)号：US07160437B2
公开(公告)日：2007-01-09
申请号：US10680920
申请日：2003-10-08
申请人： Leo D. Brown , Peter S. Maa , William N. Olmstead , Michael Siskin
发明人： Leo D. Brown , Peter S. Maa , William N. Olmstead , Michael Siskin
IPC分类号： C10B55/10 , C10G9/32
CPC分类号： C10B55/10 , C10B43/14 , C10G9/32 , C10G2300/1033 , C10G2300/107 , C10G2300/1077 , C10G2300/708 , Y10S585/95 , Y10T436/13 , Y10T436/206664 , Y10T436/21
摘要： The present invention relates to a method for determining the source of fouling in petroleum thermal conversion process units. More particularly, the invention distinguishes whether fouling occurs due to feed entrainment of small feed droplets or vapor phase condensation.
摘要翻译：本发明涉及一种确定石油热转化处理单元中污垢源的方法。更具体地，本发明区分是否由于小进料液滴的进料夹带或气相冷凝而发生结垢。

10. 发明授权

US4338184A Coal conversion in the presence of added alkali metal compounds 失效
标题翻译：在加入碱金属化合物的情况下转化煤
公开(公告)号：US4338184A
公开(公告)日：1982-07-06
申请号：US200710
申请日：1980-10-27
申请人： Peter S. Maa , Lavanga R. Veluswamy , Charles J. Vadovic
发明人： Peter S. Maa , Lavanga R. Veluswamy , Charles J. Vadovic
IPC分类号： C10G1/00 , C10G1/06 , B01J37/00
CPC分类号： C10G1/06 , C10G1/006
摘要： Coal or similar liquefiable carbonaceous solids are converted into hydrocarbon liquids by contacting the feed solids with molecular hydrogen in the absence of an added hydrocarbon solvent and in the presence of an added alkali metal compound under liquefaction conditions in one or more liquefaction zones.
摘要翻译：在不存在加入的烃溶剂的情况下和在液化条件下在一个或多个液化区中加入的碱金属化合物的存在下，将煤或类似的可液化碳质固体转化为烃液体。

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