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1. 发明申请

US20100044275A1 SELECTIVE NAPHTHA DESULFURIZATION PROCESS AND CATALYST 有权
标题翻译：选择性硫酸盐脱硫方法和催化剂
公开(公告)号：US20100044275A1
公开(公告)日：2010-02-25
申请号：US12605730
申请日：2009-10-26
申请人： Lorenz J. Bauer , Suheil F. Abdo , Laura E. Leonard , Peter Kokayeff
发明人： Lorenz J. Bauer , Suheil F. Abdo , Laura E. Leonard , Peter Kokayeff
IPC分类号： C10G29/04
CPC分类号： B01J37/0221 , B01J23/24 , B01J23/74 , B01J23/85 , B01J23/882 , B01J35/008 , B01J37/0248 , C10G45/04 , C10G45/06 , C10G45/12 , C10G2300/1044 , C10G2300/202 , C10G2300/301 , C10G2400/02
摘要： A process and catalyst for the selective hydrodesulfurization of a naphtha containing olefins. The process produces a naphtha stream having a reduced concentration of sulfur while maintaining the maximum concentration of olefins.
摘要翻译：用于含有烯烃的石脑油的选择性加氢脱硫的方法和催化剂。该方法产生具有降低的硫浓度的石脑油流，同时保持烯烃的最大浓度。

2. 发明申请

US20090082606A1 Production of Diesel Fuel from Biorenewable Feedstocks 有权
标题翻译：生物可再生原料生产柴油
公开(公告)号：US20090082606A1
公开(公告)日：2009-03-26
申请号：US12193149
申请日：2008-08-18
申请人： Terry L. Marker , Peter Kokayeff , Suheil F. Abdo , Tom N. Kalnes
发明人： Terry L. Marker , Peter Kokayeff , Suheil F. Abdo , Tom N. Kalnes
IPC分类号： C07C1/00
CPC分类号： C10G3/50 , C10G3/46 , C10G3/47 , C10G2300/1014 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2400/04 , Y02P30/20
摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant oils, animal fats and oils, and greases. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide a diesel boiling range fuel hydrocarbon product. If desired, the hydrocarbon product can be isomerized to improve cold flow properties. A portion of the hydrocarbon product is recycled to the treatment zone to increase the hydrogen solubility of the reaction mixture.
摘要翻译：已经开发了用于从可再生原料如植物油，动物油脂和油脂生产柴油沸点燃料的方法。该方法包括通过氢化和脱氧处理可再生原料以提供柴油沸程燃料烃产物。如果需要，烃产物可被异构化以改善冷流动性能。一部分烃产物被再循环到处理区以提高反应混合物的氢溶解度。

3. 发明授权

US06548721B1 Hydrotreating olefin stream with complete destruction of oxygenates 有权
标题翻译：加氢处理烯烃流完全破坏含氧化合物
公开(公告)号：US06548721B1
公开(公告)日：2003-04-15
申请号：US09862897
申请日：2001-05-22
申请人： Beth Mc Culloch , Jennifer L. Gordon , Peter Kokayeff , Suheil F. Abdo , Daniel H. Wei
发明人： Beth Mc Culloch , Jennifer L. Gordon , Peter Kokayeff , Suheil F. Abdo , Daniel H. Wei
IPC分类号： C07C502
CPC分类号： C07C7/163 , C07C2523/85 , C07C2523/883 , C07C2527/02 , C07C11/02
摘要： Disclosed is a process for completely destroying oxygenates in a feed stream. The feed stream of oxygenates typically includes olefins and it is reacted with hydrogen over a catalyst comprising a top row of Group VIII metal and a Group VI-B metal. Olefins are essentially completely saturated and any sulfur compounds present in the feed are completely converted to hydrogen sulfide. A preferred catalyst includes 2 to 5 wt-% nickel, 5 to 15 wt-% molybdenum, at least 5.5 wt-% sulfur, less than 0.05 wt-% phosphorus and no more than 0.3 wt-% silicon. The catalyst has low acidity and therefore does not promote the cracking of desired oligomeric products. The deoxygenation process is preferably a saturation process that follows an oligomerization process in which light olefins are oligomerized to heavy olefins. The saturation catalyst preferably has lower acidity which causes minimal cracking of desired oligomeric products. However, by optimally raising the temperature of the outlet of the saturation reaction zone, excessively heavy oligomers can be cracked down to desirable heavy oligomers.
摘要翻译：公开了一种在进料流中完全破坏含氧化合物的方法。含氧化合物的进料流通常包括烯烃，并且其与氢气在包含第一排VIII族金属和VI-B族金属的催化剂上反应。烯烃基本上完全饱和，并且进料中存在的任何硫化合物完全转化成硫化氢。优选的催化剂包括2至5重量％的镍，5至15重量％的钼，至少5.5重量％的硫，小于0.05重量％的磷和不超过0.3重量％的硅。催化剂具有低酸度，因此不促进所需低聚产物的裂化。脱氧方法优选是在轻烯烃低聚至重质烯烃的低聚方法之后的饱和方法。饱和催化剂优选具有较低的酸度，这导致所需低聚产物的最小裂化。然而，通过最佳地提高饱和反应区的出口的温度，过量的低聚物可以被裂化成所需的重低聚物。

4. 发明授权

US07982075B2 Production of diesel fuel from biorenewable feedstocks with lower hydrogen consumption 有权
标题翻译：从生物可再生原料生产具有较低氢消耗的柴油
公开(公告)号：US07982075B2
公开(公告)日：2011-07-19
申请号：US12193120
申请日：2008-08-18
申请人： Terry L. Marker , Peter Kokayeff , Suheil F. Abdo , Franco Baldiraghi , Luigina M. F. Sabatino
发明人： Terry L. Marker , Peter Kokayeff , Suheil F. Abdo , Franco Baldiraghi , Luigina M. F. Sabatino
IPC分类号： C07C1/20 , C07C4/00
CPC分类号： C10L1/08 , C01B3/16 , C01B3/50 , C01B2203/0415 , C01B2203/043 , C01B2203/0455 , C01B2203/0475 , C01B2203/0485 , C01B2203/148 , C10G3/46 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , C10G2300/202 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/28 , Y02E50/13 , Y02P30/20
摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant and animal fats and oils. The process involves treating a renewable feedstock by hydrogenating and deoxygenating i.e. decarboxylating, decarbonylating, and hydrodeoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel. A sulfur containing component is added to drive the conversion preferentially through carbonylation and carbonylation with reduced hydrodeoxygenation. If desired, the hydrocarbon fraction can be isomerized to improve cold flow properties.
摘要翻译：已经开发了用于从可再生原料如植物和动物脂肪和油生产柴油沸点燃料的方法。该方法包括通过氢化和脱氧处理可再生原料，即脱羧，脱羰和加氢脱氧以提供可用作柴油沸程燃料的烃馏分。加入含硫组分以优先通过羰基化和羰基化优化以减少加氢脱氧。如果需要，烃馏分可以被异构化以改善冷流动性能。

5. 发明申请

US20110024327A1 PRODUCTION OF DIESEL FUEL FROM BIORENEWABLE FEEDSTOCKS 有权
标题翻译：柴油燃料从生物柴油生产
公开(公告)号：US20110024327A1
公开(公告)日：2011-02-03
申请号：US12899221
申请日：2010-10-06
申请人： Terry L. Marker , Peter Kokayeff , Suheil F. Abdo , Tom N. Kalnes
发明人： Terry L. Marker , Peter Kokayeff , Suheil F. Abdo , Tom N. Kalnes
IPC分类号： C10G45/00
CPC分类号： C10G3/50 , C10G3/46 , C10G3/47 , C10G2300/1014 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2400/04 , Y02P30/20
摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant oils, animal fats and oils, and greases. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide a diesel boiling range fuel hydrocarbon product. If desired, the hydrocarbon product can be isomerized to improve cold flow properties. A portion of the hydrocarbon product is recycled to the treatment zone to increase the hydrogen solubility of the reaction mixture.
摘要翻译：已经开发了用于从可再生原料如植物油，动物油脂和油脂生产柴油沸点燃料的方法。该方法包括通过氢化和脱氧处理可再生原料以提供柴油沸程燃料烃产物。如果需要，烃产物可被异构化以改善冷流动性能。一部分烃产物被再循环到处理区以提高反应混合物的氢溶解度。

6. 发明授权

US07629289B2 Selective naphtha desulfurization process and catalyst 有权
标题翻译：选择性石脑油脱硫工艺及催化剂
公开(公告)号：US07629289B2
公开(公告)日：2009-12-08
申请号：US10875117
申请日：2004-06-23
申请人： Lorenz J. Bauer , Suheil F. Abdo , Laura E. Jones , Peter Kokayeff
发明人： Lorenz J. Bauer , Suheil F. Abdo , Laura E. Jones , Peter Kokayeff
IPC分类号： B01J23/00 , B01J21/00 , B01J29/00
CPC分类号： B01J37/0221 , B01J23/24 , B01J23/74 , B01J23/85 , B01J23/882 , B01J35/008 , B01J37/0248 , C10G45/04 , C10G45/06 , C10G45/12 , C10G2300/1044 , C10G2300/202 , C10G2300/301 , C10G2400/02
摘要： A process and catalyst for the selective hydrodesulfurization of a naphtha containing olefins. The process produces a naphtha stream having a reduced concentration of sulfur while maintaining the maximum concentration of olefins.
摘要翻译：用于含有烯烃的石脑油的选择性加氢脱硫的方法和催化剂。该方法产生具有降低的硫浓度的石脑油流，同时保持烯烃的最大浓度。

7. 发明授权

US08003836B2 Production of diesel fuel from biorenewable feedstocks 有权
公开(公告)号：US08003836B2
公开(公告)日：2011-08-23
申请号：US12899221
申请日：2010-10-06
申请人： Terry L. Marker , Peter Kokayeff , Suheil F. Abdo , Tom N. Kalnes
发明人： Terry L. Marker , Peter Kokayeff , Suheil F. Abdo , Tom N. Kalnes
IPC分类号： C07C4/00
CPC分类号： C10G3/50 , C10G3/46 , C10G3/47 , C10G2300/1014 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2400/04 , Y02P30/20
摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant oils, animal fats and oils, and greases. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide a diesel boiling range fuel hydrocarbon product. If desired, the hydrocarbon product can be isomerized to improve cold flow properties. A portion of the hydrocarbon product is recycled to the treatment zone to increase the hydrogen solubility of the reaction mixture.

8. 发明授权

US07982076B2 Production of diesel fuel from biorenewable feedstocks 有权
标题翻译：生物可再生原料生产柴油
公开(公告)号：US07982076B2
公开(公告)日：2011-07-19
申请号：US12193149
申请日：2008-08-18
申请人： Terry L. Marker , Peter Kokayeff , Suheil F. Abdo , Tom N. Kalnes
发明人： Terry L. Marker , Peter Kokayeff , Suheil F. Abdo , Tom N. Kalnes
IPC分类号： C07C4/00
CPC分类号： C10G3/50 , C10G3/46 , C10G3/47 , C10G2300/1014 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2400/04 , Y02P30/20
摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant oils, animal fats and oils, and greases. The process involves treating a renewable feedstock by hydrogenating and deoxygenating to provide a diesel boiling range fuel hydrocarbon product. If desired, the hydrocarbon product can be isomerized to improve cold flow properties. A portion of the hydrocarbon product is recycled to the treatment zone to increase the hydrogen solubility of the reaction mixture.
摘要翻译：已经开发了用于从可再生原料如植物油，动物油脂和油脂生产柴油沸点燃料的方法。该方法包括通过氢化和脱氧处理可再生原料以提供柴油沸程燃料烃产物。如果需要，烃产物可被异构化以改善冷流动性能。一部分烃产物被再循环到处理区以提高反应混合物的氢溶解度。

9. 发明授权

US4886935A Ni/Cu absorbent/catalyst for desulfurization and isomerization of n-paraffins 失效
标题翻译：用于正链烷烃脱硫和异构化的Ni / Cu吸收剂/催化剂
公开(公告)号：US4886935A
公开(公告)日：1989-12-12
申请号：US238779
申请日：1988-08-31
申请人： Peter Kokayeff , Suheil F. Abdo
发明人： Peter Kokayeff , Suheil F. Abdo
IPC分类号： B01J29/072 , B01J29/08 , B01J29/14 , B01J29/76 , C07C5/13 , C10G47/20
CPC分类号： C10G47/20 , B01J29/072 , B01J29/084 , B01J29/146 , B01J29/76 , B01J2229/16
摘要： A hydrocarbon-containing feedstock is desulfurized so as to contain less than 5, and preferably less than 2 ppmw of sulfur, in the first stage of a two-stage process. In the second stage, the feedstock is contacted with an isomerization catalyst useful for promoting n-paraffin isomerization reactions. A dual-function catalyst containing both Group VIII and Group IB metals and effective for simultaneously absorbing sulfur and isomerizing a hydrocarbon feedstock may be employed in the first stage. Alternatively, the dual-function catalyst may be employed in both the first and second stages. Alternatively still, the dual-function catalyst may be used to treat a feedstock containing n-paraffins in a single stage isomerization process.
摘要翻译：在两阶段工艺的第一阶段，含烃原料被脱硫以便含有少于5％，优选小于2ppmw的硫。在第二阶段中，原料与可用于促进正链烷烃异构化反应的异构化催化剂接触。可以在第一阶段中使用含有VIII族和IB族金属并且有效同时吸收硫和异构化烃原料的双功能催化剂。或者，双功能催化剂可以用于第一和第二阶段。或者，双功能催化剂可用于在单级异构化方法中处理含有正链烷烃的原料。

10. 发明申请

US20090193709A1 Production of Diesel Fuel from Biorenewable Feedstocks with Lower Hydrogen Consumption 有权
标题翻译：生产可燃低原料的生物可利用原料柴油
公开(公告)号：US20090193709A1
公开(公告)日：2009-08-06
申请号：US12193120
申请日：2008-08-18
申请人： Terry L. Marker , Peter Kokayeff , Suheil F. Abdo , Franco Baldiraghi , Luigina M.F. Sabatino
发明人： Terry L. Marker , Peter Kokayeff , Suheil F. Abdo , Franco Baldiraghi , Luigina M.F. Sabatino
IPC分类号： C10L1/18
CPC分类号： C10L1/08 , C01B3/16 , C01B3/50 , C01B2203/0415 , C01B2203/043 , C01B2203/0455 , C01B2203/0475 , C01B2203/0485 , C01B2203/148 , C10G3/46 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , C10G2300/202 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/28 , Y02E50/13 , Y02P30/20
摘要： A process has been developed for producing diesel boiling range fuel from renewable feedstocks such as plant and animal fats and oils. The process involves treating a renewable feedstock by hydrogenating and deoxygenating i.e. decarboxylating, decarbonylating, and hydrodeoxygenating to provide a hydrocarbon fraction useful as a diesel boiling range fuel. A sulfur containing component is added to drive the conversion preferentially through carbonylation and carbonylation with reduced hydrodeoxygenation. If desired, the hydrocarbon fraction can be isomerized to improve cold flow properties.
摘要翻译：已经开发了用于从可再生原料如植物和动物脂肪和油生产柴油沸点燃料的方法。该方法包括通过氢化和脱氧处理可再生原料，即脱羧，脱羰和加氢脱氧以提供可用作柴油沸程燃料的烃馏分。加入含硫组分以优先通过羰基化和羰基化优化以减少加氢脱氧。如果需要，烃馏分可以被异构化以改善冷流动性能。

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