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    • 7. 发明申请
    • Molecular sieve catalyst composition, its making and use in conversion processes
    • 分子筛催化剂组成,其制备和用途在转化过程中
    • US20050075525A1
    • 2005-04-07
    • US10677654
    • 2003-10-02
    • Yun-Feng ChangStephen VaughnKenneth ClemLuc MartensWeiguo Hu
    • Yun-Feng ChangStephen VaughnKenneth ClemLuc MartensWeiguo Hu
    • B01J29/06B01J29/84B01J29/85B01J35/00B01J37/00C07C1/20B01J27/182
    • B01J37/0045B01J29/06B01J29/84B01J29/85B01J35/002B01J37/0009C07C1/20C07C2521/04C07C2521/06C07C2521/16C07C2529/85Y02P30/20Y02P30/42Y10S502/504C07C11/02
    • This invention provides methods of making molecular sieve catalyst particles, molecular sieve slurries that can be used in such methods, molecular sieve catalyst compositions and their use in catalytic hydrocarbon conversion processes. In one of its aspects, the invention provides a method of making molecular sieve catalyst particles, the method comprising the steps of: a) providing a solution or suspension of an aluminum-containing inorganic oxide precursor in a liquid medium; b) combining the solution or suspension of aluminum-containing inorganic oxide precursor with a molecular sieve, and optionally other formulating agents, to form a catalyst formulation slurry; c) aging the catalyst formulation slurry to generate in said slurry a percentage, or increase in said slurry the existing percentage, of aluminum atoms of the aluminum-containing precursor in the form of oligomers having a sharp 27Al NMR peak at 62-63 ppm; and d) forming molecular sieve catalyst particles from the catalyst formulation slurry. The catalyst compositions obtained by the methods of the present invention have improved attrition resistance, and are particularly useful in hydrocarbon conversion processes.
    • 本发明提供制备分子筛催化剂颗粒,可用于这些方法的分子筛浆料,分子筛催化剂组合物及其在催化烃转化方法中的应用的方法。 在其一个方面,本发明提供了制备分子筛催化剂颗粒的方法,该方法包括以下步骤:a)提供含铝无机氧化物前体在液体介质中的溶液或悬浮液; b)将含铝的无机氧化物前体的溶液或悬浮液与分子筛和任选的其它配制剂组合以形成催化剂配方浆料; c)使催化剂配方浆料老化,以在所述浆料中产生百分比,或增加所述浆料中现有百分比的含铝前体的铝原子具有在62℃具有尖锐的27 C NMR峰的低聚物形式, 63 ppm; 和d)从催化剂配方浆料形成分子筛催化剂颗粒。 通过本发明的方法获得的催化剂组合物具有改善的耐磨耗性,并且在烃转化方法中特别有用。
    • 10. 发明申请
    • Molecular sieve catalyst composition, its making and use in conversion processes
    • 分子筛催化剂组成,其制备和用途在转化过程中
    • US20070260100A1
    • 2007-11-08
    • US11818403
    • 2007-06-14
    • Yun-Feng ChengStephen VaughnKenneth ClemLuc MartensWeiguo Hu
    • Yun-Feng ChengStephen VaughnKenneth ClemLuc MartensWeiguo Hu
    • C07C1/00
    • B01J37/0045B01J29/06B01J29/84B01J29/85B01J35/002B01J37/0009C07C1/20C07C2521/04C07C2521/06C07C2521/16C07C2529/85Y02P30/20Y02P30/42Y10S502/504C07C11/02
    • This invention provides methods of making molecular sieve catalyst particles, molecular sieve slurries that can be used in such methods, molecular sieve catalyst compositions and their use in catalytic hydrocarbon conversion processes. In one of its aspects, the invention provides a method of making molecular sieve catalyst particles, the method comprising the steps of: a) providing a solution or suspension of an aluminum-containing inorganic oxide precursor in a liquid medium; b) combining the solution or suspension of aluminum-containing inorganic oxide precursor with a molecular sieve, and optionally other formulating agents, to form a catalyst formulation slurry; c) aging the catalyst formulation slurry to generate in said slurry a percentage, or increase in said slurry the existing percentage, of aluminum atoms of the aluminum-containing precursor in the form of oligomers having a sharp 27 Al NMR peak at 62-63 ppm; and d) forming molecular sieve catalyst particles from the catalyst formulation slurry. The catalyst compositions obtained by the methods of the present invention have improved attrition resistance, and are particularly useful in hydrocarbon conversion processes.
    • 本发明提供制备分子筛催化剂颗粒,可用于这些方法的分子筛浆料,分子筛催化剂组合物及其在催化烃转化方法中的应用的方法。 在其一个方面,本发明提供了制备分子筛催化剂颗粒的方法,该方法包括以下步骤:a)提供含铝无机氧化物前体在液体介质中的溶液或悬浮液; b)将含铝的无机氧化物前体的溶液或悬浮液与分子筛和任选的其它配制剂组合以形成催化剂配方浆料; c)使所述催化剂配方浆料老化以在所述浆料中产生一种百分比,或增加所述浆料中含铝前体的铝原子的现有百分比,其具有尖锐的Al 2 O 3 在62-63ppm的NMR峰; 和d)从催化剂配方浆料形成分子筛催化剂颗粒。 通过本发明的方法获得的催化剂组合物具有改善的耐磨耗性,并且在烃转化方法中特别有用。