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    • 3. 发明授权
    • Continuous production of low molecular weight polyamides
    • 连续生产低分子量聚酰胺
    • US5674973A
    • 1997-10-07
    • US578703
    • 1995-12-28
    • Gunter PipperAndreas KleinkePeter Hildenbrand
    • Gunter PipperAndreas KleinkePeter Hildenbrand
    • C08G69/14B01J19/28C08G69/04C08G69/16C08G69/46C08G69/26C08G69/28
    • C08G69/16C08G69/04
    • A process for the continuous production of polyamides from a mixture of at least one lactam and water and, if required, other monomer units and/or conventional additives and fillers under polyamide-forming conditions, where the mixture of the starting materials is heated in liquid phase in a first reaction zone until a conversion of at least 70% is reached, and undergoes adiabatic decompression and further polymerization in another reaction zone, wherein, in the first reaction zone, 0.5-7% by weight of water are employed, the temperature is increased to the range from 220.degree. to 310.degree. C., and polymerization is carried out until a conversion of at least 85% is reached and, in the second reaction zone, after the decompression further polymerization is carried out in the range from 215.degree. to 300.degree. C. without heat input.
    • PCT No.PCT / EP94 / 01998 Sec。 371日期1995年12月28日第 102(e)1995年12月28日PCT PCT 1994年6月20日PCT公布。 第WO95 / 01389号公报 日期1995年1月12日一种在聚酰胺形成条件下从至少一种内酰胺和水的混合物以及如果需要的话其它单体单元和/或常规添加剂和填料连续生产聚酰胺的方法,其中起始 材料在液相中在第一反应区中加热直到达到至少70%的转化率,并在另一个反应区进行绝热减压和进一步聚合,其中在第一反应区中为0.5-7重量%的水 ,温度升高到220℃至310℃,进行聚合直至达到至少85%的转化率,并且在第二反应区中,在进一步聚合进行进一步的聚合之后 在215〜300℃的范围内,无需热量输入。
    • 9. 发明授权
    • Thermoplastic polyester molding materials having low temperature impact
strength
    • 具有低温冲击强度的热塑性聚酯成型材料
    • US4912163A
    • 1990-03-27
    • US390290
    • 1989-08-07
    • Dietrich LausbergJuergen VietmeierGraham E. McKeeHans-Georg BraunPeter Hildenbrand
    • Dietrich LausbergJuergen VietmeierGraham E. McKeeHans-Georg BraunPeter Hildenbrand
    • C08L23/08C08L51/00C08L51/04C08L51/06C08L67/00C08L67/02C08L69/00
    • C08L67/02C08L69/00
    • Thermoplastic polyester molding materials essentially contain(A) from 20 to 89% by weight of one or more aliphatic polyesters of an aromatic dicarboxylic acid,(B) from 10 to 79% by weight of one or more aromatic polycarbonates and(C) from 1 to 40% by weight of an elastomer or of a mixture of elastomers consisting ofCA from 5 to 100% by weight of an elastomeric graft polymer composed ofCA1 not less than 50% by weight of a grafting base having a glass transition temperature T.sub.g of less than -20.degree. C.,CA2 from 5 to 20% by weight of a first graft shell consisting of a mixture of a C.sub.1 -C.sub.8 -alkyl ester of acrylic acid and a vinylaromatic in a weight ratio of from 5:95 to 70:30 andCA3 from 10 to 30% by weight of a second graft shell consisting of one or more polymers having a glass transition temperature T.sub.g above 20.degree. C. andCB from 0 to 95% by weight of an ethylene copolymer composed of CB1 from 40 to 99% by weight of ethylene and CB2 from 1 to 60% by weight of one or more comonomers containing carboxyl groups and/or carboxyl group derivatives,the sum of A to C, CA and CB, CA1 to CA3 and of CB1 and CB2 being 100% by weight in each case.
    • 热塑性聚酯成型材料基本上含有(A)20至89重量%的一种或多种芳族二羧酸的脂族聚酯,(B)10至79重量%的一种或多种芳族聚碳酸酯和(C)1 至40重量%的弹性体或由CA组成的弹性体的混合物,其由5至100重量%的弹性体接枝聚合物组成,弹性体接枝聚合物由CA1组成,不小于50重量%的玻璃化转变温度Tg为 小于-20℃,CA2为5至20重量%的由丙烯酸的C1-C8烷基酯和乙烯基芳族化合物的混合物组成的第一接枝壳,其重量比为5:95至70 :30和CA3为10至30重量%的由玻璃化转变温度Tg高于20℃的一种或多种聚合物组成的第二接枝壳,CB为0至95重量%的由CB1组成的乙烯共聚物 40至99重量%的乙烯和CB 2为1至60重量%的一种或多种共聚单体 含有羧基和/或羧基衍生物时,A〜C,CA和CB,CA1〜CA3和CB1和CB2的总和在每种情况下为100重量%。