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1. 发明授权

US4920204A Ceric hydrocarbyloxy nitrates and their use in organic synthesis 失效
标题翻译： Ceric烃氧基硝酸盐及其在有机合成中的应用
公开(公告)号：US4920204A
公开(公告)日：1990-04-24
申请号：US120054
申请日：1987-11-12
申请人： Peter S. Gradeff , Fred G. Schreiber , Jean Grosbois , Heiko Mauermann
发明人： Peter S. Gradeff , Fred G. Schreiber , Jean Grosbois , Heiko Mauermann
IPC分类号： C07C27/00 , C07C29/70 , C07C31/28 , C07C67/00 , C07F5/00
CPC分类号： C07C31/28 , C07F5/003
摘要： Ceric hydrocarbyloxy nitrates having the general formula: ##STR1## are obtained by reaction of ceric ammonium nitrate with x moles of ammonia and an aliphatic, cycloaliphatic or aromatic alcohol having from two to twenty carbon atoms, and are useful in the preparation of ceric hydrocarbyl oxides difficult or expensive of access by other routes, and in synthesis of other organic ceric compounds.
摘要翻译：通过使硝酸铈铵与x摩尔氨和具有2-20个碳原子的脂族，脂环族或芳族醇反应得到具有以下通式的具有以下通式的二氧化铈碳酸氧化的硝酸酯：＆lt; IMAGE＆gt; x = 1,2或3，并且是有用的在制备难以或昂贵通过其他途径进入的铈烃基氧化物，以及其它有机铈化合物的合成中。

2. 发明授权

US4489000A Process for the preparation of ceric alkoxides 失效
标题翻译：制备二氧化铈的方法
公开(公告)号：US4489000A
公开(公告)日：1984-12-18
申请号：US521787
申请日：1983-08-09
申请人： Peter S. Gradeff , Fred G. Schreiber
发明人： Peter S. Gradeff , Fred G. Schreiber
IPC分类号： C07C27/00 , C07C29/70 , C07C31/28 , C07C67/00 , C07F5/00
CPC分类号： C07C29/70 , C07F5/003
摘要： A process is provided for preparing ceric alkoxides, which comprises reacting ceric ammonium nitrate with an alcohol, including a lower aliphatic alcohol, under anhydrous conditions in the presence of an anhydrous base at a temperature within the range from about -30.degree. C. to about 200.degree. C. but preferably from 0.degree. to about 150.degree. C. until ceric alkoxide and the nitrate salt of the base are formed; ceric alkoxides of higher alcohols can be prepared by transetherification of the resulting ceric alkoxide with the higher alcohol, either simultaneously or sequentially, at a temperature within the range from about -30.degree. C. to about 200.degree. C., thereby displacing the lower aliphatic alcohol and forming the ceric alkoxide of the higher alcohol, while distilling off free lower aliphatic alcohol in the course of the transetherification, to drive it towards completion; the nitrates formed during the reaction can be separated from the reaction mixture and the alkoxides isolated pure or as complexes with the alcohol, or in some cases the alkoxides can be used without separation from the reaction mixture in the presence of the nitrates.
摘要翻译：提供了一种用于制备二氧化铈的方法，其包括在无水条件下，在无水碱存在下，在约-30℃至约约30℃的温度下，使硝酸铈铵与包括低级脂族醇在内的醇反应 200℃，但优选0℃至150℃，直到形成了铈醇盐和碱的硝酸盐; 高级醇的高级醇的烷氧基化物可以通过在约-30℃至约200℃的温度范围内同时或依次地将所得的高级醇与高级醇进行酯交换来制备，从而将低级脂族酒精和形成高级醇的二氧化铈，同时在脱碳过程中蒸馏出游离的低级脂族醇，使其完成; 在反应过程中形成的硝酸盐可以从反应混合物中分离出来，并且醇盐被分离为纯的或与醇的复合物，或在某些情况下，在硝酸盐存在下，可以不从反应混合物中分离出醇盐。

3. 发明授权

US4703109A Tricyclopentadienyl cerium and process for preparing the same 失效
标题翻译：三环戊二烯基铈及其制备方法
公开(公告)号：US4703109A
公开(公告)日：1987-10-27
申请号：US674639
申请日：1984-11-26
申请人： Peter S. Gradeff , Fred G. Schreiber
发明人： Peter S. Gradeff , Fred G. Schreiber
IPC分类号： C07F5/00 , C07F17/00
CPC分类号： C07F5/00
摘要： A process is provided for preparing tricyclopentadienyl cerium as well as the mono and dicyclopentadienyl cerium intermediates which comprises reacting an alkali metal cyclopentadienide with ceric ammonium nitrate, in solution in an inert organic solvent in a manner to obtain either tricyclopentadienyl cerium or to form in sequence, and stepwise, monocyclopentadienyl cerium dinitrate, dicyclopentadienyl cerium mononitrate, and tricyclopentadienyl cerium, depending upon the order of addition of the reactants.
摘要翻译：提供了制备三环戊二烯基铈以及单环和二环戊二烯基铈中间体的方法，其包括使碱金属环戊二烯与硝酸铈铵在溶液中在惰性有机溶剂中以获得三环戊二烯基铈或依次形成的方式进行反应，和逐步的单环戊二烯二硝酸铈硝酸盐，二环戊二烯基一硝酸铈一硝酸铈和三环戊二烯基铈，这取决于反应物的添加顺序。

4. 发明授权

US4663439A Process for the preparation of ceric alkoxides 失效
标题翻译：制备二氧化铈的方法
公开(公告)号：US4663439A
公开(公告)日：1987-05-05
申请号：US674640
申请日：1984-11-26
申请人： Peter S. Gradeff , Fred G. Schreiber
发明人： Peter S. Gradeff , Fred G. Schreiber
IPC分类号： C07C29/68 , C07C27/00 , C07C29/70 , C07C31/28 , C07C67/00 , C07F5/00
CPC分类号： C07C29/70 , C07C31/28 , C07F5/003
摘要： A process is provided for preparing ceric alkoxides, which comprises reacting ceric ammonium nitrate complexed with and in solution in ethylene or propylene glycol ether or tetrahydrofuran with an anhydrous alkali metal alkoxide at a temperature within the range from about -30.degree. C. to about 200.degree. C., preferably from 0.degree. to about 150.degree. C., until ceric alkoxide and the nitrate salt of the base are formed; the nitrate formed during the reaction is insoluble in the glycol ether and tetrahydrofuran and can be separated from the reaction mixture, and the cerium alkoxide when soluble in the glycol ether or tetrahydrofuran can be isolated from the solution pure, or as the complex with the alcohol or with the solvent, or in some cases the alkoxide can be used without separation from the reaction mixture in the presence of the nitrate.
摘要翻译：提供了一种制备二氧化铈的方法，其包括使与乙烯或丙二醇醚或四氢呋喃中的溶液中的和硝酸铈配合的硝酸铈铵与无水碱金属醇盐在约-30℃至约200℃的温度下反应优选0℃至约150℃，直到形成了铈醇盐和碱的硝酸盐; 反应过程中形成的硝酸盐不溶于乙二醇醚和四氢呋喃，可与反应混合物分离，可溶于乙二醇醚或四氢呋喃中的醇盐可以从溶液中纯化，或作为与醇的络合物或在一些情况下，在硝酸盐存在下，可以不用分离反应混合物使用醇盐。

5. 发明授权

US4314070A Process for producing meta-phenoxybenzoic acids and esters 失效
标题翻译：间苯氧基苯甲酸和酯的制备方法
公开(公告)号：US4314070A
公开(公告)日：1982-02-02
申请号：US149588
申请日：1980-05-14
申请人： Fred G. Schreiber , Peter S. Gradeff
发明人： Fred G. Schreiber , Peter S. Gradeff
IPC分类号： B01J27/00 , C07C65/21 , C07C69/92
CPC分类号： C07C65/21 , C07C69/92
摘要： An improved process for producing meta-phenoxy benzoic acids and their lower alkyl esters in improved yields and with higher selectivity by reacting an alkali metal phenate with a lower alkyl ester of meta-halobenzoic acid in the presence of a copper sulfate catalyst.
摘要翻译：在硫酸铜催化剂存在下，通过使碱金属酚盐与间 - 卤代苯甲酸的低级烷基酯反应，以改进的产率和较高选择性制备间苯氧基苯甲酸及其低级烷基酯的改进方法。

6. 发明授权

US4800072A Anhydrous cerous nitrate-ammonium nitrate complex and a process for its preparation from ceric ammonium nitrate 失效
标题翻译：无水硝酸铈 - 硝酸铵复合物及其制备方法
公开(公告)号：US4800072A
公开(公告)日：1989-01-24
申请号：US143978
申请日：1988-01-14
申请人： Peter S. Gradeff , Fred G. Schreiber
发明人： Peter S. Gradeff , Fred G. Schreiber
IPC分类号： C01F17/00 , C07C31/28 , C07C215/08 , C07C215/12 , C07F7/08 , C06B1/04
CPC分类号： C07C215/12 , C01F17/0012 , C07C215/08 , C07C31/28 , C07F7/0836
摘要： A procedure for preparing anhydrous cerous nitrate ammonium nitrate complex comprising treating dried anhydrous ceric hexanitro ammonium complex (ceric ammonium nitrate) with a reducing agent such as ammonia whereby Ce.sup.+4 is reduced to Ce.sup.+3 under anhydrous conditions. The resulting Ce.sup.+3 species, a complex of Ce.sup.+3 nitrate and ammonia nitrate, can be used as a source of anhydrous Ce.sup.+3 ions.
摘要翻译：制备无水硝酸硝酸铵硝酸铵络合物的方法，包括用还原剂如氨处理无水硫酸铈铵络合物（硝酸铈铵），由此Ce + 4在无水条件下还原为Ce + 3。所得到的Ce + 3物质，Ce + 3硝酸盐和硝酸铵的络合物可用作无水Ce + 3离子的来源。

7. 发明授权

US4492655A Tricyclopentadienyl cerium and process for preparing the same 失效
标题翻译：三环戊二烯基铈及其制备方法
公开(公告)号：US4492655A
公开(公告)日：1985-01-08
申请号：US604756
申请日：1984-04-27
申请人： Peter S. Gradeff , Fred G. Schreiber
发明人： Peter S. Gradeff , Fred G. Schreiber
IPC分类号： C07F5/00
CPC分类号： C07F5/00
摘要： A process is provided for preparing tricyclopentadienyl cerium as well as the mono and dicyclopentadienyl cerium intermediates which comprises slowly adding alkali metal cyclopentadienide to a solution of ceric ammonium nitrate, forming, in sequence, and stepwise, monocyclopentadienyl cerium dinitrate, dicyclopentadienyl cerium mononitrate, and tricyclopentadienyl cerium.
摘要翻译：提供了一种制备三环戊二烯基铈以及单环和二环戊二烯基铈中间体的方法，其中包括向硝酸铈铵溶液中缓慢加入环戊二烯酸碱金属，依次逐步形成单环戊二烯基二硝基硝酸铈，二环戊二烯一硝酸铈一硝酸二苯酯和三环戊二烯基铈。

8. 发明授权

US4801692A Ceric alkanolatoamines 失效
标题翻译：铈链烷醇胺
公开(公告)号：US4801692A
公开(公告)日：1989-01-31
申请号：US895560
申请日：1986-08-11
申请人： Peter S. Gradeff , Fred G. Schreiber
发明人： Peter S. Gradeff , Fred G. Schreiber
IPC分类号： C07F5/00 , C08G79/00
CPC分类号： C07F5/003
摘要： A compound having the formula ##STR1## wherein R is one or more moieties selected from the group consisting of hydrogen and alkyl having from 1 to 20 carbon atoms, R.sup.2 is an alkyl group having from 1 to 20 carbon atoms, R.sup.1 is an alkyl group having from 1 to 20 carbon atoms, m is an integer from 0 to 3, y is an integer from 1 to 3, x and z are each an integer from 0 to 2, n and p are each an integer from 1 to 20, with the proviso that m+yp=4n, the sum of x, y and z is 3.
摘要翻译：具有式的化合物，其中R是一个或多个选自氢和具有1-20个碳原子的烷基的部分，R 2是具有1至20个碳原子的烷基，R 1是烷基具有1至20个碳原子，m为0至3的整数，y为1至3的整数，x和z各自为0至2的整数，n和p各自为1至20的整数，条件是m + yp = 4n，x，y和z之和为3。

9. 发明授权

US4647401A Process for preparing colloidal ceric oxide and complexes thereof with free organic acids 失效
标题翻译：制备胶体氧化铈及其与游离有机酸的配合物的方法
公开(公告)号：US4647401A
公开(公告)日：1987-03-03
申请号：US678424
申请日：1984-12-05
申请人： Peter S. Gradeff , Fred G. Schreiber , Vincent J. Charte , John F. Davison
发明人： Peter S. Gradeff , Fred G. Schreiber , Vincent J. Charte , John F. Davison
IPC分类号： B01J13/00 , C01F17/00 , C07C51/41 , C07F5/00 , C09D191/00 , C09D3/26 , C09K11/07
CPC分类号： C07C309/00 , C01F17/0012 , C01F17/0043 , C07C51/414 , C07F5/00 , C01P2002/01
摘要： A process is provided for preparing colloidal dispersions of ceric dioxide in inert organic media which comprises(1) heating(a) ceric dioxide comprising ammonium nitrate or ammonium and nitrate ions in an amount within the range from about 3 to about 14% by weight of the ceric dioxide and a member selected from the group consisting of water, methanol, acetic acid and mixtures thereof in an amount usually from about 10 to about 60 g per mole of CeO.sub.2, sufficient to effect reaction with(b) an organic acid having from about ten to about forty carbon atoms(c) an organic solvent selected from the group consisting of(i) aliphatic and aromatic hydrocarbons, such as petroleum spirits, benzene, toluene, chlorobenzene, chlorotoluene, etc.(ii) aliphatic and cycloaliphatic ethers, such as isopropyl ether or dicyclohexyl ether(iii) aliphatic and cycloaliphatic ketones, such as diisobutylketone or cyclohexanone at a temperature within the range from about 60.degree. to about 200.degree. C. thereby effecting dispersion of the ceric dioxide;(2) removing water, methanol, acetic acid or mixtures thereof, and separating undissolved particles of solid material such as ammonium nitrate and undissolved cerium dioxide.Association complexes are also provided, composed of ceric dioxide and organic acid having from about ten to about forty carbon atoms in a molar ratio CeO.sub.2 /organic acid of at least 4:1.
摘要翻译：提供了一种用于制备惰性有机介质中二氧化铈的胶体分散体的方法，其包括（1）加热（a）包含硝酸铵或铵和硝酸根离子的二氧化铈，其量为约3至约14重量％二氧化铈和选自水，甲醇，乙酸及其混合物的成员，其量通常为每摩尔CeO 2约10至约60g，足以与（b）有机酸反应约10至约40个碳原子（c）选自（i）脂族和芳族烃如石油醚，苯，甲苯，氯苯，氯甲苯等的有机溶剂。（ii）脂族和脂环族醚，例如异丙醚或二环己基醚（iii）脂族和脂环族酮，例如二异丁基酮或环己酮，温度范围为约60-约200℃。分散二氧化铈; （2）除去水，甲醇，乙酸或其混合物，并分离固体物质如硝酸铵和未溶解的二氧化铈的未溶解颗粒。还提供了由二氧化铈和具有至少4:1的CeO 2 /有机酸的摩尔比约10至约40个碳原子的有机酸组成的缔合络合物。

10. 发明授权

US4545923A Process for preparing colloidal ceric oxide and complexes thereof with free organic acids 失效
标题翻译：制备胶体氧化铈及其与游离有机酸的配合物的方法
公开(公告)号：US4545923A
公开(公告)日：1985-10-08
申请号：US460694
申请日：1983-01-24
申请人： Peter S. Gradeff , Vincent J. Charte , Fred G. Schreiber , John F. Davison
发明人： Peter S. Gradeff , Vincent J. Charte , Fred G. Schreiber , John F. Davison
IPC分类号： B01F17/00 , B01J13/00 , C01F17/00 , C07C51/41 , C07F5/00 , C07F17/00 , C07C143/24 , C11C1/00
CPC分类号： C07C309/00 , C01F17/0012 , C01F17/0043 , C07C51/414 , C07F5/00 , C01P2002/01
摘要： A process is provided for preparing colloidal dispersions of ceric dioxide in inert organic media which comprises(1) heating(a) ceric dioxide comprising ammonium nitrate or ammonium and nitrate ions in an amount within the range from about 3 to about 14% by weight of the ceric dioxide and a member selected from the group consisting of water, methanol, acetic acid and mixtures thereof in an amount usually from about 10 to about 60 g per mole of CeO.sub.2, sufficient to effect reaction with(b) an organic acid having from about ten to about forty carbon atoms(c) an organic solvent selected from the group consisting of(i) aliphatic and aromatic hydrocarbons, such as petroleum spirits, benzene, toluene, chlorobenzene, chlorotoluene, etc.(ii) aliphatic and cycloaliphatic ethers, such as isopropyl ether or dicyclohexyl ether(iii) aliphatic and cycloaliphatic ketones, such as diisobutylketone or cyclohexanone at a temperature within the range from about 60 to about 200.degree. C. thereby effecting dispersion of the ceric dioxide;(2) removing water, methanol, acetic acid or mixtures thereof, and separating undissolved particles of solid material such as ammonium nitrate and undissolved cerium dioxide.Association complexes are also provided, composed of ceric dioxide and organic acid having from about ten to about forty carbon atoms in a molar ratio CeO.sub.2 /organic acid of at least about 4:1.
摘要翻译：提供了一种用于制备惰性有机介质中二氧化铈的胶体分散体的方法，其包括（1）加热（a）包含硝酸铵或铵和硝酸根离子的二氧化铈，其量为约3至约14重量％二氧化铈和选自水，甲醇，乙酸及其混合物的成员，其量通常为每摩尔CeO 2约10至约60g，足以与（b）有机酸反应约10至约40个碳原子（c）选自（i）脂族和芳族烃如石油醚，苯，甲苯，氯苯，氯甲苯等的有机溶剂。（ii）脂族和脂环族醚，例如异丙醚或二环己基醚（iii）脂族和脂环族酮，例如二异丁基酮或环己酮，温度范围为约60至约200℃，从而实现二氧化铈的分散体; （2）除去水，甲醇，乙酸或其混合物，并分离固体物质如硝酸铵和未溶解的二氧化铈的未溶解颗粒。还提供了由具有约10至约40个碳原子的二氧化铈和具有至少约4:1的摩尔比CeO 2 /有机酸的有机酸组成的缔合络合物。

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