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    • 4. 发明授权
    • Resilient battery separator
    • 弹性电池分离器
    • US5645956A
    • 1997-07-08
    • US508061
    • 1995-07-27
    • Peter John DegenJoseph Yuen LeeIoannis P. Sipsas
    • Peter John DegenJoseph Yuen LeeIoannis P. Sipsas
    • D04H3/00H01M2/16
    • H01M2/162
    • The present invention provides a battery separator comprising a nonwoven web of first and second fibers having a mean diameter of about 15 .mu.m or less, wherein the first fibers comprise at least about 60 wt. % of a first polyolefin having a first melting temperature and no more than about 40 wt. % of a second polyolefin having a second melting temperature which is lower than the first melting temperature, the second fibers comprise a third polyolefin having a third melting temperature which is higher than the second melting temperature, the nonwoven web has two sides, one of which sides has been contacted with a heated surface such that the nonwoven web has been subjected to a temperature higher than the second melting temperature and lower than the first and third melting temperatures so as to render the contacted side more smooth than the other side, the battery separator is spontaneously wettable by an electrolyte, the battery separator has a thickness of at least about 50 .mu.m, and the battery separator has a percent rebound thickness of at least about 92% after the application of pressure up to 80 kPa. The present inventive battery separator preferably comprises two such nonwoven webs mated to each other nonsmooth side-to-nonsmooth side. The present invention also provides a method of preparing such a battery separator, as well as a battery incorporating such a battery separator.
    • 本发明提供了一种电池隔板,其包括平均直径约15μm或更小的第一和第二纤维的非织造纤维网,其中第一纤维包含至少约60wt。 %的第一聚烯烃具有第一熔融温度并且不超过约40wt。 %的具有低于第一熔融温度的第二熔融温度的第二聚烯烃,第二纤维包括第三聚烯烃,其具有高于第二熔融温度的第三熔融温度,非织造纤维网具有两个侧面,其中一个 侧面已经与加热表面接触,使得非织造纤维网经受比第二熔融温度高且低于第一和第三熔化温度的温度,以使接触侧比另一侧更光滑,电池 分离器可由电解质自发润湿,电池隔板的厚度至少约为50微米,电池隔膜的施加压力高达80千帕时的回弹厚度百分比至少为92%。 本发明的电池隔板优选地包括两个这样的非织造纤维网,彼此非光滑的侧向到非光滑的一侧配合。 本发明还提供一种制备这种电池隔板的方法,以及包含这种电池隔板的电池。
    • 5. 发明授权
    • Polyvinylidene fluoride membrane and method for removing viruses from
solutions
    • 聚偏二氟乙烯膜和从溶液中除去病毒的方法
    • US5736051A
    • 1998-04-07
    • US327622
    • 1994-10-24
    • Peter John DegenIoannis P. SipsasGregory C. RapisardaJoseph Gregg
    • Peter John DegenIoannis P. SipsasGregory C. RapisardaJoseph Gregg
    • B01D67/00B01D69/02B01D71/34B01D71/32C12N7/00C12Q1/70
    • B01D67/0095B01D67/0011B01D67/0093B01D69/02B01D71/34B01D2323/30B01D2325/04
    • The present invention provides an isotropic, skinless, porous, polyvinylidene fluoride membrane having a K.sub.UF of at least about 15 psi (103 kPa), and preferably below about 50 psi (345 kPa), when tested using liquid pairs having an interfacial tension of about 4 dynes/cm (4 mN/m). The present inventive membrane preferably has a titer reduction of at least about 10.sup.8 against T.sub.1 bacteriophage, more preferably also against PR772 coliphage, and even more preferably also against PP7 bacteriophage. The present inventive membrane can have a thickness of about 20 mil (500 .mu.m) or less and even as low as about 5 mil (125 .mu.m) or less. The present invention also provides a method of preparing such a membrane by providing a casting solution comprising polyvinylidene fluoride and a solvent therefor, heating the casting solution to a uniform temperature of about 57.degree. C. to about 60.degree. C., spreading the casting solution onto a substrate to form a film, quenching the film in a quench bath so as to form a porous membrane, and washing and drying the porous membrane.
    • 本发明提供了具有至少约15psi(103kPa),优选低于约50psi(345kPa)的KUF的各向同性,无表皮,多孔的聚偏二氟乙烯膜,当使用具有约 4达因/厘米(4毫米/米)。 本发明的膜优选具有针对T1噬菌体至少约108的滴度降低,更优选地还针对PR772大肠杆菌噬菌体,甚至更优选地也针对PP7噬菌体。 本发明的膜可以具有约20密耳(500μm)或更低,甚至低至约5密耳(125μm)或更低的厚度。 本发明还提供一种通过提供包含聚偏二氟乙烯和其溶剂的浇铸溶液来制备这种膜的方法,将浇铸溶液加热到约57℃至约60℃的均匀温度,将浇铸溶液 在基板上形成膜,在骤冷槽中淬火以形成多孔膜,并洗涤并干燥多孔膜。