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1. 发明授权

US06251989B1 Oligomerized organopolysiloxane cocondensate, its production and its use for treatment of surfaces 失效
标题翻译：低聚有机聚硅氧烷缩聚物，其生产及其用于表面处理
公开(公告)号：US06251989B1
公开(公告)日：2001-06-26
申请号：US09318839
申请日：1999-05-26
申请人： Roland Edelmann , Albert-Johannes Frings , Michael Horn , Peter Jenkner , Eckhard Just , Manfred Kaussen , Ralf Laven , Helmut Lohmann , Helmut Mack , Jaroslaw Monkiewicz , Stephan Ramlow , Burkhard Standke , Tilman Taeger
发明人： Roland Edelmann , Albert-Johannes Frings , Michael Horn , Peter Jenkner , Eckhard Just , Manfred Kaussen , Ralf Laven , Helmut Lohmann , Helmut Mack , Jaroslaw Monkiewicz , Stephan Ramlow , Burkhard Standke , Tilman Taeger
IPC分类号： C08G7718
CPC分类号： C08G77/045 , C08G77/24 , C08G77/26 , C09K3/18
摘要： An oligomerized polyorganosiloxane cocondensate which may be obtained, in part, by mixing an water-soluble amino-functional organosilane represented with at least one of the followoing: a fluoro-functional organosilane, an organosilane, and an organosilane. The cocondensate may be used, for example, in a method of treating surfaces.
摘要翻译：低聚聚有机硅氧烷缩聚物，其部分可以通过混合由至少一个以下代表的水溶性氨基官能的有机硅烷：氟官能的有机硅烷，有机硅烷和有机硅烷而获得。缩聚物可以用于例如处理表面的方法中。

2. 发明授权

US06177582B1 Fluoroalkyl-functional organosiloxane-containing compositions based on alcohol, a process for their preparation and their use 失效
标题翻译：基于醇的含氟烷基官能的有机硅氧烷的组合物，其制备方法及其用途
公开(公告)号：US06177582B1
公开(公告)日：2001-01-23
申请号：US08984162
申请日：1997-12-03
申请人： Peter Jenkner , Albert-Johannes Frings , Michael Horn , Eckhard Just , Jaroslaw Monkiewicz , Burkhard Standke
发明人： Peter Jenkner , Albert-Johannes Frings , Michael Horn , Eckhard Just , Jaroslaw Monkiewicz , Burkhard Standke
IPC分类号： C07P708
CPC分类号： C03C25/40 , C08G77/24 , C09D183/08 , C09K3/18 , D06M13/513 , D06M15/657 , D21H19/32 , D21H21/16
摘要： An alcoholic fluoroalkyl-functional group containing organosiloxane based composition is prepared by the controlled hydrolysis of at least one fluoroalkyl-functional group containing organosilane of formula I: R1—Y—(CH2)2SiHx(R2)y(OR)3−x−y (I), in which R1 is a mono, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH2, O or S group, R2 and R are each independently a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and x=0, 1 or 2 and y=0, 1 or 2, where (x+y)≦2, at a temperature in the range of 0-120° C. over a period of 0.5-24 hours and with thorough mixing in an alcoholic medium which contains water and a weak mono- or polybasic acid or a weak base or a weak mono- or polybasic acid and a weak base or an acid or basic salt, the water employed and the alkoxysilane employed being in a molar ratio of 2-500:1.
摘要翻译：含有有机硅氧烷的组合物的含氟烷基官能团的组合物是通过控制水解含有式I的有机硅烷的至少一个氟代烷基官能团制备的：其中R 1是具有1-9个C原子的单，低聚或全氟化烷基或单，低聚或全氟化芳基，Y是CH 2，O或S基团，R 2和R 3各自独立地为具有1-8个碳原子或芳基且x = 0的直链，支链或环状的烷基， 1或2，y = 0,1或2，其中（x + y）<= 2，在0〜120℃的温度范围内，在0.5-24小时内，并在酒精中充分混合含有水和弱单或多元酸或弱碱或弱单或多元酸和弱碱或酸或碱性盐的介质，所用的水和使用的烷氧基硅烷的摩尔比为2- 500：1。

3. 发明授权

US06713186B1 Fluoroalkyl-functional organosiloxane-containing compositions based on alcohol, a process for their preparation and their use 失效
标题翻译：基于醇的含氟烷基官能的有机硅氧烷的组合物，其制备方法及其用途
公开(公告)号：US06713186B1
公开(公告)日：2004-03-30
申请号：US09685341
申请日：2000-10-11
申请人： Peter Jenkner , Albert-Johannes Frings , Michael Horn , Eckhard Just , Jaroslaw Monkiewicz , Burkhard Standke
发明人： Peter Jenkner , Albert-Johannes Frings , Michael Horn , Eckhard Just , Jaroslaw Monkiewicz , Burkhard Standke
IPC分类号： B32B1500
CPC分类号： C09K3/18 , C03C25/40 , C08G77/24 , C09D183/08 , D06M13/513 , D06M15/657 , D21H19/32 , D21H21/16 , Y10T428/31663
摘要： An alcoholic fluoroalkyl-functional group containing organosiloxane based composition prepared is prepared by the controlled hydrolysis of at least one fluoroalkyl-functional group containing organosilane of formula I: R1—Y—(CH2)2SiHx(R2)y(OR)3−x−y (I), in which R1 is a mono, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH2, O or S group, R2 and R are each independently a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and x=0, 1 or 2 and y=0, 1 or 2, where (x+y)≦2, at a temperature in the range of 0-120° C. over a period of 0.5-24 hours and with thorough mixing in an w alcoholic medium which contains water and a weak mono- or polybasic acid or a weak base or a weak mono- or polybasic acid and a weak base or an acid or basic salt, the water employed and the alkoxysilane employed being in a molar ratio of 2-500:1.
摘要翻译：制备的含有机硅氧烷的组合物的含氟烷基官能团的组合物是通过控制水解至少一个含有氟代烷基官能团的式I有机硅烷来制备的：其中R 1是具有1-羟基的单，低聚或全氟化的烷基， 9个C原子或单，低聚或全氟化芳基，Y为CH 2，O或S基团，R 2和R 3各自独立地为具有1-8个C原子的直链，支链或环状烷基或芳基和x = 0,1或2，y = 0,1或2，其中（x + y）<= 2，在0〜120℃的温度下，在0.5-24小时内并且在含有水和弱单或多元酸或弱碱或弱单或多元酸和弱碱或酸或碱性盐的w-醇介质中充分混合，使用的水和使用的烷氧基硅烷摩尔比为2-500:1。

4. 发明申请

US20090005518A1 Block Condensates of Organofunctional Siloxanes, Their Preparation and Use, and Their Properties 审中-公开
公开(公告)号：US20090005518A1
公开(公告)日：2009-01-01
申请号：US11572555
申请日：2005-06-03
申请人： Eckhard Just , Sabine Giessler-Blank , Burkhard Standke
发明人： Eckhard Just , Sabine Giessler-Blank , Burkhard Standke
IPC分类号： C09D183/04 , B05D3/10
CPC分类号： C08G77/24 , C08G77/26 , C09D183/08
摘要： The present invention relates to a composition which comprises (i) at least one block condensate of organofunctional siloxanes of the general formula (I) [F]e[QcPb]d (I) and/or (ii) at least one mixture composed of e[F] and d(c[Q]+b[P]) and, where appropriate d[QcPb]. These compositions or block condensates are obtainable via reaction of block units F with block units Q, P, and/or QP, by one of the following methods:—c1) diluting block unit F optionally with an alcohol, adding an organic or inorganic acid and from 0.5 to 150 mol of water per mole of Si of the siloxane used, whereupon at least partial hydrolysis of the block units used takes place, then adding block unit Q and block unit P, and allowing the mixture to react, or—c2) diluting block unit F optionally with an alcohol, mixing with Q, P, and/or block unit QP, then adding an organic or inorganic acid and, using from 0.5 to 150 mol of water per mole of Si of the siloxanes used, carrying out partial hydrolysis and block-condensation, or—c3) diluting block unit F optionally with an alcohol, adding an organic or inorganic acid and from 0.5 to 150 mol of water per mole of Si of the siloxane used, with at least partial hydrolysis, adding block unit QP, and allowing the mixture to react, or—c4) diluting block units Q, P, and/or QP, optionally with an alcohol, adding an organic or inorganic acid and from 0.5 to 1.5 mol of water per mole of Si of the siloxanes used, and at least partially hydrolyzing, then adding block unit F and also from 0 to 148.5 mol of water per mole of Si of the siloxanes used, and allowing the mixture to react, or—c5) diluting block unit F optionally with an alcohol, mixing with from 0.5 to 150 mol of water per mole of Si of the siloxanes used, and with an organic or inorganic acid, and then adding a tetraalkoxysiloxane, and allowing the mixture to react. The present invention further relates to a process for the preparation of these compositions or block condensates, and to their use and to items thus obtainable: abrasion-resistant easy-clean coatings and items equipped with this type of coating.

5. 发明授权

US08298679B2 Aqueous silane systems based on bis(trialkoxysilylalkyl)amines 有权
标题翻译：基于双（三烷氧基甲硅烷基烷基）胺的水性硅烷体系
公开(公告)号：US08298679B2
公开(公告)日：2012-10-30
申请号：US12674271
申请日：2008-07-02
申请人： Philipp Albert , Eckhard Just , Christian Wassmer , Burkhard Standke
发明人： Philipp Albert , Eckhard Just , Christian Wassmer , Burkhard Standke
IPC分类号： B32B9/04
CPC分类号： C04B41/64 , C03C17/30 , C04B41/009 , C04B41/4961 , C08L83/08 , C09D4/00 , C09D183/08 , C23C2222/20 , Y10T428/1317 , Y10T428/31663 , Y10T428/31667 , C04B28/02 , C08L2666/34 , C08G77/26 , C08G77/00
摘要： The invention relates to an aqueous composition of bis-amino-functional silicon compounds which is essentially free of organic solvents and releases essentially no further alcohol in the course of crosslinking, and to processes for preparing it and to the use thereof, for example for hydrophobization of metal or glass surfaces.
摘要翻译：本发明涉及双官能硅化合物的水性组合物，其基本上不含有机溶剂，并且在交联过程中基本上不释放其它醇，以及其制备方法及其用途，例如疏水化的金属或玻璃表面。

6. 发明申请

US20110268899A1 AQUEOUS SILANE SYSTEMS BASED ON BIS(TRIALKOXYSILYLALKYL)AMINES 有权
标题翻译：基于BIS（三甲基甲硅烷基）胺的氨基硅烷系统
公开(公告)号：US20110268899A1
公开(公告)日：2011-11-03
申请号：US12674271
申请日：2008-07-02
申请人： Philipp Albert , Eckhard Just , Christian Wassmer , Burkhard Standke
发明人： Philipp Albert , Eckhard Just , Christian Wassmer , Burkhard Standke
IPC分类号： B32B1/08 , C09D5/00 , B32B9/04 , C09D7/00
CPC分类号： C04B41/64 , C03C17/30 , C04B41/009 , C04B41/4961 , C08L83/08 , C09D4/00 , C09D183/08 , C23C2222/20 , Y10T428/1317 , Y10T428/31663 , Y10T428/31667 , C04B28/02 , C08L2666/34 , C08G77/26 , C08G77/00
摘要： The invention relates to an aqueous composition of bis-amino-functional silicon compounds which is essentially free of organic solvents and releases essentially no further alcohol in the course of crosslinking, and to processes for preparing it and to the use thereof, for example for hydrophobization of metal or glass surfaces.
摘要翻译：本发明涉及双官能硅化合物的水性组合物，其基本上不含有机溶剂，并且在交联过程中基本上不释放进一步的醇，以及其制备方法及其用途，例如疏水化的金属或玻璃表面。

7. 发明申请

US20110118496A1 PROCESS FOR PREPARING ALKYLAMINOALKYLALKOXYSILANES 有权
标题翻译：制备烷基氨基烷基氧化硅的方法
公开(公告)号：US20110118496A1
公开(公告)日：2011-05-19
申请号：US12995852
申请日：2009-04-17
申请人： Eckhard Just , Philipp Albert , Peter Jenkner
发明人： Eckhard Just , Philipp Albert , Peter Jenkner
IPC分类号： C07F7/20
CPC分类号： C07F7/1892 , Y02P20/582
摘要： A process for preparing an alkylaminoalkylalkoxysilane of formula (I) R—(NR′)—Y—Si(R1)n(OR2)3-n (I) in which R is a linear, branched or cyclic alkyl group having 1 to 12 carbon atoms, R′ is a hydrogen (H) or is a linear, branched or cyclic alkyl group having 1 to 12 carbon atoms, Y is a bivalent alkyl group from the group of —CH2—, —(CH2)2—, —(CH2)3—, —(CH2)(CH(CH3))(CH2)— and —(CH2)4—, R1 and R2 groups are the same or different and are each a linear or branched alkyl group having 1 to 4 carbon atoms, and n is 0 or 1 or 2, by reacting an alkylamine, used in excess, with a haloalkylalkoxysilane, distilling off excess free alkylamine, treating the remaining product mixture with the alkylaminoalkylalkoxysilane and working up.
摘要翻译：制备式（I）所示的烷基氨基烷基烷氧基烷氧基硅烷的方法R-（NR'）-Y-Si（R 1）n（OR 2）3-n（I）其中R是具有1至12个直链，支链或环状的烷基碳原子，R'是氢（H）或是具有1至12个碳原子的直链，支链或环状烷基，Y是来自-CH 2 - ， - （CH 2）2 - ， - （CH 2）3 - ， - （CH 2）（CH（CH 3））（CH 2） - 和 - （CH 2）4 - ，R 1和R 2相同或不同，各自为具有1-4个碳原子，n为0或1或2，通过使过量使用的烷基胺与卤代烷基烷氧基硅烷反应，蒸馏掉过量的游离烷基胺，用烷基氨基烷基烷氧基硅烷处理剩余的产物混合物并加工。

8. 发明申请

US20110259240A1 COMPOSITION CONTAINING LOW-VOC, AMINOALKYL-FUNCTIONAL SILICON COMPOUNDS FOR COATING COLORS FOR THE TREATMENT OF PAPER OR FILM 审中-公开
标题翻译：包含用于处理纸张或胶片的涂料的低VOC，氨基官能化硅化合物的组合物
公开(公告)号：US20110259240A1
公开(公告)日：2011-10-27
申请号：US12674601
申请日：2008-07-04
申请人： Peter Jenkner , Christoph Batz-Sohn , Heinz Lach , Stefan Scharfe , Philipp Albert , Eckhard Just
发明人： Peter Jenkner , Christoph Batz-Sohn , Heinz Lach , Stefan Scharfe , Philipp Albert , Eckhard Just
IPC分类号： C09D7/00
CPC分类号： C08G77/54 , B41M5/52 , B41M5/5218 , B41M5/529 , C08L83/14 , C09D183/14
摘要： The present invention relates to the use of a composition in coating agents, which is poor in volatile organic compounds (VOC) or essentially free of VOC, wherein the composition is at least partially based on one or more partially or fully hydrolyzed and optionally condensed or co-condensed aminoalkyl- and oligosilylated-aminoalkyl-, alkoxy- or hydroxy-functional silicon compounds and the alcohol is at least partially removed from the composition. The invention also relates to a composition containing aminoalkyl- or oligosilylated-aminoalkyl-, hydroxy- and optionally alkoxy-functional silicon compounds and to a method for producing such a composition.
摘要翻译：本发明涉及组合物在包衣剂中的用途，其在挥发性有机化合物（VOC）中较差或基本上不含VOC，其中该组合物至少部分基于一种或多种部分或全部水解并任选地缩合或共缩合氨基烷基 - 和寡甲硅烷基化 - 氨基烷基 - ，烷氧基 - 或羟基官能的硅化合物和醇至少部分地从组合物中除去。本发明还涉及包含氨基烷基 - 或寡甲硅烷基化的 - 氨基烷基 - 羟基 - 和任选的烷氧基官能的硅化合物的组合物以及用于制备这种组合物的方法。

9. 发明授权

US07598409B2 Specific process for preparing silicon compounds bearing fluoroalkyl groups by hydrosilylation 有权
标题翻译：通过氢化硅烷化制备带有氟烷基的硅化合物的具体方法
公开(公告)号：US07598409B2
公开(公告)日：2009-10-06
申请号：US10583553
申请日：2004-10-21
申请人： Eckhard Just , Sabine Giessler , Peter Jenkner
发明人： Eckhard Just , Sabine Giessler , Peter Jenkner
IPC分类号： C07F7/04
CPC分类号： C07F7/14
摘要： The present invention relates to a process for preparing silicon compounds bearing fluoroalkyl groups by hydrosilylation of a fluoroolefin in the presence of a hydrosilylation catalyst, which comprises initially charging and heating a hydrogenchlorosilane, then metering in the fluoroolefin and reacting the reaction mixture and subsequently isolating the hydrosilylation product.
摘要翻译：本发明涉及一种在氢化硅烷化催化剂存在下通过氟代烯烃的氢化硅烷化制备含氟烷基的硅化合物的方法，该方法包括首先加入和加热氢氯硅烷，然后计量氟代烯烃并使反应混合物反应，氢化硅烷化产物。

10. 发明申请

US20070112213A1 Specific process for preparing silicon compounds bearing fluoroalkyl groups by hydrosilylation 有权
标题翻译：通过氢化硅烷化制备带有氟烷基的硅化合物的具体方法
公开(公告)号：US20070112213A1
公开(公告)日：2007-05-17
申请号：US10583553
申请日：2004-10-21
申请人： Eckhard Just , Sabine Giessler , Peter Jenkner
发明人： Eckhard Just , Sabine Giessler , Peter Jenkner
IPC分类号： C07F7/00
CPC分类号： C07F7/14
摘要： The present invention relates to a process for preparing silicon compounds bearing fluoroalkyl groups by hydrosilylation of a fluoroolefin in the presence of a hydrosilylation catalyst, which comprises initially charging and heating a hydrogenchlorosilane, then metering in the fluoroolefin and reacting the reaction mixture and subsequently isolating the hydrosilylation product.
摘要翻译：本发明涉及一种在氢化硅烷化催化剂存在下通过氟代烯烃的氢化硅烷化制备含氟烷基的硅化合物的方法，该方法包括首先加入和加热氢氯硅烷，然后计量氟代烯烃并使反应混合物反应，氢化硅烷化产物。

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